Materials science of polymers for engineers:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Munich
Hanser [u.a.]
2003
|
| Ausgabe: | 2. ed. |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XVIII, 622 S. graph. Darst. |
| ISBN: | 1569903484 3446224645 |
Internformat
MARC
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| 100 | 1 | |a Osswald, Tim A. |d 1958- |e Verfasser |0 (DE-588)1062689453 |4 aut | |
| 245 | 1 | 0 | |a Materials science of polymers for engineers |c Tim A. Osswald ; Georg Menges |
| 250 | |a 2. ed. | ||
| 264 | 1 | |a Munich |b Hanser [u.a.] |c 2003 | |
| 300 | |a XVIII, 622 S. |b graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 650 | 7 | |a Matières plastiques |2 ram | |
| 650 | 7 | |a Polymères |2 ram | |
| 650 | 4 | |a Plastics | |
| 650 | 4 | |a Polymers | |
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| 650 | 0 | 7 | |a Kunststoff |0 (DE-588)4033676-1 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Werkstoffkunde |0 (DE-588)4079184-1 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Polymere |0 (DE-588)4046699-1 |2 gnd |9 rswk-swf |
| 655 | 7 | |0 (DE-588)4123623-3 |a Lehrbuch |2 gnd-content | |
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Datensatz im Suchindex
| _version_ | 1804129961459580928 |
|---|---|
| adam_text | Table
of
Contents
Part
I
Basic
Principles
....................................................................................... 1
1
Introduction
to Polymers
..................................................................................
З
1.1
General
Properties
.............................................................................
З
1.2
Identification of Polymers
................................................................10
Problems
.......................................................................................13
References
.......................................................................................13
2.
Historical Background
.......................................................................................15
2.1
From Natural to Synthetic Rubber
.................................................15
2.2
Cellulose and the
$10,000
Idea
.........................................................21
2.3 Galalith -
The Milk Stone
..................................................................24
2.4
Leo Baekeland and the Plastic Industry
.........................................25
2.5
Herman Mark and the American Polymer Education
.................27
2.6
Wallace Hume Carothers and Synthetic Polymers
......................31
2.7
Polyethylene
-
A Product of Brain and Brawn
..............................34
2.8
The Super Fiber and the Woman who Invented it
.......................37
2.9
One last Word
-
Plastics
....................................................................38
References
.......................................................................................41
3
Structure of Polymers
.......................................................................................43
3.1
Macromolecular Structure of Polymers
.........................................43
3.2
Molecular Bonds and Inter-Molecular Attraction
........................45
3.3
Molecular Weight
..............................................................................45
3.4
Conformation and Configuration of Polymer Molecules
..........51
3.5
Arrangement of Polymer Molecules
..............................................55
3.5.1
Thermoplastic Polymers
.......................................................55
3.5.2
Amorphous Thermoplastics
.................................................56
3.5.3
Semi-Crystalline Thermoplastics
........................................58
3.5.4
Thermosets
and Cross-Linked Elastomers
........................67
3.6
Copolymers and Polymer Blends
...................................................68
3.7
Polymer Additves
..............................................................................71
3.7.1
Flame
Retardants
...................................................................71
3.7.2
Stabilizers
................................................................................73
3.7.3
Antistatic Agents
....................................................................74
3.7.4
Fillers
.......................................................................................74
3.7.5
Blowing Agents
......................................................................75
3.8
Viscoelastic Behavior of Polymers
.................................................76
3.8.1
Stress Relaxation Test
............................................................76
3.8.2
Time-Temperature Superposition (WLF-Equationa)
.......78
3.8.3
The Boltzmann Superposition Principle
............................80
xii
Table
of
Contents
3.8.4
Applying Linear Viscoelasticity to Describe the
behavior of Polymers
............................................................81
Examples
.......................................................................................88
Problems
.......................................................................................91
References
.......................................................................................94
Thermal Properties of Polymers
.....................................................................97
4.1
Material Properties
..........................................................................100
4.1.1
Thermal Conductivity
.........................................................100
4.1.2
Specific Heat
..........................................................................107
4.1.3
Density
...................................................................................109
4.1.4
Thermal Diffusivity
.............................................................112
4.1.5
Linear Coefficient of Thermal Expansion
........................113
4.1.6
Thermal Penetration
............................................................115
4.1.7
Glass Transition Temperature
...........................................115
4.1.8
Melting Temperature
..........................................................116
4.2
Measuring Thermal Data
................................................................116
4.2.1
Differential Thermal Analysis (DTA)
...............................117
4.2.2
Differential Scanning Calorimeter (DSC)
