Development of thermoplastic elastomers with improved elastic properties based on semicrystalline block copolymers:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | German |
| Veröffentlicht: |
2003
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | Bayreuth, Univ., Diss., 2002. - Auch als Online-Diss. mit der URL: http://nbn-resolving.de/urn:nbn:de:bvb:703-opus-275 |
| Beschreibung: | IV, 277 S. Ill., graph. Darst. |
Internformat
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| 245 | 1 | 0 | |a Development of thermoplastic elastomers with improved elastic properties based on semicrystalline block copolymers |c vorgelegt von Holger Schmalz |
| 264 | 1 | |c 2003 | |
| 300 | |a IV, 277 S. |b Ill., graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 500 | |a Bayreuth, Univ., Diss., 2002. - Auch als Online-Diss. mit der URL: http://nbn-resolving.de/urn:nbn:de:bvb:703-opus-275 | ||
| 650 | 0 | 7 | |a Blockcopolymere |0 (DE-588)4146026-1 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Copolymere |0 (DE-588)4010542-8 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Elastizität |0 (DE-588)4014159-7 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Thermoelast |0 (DE-588)4185142-0 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Teilkristalline Struktur |0 (DE-588)4327756-1 |2 gnd |9 rswk-swf |
| 655 | 7 | |0 (DE-588)4113937-9 |a Hochschulschrift |2 gnd-content | |
| 689 | 0 | 0 | |a Thermoelast |0 (DE-588)4185142-0 |D s |
| 689 | 0 | 1 | |a Elastizität |0 (DE-588)4014159-7 |D s |
| 689 | 0 | 2 | |a Copolymere |0 (DE-588)4010542-8 |D s |
| 689 | 0 | |5 DE-604 | |
| 689 | 1 | 0 | |a Thermoelast |0 (DE-588)4185142-0 |D s |
| 689 | 1 | 1 | |a Blockcopolymere |0 (DE-588)4146026-1 |D s |
| 689 | 1 | 2 | |a Teilkristalline Struktur |0 (DE-588)4327756-1 |D s |
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| 943 | 1 | |a oai:aleph.bib-bvb.de:BVB01-010219870 | |
Datensatz im Suchindex
| _version_ | 1807503988388528128 |
|---|---|
| adam_text |
TABLE
OF
CONTENTS
I
IMNUWCUUN
YYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYA
1
1.1
THERMOPLASTIC
ELASTOMERS
.
1
1.2
MICROPHASE
SEPARATION
IN
BLOCK
COPOLYMERS
.
3
1.3
CRYSTALLIZATION
IN
BLOCK
COPOLYMERS
.
11
1.4
PBT-BASED
COPOLY(ETHER
ESTER)S
.
18
1.5
ABA
AND
ABC
TRIBLOCK
COPOLYMERS
.
27
1.5.1
PB-B-PI-B-PEO
AND
PE-Z -PEP-B-PEO
TRIBLOCK
COPOLYMERS
.
30
1.5.2
PS-Z -P1-Z -P(S/B)
AND
PS-Z -PEP-Z -P(S/E)
TRIBLOCK
COPOLYMERS
.
37
1.6
REFERENCES
.41
2
EXPERIMENTAL
PART
_
49
2.1
MATERIALS
.
49
2.2
SYNTHESIS
OF
COPOLY(ETHER
ESTER)S
.
49
2.2.1
SYNTHESIS
OF
PEO-B-PEB-B-PEO
TRIBLOCK
COPOLYMERS
.
49
2.2.2
MELT
POLYCONDENSATION
.
51
2.3
SYNTHESIS
OF
ABA
AND
ABC
TRIBLOCK
COPOLYMERS
.
52
2.3.1
PB-6-PI-B-PEO
TRIBLOCK
COPOLYMERS
.
52
2.3.2
PS-6-PI-B-P(S/B)
TRIBLOCK
COPOLYMERS
.
54
2.3.3
HYDROGENATION
.
56
2.4
EQUIPMENT
.
59
2.4.1
NMR
SPECTROSCOPY
.
59
2.4.2
DIFFERENTIAL
SCANNING
CALORIMETIY
(DSC)
.
60
2.4.3
SIZE
EXCLUSION
CHROMATOGRAPHY
(SEC)
.
