Metal complexes and metals in macromolecules: synthesis, structure and properties
Gespeichert in:
| Format: | Buch |
|---|---|
| Sprache: | English |
| Veröffentlicht: |
Weinheim
Wiley-VCH
2003
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| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | Literaturangaben |
| Beschreibung: | XVIII, 667 S. Ill., graph. Darst. |
| ISBN: | 3527304991 |
Internformat
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| 245 | 1 | 0 | |a Metal complexes and metals in macromolecules |b synthesis, structure and properties |c Dieter Wöhrle ; Anatolii D. Pomogailo |
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Datensatz im Suchindex
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| adam_text | DIETER WOEHRLE, ANATOLII D. POMOGAILO METAL COMPLEXES AND METALS IN
MACROMOLECULES SYNTHESIS, STRUCTURE AND PROPERTIES WITH CONTRIBUTIONS
FROM Y. AMAO, M. KANEKO, E. A. KARAKHANOV, Y. S. KANG, A. L. MAXIMOV, H.
NISHIDE, T. OHSAKA, I. OKURA, R. * RAJ AND J. WON WILEY- VCH WILEY-VCH
GMBH & CO. KGAA CONTENTS A OVERVIEW AND BIOLOGICAL SYSTEMS 1
DEFINITIONS, CLASSIFICATIONS, HISTORY, PROPERTIES (D. WOEHRLE AND A.
POMOGAILO) 3 1.1 DEFINITIONS 3 1.2 CLASSIFICATION OF METAL COMPLEXES AND
METALS IN MACROMOLECULES 7 1.2.1 CLASSIFICATION BY KIND OF METAL
COMPLEX/METAL BINDING 7 1.2.2 CLASSIFICATION BY CONNECTIVITIES 10 1.2.3
CLASSIFICATION BY DIMENSIONALITY 11 1.3 METALS IN NATURE AND THE HISTORY
OF ARTIFICIAL METAL COMPLEXES AND METALS IN MACROMOLECULES 11 1.4
PROPERTIES AND POTENTIAL APPLICATIONS OF METAL COMPLEXES AND METALS IN
MACROMOLECULES 14 1.5 EXAMPLES OF INORGANIC POLYMERS 17 1.6 REFERENCES
21 2 MACROMOLECULAR METAL COMPLEXES IN BIOLOGICAL SYSTEMS (D. WOEHRLE AND
M. KANEKO) 25 2.1 ELEMENTS ESSENTIAL FOR LIFE 25 2.2 SOME FUNCTIONS OF
METALS 30 2.2.1 METALS AS COFACTORS OF PROTEINS, METALLOPROTEINS 30
2.2.2 METALLOENZYMES 31 2.2.3 INTERFERENCE OF DETRIMENTAL METAL IONS
WITH NORMAL CELL METABOLISM 32 2.2.4 COMMUNICATIVE FUNCTIONS OF METALS
IN BIOLOGY 34 2.2.5 INTERACTIONS OF NUCLEIC ACIDS WITH METAL IONS 34
2.2.6 BIOMETAL-ORGANIC CHEMISTRY 34 2.3 HEME PROTEINS 37 2.3.1 OXYGEN
TRANSPORT HEMES 38 2.3.2 OXYGEN TRANSFER HEMES 45 2.3.3 ELECTRON
TRANSFER HEMES 48 2.4 NON-HEME PROTEINS 49 2.4.1 OXYGEN TRANSPORT
NON-HEME PROTEINS 49 2.4.2 OXYGEN TRANSFER NON-HEMES 50 2.4.3 ELECTRON
TRANSFER NON-HEMES 51 2.5 COPPER PROTEINS 53 2.5.1 TYPE I COPPER
PROTEINS 53 2.5.2 TYPE II COPPER PROTEINS 54 2.5.3 TYPE III COPPER
PROTEINS 55 2.5.4 MIXED TYPE 55 2.6 MANGANESE PROTEINS 56 2.6.1 OXYGEN
EVOLVING CENTER (OEC) OF PHOTOSYNTHESIS 57 2.6.2 MN-SUPEROXIDE DISMUTASE
(MN-SOD) 58 2.7 MAGNESIUM PROTEINS - CHLOROPHYLL 58 2.8 ZINC PROTEINS 61