........................118
4.2.3
Thermomechanical Analysis
(TMA)
.................................120
4.2.4
Thermogravimetry (TGA)
..................................................121
4.2.5
Density Measurements
........................................................122
Examples
.....................................................................................123
Problems
.....................................................................................124
References
.....................................................................................128
Rheology of Polymer Melts
...........................................................................129
5.1
Introduction
.....................................................................................129
5.1.1
Continuum Mechanics
........................................................129
5.1.2
The Generalized Newtonian Fluid
...................................131
5.1.3
Normal Stresses in Shear Flow
..........................................133
5.1.4
Deborah Number
.................................................................134
5.2
Viscous Flow Models
......................................................................137
5.2.1
The Power Law Model
........................................................137
5.2.2
The Bird-Carreau-Yasuda Model
.....................................139
5.2.3
The Bingham Fluid
..............................................................140
5.2.4
Elongational Viscosity
........................................................140
5.2.5
Rheology of Curing
Thermosets
.......................................142
5.2.6
Suspension Rheology
..........................................................146
5.3
Simplified Flow Models Common in Polymer Processing
.....147
5.3.1
Simple Shear Flow
...............................................................148
5.3.2
Pressure Flow Through a Slit
.............................................148
5.3.3
Pressure Flow Through a Tube
-
Hagen-Poiseuille
Flow
.....................................................................................149
Table
of Contents
xiii
5.3.4
Couette
Flow
........................................................................150
5.4
Viscoelastic Flow Models
...............................................................151
5.4.1
Differential Viscoelastic Models
.......................................151
5.4.2
Integral Viscoelastic Models
..............................................154
5.5
Rheometry
.....................................................................................159
5.5.1
The Melt Flow
Indexer
........................................................159
5.5.2
The Capillary Viscometer
..................................................159
5.5.3
Computing Viscosity Using the Bagley and
.............
Weissenberg-Rabinowitsch Equations
.............................162
5.5.4
Viscosity Approximation Using the Representative
....
Viscosity Method
.................................................................163
5.5.5
The Cone-Plate Rheometer
................................................164
5.5.6
The
Couette
Rheometer
......................................................166
5.5.7
Extensional Rheometry
.......................................................167
5.6
Surface Tension
.................................................................................170
Examples
.....................................................................................174
Problems
.....................................................................................179
References
.....................................................................................180
Part II Influence of Processing on Properties
...............................................183
6
Introduction to Processing
..............................................................................185
6.1
Extrusion
.....................................................................................185
6.1.1
The Plasticating Extruder
....................................................188
6.1.1.1
The Solids Conveying Zone
...................................191
6.1.1.2
The Melting Zone
.....................................................195
6.1.1.3
The Metering Zone
..................................................197
6.1.2
Extrusion Dies
.......................................................................199
6.1.2.1
Sheeting Dies
............................................................199
6.1.2.2
Tubular Dies
..............................................................201
6.2
Mixing Processes
..............................................................................202
6.2.1
Distributive Mixing
.............................................................204
6.2.1.1
Effect of Orientation
................................................205
6.2.2
Dispersive Mixing
................................................................208
6.2.2.1
Break-Up of Particulate Agglomerates
................208
6.2.2.2
Break-Up of Fluid Droplets
....................................211
6.2.3
Mixing Devices
.....................................................................214
6.2.3.1
Static Mixers
..............................................................215
6.2.3.2
Banbury Mixer
..........................................................216
6.2.3.3
Mixing in Single Screw Extruders
.........................218
6.2.3.4
Cokneader
.................................................................220
6.2.3.5
Twin Screw Extruders
..............................................221
6.2.4
Energy Consumption During Mixing
..............................224
6.2.5
Mixing Quality and Efficiency
...........................................225
xiv
Table
of
Contents
6.2.6
Plasticization
.........................................................................227
6.3
Injection
Molding
.............................................................................233
6.3.1
The Injection
Molding
Cycle
..............................................234
6.3.2
The Injection
Molding
Machine
.........................................238
6.3.2.1
The Plasticating and Injection Unit
.......................238
6.3.2.2
The Clamping Unit
..................................................239
6.3.2.3
The Mold Cavity......................................................
