The lanthanides and their interrelations with biosystems:
Gespeichert in:
| Format: | Buch |
|---|---|
| Sprache: | English |
| Veröffentlicht: |
New York [u.a.]
Dekker
2003
|
| Schriftenreihe: | Metal ions in biological systems
40 |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | LVII, 799 S. graph. Darst. |
| ISBN: | 0824742451 |
Internformat
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| 245 | 1 | 0 | |a The lanthanides and their interrelations with biosystems |c ed. by Astrid Sigel ... |
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| 300 | |a LVII, 799 S. |b graph. Darst. | ||
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Datensatz im Suchindex
| _version_ | 1804130048189399040 |
|---|---|
| adam_text | Contents
PREFACE TO THE SERIES iii
PREFACE TO VOLUME 40 v
CONTRIBUTORS xvii
CONTENTS OF PREVIOUS VOLUMES xxi
HANDBOOK ON TOXICITY OF INORGANIC COMPOUNDS lvii
HANDBOOK ON METALS IN CLINICAL
AND ANALYTICAL CHEMISTRY lvii
HANDBOOK ON METALLOPROTEINS lvii
Chapter 1
DISTRIBUTION OF THE LANTHANIDES IN THE
EARTH S CRUST 1
Stuart Ross Taylor and Scott M. McLennan
1. Geochemical Behavior of the Lanthanides 2
2. Lanthanide Mineralogy 10
3. Samarium Neodymium and Hafnium Lutetium Isotope
Geochemistry 11
4. The Oceanic Crust of the Earth 12
5. The Continental Crust 14
6. Lanthanides in the Continental Crust 21
7. Europium as a Geochemical Tracer 32
Abbreviations and Definitions 33
References 35
vii
viii CONTENTS
Chapter 2
MOBILIZATION OF LANTHANIDES THROUGH THE
TERRESTRIAL BIOSPHERE 39
Robert A. Bulman
1. Basic Lanthanide Chemistry 40
2. Sources of Lanthanides for Environmental Processes 42
3. Weathering of Rocks: Formation of Soil and Abundance
of Lanthanides 44
4. Microbial Interactions with Lanthanides 51
5. Uptake of Lanthanides into Plants 55
6. General Conclusions 61
Acknowledgments 61
Abbreviations and Definitions 62
References 62
Chapter 3
COMPLEXES OF LANTHANIDE IONS WITH AMINO ACIDS,
NUCLEOTIDES, AND OTHER LIGANDS OF BIOLOGICAL
INTEREST IN SOLUTION 69
Herbert B. Silber and Sarah J. Paquette
1. Introduction 70
2. Results from Complexes with Model Ligands 75
3. Complexes of Amino Acids with Lanthanide Ions 79
4. Lanthanide Phospholipid Complexes 84
5. Interactions of Nucleotides and Lanthanide Ions 86
6. Complexes of Lanthanides with Sugar Type Ligands 89
7. Conclusions and Perspectives 93
Acknowledgments 94
Abbreviations and Definitions 94
References 95
Chapter 4
BIOLOGICALLY RELEVANT STRUCTURAL
COORDINATION CHEMISTRY OF SIMPLE
LANTHANIDE ION COMPLEXES 105
Jack M. Harrowfield
CONTENTS ix
1. Introduction 106
2. X Ray Structural Studies of Simple Lanthanide Ion Complexes 107
3. Summary and Overview 136
Acknowledgments 145
Abbreviations 145
References 146
Chapter 5
LANTHANIDE IONS AS PROBES IN STUDIES OF METAL
ION DEPENDENT ENZYMES 161
Etsuro Yoshimura and Tokuko Watanabe
1. Introduction 162
2. Modulation of Enzyme Activity by Lanthanide Ions and
Suitability as Probes 163
3. Conclusions 181
4. Appendix: Methodologies 183
Abbreviations 188
References 188
Chapter 6
LANTHANIDE CHELATES AS FLUORESCENCE LABELS
FOR DIAGNOSTICS AND BIOTECHNOLOGY 191
Kazuko Matsumoto andJingli Yuan
1. Introduction 192
2. Lanthanide Fluorescent Complexes and Labels 194
3. Application to Time Resolved Fluoroimmunoassay 210
4. Application to DNA Hybridization Assay and Cell
Activity Assay 216
5. Application to Chromatography 219
6. Application to Time Resolved Fluorescence Imaging 221
7. Conclusions 223
Abbreviations 224
References 226
X CONTENTS
Chapter 7
RESPONSIVE LUMINESCENT LANTHANIDE COMPLEXES 233
David Parker and J. A. Gareth Williams
1. Introduction 234
2. Mechanistic Basis for Mode of Action 243
3. pH Dependent Luminescence 251
4. Anion Dependent Luminescence 262
5. Oxygen Dependent Luminescence 269
6. Modulation by Metal Ions and Selected Molecules 271
7. Concluding Remarks 274
Abbreviations 275
References 276
Chapter 8
LANTHANIDE IONS AS PROBES OF ELECTRON
TRANSFER IN PROTEINS 281
Ronald M. Supkowski and William DeW. Horrocks, Jr.