2.9 REFERENCES 62 X CONTENTS * SYNTHESIS AND STRUCTURES 3 KINETICS AND
THERMODYNAMICS OF FORMATION OF MACROMOLECULAR METAL COMPLEXES AND THEIR
STRUCTURAL ORGANIZATION (A. POMOGAILO) 67 3.1 COMPLEXATION IN DILUTE
POLYMER SOLUTIONS 68 3.2 COMPLEXATION WITH INSOLUBLE POLYMERS
(HETEROGENEOUS COMPLEXATION) 79 3.3 THE STRUCTURAL ORGANIZATION OF MMCS
82 3.4 MAIN APPROACHES TO DESCRIBING THE THERMODYNAMICS OF MMC FORMATION
84 3.5 THE PROBLEM OF THE TOPOCHEMISTRY OF MMCS 90 3.6 REFERENCES 94 4
POLYMERIZATION OF METAL-CONTAINING MONOMERS (MCMS) AS A METHOD FOR
INCORPORATING METALS IN MACROMOLECULES (A. POMOGAILO) 97 4.1 MCM
CLASSIFICATION 98 4.2 OVERVIEW OF THE DIFFERENT METHODS OF SYNTHESIS OF
MCMS 99 4.2.1 SYNTHESIS OFA-MCMS OF THE ORGANOMETALLIC TYPE 99 4.2.2
**-**** ORGANOELEMENTAL MONOMERS 102 4.2.3 IONIC-TYPE MCMS 105 4.2.4
V-TYPEMCMS 106 4.2.5 7I-TYPE METAL-CONTAINING MONOMERS 109 4.2.6
POLYMERIZABLE CHELATE-**** MCMS 109 4.2.7 MCMS WITH MACROCYCLIC CHELATE
NODES 111 4.2.8 POLYNUCLEAR AND CLUSTER MCMS 113 4.3 HOMOPOLYMERIZATION
OF METAL-CONTAINING MONOMERS 117 4.3.1 THE SPECIFIC CHARACTER OF THE
HOMOPOLYMERIZATION OF TRUE ORGANOMETALLIC MONOMERS 117 4.3.2
HOMOPOLYMERIZATION OF ORGANOELEMENTAL MONOMERS 120 4.3.3 RADICAL
POLYMERIZATION OF SALTS OF UNSATURATED CARBOXYLIC ACIDS 122 4.3.4
HOMOPOLYMERIZATION OF RCV-TYPE MCMS 125 4.3.5 FRONTAL POLYMERIZATION OF
ACRYLAMIDE COMPLEXES 128 4.3.6 HOMOPOLYMERIZATION OF *-**** MCMS 131
4.3.7 POLYMERIZATION OF CHELATE-**** MCMS 134 4.4 MCM COPOLYMERIZATION
136 4.4.1 ORGANOMETALLIC MONOMERS IN COPOLYMERIZATION REACTIONS 137
4.4.2 COPOLYMERIZATION OF IONIC-TYPE MCMS 140 4.4.3 PECULIARITIES OF
COPOLYMERIZATION OF DONOR-ACCEPTOR TYPE MCMS 145 4.4.4 COPOLYMERIZATION
OFTI-MCMS 148 4.4.5 CHELATE-**** MONOMERS IN COPOLYMERIZATION WITH
CONVENTIONAL MONOMERS... 150 4.4.6 MUTUAL MCM COPOLYMERIZATION 154 4.4.7
COPOLYMERIZATION OF CLUSTER-CONTAINING MONOMERS 155 4.5 THE FUTURE
DEVELOPMENT OF POLYMERIZATION AND COPOLYMERIZATION OF MCMS 157 4.6
EXPERIMENTAL 159 4.7 REFERENCES 166 5 BINDING OF METAL IONS AND METAL
COMPLEXES TO MACROMOLECULAR CARRIERS (D. WOEHRLE) 173 5.1 BINDING OF
METAL IONS 179 5.1.1 METAL ION BINDING AT POLYMERIC OXYGEN DONOR LIGANDS
180 5.1.2 METAL ION BINDING AT POLYMERIC NITROGEN DONOR LIGANDS 186
5.1.3 METAL ION BINDING AT POLYMERIC OXYGEN/NITROGEN DONOR LIGANDS 191
5.1.4 METAL ION BINDING AT POLYMERIC SULFUR OR PHOSPHORUS LIGANDS 193
CONTENTS XI 5.2 BINDING OF METAL COMPLEXES 195 5.2.1 COVALENT BINDING OF
METAL COMPLEXES 195 5.2.2 COORDINATIVE BINDING OF METAL COMPLEXES 201
5.2.3 IONIC BINDING OF METAL COMPLEXES 205 5.3 EXAMPLES OF
