Autoxidation of hydrocarbons and polyolefins: kinetics and mechanisms
Gespeichert in:
| Hauptverfasser: | , |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
New York
Dekker
1969
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XI, 527 S. |
Internformat
MARC
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| 650 | 4 | |a Chimie - Réactions | |
| 650 | 4 | |a Hydrocarbures | |
| 650 | 4 | |a Oxydation | |
| 650 | 4 | |a Chemical kinetics | |
| 650 | 4 | |a Hydrocarbons | |
| 650 | 4 | |a Oxidation | |
| 650 | 4 | |a Polyolefins | |
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| 650 | 0 | 7 | |a Reaktionsmechanismus |0 (DE-588)4177123-0 |2 gnd |9 rswk-swf |
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Datensatz im Suchindex
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|---|---|
| adam_text | AUTOXIDATION OF HYDROCARBONS
AND POLYOLEFINS *
Kinetics and Mechanisms
Leo Reich
POLYMER RESEARCH BRANCH
PICATINNY ARSENAL
DOVER, NEW JERSEY
Salvatore S Stivala
DEPARTMENT OF CHEMISTRY AND CHEMICAL ENGINEERING
STEVENS INSTITUTE OF TECHNOLOGY
HOBOKEN, NEW JERSEY
MARCELDEKKER,INC,NewYork
Contents
Preface v
1 Introduction 1
I Some Early Historical Developments 1
II General Kinetic Aspects of Free Radical Reactions 6
References 28
2 Oxidation of Simple Hydrocarbons in the Absence of
Inhibitors and Accelerators 31
I Major Assumptions in the Derivation of Rate Expressions from
Basic Autoxidation Scheme 32
II Various Steps in the Basic Autoxidation Scheme 49
III Kinetic Aspects of Modified Basic Autoxidation Scheme 90
IV Cooxidation 101
V Absolute Rate Constants and Activation Energies of Various
Autoxidation Steps 109
VI Some Recent Aspects of the Autoxidation of Olefins to Polyper-
oxides and Epoxides 115
References 124
Problems 127
«
3 Oxidation of Simple Hydrocarbons in the Presence of
Antioxidants 139
I Modes of Antioxidant Action 140
II Isotopic Evidence for Various Reactions of Antioxidants during
Inhibited Autoxidations 152
i x
X I CONTENTS
III Kinetic Evidence for Various Steps during Inhibited Autoxida-
tions 162
IV Some Inhibited Autoxidations of Other Substrate Types 183
V Classification of Antioxidants According to Their Activity 190
VI Factors Affecting Antioxidant Efficiency 196
VII Fate of Antioxidant Molecules 212
VIII Synergism, Antagonism, and Critical Antioxidant Concentration
in Antioxidant Action 220
IX Generalized Treatment of Inhibited Autoxidation 226
References 229
Problems 232
4 Oxidation of Simple Hydrocarbons in the Presence of
Metal Catalysts 247
I Various Modes of Metal Catalyst Participation during Autoxida
tion 248
II Kinetic Justification for the Participation of Metal Catalysts in
Various Reactions during Autoxidation of Hydrocarbons 273
III Factors Affecting Metal Catalyst Activity 307
IV Cooxidation 330
References 333
Problems 335
5 Weak Chemiluminescence During Hydrocarbon
Autoxidation 343
I Hydrocarbon Autoxidation in the Absence of Inhibitors and
Metal Catalysts 344
II Hydrocarbon Autoxidation in the Presence of Inhibitors 352
III Hydrocarbon Autoxidation in the Presence of Metal Catalysts 364
IV Some Recent Developments on the Origin of Chemiluminescence
during Hydrocarbon Autoxidation 370
References 379
Problems 381
6 Qualitative Aspects of the Autoxidation of Saturated
Polyolefins 385
I Polymer Morphology: Crystallinity and Amorphicity 385
II Polymer Chain Structure 391
III Sample Thickness 395
IV Sample Impurities 399
CONTENTS I xi
V Effect of Temperature and Oxygen Concentration 401
VI Effect of Inhibitors 402
VII Effect of Metal Catalysts 412
VIII Other Factors 416
References 423
7 Quantitative Aspects of the Autoxidation of Saturated
Polyolefins 427
I Autoxidation in the Absence of Inhibitors and Metal Catalysts 427
II Autoxidation in the Presence of Inhibitors 442
References 450
Problems 451