1. Introduction 282
2. The Parvalbumin/Lanthanide Model System 285
3. Proof of Electron Transfer in the Model System 290
4. Application of Markus Theory of Electron Transfer to
the Model System 295
5. Conclusions 316
Acknowledgments 317
Abbreviations and Definitions 318
References 318
Chapter 9
LANTHANIDE IONS AS LUMINESCENT PROBES
OF PROTEINS AND NUCLEIC ACIDS 323
Claudia Turro, Patty K. L. Fu, and Patricia M. Bradley
1. Introduction 324
2. Photophysical Properties of Lanthanides 325
3. Nucleic Acids 333
CONTENTS xi
4. Proteins and Enzymes 340
5. Conclusions 345
Acknowledgments 345
Abbreviations 345
References 347
Chapter 10
LANTHANIDE PROMOTED PEPTIDE BOND HYDROLYSIS 355
Makoto Komiyama and Tohru Takarada
1. Introduction 356
2. Peptide Hydrolysis by Ce(IV) 357
3. Activities of Other Lanthanide and Non Lanthanide Ions 359
4. Mechanism of Peptide Hydrolysis 360
5. Homogeneous Hydrolysis of Peptides by
Lanthanide Cyclodextrin Complexes 363
6. Origin of the Remarkable Activity of Ce(IV) 364
7. Conclusion 365
Acknowledgments 366
Abbreviations 366
References 366
Chapter 11
LANTHANIDE CATALYZED HYDROLYSIS OF PHOSPHATE
ESTERS AND NUCLEIC ACIDS 369
Hans Jorg Schneider and Anatoly K. Yatsimirsky
1. Introduction and Scope 370
2. Mechanisms of Phosphate Ester Hydrolysis 374
3. Formation of Lanthanide Complexes in Water and
Their Catalytic Use 394
4. Kinetics of Catalytic Phosphate Ester Hydrolysis 400
5. Lanthanide Alkoxide and Hydroperoxide Complexes 421
6. Catalysis with Di and Polynuclear Complexes 425
7. Analogs of Functional Amino Acids in Catalytic Centers 431
8. Other Lanthanide Based Systems 438
9. A Final Performance Comparison of Lanthanides
with Other Metal Ions 440
xii CONTENTS
10. Conclusions and Outlook 443
Acknowledgments 444
Abbreviations 444
References 446
Chapter 12
SEQUENCE SELECTIVE SCISSION OF DNAAND RNA
BY LANTHANIDE IONS AND THEIR COMPLEXES 463
Makoto Komiyama
1. Significance of Site Selective Scission of DNA and RNA 464
2. Molecular Design for a Sequence Selective Scission 465
3. Sequence Selective DNA Cutters (Artificial
Restriction Enzymes) 466
4. Sequence Selective RNA Cutters (Ribozyme Mimics) 468
5. Conclusion 472
Acknowledgments 473
Abbreviations 473
References 473
Chapter 13
LANTHANIDE IONS AS PROBES FOR METAL IONS IN
THE STRUCTURE AND CATALYTIC MECHANISM
OF RIBOZYMES 477
Roland K. O. Sigel and Anna Marie Pyle
1. Introduction 478
2. Using Lanthanides to Study the Catalytic Mechanism
ofRibozymes 481
3. Defining Metal Ion Binding Sites by Lanthanide Induced
Cleavage of the Phosphodiester Backbone 492
4. X Ray Crystal Structures of Ribozymes and Lanthanides 503
5. Conclusions and Possible Future Applications of
Lanthanides in Ribozyme Chemistry 504
Acknowledgments 504
Abbreviations and Definitions 504
References 505
CONTENTS Xiii
Chapter 14
LANTHANIDES AS SHIFT AND RELAXATION AGENTS IN
ELUCIDATING THE STRUCTURE OF PROTEINS
AND NUCLEIC ACIDS 513
Carlos F. G. C. Geraldes and Claudio Luchinat
1. Introduction 514
2. Lanthanides as Structural Probes 516
3. Theory of Paramagnetic NMR Effects of Lanthanide Ions 518
4. Stable Lanthanide Macromolecule Complexes 531
5. Structural Studies of Proteins in Solution 542
6. Probing Protein Surfaces and Protein Interactions with
Lanthanide Chelates 562
7. Ln3+ as Probes of Nucleic Acids 568
8. Conclusions and Perspectives 572
Acknowledgments 575
Abbreviations 575
References 577
Chapter 15
LANTHANIDE IONS AS MAGNETIC RESONANCE IMAGING
AGENTS. NUCLEAR AND ELECTRONIC RELAXATION
PROPERTIES. APPLICATIONS 589
Lothar Helm, Eva Toth, and Andre E. Merbach
1. Introduction 590
2. Physical Principles of Medical Imaging by Nuclear
Magnetic Resonance 593