ORGANOMETALLIC COMPOUNDS AND 7T-COMPLEXES 208 5.4 EXPERIMENTAL 209 5.5
REFERENCES 222 6 METAL COMPLEXES AS PART OF LINEAR OR CROSS-LINKED
MACROMOLECULES VIA THE LIGAND (D. WOEHRLE) 229 6.1 POLYMERIC METAL
COMPLEXES WITH NONCYCLIC ORGANIC LIGANDS 230 6.2 POLYMERIC METAL
COMPLEXES WITH CYCLIC ORGANIC LIGANDS 238 6.2.1 CYCLIZATION OF
BIFUNCTIONAL AND HIGHER-FUNCTIONAL LIGAND/CHELATE PRECURSORS 238 6.2.2
POLYREACTIONS OF BIFUNCTIONAL OR HIGHER-FUNCTIONAL PORPHYRINS AND
PHTHALOCYANINES 245 6.3 ELECTROPOLYMERIZATION OF METAL COMPLEXES 250 6.4
DENDRIMERS CONSTRUCTED VIA THE LIGAND OF A METAL COMPLEX 259 6.5
HYDROGEN-BONDED NETWORKS VIA THE LIGAND 262 6.6 EXPERIMENTAL 264 6.7
REFERENCES 270 7 METALS OR METAL COMPLEXES AS PART OF LINEAR OR
CROSSLINKED MACROMOLECULES VIA THE METAL (D. WOEHRLE) 279 7.1 HOMOCHAIN
POLYMERS WITH COVALENT METAL-METAL BONDS 280 7.2 HETEROCHAIN POLYMERS
WITH COVALENT BONDS BETWEEN METALS AND ANOTHER ELEMENT 281 7.3
HETEROCHAIN POLYMERS WITH COORDINATIVE BONDS BETWEEN METAL AND ANOTHER
ELEMENT 284 7.3.1 CHAIN-FORMING COORDINATION POLYMERS 284 7.3.2
SUPRAMOLECULAR ORGANIZATION OF COORDINATION POLYMERS 291 7.3.2.1
NON-INTERPENETRATING COORDINATION POLYMERS 292 7.3.2.2 INTERPENETRATING
COORDINATION POLYMERS 301 7.4 METALLOCENES AS PART OF A POLYMER CHAIN
304 7.5 COFACIALLY STACKED POLYMERIC METAL COMPLEXES 306 7.6
METALLODENDRIMERS 309 7.7 EXPERIMENTAL 312 7.8 REFERENCES 317 8 METAL
COMPLEXES OR CLUSTERS PHYSICALLY EMBEDDED IN MACROMOLECULES (A.
POMOGAILO AND D. WOEHRLE) 325 8.1 INTRODUCTION 325 8.2 METAL COMPLEXES
EMBEDDED PHYSICALLY IN MACROMOLECULES 325 8.2.1 INCORPORATION IN ORGANIC
POLYMERS 326 8.2.2 INCORPORATION IN INORGANIC MACROMOLECULES 332 8.3
METAL-CLUSTER AND NANOSIZED PARTICLES EMBEDDED IN POLYMERS 334 8.3.1 THE
GENERAL CHARACTERISTICS OF METALLOPOLYMER SYSTEMS 335 8.3.2
MICROENCAPSULATION OF METALLOCOMPLEXES AND NANOPARTICLES BY POLYMERS 335
8.3.3 MECHANOCHEMICAL DISPERSION OF NANOPARTICLES WITH POLYMERS 337
8.3.4 SPRAY-COATING OF POLYMERS BY ATOMIC METALS 338 8.3.5 FORMATION OF
NANOCOMPOSITES IN POLYMER SOLUTIONS 339 XII CONTENTS 8.3.6 STRUCTURAL
ORGANIZATION OF NANOPARTICLES IN BLOCK COPOLYMERS 340 8.3.7
METALLOPOLYMER FORMATION IN HETEROGENEOUS SYSTEMS 342 8.3.8
METALLOPOLYMERS OBTAINED BY POLYMERIZATION (POLYCONDENSATION) OF THEIR
STABILIZING COVER 345 8.3.9 ARCHITECTURE OF METALLOPOLYMERS WITH
DENDRIMERS 347 8.3.10 SELF-ORGANIZED HYBRID
METALLOPOLYMERS-LANGMUIR-BLODGETT FILMS 350 8.3.11 DESIGN OF
POLYMER-INORGANIC NANOMATERIALS BASED ON INCORPORATED METALLOPARTICLES
351 8.3.12 CONCLUSION 353 8.4 EXPERIMENTAL 354 8.5 REFERENCES 356 *
PROPERTIES 9 BINDING OF SMALL MOLECULES (J. WON, Y.S. KANG AND H.