8 Investigation of Polyolefin Oxidation by Various Techniques 455
I Polyethylene 456
II Polypropylene 475
III Poly(butene-l) 494
References 502
Author Index 505
Subject Index 517
|
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| author | Reich, Leo Stivala, Salvatore S. |
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| dewey-ones | 547 - Organic chemistry |
| dewey-raw | 547/.23 |
| dewey-search | 547/.23 |
| dewey-sort | 3547 223 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie |
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| illustrated | Not Illustrated |
| indexdate | 2024-07-09T19:12:03Z |
| institution | BVB |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-010236398 |
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| physical | XI, 527 S. |
| psigel | TUB-nb |
| publishDate | 1969 |
| publishDateSearch | 1969 |
| publishDateSort | 1969 |
| publisher | Dekker |
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| spelling | Reich, Leo Verfasser aut Autoxidation of hydrocarbons and polyolefins kinetics and mechanisms Leo Reich ; Salvatore S. Stivala New York Dekker 1969 XI, 527 S. txt rdacontent n rdamedia nc rdacarrier Chimie - Réactions Hydrocarbures Oxydation Chemical kinetics Hydrocarbons Oxidation Polyolefins Autoxidation (DE-588)4143725-1 gnd rswk-swf Kohlenwasserstoffe (DE-588)4125165-9 gnd rswk-swf Reaktionsmechanismus (DE-588)4177123-0 gnd rswk-swf Polyolefine (DE-588)4175093-7 gnd rswk-swf Reaktionskinetik (DE-588)4048655-2 gnd rswk-swf Kohlenwasserstoffe (DE-588)4125165-9 s DE-604 Autoxidation (DE-588)4143725-1 s Reaktionsmechanismus (DE-588)4177123-0 s Reaktionskinetik (DE-588)4048655-2 s Polyolefine (DE-588)4175093-7 s Stivala, Salvatore S. Verfasser aut HEBIS Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=010236398&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Reich, Leo Stivala, Salvatore S. Autoxidation of hydrocarbons and polyolefins kinetics and mechanisms Chimie - Réactions Hydrocarbures Oxydation Chemical kinetics Hydrocarbons Oxidation Polyolefins Autoxidation (DE-588)4143725-1 gnd Kohlenwasserstoffe (DE-588)4125165-9 gnd Reaktionsmechanismus (DE-588)4177123-0 gnd Polyolefine (DE-588)4175093-7 gnd Reaktionskinetik (DE-588)4048655-2 gnd |
| subject_GND | (DE-588)4143725-1 (DE-588)4125165-9 (DE-588)4177123-0 (DE-588)4175093-7 (DE-588)4048655-2 |
| title | Autoxidation of hydrocarbons and polyolefins kinetics and mechanisms |
| title_auth | Autoxidation of hydrocarbons and polyolefins kinetics and mechanisms |
| title_exact_search | Autoxidation of hydrocarbons and polyolefins kinetics and mechanisms |
| title_full | Autoxidation of hydrocarbons and polyolefins kinetics and mechanisms Leo Reich ; Salvatore S. Stivala |
| title_fullStr | Autoxidation of hydrocarbons and polyolefins kinetics and mechanisms Leo Reich ; Salvatore S. Stivala |
| title_full_unstemmed | Autoxidation of hydrocarbons and polyolefins kinetics and mechanisms Leo Reich ; Salvatore S. Stivala |
| title_short | Autoxidation of hydrocarbons and polyolefins |
| title_sort | autoxidation of hydrocarbons and polyolefins kinetics and mechanisms |
| title_sub | kinetics and mechanisms |
| topic | Chimie - Réactions Hydrocarbures Oxydation Chemical kinetics Hydrocarbons Oxidation Polyolefins Autoxidation (DE-588)4143725-1 gnd Kohlenwasserstoffe (DE-588)4125165-9 gnd Reaktionsmechanismus (DE-588)4177123-0 gnd Polyolefine (DE-588)4175093-7 gnd Reaktionskinetik (DE-588)4048655-2 gnd |
| topic_facet | Chimie - Réactions Hydrocarbures Oxydation Chemical kinetics Hydrocarbons Oxidation Polyolefins Autoxidation Kohlenwasserstoffe Reaktionsmechanismus Polyolefine Reaktionskinetik |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=010236398&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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