Investigation of the doping process in organic molecular thin films:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Abschlussarbeit Buch |
| Sprache: | English |
| Veröffentlicht: |
2002
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | 92 S. Ill., graph Darst. : 21 cm |
Internformat
MARC
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| 100 | 1 | |a Nollau, Andreas |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a Investigation of the doping process in organic molecular thin films |c vorgelegt von Andreas Nollau |
| 264 | 1 | |c 2002 | |
| 300 | |a 92 S. |b Ill., graph Darst. : 21 cm | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 502 | |a Dresden, Techn. Univ., Diss., 2002 | ||
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Datensatz im Suchindex
| _version_ | 1807772394063921152 |
|---|---|
| adam_text |
CONTENTS
1
INTRODUCTION
.
11
2
CHARGE
CARRIERS
IN
ORGANIC
SOLIDS
.
15
2.1
ORGANIC
MOLECULAR
CRYSTALS
.
15
2.2
CHARGE
CARRIERS
IN
ORGANIC
CRYSTALS
.
16
2.2.1
THE
IONIZED
MOLECULE
.
16
2.2.2
POLARONS
.
17
2.3
GENERATION
OF
CHARGE
CARRIERS
-
THE
DOPING
PROCESS
.
18
2.3.1
DEEP
AND
SHALLOW
TRAP
LEVELS
.
19
2.4
CHARGE
CARRIER
TRANSPORT
.
20
2.4.1
BAND
TRANSPORT
.
20
2.4.2
HOPPING
TRANSPORT
.
21
2.4.2.1
PHONON
ASSISTED
HOPPING
.
21
2.4.2.2
NEAREST-NEIGHBOR
HOPPING
.
22
2.4.2.3
DAVIS-MOTT
MODEL
.
22
3
MATERIALS
AND
EXPERIMENTS
.
23
3.1
MATERIALS
.
23
3.1.1
NTCDA,
PTCDA,
ME-PTCDI
AND
THEIR
DOPANT
BEDT-TTF
.
23
3.1.2
ALQ
3
.
25
3.1.3
THE
P-TYPE
MODEL
SYSTEM:
ZNPC
DOPED
WITH
F-TCNQ
.
25
3.2
SAMPLE
PREPARATION
.
26
3.3
PURIFICATION
AND
MASS
SPECTROSCOPY
.
28
3.4
EXPERIMENTAL
SET-UPS
.
31
3.4.1
ELECTRICAL
MEASUREMENTS
.
31
3.4.2
ESR
MEASUREMENTS
.
33
4
N-DOPING
.
35
4.1
INTRODUCTION
.
35
4.2
THEORY
OF
THE
SEEBECK
EFFECT
.
36
4.2.1
SEEBECK
EFFECT
.
36
4.2.2
STANDARD
MODEL
.
37
4.2.2.1
BAND
TRANSPORT
.
37
4.2.2.2
CONDUCTION
IN
LOCALIZED
STATES
.
38
4.2.2.3
PERCOLATION
.
39
4.2.2.4
IDEAL
MOBILITY
.
39
4.2.3
CONDUCTION
NEAR
THE
FERMI
LEVEL
.
40
4.2.4
CONDUCTION
IN
AN
EXTENDED
DISTRIBUTION
OF
STATES
.
40
4.2.4.1
HOMOGENEOUS
SYSTEM
.
40
4.2.4.2
LONG
RANGE
DISORDER
.
47
4
CONTENTS
4.3
RESULTS
AND
DISCUSSION
OF
THE
N-DOPING
EXPERIMENTS
.
48
4.3.1
NAPHTHALENETETRACARBOXYLIC
DIANHYDRIDE
(NTCDA)
.
48
4.3.2
PERYLENETETRACARBOXYLIC
DIANHYDRIDE
(PTCDA)
.
53
4.3.3
DIMETHYLPERYLENE
DICARBOXIMIDE
(ME-PTCDI)
.
56
4.3.4
TRIS-HYDROXYQUINOLINE
ALUMINUM
(ALQ
3
)
.
59
4.4
SUMMARY
OF
THE
N-DOPING
EXPERIMENTS
.
61
5
ELECTRON
SPIN
RESONANCE
.
63
5.1
INTRODUCTION
.
63
5.2
THEORY
OF
ESR
.
65
5.2.1
BASIC
THEORY
.