241
6.3.3
Related
Injection
Molding Processes
................................243
6.4
Secondary Shaping
...........................................................................245
6.4.1
Fiber Spinning
......................................................................245
6.4.2
Film Production
...................................................................246
6.4.2.1
Cast Film Extrusion
.................................................246
6.5.2.2
Film Blowing
............................................................247
6.4.3
Blow Molding
.......................................................................249
6.4.3.1
Extrusion Blow Molding
.........................................249
6.4.3.2
Injection Blow Molding
..........................................251
6.4.3.3
Thermoforming
........................................................253
6.5
Calendering
.....................................................................................255
6.6
Coating
.....................................................................................257
6.7
Compression Molding
....................................................................260
6.8
Foaming
.....................................................................................262
6.9
Rotational Molding
.........................................................................264
Examples
.....................................................................................266
Problems
.....................................................................................275
References
.....................................................................................279
Anisotropy Development During Processing
............................................283
7.1
Orientation in the Final Part
..........................................................283
7.1.1
Processing Thermoplastic Polymers
................................283
7.1.2
Processing Thermoset Polymers
.......................................292
7.2
Predicting Orientation in the Final Part
......................................297
7.2.1
Planar Orientation Distribution Function
.......................298
7.2.2
Single Particle Motion
.........................................................300
7.2.3
Jeffery s Model
......................................................................302
7.2.4
Folgar-Tucker Model
..........................................................303
7.2.5
Tensor Representation of Fiber Orientation
...................304
7.2.5.1
Predicting Orientation in Complex Parts Using
Computer Simulation
.............................................306
7.3
Fiber Damage
...................................................................................312
Examples
.....................................................................................314
Problems
.....................................................................................316
References
.....................................................................................318
Table
of
Contents
xv
8
Solidification
of Polymers
.............................................................................321
8.1
Solidification
of Thermoplastics
...................................................321
8.1.1
Thermodynamics During Cooling
...................................321
8.1.2
Morphological Structure
.....................................................325
8.1.3
Crystallization
......................................................................326
8.1.4
Heat Transfer During Solidification
.................................329
8.2
Solidification of
Thermosets
..........................................................334
8.2.1
Curing Reaction
...................................................................334
8.2.2
Cure Kinetics
........................................................................336
8.2.3
Heat Transfer During Cure
................................................340
8.3
Residual Stresses and Warpage of Polymeric Parts
...................343
8.3.1
Residual Stress Models
........................................................346
8.3.1.1
Residual Stress Model Without Phase Change
Effects
.........................................................................349
8.3.1.2
Model to Predict Residual Stresses with Phase
..