NISHIDE) 363 9.1 INTRODUCTION 363 9.2 BINDING OF SMALL MOLECULES TO
METAL COMPLEXES IN MACROMOLECULES 365 9.2.1 FORMATION OF SILVER-POLYMER
COMPLEXES 365 9.2.2 OLEFIN BINDING AND REVERSIBILITY 367 9.2.3 FORMATION
OF METALLOPORPHYRIN-POLYMER COMPLEXES 370 9.2.4 OXYGEN-BINDING AND
REVERSIBILITY 374 9.3 SMALL MOLECULE TRANSPORT THROUGH MEMBRANES OF
METAL COMPLEXES IN MACROMOLECULES 380 9.3.1 MEMBRANE GAS SEPARATION 380
9.3.2 FACILITATED OLEFIN TRANSPORT 382 9.3.3 FACILITATED OXYGEN
TRANSPORT 385 9.3.4 OTHER SMALL-MOLECULE TRANSPORT 390 9.4 OTHER
APPLICATIONS OF METAL COMPLEXES IN MACROMOLECULES WITH SMALL
MOLECULE-BINDING ABILITIES 391 9.5 EXPERIMENTAL 396 9.6 REFERENCES 401
10 PHYSICAL AND OPTICAL SENSORS 405 10.1 OPTICAL SENSORS (I. OKURA AND
Y. AMAO) 405 10.1.1 PRINCIPLE OF OPTICAL GAS SENSORS 405 10.1.2
LUMINESCENCE QUENCHING-BASED OXYGEN SENSORS 409 10.1.3 OPTICAL
OXYGEN-SENSING SYSTEMS BASED ON TRIPLET-TRIPLET ABSORPTION OF ORGANIC
DYE 414 10.1.4 OPTICAL OXYGEN SENSORS USING AN ULTRA-THIN FILM OF A
MACROMOLECULE DYE ....420 10.1.5 EXPERIMENTAL 426 10.2 ELECTROCHEMICAL
SENSORS BASED ON SELF-ASSEMBLED MONOLAYERS (SAMS) OF METALLOMACROCYCLES
(T. OHSAKA AND * RETNA RAJ) 428 10.2.1 INTRODUCTION 428 10.2.2 A
VOLTAMMETRIC SENSOR BASED ON SELF-ASSEMBLY OF A MACROCYCLIC NICKEL(II)
COMPLEX 429 10.2.2.1 NICKEL IN BIOLOGY 429 10.2.2.2 ELECTROCHEMISTRY OF
MNC 430 10.2.2.3 ANION RECOGNITION 432 10.2.2.4 VOLTAMMETRIC OF H 2 0 2
SENSOR 433 10.2.2.5 VOLTAMMETRIC OF NADH SENSOR 435 10.2.2.6
VOLTAMMETRIC OF PH SENSOR 438 10.2.3 ELECTROCHEMICAL SUPEROXIDE
BIOSENSOR BASED ON SELF-ASSEMBLY OF METALLOENZYMES 442 CONTENTS XIII
10.2.3.1 DIRECT ELECTRON TRANSFER OF SOD AT CYS/AU ELECTRODE 443
10.2.3.2 SOD-BASED THIRD GENERATION BIOSENSOR FOR SUPEROXIDE ION 446
10.2.4 EXPERIMENTAL 450 10.3 REFERENCES 451 11 CATALYSIS BY SOLUBLE
MACROMOLECULAR METAL COMPLEXES (E.A. KARAKHANOV AND A.L. MAXIMOV) 457
11.1 WATER-SOLUBLE METAL COMPLEXES WITH MODIFIED POLYETHYLENE OXIDE)S IN
CATALYSIS 458 11.2 POLYAMIDES AND POLYACIDS BASED ON SOLUBLE
MACROMOLECULAR METAL COMPLEX CATALYSTS 469 11.3 CATALYSIS BY SOLUBLE
DENDRIMERS 473 11.4 MACROMOLECULAR METAL COMPLEX CATALYSTS SOLUBLE IN
NONPOLAR SOLVENTS 47 8 11.5 METAL COMPLEXES WITH LIGANDS BASED ON OTHER
POLYMERS 482 11.6 MACROMOLECULAR METAL COMPLEXES CAPABLE OF FORMING
