Inorganic experiments:
Gespeichert in:
Format: | Buch |
---|---|
Sprache: | English |
Veröffentlicht: |
Weinheim
Wiley-VCH
2003
|
Ausgabe: | 2., completely rev. and enl. ed. |
Schlagworte: | |
Online-Zugang: | Inhaltsverzeichnis |
Beschreibung: | XXI, 377 S. graph. Darst. |
ISBN: | 3527305106 |
Internformat
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245 | 1 | 0 | |a Inorganic experiments |c ed. by J. Derek Woollins |
250 | |a 2., completely rev. and enl. ed. | ||
264 | 1 | |a Weinheim |b Wiley-VCH |c 2003 | |
300 | |a XXI, 377 S. |b graph. Darst. | ||
336 | |b txt |2 rdacontent | ||
337 | |b n |2 rdamedia | ||
338 | |b nc |2 rdacarrier | ||
650 | 4 | |a Anorganische Chemie - Praktikum | |
650 | 4 | |a Chemistry, Inorganic |x Experiments | |
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Datensatz im Suchindex
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adam_text | Titel: Inorganic experiments
Autor: Woollins, John Derek
Jahr: 2003
Contents
Preface
1 Introduction 1
1.1 Introduction 3
1.2 Introduction to Discovery Oriented/Group Leaning Laboratory
Experiences 4
Allen D. Hunter
2 Introductory Experiments 7
2.1 Preparation and Investigation of Some Coordination Compounds 9
Roderick D. Cannon and Manfred Bochmann
2.2 Gravimetric Analysis of Hexaammine Nickel(II) Tetrafluoroborate,
[Ni(NH3)6](BF4)2 12
Roderick D. Cannon and Manfred Bochmann
2.3 Analysis of an Iron(III) Oxalate Complex 17
Roderick D. Cannon and Manfred Bochmann
2.4 Characterisation of a Copper Oxalate Complex KflCufc (C204)c • dH20 22
Andrew W. G. Piatt
2.5 Vanadium Alum: An Experiment in Electrosynthesis 24
David T. Richens
2.6 Ammonium Dichromate, Chromium(III) Oxide, Potassium Chromate
and Potassium Tetraperoxochromate (V) 27
Antonin RuXicka and Zdirad Zak
2.7 Linkage Isomerism: An Infra-Red Study 31
David T. Richens and Christopher Glidewell
2.8 Preparation and Complexation of
Tris{3,5-dimethylpyrazoyl)hydroborate 33
Manfred Bochmann
Tetraiodotin(IV) and its Triphenylphosphine Complex 36
J. Derek Wooluns
Silicon Oxygen Compounds and Siloxane Polymers 38
Paul D. Lickiss
Preparation and NMR Identification of Two Phosphorus Esters 42
Christopher Glidewell
The Preparation of Potassium Peroxodisulphate, K2S208 44
Zdirad 2ak and Antonin Ruzicka
K2ON (S03)2 (Frem/s Salt) and [Ph3PCH2C6H4CH2PPh3]ON (S03)2 47
David M. L. Goodgame
Polyiodides, Me4NIx 49
Andrew W. G. Platt
Interhalogen Compounds 51
Ivan P. Parkin
Synthesis and Infrared Spectroscopic Characterisation of Boranes
and Germanes 56
Ivan P. Parkin
Deduction of the Coordination Mode of BH4 in Bis(triphenylphosphine)
Copper(I) Borohydride (Ph3P)2CuBH4 61
Andrew W. G. Platt
Synthesis and Characterisation of a Metal Hydride Complex 64
Andrew W. G. Platt
Preparation and Identification of a Copper(I) Complex 66
Andrew W. G. Platt
Synthesis of [NH4][BF4] and Synthesis and Titrimetric Analysis of
[Zn(NH3)4][BF4]2 68
Michael A. Beckett
Iron(II) and Lead(ll) Formates 71
Francisco J. Arnaiz, Maria R. Pedrosa and Rafael Aguado
Preparation of Copper(I) Iodide 75
F. J. Arnaiz, M. R. Pedrosa and S. Arnaiz
Discovery Research with Siloxane Chemistry 77
Allen D. Hunter
Contents | XI
3 Intermediate Experiments 83
3.1 Ferrocene, (^5-C5H5)2Fe, and Its Derivatives 85
J. Derek Woollins
3.2 The Use of Organolithium Reagents in the Preparation of Ferrocene
Derivatives 88
Ian R. Butler
3.3 Complexes of ir-Bonding Arene Ligands 95
Andrew W. G. Platt
3.4 Organotin Chemistry 98
Kieran C. Molloy and Timothy T. Paget
3.5 Nickel Catalysed Cross-Coupling of Alkylmagnesium with Haloarene 105
G. Brent Young
3.6 Transition Metal Catalysis 109
Neil M. Boag
3.7 Transition Metal-Carbon Bonds in Chemistry and Biology 113
C. J. Jones
3.8 Cobalt Complexes of Dioxygen 124
David T. Richens and Christopher Glidewell
3.9 Preparation of Nitrosyl Complexes of Iron and Nickel 127
Andrew W. G. Plait and John F. Gibson
3.10 Preparation of an Iron Dinitrogen Complex 130
Andrew W. G. Plait