Change Effects
..........................................................350
8.3.2
Other Simple Models to Predict Residual Stresses and
Warpage
.................................................................................353
8.3.2.1
Uneven Mold Temperature
....................................354
8.3.2.2
Residual Stress in a Thin Thermoset Part
............355
8.3.2.3
Anisotropy Induced Curvature Change
..............357
8.3.3
Predicting Warpage in Actual Parts
..................................358
Examples
.....................................................................................362
Problems
.....................................................................................364
References
.....................................................................................366
Part III Engineering Design Properties
...........................................................369
9
Mechanical Behavior of Polymers
................................................................371
9.1
Basic Concepts of Stress and Strain
...............................................371
9.1.1
Plane Stress
............................................................................372
9.1.2
Plane Strain
...........................................................................373
9.2
The Short-Term Tensile Test
..........................................................373
9.2.1
Rubber Elasticity
..................................................................373
9.2.2
The Tensile Test and Thermoplastic Polymers
...............379
9.3
Long-Term Tests
...............................................................................388
9.3.1
Isochronous and Isometric Creep Plots
...........................391
9.4
Dynamic Mechanical Tests
.............................................................393
9.4.1
Torsion Pendulum
...............................................................393
9.4.2
Sinusoidal Oscillatory Test
.................................................397
9.5
Viscoelastic Behavior of Polymers
...............................................398
9.5.1
Kelvin Model
........................................................................399
9.5.1.1
Kelvin Model Creep Response
..............................400
9.5.1.2
Kelvin Model Stress Relaxation
............................400
xvi
Table
of Contents
9.5.1.3
Kelvin Model Strain Recovery
..............................401
9.5.1.4
Kelvin Model Dynamic Response
.........................401
9.5.2
Jeffrey Model
........................................................................401
9.5.2.1
Jeffrey Model Creep Response
..............................402
9.5.2.2
Jeffrey Model Stress Relaxation
.............................403
9.5.2.3
Jeffrey Model Strain Recovery
...............................403
9.5.3
Standard Linear Solid Model
.............................................403
9.5.3.1
Standard Linear Solid Model Creep Response...
404
9.5.3.2
Standard Linear Solid Model Stress Relaxation.
.405
9.5.4
Maxwell-Wiechert Model
...................................................405
9.5.4.1
Maxwell-Wiechert Model Stress Relaxation
.......406
9.5.4.2
Maxwell-Wiechert Model Dynamic Response....
407
9.6
Effects of Structure and Composition on Mechanical
Properties
.....................................................................................407
9.6.1
Amorphous Thermoplastics
...............................................409
9.6.2
Semi-Crystalline Thermoplastics
......................................410
9.6.3
Oriented Thermoplastics
....................................................412
9.6.4
Cross-Linked Polymers
......................................................418
9.7
Mechanical Behavior of Filled and Reinforced Polymers
..........420
9.7.1 Anisotropie
Strain-Stress Relation
....................................422
9.7.2
Aligned Fiber Reinforced Composite Laminates
..........423
9.7.3
Transformation of Fiber Reinforced Composite
Laminate Properties
............................................................426
9.7.4
Reinforced Composite Laminates with a Fiber
Orientation Distribution Function
....................................429
9.8
Strength Stability Under Heat
.........................................................429
Examples
.....................................................................................431
Problems
.....................................................................................440
References
.....................................................................................444
10
Failure and Damage of Polymers
.................................................................447
10.1
Fracture Mechanics
..........................................................................447
10.1.1
Fracture Predictions Based on the Stress Intensity
Factor
.....................................................................................448
10.1.2
Fracture Predictions Based on an Energy Balance
..........450
10.1.3
Linear Viscoelastic Fracture Predictions Based on
J-Integrals
..............................................................................453
10.2
Short-Term Tensile Strength
..........................................................455