HOST-GUEST COMPLEXES 483 11.7 EXPERIMENTAL 489 11.8 REFERENCES 494 12
THE STATE OF THE ART AND PERSPECTIVES IN CATALYSIS BY HETEROGENIZED
POLYMER-BOUND METAL COMPLEXES (A. POMOGAILO) 503 12.1 THE PLACE OF
POLYMER-IMMOBILIZED METAL COMPLEXES IN CATALYSIS 503 12.2 THE FEATURES
OF HYDROGENATION REACTIONS CATALYZED BY MACROMOLECULAR METAL COMPLEXES
507 12.2.1 GENERAL KINETIC REGULARITIES 507 12.2.2 THE INFLUENCE OF THE
NATURE OF A METAL COMPLEX ON ITS CATALYTIC PROPERTIES 510 12.2.3
FORMATION OF COORDINATIVELY UNSATURATED AND ISOLATED COMPLEXES 513
12.2.4 THE INFLUENCE OF SOLVENT PROPERTIES 515 12.2.5 THE INFLUENCE OF
REACTION TEMPERATURE 517 12.2.6 SURFACE DENSITY 519 12.2.7 SIZE EFFECTS
IN HYDROGENATION BY POLYMER-IMMOBILIZED COMPLEXES 520 12.2.8 PROBLEMS OF
SELECTIVITY IN HYDROGENATION REACTIONS CATALYZED BY MACROMOLECULAR METAL
COMPLEXES 522 12.2.9 PERSPECTIVES IN THE DEVELOPMENT OF HYDROGENATION
CATALYSIS BY MACROMOLECULAR COMPLEXES 524 12.3 POLYMERIZATION PROCESSES
INITIATED BY MACROMOLECULAR COMPLEXES 527 12.3.1 PECULIARITIES OF OLEFIN
POLYMERIZATION 528 12.3.2 ETHYLENE POLYMERIZATION BY TITANIUM-MAGNESIUM
CATALYSTS 534 12.3.3 GEL-IMMOBILIZED SYSTEMS 534 12.3.4 STEREOSPECIFIC
PROPYLENE POLYMERIZATION 535 12.3.5 THE HETEROGENIZATION OF HOMOGENEOUS
METALLOCENE CATALYSTS FOR OLEFIN POLYMERIZATION 535 12.3.6
POLYMERIZATION OF VINYL MONOMERS IN THE PRESENCE OF MACROMOLECULAR
COMPLEXES 539 12.3.7 OTHER PERSPECTIVES IN POLYMERIZATION CATALYSIS BY
MACROMOLECULAR COMPLEXES 541 12.4 OXIDATION CATALYSIS IN THE PRESENCE OF
MACROMOLECULAR COMPLEXES 542 12.4.1 THE ROLE OF METAL IONS IN OXIDATION
543 12.4.2 REACTIONS OF HYDROCARBON OXIDATION BY OXYGEN 545 12.4.3
PEROXIDE OXIDATION OF ALKYLARENES AND HYDROXYARENES 551 12.4.4 CATALYSIS
OF OLEFIN EPOXIDATION BY ALKYLHYDROPEROXIDES 552 XIV CONTENTS 12.4.5
CATALYTIC OXIDATION OF OXYGEN-CONTAINING SUBSTRATES AND PROSPECTS FOR
OXIDATION CATALYSIS 555 12.5 HYDROFORMYLATION IN THE PRESENCE OF
POLYMER-IMMOBILIZED METAL COMPLEXES 559 12.5.1 HYDROFORMYLATION OF
OLEFINS 559 12.5.2 PROBLEMS OF POLYFIMCTIONAL CATALYSIS BY IMMOBILIZED
METAL COMPLEXES 560 12.5.3 ASYMMETRIC HYDROFORMYLATION REACTIONS 562
12.5.4 OTHER PROSPECTIVE OXO-PROCESSES 562 12.6 CONCLUSION 564 12.7
EXPERIMENTAL 564 12.8 REFERENCES 566 13 PHOTOCATALYTIC PROPERTIES (M.