3.11 Nickel Dihalide Phosphine Complexes 132
Ivan P. Parkin
3.12 Influence of Ligand Field Tetragonality on the Ground-State Spin of
Nickel(II) Complexes 136
David M. L. Goodgame
3.13 Preparation ofTrans-PtHCl{PPh3)2 and Measurement of its 1H, 31Pand
195PtNMR Spectra 139
William P. Griffith
3.14 Identification of Stereochemical (Geometrical) Isomers of [Mo(CO)4(L)2]
by Infra-Red Spectroscopy 143
Michael A. Beckett
3.15 Five Coordinate Complexes: [VO(acac)2] and [Cr(NH3)6][CuCl5] 146
Christopher P. Morley
3.16 Metal Acetylacetonate Complexes: Preparation and Characterisation 149
Christopher Glidewell
XII J Contents
3.17 Nickel(II) Complexes of Some SchiffBase Ligands 160
C. J. Jones
3.18 The Synthesis and Coordination Chemistry of Macrocyclic
Complexes 167
Martin Schroder
3.19 Synthesis and Reactivity of Tertiary Phosphines 172
Neil M. Boag
3.20 Inorganic Heterocycles: Cyclophosphazenes 176
Josef Novosad and Milan Alberti
3.21 Inorganic (Carbon-Free) Chelate Rings: A Dithioimidodiphosphinato
Ligand and Some of its Metal Complexes 179
lONEL HAIDUC
3.22 Amidosulfuric Acid.Trisilveramidosulfate Monohydrate and S03 • N(CH3)3
Complexes 184
Antonin RuIicka and Zdirad !Zak
3.23 Four Methods for Analysing First Order Kinetics 188
Veronique Pimienta, Dominique Lavabre, Jean-Claude Micheau
and Gaston Levy
3.24 Inorganic (Carbon-Free) Chelate Rings II: Asymmetrical Mixed-Donor
P-N-P Ligand and its Palladium Complex 194
David J. Birdsall and Josef Novosad
3.25 [Mo02Br2(H20)2] ¦ (diglyme) and [Mo02Br2(DMF)2] 199
Francisco J. Arnaiz, Maria R. Pedrosa and Rafael Aguado
3.26 Nitration of Cobalt(III)acetylacetonate 203
David J. Otway
3.27 [Co(dinosar)]Cl3: An Encapsulation Complex Prepared by a Template
Reaction 205
David J. Otway
3.28 Anomalous Paramagnetism in Some Iron(III) Chelates Studied by the
Evans NMR Method 208
David J Otway
3.29 Solid Sodium Amalgam 211
Allen D. Hunter
3.30 Discovery Research with Cyclopentadienyl Iron Carbonyl Chemistry 214
Allen D. Hunter
3.31 Discovery Research with Model One-Dimensional Organometallic
Materials of Ni, Pd, andPt 222
Allen D. Hunter
Contents | XIII
4 Advanced Experiments 227
4.1 Chlorotris(tert-butylimido)manganese(VII) 229
Andreas A. Danopoulos and Geoffrey Wilkinson
4.2 2,2 : 6 ,2 -Terpyridine Complexes and Metal Directed Reactivity 232
Edwin C. Constable
4.3 Electronic Characterisation of a Transition-Metal Complex Using
Electrochemical UV/Vis and EPR Techniques 235
Lesley J. Yellowlees
4.4 The Synthesis of ^-Arenetricarbonyl Chromium(O) Complexes 238
David A. Widdowson
4.5 Migratory Insertion Reactions in Organo Transition-Metal Chemistry 241
Mark J. Winter
4.6 Organometallic Molybdenum Compounds 246
Manfred Bochmann and Paul Hammerton
4.7 The Preparation of rac-Ethylene-l,2-bis(l-indenyl)zirconium Dichloride
and Dibenzyl Complexes 252
Manfred Bochmann and Simon J. Lancaster
4.8 Halfsandwich Carbonyl Vanadium Complexes 257
Max Herberhold and Matthias Schrepfermann
4.9 Covalent and Ionic Metallocene Hexafluoroarsenate Complexes 263
Inis C. Tornieporth-Oetting and Thomas M. Klapotke
4.10 Preparation of the Iron Tricarbonyl Complex of Methyl-2-Acetamidoacrylate
266
Simon R. Drake, M. Elena Lasterra-Sanchez and Susan E. Thomas
4.11 A Transition-Metal Alkylidyne Complex 268
Stephen Anderson, Darren Cook and Anthony F. Hill
4.12 Preparation of IBu4NJ[B3H8] and the Formation of
RuH[B3H8](CO)(PPh3)2 271
Anthony F. Hill and J. Derek Woollins
4.13 Vacuum Line Techniques: Preparation of SiF4 and SiF4{C5H5N)2 275
Dennis F. Evans and J. Derek Woollins
4.14 Preparation and Structure of the Acetyl Chloride-Antimony Pentachloride
Complex 279
Peter N. Gates
4.15 Arsenium Cations: Carbene Analogues 282
Neil Burford and Trenton M. Parks
Preparation and Some Reactions of the Folded P2N4S2 Ring 287
Tristram Chivers, Daniel D. Doxsee and Robert W. Hilts
Sulfur-Rich Homocycles and Heterocycles: Titanocene Pentasulfide,
Cyc/o-Heptasulfur and 1,2,3,4,5,6,7-Heptathionane 291
