MALDI-TOF mass spectrometry of synthetic polymers: with 45 tables
Gespeichert in:
| Hauptverfasser: | , |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Berlin [u.a.]
Springer
2003
|
| Schriftenreihe: | Springer laboratory
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | Literaturangaben |
| Beschreibung: | XVIII, 298 S. graph. Darst. |
| ISBN: | 3540442596 |
Internformat
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Datensatz im Suchindex
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|---|---|
| adam_text | HARALD PASCH * WOLFGANG SCHREPP
MALDI-TOF MASS
SPECTROMETRY OF SYNTHETIC
POLYMERS
WITH 158 FIGURES AND 45 TABLES
SPRINGER
TABLE OF CONTENTS
1 INTRODUCTION 1
WOLFGANG SCHREPP
1.1 MOLECULAR HETEROGENEITY OF POLYMERS 2
1.2 DETERMINATION OF MOLAR MASSES 6
1.2.1 LIGHT SCATTERING 7
1.2.2 ANALYTICAL ULTRACENTRIFUGATION 9
1.2.3 VISCOMETRY 12
1.2.4 SIZE EXCLUSION CHROMATOGRAPHY 13
REFERENCES 17
2 MASS SPECTROMETRIC INSTRUMENTATION .... 19
WOLFGANG SCHREPP
2.1 IONSOURCES 21
2.1.1 GAS PHASE LONIZATION 22
2.1.2 SPRAY TECHNIQUES 22
2.1.3 LONIZATION FROM THE CONDENSED PHASE 24
2.1.3.1 FIELD DESORPTION (FD) 25
2.1.3.2 FAST PARTICLES (FAST ATOM
BOMBARDMENT, FAB; SECONDARY
ION MASS SPECTROMETRY, SIMS) 25
2.1.3.3 PHOTONS 28
2.2 MASS ANALYZERS 29
2.2.1 QUADRUPOLE ANALYZER 29
2.2.2 FOURIER TRANSFORM ANALYZER 32
2.2.3 TIME-OF-FLIGHT ANALYZER 34
2.2.3.1 THE REFLECTRON 36
2.2.3.2 TIME-LAG FOCUSING 37
2.2.3.3 PRACTICAL CONSEQUENCES 38
2.3 DETECTORS 38
2.4 DATA PROCESSING 40
2.5 COUPLING OF MS TECHNIQUES 42
2.6 CLASSICAL MASS SPECTROMETRY OF POLYMERS 44
2.6.1 FIELD- AND LASER-DESORPTION MASS
SPECTROMETRY 44
2.6.2 PYROLYSIS MS OF POLYMERS 46
XVI
TABLE OF CONTENTS
2.6.3 SECONDARY ION MASS SPECTROMETRY 48
2.6.4 ELECTROSPRAY IONIZATION (ESI)
MASS SPECTROMETRY 50
REFERENCES 53
3 FUNDAMENTALS OF MALDI-TOF MASS
SPECTROMETRY 57
WOLFGANG SCHREPP
3.1 THE MALDI PROCESS 57
3.1.1 PRIMARY ION FORMATION 59
3.1.2 SECONDARY IONIZATION 61
3.1.2.1 GAS PHASE PROTON TRANSFER 61
3.1.2.2 GAS PHASE CATIONIZATION 62
3.2 MATRICES AND SAMPLE PREPARATION 62
3.3 INTERPRETATION OF SPECTRA 67
3.4 EXPERIMENTAL PARAMETERS 70
3.4.1 INFLUENCE OF THE MATRIX 70
3.4.2 INFLUENCE OF THE CATIONIZING AGENT 71
3.4.3 INFLUENCE OF THE LASER POWER 73
3.4.4 TYPE OF TOF ANALYZER 73
3.4.5 MOLAR MASS DISTRIBUTION 78
REFERENCES 82
4 IDENTIFICATION OF POLMERS 85
WOLFGANG SCHREPP
4.1 INTRODUCTION 85
4.2 ANALYSIS OF HOMOPOLYMERS 89
4.2.1 IDENTIFICATION OF LOW MOLAR MASS
HOMOPOLYMERS 89
4.2.2 POLSULFONES 91
4.2.3 POLYESTER DIOLS 93
4.2.4 POLY(OXYMETHYLENE) 95
4.2.5 EMULSIFIERS 96
4.2.6 POLYSILOXANE 99
4.3 COPOLYMERS 100
4.3.1 CAPROLACTAM-PYRROLIDONE COPOLYMER .... 100
4.3.2 POST SOURCE DECAY 102
REFERENCES 104
5 MOLAR MASS DETERMINATION 107
HARALD PASCH
5.1 INTRODUCTION 107
5.2 ANALYSIS OF POLYMERS WITH NARROW MOLAR
MASS DISTRIBUTION 112
TABLE OF CONTENTS XVII
5.2.1 OLIGOMER SAMPLES 112
5.2.2 HYDROCARBON POLYMERS [12] 115
5.2.3 POLYMERS WITH VARYING POLYDISPERSITY [5] ... 121
5.3 ANALYSIS OF POLYMERS WITH BROAD MOLAR
MASS DISTRIBUTION 123
5.3.1 MIXTURES OF POLYETHYLENE GLYCOLS 123
5.3.2 MIXTURES OF POLYSTYRENES AND POLYMETHYL
METHACRYLATES [17] 127
5.4 FURTHER APPLICATIONS 133
REFERENCES 133
6 ANALYSIS OF COMPLEX POLYMERS 135
HARALD PASCH
6.1 INTRODUCTION 135
6.2 DETERMINATION OF ENDGROUPS 136
6.2.1 POLYAMIDES [5] 138
6.2.2 TRIAZINE-BASED POLYAMINES [6] 143
6.2.3 POLY(METHYLPHENYL SILANE) [8] 150
6.2.4 GTPPOLYMERIZEDPMMA[10] 155
6.2.5 POLY--CAPROLACTONE [13] 162
6.2.6 FURTHER APPLICATIONS 168
6.3 ANALYSIS OF COPOLYMERS 168
6.3.1 DIBLOCK COPOLYMERS OF OC-METHYLSTYRENE
AND 4-VINYLPYRIDINE [45] 169