KANEKO AND D. WOHRLE) 573 13.1 PHOTOCATALYSIS 573 13.2 PHOTOCATALYSIS
TOWARDS FUTURE ARTIFICIAL PHOTOSYNTHESIS 574 13.2.1 PHOTOSYNTHESIS AND
THE ENERGY CYCLE ON THE EARTH 574 13.2.2 A MODEL FOR ARTIFICIAL
PHOTOSYNTHESIS 576 13.2.3 DARK CATALYSIS AND PHOTOCATALYSIS FOR
ARTIFICIAL PHOTOSYNTHESIS 577 13.2.3.1 DARK CATALYSIS FOR WATER
OXIDATION 578 13.2.3.2 DARK CATALYSIS FOR PROTON REDUCTION 581 13.2.3.3
DARK CATALYSIS FOR CARBON DIOXIDE REDUCTION 583 13.2.3.4
PHOTOEXCITED-STATE ELECTRON TRANSFER IN POLYMER MATRIXES 584 13.2.3.5
PHOTOCHEMICAL H 2 AND 0 2 EVOLUTION AS HALF-REACTION MODELS FOR FUTURE
ARTIFICIAL PHOTOSYNTHESIS 587 13.3 PHOTOCATALYSIS FOR SOLAR CELLS AND
WATER PHOTOLYSIS BY TI0 2 588 13.4 PHOTOINDUCED ENERGY TRANSFER 592 13.5
EXPERIMENTAL 595 13.6 REFERENCES 599 14 ELECTRON- AND PHOTON-INDUCED
PROCESSES (M. KANEKO) 601 14.1 CHARGE TRANSPORT BY METAL COMPLEXES IN
THE GROUND STATE CONFINED IN POLYMER MATRIXES 602 14.1.1 FUNDAMENTAL
ASPECTS 602 14.1.2 THE MECHANISM OF CHARGE TRANSFER 605 14.1.3 DISTANCE
OF CHARGE HOPPING WITH BOUNDED MOTION 614 14.1.4 THE PERCOLATION PROCESS
FOR CHARGE HOPPING WITHOUT BOUNDED MOTION 616 14.1.5 ELECTROCATALYSIS -
A COMBINATION OF CHARGE TRANSFER AND CATALYSIS 619 14.2 CHARGE TRANSFER
IN A PHOTOEXCITED STATE - PHOTOCHEMISTRY 621 14.2.1 FUNDAMENTAL BEHAVIOR
621 14.2.2 PHOTOEXCITED STATE ELECTRON TRANSPORT IN SOLID POLYMER
MATRIXES 622 14.2.3 THE MECHANISM OF PHOTOEXCITED STATE ELECTRON
TRANSPORT IN POLYMER SOLID MATRIXES 624 14.2.4 PHOTOELECTROCHEMICAL
DEVICES UTILIZING CHARGE TRANSFER IN PHOTOEXCITED AND GROUND STATES 626
14.3 NEW ASPECTS AND FUTURE SCOPE OF CHARGE TRANSFER IN POLYMERIC
QUASI-SOLIDS 630 14.4 ORGANIC ELECTROLUMINESCENT DEVICES 634 14.4.1
GENERAL OVERVIEW 634 14.4.2 STRUCTURE AND MECHANISM OF EL DEVICES 634
14.4.3 MATERIALS FOR EL DEVICES 637 14.4.4 COMMERCIALIZATION 644
CONTENTS XV 14.5 EXPERIMENTAL 645 14.6 REFERENCES 648 15 OUTLOOK (D.