65
5.2.2
COUPLING
OF
SPINS
.
68
5.2.2.1
DIPOLE-DIPOLE-INTERACTION
AND
THE
METHOD
OF
MOMENTS
.
68
5.2.2.2
FINE
STRUCTURE
.
70
5.2.2.3
HYPERFINE
COUPLING
.
71
5.2.3
DYNAMIC
PROCESSES
.
73
5.2.3.1
QUENCHING
OF
THE
HYPERFINE
STRUCTURE
.
74
5.3
RESULTS
AND
DISCUSSION
OF
THE
ESR-EXPERIMENTS
.
75
5.3.1
GENERAL
BEHAVIOR
OF
THE
ESR-SPECTRUM
.
75
5.3.2
THE
G-VALUE
.
76
5.3.3
INTENSITY
OF
THE
ESR
SIGNAL
.
78
5.3.4
HYPERFINE
STRUCTURE
.
79
5.3.5
LINE
SHAPE
AND
WIDTH
.
80
5.4
SUMMARY
OF
THE
ESR
RESULTS
.
83
6
CONCLUSION
AND
OUTLOOK
.
85
6.1
CONCLUSION
.
85
6.2
OUTLOOK
.
86
APPENDIX
INTERPRETATION
OF
P-DOPED
ZNPC
WITH
A
GAUSSIAN
DISTRIBUTED
DOS
.
87
BIBLIOGRAPHY
.
89 |
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| genre_facet | Hochschulschrift |
| id | DE-604.BV015822854 |
| illustrated | Illustrated |
| indexdate | 2024-08-19T00:08:21Z |
| institution | BVB |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-010130103 |
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| physical | 92 S. Ill., graph Darst. : 21 cm |
| publishDate | 2002 |
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| spelling | Nollau, Andreas Verfasser aut Investigation of the doping process in organic molecular thin films vorgelegt von Andreas Nollau 2002 92 S. Ill., graph Darst. : 21 cm txt rdacontent n rdamedia nc rdacarrier Dresden, Techn. Univ., Diss., 2002 Dotierung (DE-588)4130672-7 gnd rswk-swf Elektronischer Transport (DE-588)4210733-7 gnd rswk-swf Organischer Festkörper (DE-588)4172779-4 gnd rswk-swf Seebeck-Effekt (DE-588)4180622-0 gnd rswk-swf Dünne Schicht (DE-588)4136925-7 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Organischer Festkörper (DE-588)4172779-4 s Dünne Schicht (DE-588)4136925-7 s Dotierung (DE-588)4130672-7 s Elektronischer Transport (DE-588)4210733-7 s Seebeck-Effekt (DE-588)4180622-0 s DE-604 DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=010130103&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Nollau, Andreas Investigation of the doping process in organic molecular thin films Dotierung (DE-588)4130672-7 gnd Elektronischer Transport (DE-588)4210733-7 gnd Organischer Festkörper (DE-588)4172779-4 gnd Seebeck-Effekt (DE-588)4180622-0 gnd Dünne Schicht (DE-588)4136925-7 gnd |
| subject_GND | (DE-588)4130672-7 (DE-588)4210733-7 (DE-588)4172779-4 (DE-588)4180622-0 (DE-588)4136925-7 (DE-588)4113937-9 |
| title | Investigation of the doping process in organic molecular thin films |
| title_auth | Investigation of the doping process in organic molecular thin films |
| title_exact_search | Investigation of the doping process in organic molecular thin films |
| title_full | Investigation of the doping process in organic molecular thin films vorgelegt von Andreas Nollau |
| title_fullStr | Investigation of the doping process in organic molecular thin films vorgelegt von Andreas Nollau |
| title_full_unstemmed | Investigation of the doping process in organic molecular thin films vorgelegt von Andreas Nollau |
| title_short | Investigation of the doping process in organic molecular thin films |
| title_sort | investigation of the doping process in organic molecular thin films |
| topic | Dotierung (DE-588)4130672-7 gnd Elektronischer Transport (DE-588)4210733-7 gnd Organischer Festkörper (DE-588)4172779-4 gnd Seebeck-Effekt (DE-588)4180622-0 gnd Dünne Schicht (DE-588)4136925-7 gnd |
| topic_facet | Dotierung Elektronischer Transport Organischer Festkörper Seebeck-Effekt Dünne Schicht Hochschulschrift |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=010130103&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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