6.3.2 COPOLYMERS OF ETHYLENE OXIDE AND
PROPYLENE OXIDE [47] 176
6.3.3 MODIFIED SILICONE COPOLYMERS [50] 181
6.3.4 MONITORING THE SULFONATION OF
POLYSTYRENE [52] 185
6.3.5 MODIFIED PHENOL-FORMALDEHYDE RESINS [53] . 190
6.3.6 POLYURETHANES 199
6.3.7 FURTHER APPLICATIONS 203
REFERENCES 204
7 COUPLING OF LIQUID CHROMATOGRAPHY
AND MALDI-TOF MASS SPECTROMETY 209
HARALD PASCH
7.1 INTRODUCTION 209
7.2 NEED FOR LC-MALDI-TOF COUPLING 210
7.3 OFF-LINE MEASUREMENT OF LC FRACTIONS 213
7.3.1 CALIBRATION OF SIZE EXCLUSION
CHROMATOGRAPHY [29] 214
7.3.2 MOLAR MASS DISTRIBUTION OF POLYESTER
COPOLYMERS [31,32] 219
XVIII TABLE OF CONTENTS
7.3.3 POLYETHYLENE OXIDES) [28] 222
7.3.4 BLOCK COPOLYMERS OF ETHYLENE OXIDE
AND PROPYLENE OXIDE 230
7.3.5 EPOXY RESINS [37] 233
7.3.6 BLOCK COPOLYMERS OF L-LACTIDE AND
ETHYLENE OXIDE [38] 245
7.3.7 FURTHER APPLICATIONS 250
7.4 INTERFACES FOR COUPLING LC AND MALDI-TOF MS . . 251
7.4.1 LC TRANSFORM INTERFACE 252
7.4.2 PROBOT INTERFACE 254
7.5 MEASUREMENT OF LC FRACTIONS USING A
MALDI-TOF INTERFACE 256
7.5.1 SEC-MALDI-TOF ANALYSIS OF POLY
(N-BUTYLMETHACRYLATE-WOC/C-METHYL
METHACRYLATE) [72] 257
7.5.2 ANALYSIS OF CALIXARENES BY
LC-CC-MALDI-TOF [73] 262
7.5.3 ANALYSIS OF POLYCARBONATE BY
USEC-MALDI-TOF [76,77] 266
7.5.4 SEC-MALDI-TOF AND LC-CC-MALDI-TOF
OF POLYPROPYLENE OXIDES [79] 269
7.6 DIRECT COUPLING OF LIQUID CHROMATOGRAPHY
AND MALDI-TOF MS 279
REFERENCES 284
8 RECENT DEVELOPMENTS AND OUTLOOK 289
WOLFGANG SCHREPP
REFERENCES 293
9 SUBJECT INDEX 295
|
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| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie Chemie |
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| spelling | Pasch, Harald 1952- Verfasser (DE-588)1048212629 aut MALDI-TOF mass spectrometry of synthetic polymers with 45 tables Harald Pasch ; Wolfgang Schrepp Berlin [u.a.] Springer 2003 XVIII, 298 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Springer laboratory Literaturangaben MALDI-MS (DE-588)4586449-4 gnd rswk-swf Polymere (DE-588)4046699-1 gnd rswk-swf (DE-588)4143413-4 Aufsatzsammlung gnd-content Polymere (DE-588)4046699-1 s MALDI-MS (DE-588)4586449-4 s DE-604 Schrepp, Wolfgang Verfasser aut DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=010324428&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Pasch, Harald 1952- Schrepp, Wolfgang MALDI-TOF mass spectrometry of synthetic polymers with 45 tables MALDI-MS (DE-588)4586449-4 gnd Polymere (DE-588)4046699-1 gnd |
| subject_GND | (DE-588)4586449-4 (DE-588)4046699-1 (DE-588)4143413-4 |
| title | MALDI-TOF mass spectrometry of synthetic polymers with 45 tables |
| title_auth | MALDI-TOF mass spectrometry of synthetic polymers with 45 tables |
| title_exact_search | MALDI-TOF mass spectrometry of synthetic polymers with 45 tables |
| title_full | MALDI-TOF mass spectrometry of synthetic polymers with 45 tables Harald Pasch ; Wolfgang Schrepp |
| title_fullStr | MALDI-TOF mass spectrometry of synthetic polymers with 45 tables Harald Pasch ; Wolfgang Schrepp |
| title_full_unstemmed | MALDI-TOF mass spectrometry of synthetic polymers with 45 tables Harald Pasch ; Wolfgang Schrepp |
| title_short | MALDI-TOF mass spectrometry of synthetic polymers |
| title_sort | maldi tof mass spectrometry of synthetic polymers with 45 tables |
| title_sub | with 45 tables |
| topic | MALDI-MS (DE-588)4586449-4 gnd Polymere (DE-588)4046699-1 gnd |
| topic_facet | MALDI-MS Polymere Aufsatzsammlung |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=010324428&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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