WOEHRLE AND A. POMOGAILO) 653 INDEX 661
|
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| discipline | Chemie / Pharmazie |
| format | Book |
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| id | DE-604.BV016522632 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T19:11:30Z |
| institution | BVB |
| isbn | 3527304991 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-010211184 |
| oclc_num | 249232120 |
| open_access_boolean | |
| owner | DE-703 DE-20 DE-1046 DE-19 DE-BY-UBM DE-634 DE-11 |
| owner_facet | DE-703 DE-20 DE-1046 DE-19 DE-BY-UBM DE-634 DE-11 |
| physical | XVIII, 667 S. Ill., graph. Darst. |
| publishDate | 2003 |
| publishDateSearch | 2003 |
| publishDateSort | 2003 |
| publisher | Wiley-VCH |
| record_format | marc |
| spelling | Metal complexes and metals in macromolecules synthesis, structure and properties Dieter Wöhrle ; Anatolii D. Pomogailo Weinheim Wiley-VCH 2003 XVIII, 667 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Literaturangaben Metallkomplexe - Biomolekül Metallkomplexe - Katalysator Metallproteide - Modellverbindung Macromolecules Metal complexes Modellverbindung (DE-588)4327521-7 gnd rswk-swf Katalysator (DE-588)4029919-3 gnd rswk-swf Metallproteide (DE-588)4169623-2 gnd rswk-swf Metallkomplexe (DE-588)4038898-0 gnd rswk-swf Biomolekül (DE-588)4135124-1 gnd rswk-swf Metallkomplexe (DE-588)4038898-0 s Biomolekül (DE-588)4135124-1 s DE-604 Katalysator (DE-588)4029919-3 s Metallproteide (DE-588)4169623-2 s Modellverbindung (DE-588)4327521-7 s Wöhrle, Dieter Sonstige oth Pomogailo, Anatoly D. Sonstige oth GBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=010211184&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Metal complexes and metals in macromolecules synthesis, structure and properties Metallkomplexe - Biomolekül Metallkomplexe - Katalysator Metallproteide - Modellverbindung Macromolecules Metal complexes Modellverbindung (DE-588)4327521-7 gnd Katalysator (DE-588)4029919-3 gnd Metallproteide (DE-588)4169623-2 gnd Metallkomplexe (DE-588)4038898-0 gnd Biomolekül (DE-588)4135124-1 gnd |
| subject_GND | (DE-588)4327521-7 (DE-588)4029919-3 (DE-588)4169623-2 (DE-588)4038898-0 (DE-588)4135124-1 |
| title | Metal complexes and metals in macromolecules synthesis, structure and properties |
| title_auth | Metal complexes and metals in macromolecules synthesis, structure and properties |
| title_exact_search | Metal complexes and metals in macromolecules synthesis, structure and properties |
| title_full | Metal complexes and metals in macromolecules synthesis, structure and properties Dieter Wöhrle ; Anatolii D. Pomogailo |
| title_fullStr | Metal complexes and metals in macromolecules synthesis, structure and properties Dieter Wöhrle ; Anatolii D. Pomogailo |
| title_full_unstemmed | Metal complexes and metals in macromolecules synthesis, structure and properties Dieter Wöhrle ; Anatolii D. Pomogailo |
| title_short | Metal complexes and metals in macromolecules |
| title_sort | metal complexes and metals in macromolecules synthesis structure and properties |
| title_sub | synthesis, structure and properties |
| topic | Metallkomplexe - Biomolekül Metallkomplexe - Katalysator Metallproteide - Modellverbindung Macromolecules Metal complexes Modellverbindung (DE-588)4327521-7 gnd Katalysator (DE-588)4029919-3 gnd Metallproteide (DE-588)4169623-2 gnd Metallkomplexe (DE-588)4038898-0 gnd Biomolekül (DE-588)4135124-1 gnd |
| topic_facet | Metallkomplexe - Biomolekül Metallkomplexe - Katalysator Metallproteide - Modellverbindung Macromolecules Metal complexes Modellverbindung Katalysator Metallproteide Metallkomplexe Biomolekül |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=010211184&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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