Jorg Albertsen and Ralf Steudel
Reaction of Alkali Metal Polyselenides and Polytellurides with Group 6
Metal Carbonyls 295
Joseph W. Kolis
Sulphur-Nitrogen Heterocycles and [SNBr0.4]x Polymer 300
}. Derek Woollins
Chlorothionitrene and Cydothiazeno Complexes of Tungsten 304
Kurt Dehnicke
Selenium-Nitrogen and Tellurium-Nitrogen Compounds 307
Herbert W. Roesky and Judith Gindl
Nitride Chlorides of Selenium(III) and Selenium(IV): Se2NCl3 and
Se2NCls 311
Kurt Dehnicke
Structural, Electrical and Magnetic Properties of Perovskite Ceramics 315
Colin Greaves
Metal-containing Liquid Crystals. The Synthesis of trans-bis(4-Alkyl-4 -
cyano-l.r-biphenyl)dichloroplatinum(II) and Related Species-
The Use of Melt Syntheses 321
Duncan W. Bruce
Magnetochemistry Experiments: Exchange Coupling in Copper(II)-
Nickel(II) Bimetallic Complexes and Spin Transition in
Iron Complexes 329
E. Coronado and J. J. Borras-Almenar
N-Ferrocenyl Amine and Some Reactive Derivatives 333
Max Herberhold, Heidi E. Maisel and Bernd Wrackmeyer
Polyoxomolybdate Clusters: Nanoscopic Wheels and Balls 340
Leroy Cronin, Ekkehard Diemann and Achim Muller
One-Pot Preparation of Ru3(CO)12 from RuCl3 * 3 HzO 347
Guy Lavigne, Catherine Saccavini and Remi Chauvin
Low Temperature Synthesis of Barium Amides and Phenoxides 352
Simon R. Drake, Philip Hall and David J. Otway
Alumazene - Inorganic Benzene Analog 357
Jiri Pinkas
Contents | XV
4.31 Coordination Chemistry of Organic Free Radicals: Synthesis and Magnetic
Properties 360
A. Alberola, E. Coronado and F. M. Romero
4.32 Discovery Research with Arene Chromium Tricarbonyl Chemistry 364
Allen D. Hunter
4.33 Discovery Research with Cr, Mo, and W Nitrosyl Complexes: A Multi-Step
Organometallic Synthesis 368
Allen D. Hunter and J. D. Woollins
Subject Index 373
|
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indexdate | 2024-07-09T19:11:39Z |
institution | BVB |
isbn | 3527305106 |
language | English |
oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-010218003 |
oclc_num | 249291355 |
open_access_boolean | |
owner | DE-20 DE-384 DE-19 DE-BY-UBM DE-703 DE-1046 DE-91G DE-BY-TUM DE-634 DE-83 DE-11 DE-188 |
owner_facet | DE-20 DE-384 DE-19 DE-BY-UBM DE-703 DE-1046 DE-91G DE-BY-TUM DE-634 DE-83 DE-11 DE-188 |
physical | XXI, 377 S. graph. Darst. |
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spelling | Inorganic experiments ed. by J. Derek Woollins 2., completely rev. and enl. ed. Weinheim Wiley-VCH 2003 XXI, 377 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Anorganische Chemie - Praktikum Chemistry, Inorganic Experiments Anorganische Chemie (DE-588)4002145-2 gnd rswk-swf Praktikum (DE-588)4127380-1 gnd rswk-swf Anorganische Chemie (DE-588)4002145-2 s Praktikum (DE-588)4127380-1 s DE-604 Woollins, J. Derek Sonstige oth HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=010218003&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
spellingShingle | Inorganic experiments Anorganische Chemie - Praktikum Chemistry, Inorganic Experiments Anorganische Chemie (DE-588)4002145-2 gnd Praktikum (DE-588)4127380-1 gnd |
subject_GND | (DE-588)4002145-2 (DE-588)4127380-1 |
title | Inorganic experiments |
title_auth | Inorganic experiments |
title_exact_search | Inorganic experiments |
title_full | Inorganic experiments ed. by J. Derek Woollins |
title_fullStr | Inorganic experiments ed. by J. Derek Woollins |
title_full_unstemmed | Inorganic experiments ed. by J. Derek Woollins |
title_short | Inorganic experiments |
title_sort | inorganic experiments |
topic | Anorganische Chemie - Praktikum Chemistry, Inorganic Experiments Anorganische Chemie (DE-588)4002145-2 gnd Praktikum (DE-588)4127380-1 gnd |
topic_facet | Anorganische Chemie - Praktikum Chemistry, Inorganic Experiments Anorganische Chemie Praktikum |
url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=010218003&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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