10.2.1
Brittle Failure
........................................................................456
10.2.2
Ductile Failure
......................................................................459
10.2.3
Failure of Highly Filled Systems or Composites
..........464
10.3
Impact Strength
................................................................................467
10.3.1
Impact Test Methods
............................................................473
10.3.2
Fracture Mechanics Analysis of Impact Failure
..............478
Table
of Contents
xvii
10.4
Creep Rupture
..................................................................................483
10.4.1
Creep Rupture Tests
............................................................484
10.4.2
Fracture Mechanics Analysis of Creep Rupture
.............487
10.5
Fatigue
.....................................................................................488
10.5.1
Fatigue Test Methods
..........................................................488
10.5.2
Fracture Mechanics Analysis of Fatigue Failure
............498
10.6
Friction and Wear
............................................................................499
10.7
Stability of Polymer Structures
.....................................................503
10.8
Environmental Effects on Polymer Failure
.................................505
10.8.1
Weathering
............................................................................505
10.8.2
Chemical Degradation
........................................................511
10.8.3
Thermal Degradation of Polymers
...................................513
Examples
.....................................................................................515
Problems
.....................................................................................517
References
.....................................................................................518
11
Electrical Properties of Polymers
..................................................................521
11.1
Dielectric Behavior
..........................................................................521
11.1.1
Dielectric Coefficient
...........................................................521
11.1.2
Mechanisms of Dielectrical Polarization
.........................524
11.1.3
Dielectric Dissipation Factor
..............................................528
11.1.4
Implications of Electrical and Thermal Loss in a
Dielectric
................................................................................532
11.2
Electric Conductivity
.......................................................................532
11.2.1
Electric Resistance
................................................................532
11.2.2
Physical Causes of Volume Conductivity
.......................534
11.3
Application Problems
.....................................................................537
11.3.1
Electric Breakdown
..............................................................537
11.3.2
Electrostatic Charge
.............................................................540
11.3.3
Electrets
..................................................................................542
11.3.4
Electromagnetic Interference Shielding
(EMI Shielding)
....................................................................542
11.4
Magnetic Properties
.........................................................................543
11.4.1
Magnetizability
....................................................................543
11.4.2
Magnetic Resonance
............................................................543
References
.....................................................................................544
12
Optical Properties of Polytmers
....................................................................545
12.1
Index of Refraction
...........................................................................545
12.2
Photoelasticity and Birefringence
.................................................548
12.3
Transparency, Reflection, Absorption, and Transmittance
......553
12.4
Gloss
.....................................................................................559
12.5
Color
.....................................................................................560
12.6
Infrared Spectroscopy
......................................................................563
xviii
Table
of
Contents
12.7
Infrared Pyrometry
..........................................................................565
12.8
Heating with Infrared Radiation
...................................................567
References
.....................................................................................569
13
Permeability Properties of Polymers
...........................................................571
13.1 Sorption .....................................................................................571
13.2
Diffusion and Permeation
..............................................................573
13.3
Measuring
S, D
and
Ρ
.......................................................................579
13.4
Corrosion of Polymers and Cracking
..........................................580