3. Relaxation Enhancement Induced by Gd(III) Complexes 594
4. Application: Design of High Relaxivity Agents 617
5. Conclusions 626
Acknowledgments 627
Abbreviations 627
Structural Formulas of Ligands 628
References 635
Xjv CONTENTS
Chapter 16
INTERACTIONS OF LANTHANIDES AND THEIR
COMPLEXES WITH PROTEINS. CONCLUSIONS
REGARDING MAGNETIC RESONANCE IMAGING 643
Silvio Aime, Alessandro Barge, Mauro Botta, andEnzo Terreno
1. Generalities on Magnetic Resonance Imaging and Gd(III) Based
Contrast Agents 644
2. Interactions of Lanthanide(III) Ions with Proteins 651
3. Interactions of Gadolinium(III) Complexes with Proteins 653
4. Responsive Systems Based on Protein Binding 667
5. Concluding Remarks 677
Acknowledgments 677
Abbreviations 678
References 679
Chapter 17
METABOLISM AND TOXICITY OF THE LANTHANIDES 683
Robert A. Bulman
1. Introduction 684
2. Chemistry 684
3. Sites of Deposition in Animals 687
4. Routes of Uptake by Man 689
5. Aspects of Biochemical Behavior and Toxicity 697
6. General Conclusions 700
Acknowledgments 701
Abbreviations 701
References 701
Chapter 18
CELL RESPONSES TO LANTHANIDES AND POTENTIAL
PHARMACOLOGICAL ACTIONS OF LANTHANIDES 707
Kui Wang, Yi Cheng, Xiaoda Yang, and Rongchang Li
1. Introduction 709
2. Biological Effects of Potential Medical Significance 712
CONTENTS XV
3. Therapeutic Significances of the Biological
Effects of Lanthanides 724
4. Problems to Be Solved 738
Acknowledgment 739
Abbreviations 739
References 741
SUBJECT INDEX 753
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| spelling | The lanthanides and their interrelations with biosystems ed. by Astrid Sigel ... New York [u.a.] Dekker 2003 LVII, 799 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Metal ions in biological systems 40 Iones - Metabolismo - Publicaciones periódicas Metales - Efectos fisiológicos - Publicaciones periódicas Biological systems Rare earth metals Biologie (DE-588)4006851-1 gnd rswk-swf Lanthanoide (DE-588)4074013-4 gnd rswk-swf (DE-588)4143413-4 Aufsatzsammlung gnd-content Lanthanoide (DE-588)4074013-4 s Biologie (DE-588)4006851-1 s DE-604 Sigel, Astrid Sonstige (DE-588)103367866X oth Metal ions in biological systems 40 (DE-604)BV000028701 40 HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=010362095&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | The lanthanides and their interrelations with biosystems Metal ions in biological systems Iones - Metabolismo - Publicaciones periódicas Metales - Efectos fisiológicos - Publicaciones periódicas Biological systems Rare earth metals Biologie (DE-588)4006851-1 gnd Lanthanoide (DE-588)4074013-4 gnd |
| subject_GND | (DE-588)4006851-1 (DE-588)4074013-4 (DE-588)4143413-4 |
| title | The lanthanides and their interrelations with biosystems |
| title_auth | The lanthanides and their interrelations with biosystems |
| title_exact_search | The lanthanides and their interrelations with biosystems |
| title_full | The lanthanides and their interrelations with biosystems ed. by Astrid Sigel ... |
| title_fullStr | The lanthanides and their interrelations with biosystems ed. by Astrid Sigel ... |
| title_full_unstemmed | The lanthanides and their interrelations with biosystems ed. by Astrid Sigel ... |
| title_short | The lanthanides and their interrelations with biosystems |
| title_sort | the lanthanides and their interrelations with biosystems |
| topic | Iones - Metabolismo - Publicaciones periódicas Metales - Efectos fisiológicos - Publicaciones periódicas Biological systems Rare earth metals Biologie (DE-588)4006851-1 gnd Lanthanoide (DE-588)4074013-4 gnd |
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