60
2.4.4
DYNAMIC
MECHANICAL
ANALYSIS
(DMA)
.61
2.4.5
MECHANICAL
TESTING
.61
2.4.6
TRANSMISSION
ELECTRON
MICROSCOPY
(TEM)
.
62
2.4.7
SCANNING
ELECTRON
MICROSCOPY
(SEM)
.
63
2.4.8
SCANNING
FORCE
MICROSCOPY
(SFM)
.
63
2.4.9
X-RAY
SCATTERING
.
64
2.4.9.1
SMALL
ANGLE
X-RAY
SCATTERING
(S
AXS)
.
64
2.4.9.2
WIDE
ANGLE
X-RAY
DIFFRACTION
(WAXD)
.
64
2.4.10
MATRIX
ASSISTED
LASER
DESORPTION
IONIZATION
TIME
OF
FLIGHT
MASS
SPECTROMETRY
(MALDI-TOF
MS)
.
64
2.4.11
ONLINE
FOURIER-TRANSFORM
NEAR
INFRARED
(FT-NIR)
FIBER-OPTIC
SPECTROSCOPY
.
65
2.5
REFERENCES
.
67
TABLE
OF
CONTENTS
3
PUB
YYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYY*YYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYY*YYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYY
69
3.1
PBT-BASED
COPOLY(ETHER
ESTER)S
.
69
3.1.1
NEW
THERMOPLASTIC
ELASTOMERS
BY
INCORPORATION
OF
NONPOLAR
SOFT
SEGMENTS
IN
PBT
BASED
COPOLYESTERS
.
69
3.1.2
MORPHOLOGY,
SURFACE
STRUCTURE
AND
ELASTIC
PROPERTIES
OF
PBT-BASED
COPOLYESTERS
WITH
PEO-6-PEB-6-PEO
TRIBLOCK
COPOLYMER
SOFT
SEGMENTS
.
88
3.1.3
MORPHOLOGY
AND
MOLECULAR
MISCIBILITY
OF
SEGMENTED
COPOLY(ETHER
ESTER)S
WITH
IMPROVED
ELASTIC
PROPERTIES
AS
STUDIED
BY
SOLID-STATE
NMR
.
ILL
3.2
PB-FC-PI-B-PEO
AND
PE-6-PEP-6-PEO
TRIBLOCK
COPOLYMERS
.
127
3.2.1
SYNTHESIS
AND
CHARACTERIZATION
OF
ABC
TRIBLOCK
COPOLYMERS
WITH
TWO
DIFFERENT
CRYSTALLINE
END
BLOCKS:
INFLUENCE
OF
CONFINEMENT
ON
CRYSTALLIZATION
BEHAVIOR
AND
MORPHOLOGY
.
127
3.2.2
CRYSTALLIZATION
IN
ABC
TRIBLOCK
COPOLYMERS
WITH
TWO
DIFFERENT
CRYSTALLINE
END
BLOCKS:
INFLUENCE
OF
CONFINEMENT
ON
SELF-NUCLEATION
BEHAVIOR
.
155
3.2.3
THERMAL
AND
SELF-NUCLEATION
BEHAVIOR
OF
MOLECULAR
COMPLEXES
FORMED
BY
P
NITROPHENOL
AND
THE
POLY(ETHYLENE
OXIDE)
END
BLOCK
WITHIN
AN
ABC
TRIBLOCK
COPOLYMER
.
184
3.3
PS-I-PI-I-P(B/S)
AND
PS-I-PEP-*-P(S/E)
TRIBLOCK
COPOLYMERS
.
191
3.3.1
SYNTHESIS
AND
PROPERTIES
OF
ABA
AND
ABC
TRIBLOCK
COPOLYMERS
WITH
GLASSY
(A),
ELASTOMERIC
(B),
AND
CRYSTALLINE
(C)
BLOCKS
.
191
3.3.2
THERMOPLASTIC
ELASTOMERS
BASED
ON
SEMICRYSTALLINE
BLOCK
COPOLYMERS
.
216
3.4
ANIONIC
POLYMERIZATION
OF
ETHYLENE
OXIDE
IN
THE
PRESENCE
OF
THE
PHOSPHAZENE
BASE
R-BUP,
-
KINETIC
INVESTIGATIONS
USING
IN-SITU
FT-NIR
SPECTROSCOPY
AND
MALDI-TOFMS
.