13.5
Diffusion of Polymer Molecules and Self-Diffusion
..................583
References
.....................................................................................584
14
Acoustic Properties of Polymers
...................................................................585
14.1
Speed of Sound
.................................................................................585
14.2
Sound Reflection
..............................................................................587
14.3
Sound Absorption
............................................................................589
References
.....................................................................................590
Appendix
.....................................................................................591
Subject Index
.....................................................................................611
Author Index
.....................................................................................618
|
| any_adam_object | 1 |
| author | Osswald, Tim A. 1958- |
| author_GND | (DE-588)1062689453 |
| author_facet | Osswald, Tim A. 1958- |
| author_role | aut |
| author_sort | Osswald, Tim A. 1958- |
| author_variant | t a o ta tao |
| building | Verbundindex |
| bvnumber | BV017072892 |
| callnumber-first | T - Technology |
| callnumber-label | TA455 |
| callnumber-raw | TA455.P58 |
| callnumber-search | TA455.P58 |
| callnumber-sort | TA 3455 P58 |
| callnumber-subject | TA - General and Civil Engineering |
| classification_rvk | UV 1000 ZM 5000 |
| classification_tum | WER 550f |
| ctrlnum | (OCoLC)51969004 (DE-599)BVBBV017072892 |
| dewey-full | 620.1/92 |
| dewey-hundreds | 600 - Technology (Applied sciences) |
| dewey-ones | 620 - Engineering and allied operations |
| dewey-raw | 620.1/92 |
| dewey-search | 620.1/92 |
| dewey-sort | 3620.1 292 |
| dewey-tens | 620 - Engineering and allied operations |
| discipline | Physik Werkstoffwissenschaften Werkstoffwissenschaften / Fertigungstechnik |
| edition | 2. ed. |
| format | Book |
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| genre | (DE-588)4123623-3 Lehrbuch gnd-content |
| genre_facet | Lehrbuch |
| id | DE-604.BV017072892 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T19:13:27Z |
| institution | BVB |
| isbn | 1569903484 3446224645 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-010300230 |
| oclc_num | 51969004 |
| open_access_boolean | |
| owner | DE-12 DE-210 DE-91G DE-BY-TUM DE-29T DE-703 DE-1050 DE-1102 DE-1043 DE-1051 DE-83 |
| owner_facet | DE-12 DE-210 DE-91G DE-BY-TUM DE-29T DE-703 DE-1050 DE-1102 DE-1043 DE-1051 DE-83 |
| physical | XVIII, 622 S. graph. Darst. |
| publishDate | 2003 |
| publishDateSearch | 2003 |
| publishDateSort | 2003 |
| publisher | Hanser [u.a.] |
| record_format | marc |
| spelling | Osswald, Tim A. 1958- Verfasser (DE-588)1062689453 aut Materials science of polymers for engineers Tim A. Osswald ; Georg Menges 2. ed. Munich Hanser [u.a.] 2003 XVIII, 622 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Matières plastiques ram Polymères ram Plastics Polymers Stoffeigenschaft (DE-588)4192147-1 gnd rswk-swf Kunststoff (DE-588)4033676-1 gnd rswk-swf Werkstoffkunde (DE-588)4079184-1 gnd rswk-swf Polymere (DE-588)4046699-1 gnd rswk-swf (DE-588)4123623-3 Lehrbuch gnd-content Kunststoff (DE-588)4033676-1 s Werkstoffkunde (DE-588)4079184-1 s DE-604 Polymere (DE-588)4046699-1 s Stoffeigenschaft (DE-588)4192147-1 s 1\p DE-604 Menges, Georg Sonstige oth Digitalisierung UB Bayreuth application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=010300230&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | Osswald, Tim A. 1958- Materials science of polymers for engineers Matières plastiques ram Polymères ram Plastics Polymers Stoffeigenschaft (DE-588)4192147-1 gnd Kunststoff (DE-588)4033676-1 gnd Werkstoffkunde (DE-588)4079184-1 gnd Polymere (DE-588)4046699-1 gnd |
| subject_GND | (DE-588)4192147-1 (DE-588)4033676-1 (DE-588)4079184-1 (DE-588)4046699-1 (DE-588)4123623-3 |
| title | Materials science of polymers for engineers |
| title_auth | Materials science of polymers for engineers |
| title_exact_search | Materials science of polymers for engineers |
| title_full | Materials science of polymers for engineers Tim A. Osswald ; Georg Menges |
| title_fullStr | Materials science of polymers for engineers Tim A. Osswald ; Georg Menges |
| title_full_unstemmed | Materials science of polymers for engineers Tim A. Osswald ; Georg Menges |
| title_short | Materials science of polymers for engineers |
| title_sort | materials science of polymers for engineers |
| topic | Matières plastiques ram Polymères ram Plastics Polymers Stoffeigenschaft (DE-588)4192147-1 gnd Kunststoff (DE-588)4033676-1 gnd Werkstoffkunde (DE-588)4079184-1 gnd Polymere (DE-588)4046699-1 gnd |
| topic_facet | Matières plastiques Polymères Plastics Polymers Stoffeigenschaft Kunststoff Werkstoffkunde Polymere Lehrbuch |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=010300230&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT osswaldtima materialsscienceofpolymersforengineers AT mengesgeorg materialsscienceofpolymersforengineers |