231
4
YYYYYYYYYYYYYYYYYYYY
YYYYYYYY
YYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYYY
YYYYYYYYYYYY
YYYYYY
266
5
6 |
| any_adam_object | 1 |
| author | Schmalz, Holger |
| author_GND | (DE-588)1156329280 |
| author_facet | Schmalz, Holger |
| author_role | aut |
| author_sort | Schmalz, Holger |
| author_variant | h s hs |
| building | Verbundindex |
| bvnumber | BV016540015 |
| classification_rvk | VC 7600 |
| ctrlnum | (OCoLC)643299100 (DE-599)BVBBV016540015 |
| discipline | Chemie / Pharmazie |
| format | Book |
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| genre | (DE-588)4113937-9 Hochschulschrift gnd-content |
| genre_facet | Hochschulschrift |
| id | DE-604.BV016540015 |
| illustrated | Illustrated |
| indexdate | 2024-08-16T01:02:08Z |
| institution | BVB |
| language | German |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-010219870 |
| oclc_num | 643299100 |
| open_access_boolean | |
| owner | DE-703 DE-12 |
| owner_facet | DE-703 DE-12 |
| physical | IV, 277 S. Ill., graph. Darst. |
| publishDate | 2003 |
| publishDateSearch | 2003 |
| publishDateSort | 2003 |
| record_format | marc |
| spelling | Schmalz, Holger Verfasser (DE-588)1156329280 aut Development of thermoplastic elastomers with improved elastic properties based on semicrystalline block copolymers vorgelegt von Holger Schmalz 2003 IV, 277 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Bayreuth, Univ., Diss., 2002. - Auch als Online-Diss. mit der URL: http://nbn-resolving.de/urn:nbn:de:bvb:703-opus-275 Blockcopolymere (DE-588)4146026-1 gnd rswk-swf Copolymere (DE-588)4010542-8 gnd rswk-swf Elastizität (DE-588)4014159-7 gnd rswk-swf Thermoelast (DE-588)4185142-0 gnd rswk-swf Teilkristalline Struktur (DE-588)4327756-1 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Thermoelast (DE-588)4185142-0 s Elastizität (DE-588)4014159-7 s Copolymere (DE-588)4010542-8 s DE-604 Blockcopolymere (DE-588)4146026-1 s Teilkristalline Struktur (DE-588)4327756-1 s DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=010219870&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Schmalz, Holger Development of thermoplastic elastomers with improved elastic properties based on semicrystalline block copolymers Blockcopolymere (DE-588)4146026-1 gnd Copolymere (DE-588)4010542-8 gnd Elastizität (DE-588)4014159-7 gnd Thermoelast (DE-588)4185142-0 gnd Teilkristalline Struktur (DE-588)4327756-1 gnd |
| subject_GND | (DE-588)4146026-1 (DE-588)4010542-8 (DE-588)4014159-7 (DE-588)4185142-0 (DE-588)4327756-1 (DE-588)4113937-9 |
| title | Development of thermoplastic elastomers with improved elastic properties based on semicrystalline block copolymers |
| title_auth | Development of thermoplastic elastomers with improved elastic properties based on semicrystalline block copolymers |
| title_exact_search | Development of thermoplastic elastomers with improved elastic properties based on semicrystalline block copolymers |
| title_full | Development of thermoplastic elastomers with improved elastic properties based on semicrystalline block copolymers vorgelegt von Holger Schmalz |
| title_fullStr | Development of thermoplastic elastomers with improved elastic properties based on semicrystalline block copolymers vorgelegt von Holger Schmalz |
| title_full_unstemmed | Development of thermoplastic elastomers with improved elastic properties based on semicrystalline block copolymers vorgelegt von Holger Schmalz |
| title_short | Development of thermoplastic elastomers with improved elastic properties based on semicrystalline block copolymers |
| title_sort | development of thermoplastic elastomers with improved elastic properties based on semicrystalline block copolymers |
| topic | Blockcopolymere (DE-588)4146026-1 gnd Copolymere (DE-588)4010542-8 gnd Elastizität (DE-588)4014159-7 gnd Thermoelast (DE-588)4185142-0 gnd Teilkristalline Struktur (DE-588)4327756-1 gnd |
| topic_facet | Blockcopolymere Copolymere Elastizität Thermoelast Teilkristalline Struktur Hochschulschrift |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=010219870&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT schmalzholger developmentofthermoplasticelastomerswithimprovedelasticpropertiesbasedonsemicrystallineblockcopolymers |