Late transition metal polymerization catalysis:
Gespeichert in:
| Format: | Buch |
|---|---|
| Sprache: | English |
| Veröffentlicht: |
Weinheim
Wiley-VCH
2003
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | Literaturangaben |
| Beschreibung: | XIV, 331 S. Ill., graph. Darst. : 25 cm |
| ISBN: | 3527304355 |
Internformat
MARC
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| 245 | 1 | 0 | |a Late transition metal polymerization catalysis |c Bernhard Rieger ... (eds.) |
| 264 | 1 | |a Weinheim |b Wiley-VCH |c 2003 | |
| 300 | |a XIV, 331 S. |b Ill., graph. Darst. : 25 cm | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 500 | |a Literaturangaben | ||
| 650 | 7 | |a Homogene katalyse |2 gtt | |
| 650 | 7 | |a Overgangsmetaalcomplexen |2 gtt | |
| 650 | 7 | |a Polymerisatie |2 gtt | |
| 650 | 4 | |a Polymerization | |
| 650 | 4 | |a Transition metal catalysts | |
| 650 | 0 | 7 | |a Katalyse |0 (DE-588)4029921-1 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Polymerisation |0 (DE-588)4046704-1 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Übergangsmetallkomplexe |0 (DE-588)4131837-7 |2 gnd |9 rswk-swf |
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| 689 | 0 | 1 | |a Polymerisation |0 (DE-588)4046704-1 |D s |
| 689 | 0 | 2 | |a Katalyse |0 (DE-588)4029921-1 |D s |
| 689 | 0 | |5 DE-604 | |
| 700 | 1 | |a Rieger, Bernhard |e Sonstige |4 oth | |
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Datensatz im Suchindex
| _version_ | 1808135771920531456 |
|---|---|
| adam_text |
V
CONTENTS
PREFACE
XI
LIST
OF
CONTRIBUTORS
XII
1
NICKEL
POLYMERIZATION
CATALYSTS
WITH
YLIDE
STEERING
LIGANDS
1
ALEKSANDER
OSTOJA
STARZEWSKI
1.1
INTRODUCTION
1
1.1.1
YLIDES
AND
YLIDIC
BOND
SYSTEMS
1
1.1.2
YLIDE
LIGAND
PROPERTIES
AND
COORDINATION
MODES
3
1.2
YLIDE
NICKEL
COMPLEXES:
NOVEL
POLYMERIZATION
CATALYSTS
5
1.2.1
YLIDE
NICKEL
COMPLEX
SYNTHESIS
6
1.2.2
SPECTROSCOPY
6
1.2.2.1
NIPH(PH
2
PCHCPHO)(ME
3
PCH
2
)
LA
7
1.2.3
X-RAY
STRUCTURE
ANALYSIS
8
1.3
ETHYLENE
POLYMERIZATION
10
1.3.1
CATALYST
ACTIVITY
10
1.3.2
NOVEL
LIGAND
CONTROL
OF
PE
MOLECULAR
WEIGHT
11
1.3.3
LINEAR
AND
BRANCHED
MACROMOLECULES
13
1.3.3.1
LINEAR
MACROMOLECULES
13
1.3.3.2
SHORT
CHAIN-BRANCHED
MACROMOLECULES
13
1.3.3.3
LONG
CHAIN-BRANCHED
MACROMOLECULES
14
1.3.4
STYRYL-TERMINATED
OLIGO-/POLYETHYLENES
15
1.4
CYCLOOLEFIN
POLYMERIZATION
16
1.5
BUTADIENE
POLYMERIZATION
17
1.6
POLAR
MONOMER
POLYMERIZATION
17
1.7
ACETYLENE
POLYMERIZATION
18
1.7.1
CATALYST
ACTIVITY
18
1.7.2
MATPAC,
NOVEL
HIGHLY
POLAR
MATRIX
POLYACETYLENES
18
1.7.3
POLPAC,
A
TAILOR-MADE
POLYACETYLENE
APPLICATION
22
1.7.4
MATPAC
FOR
NLO
DEVICES
23
1.8
REFERENCES
24
VI
CONTENTS
2
MICROSTRUCTURE
CONTROL
OF
ETHENE
HOMOPOLYMERS
THROUGH
TAILORED
NI,PD(LL)
CATALYSTS
27
JURGEN
KUKRAL,
ALEXANDRA
ABELE,
GABI
MULLER,
AND
BERNHARD
RIEGER
2.1
2.2
INTRODUCTION
27
NOVEL
2,6-DIARYL-SUBSTITUTED
DIIMINE
CATALYSTS:
A
VERSATILE
CONCEPT
FOR
TAILORED
POLYMER
PROPERTIES
FROM
SIMPLE
C
2
MONOMERS
31
2.2.1
2.2.2
2.2.3
2.2.3.1
2.23.2
2.3
2.3.1
2.3.2
2.4
LIGAND
AND
COMPLEX
SYNTHESIS
32
SOLID
STATE
STRUCTURES
33
ETHENE
POLYMERIZATION
EXPERIMENTS
37
PALLADIUM
MONOMETHYL
COMPLEXES
37
NICKEL
DIBROMIDES
37
DESYMMETRIZED
PALLADIUM
AND
NICKEL
DIIMINE
CATALYSTS
40
LIGAND
AND
COMPLEX
SYNTHESIS
40
POLYMERIZATION
REACTIONS
41
PALLADIUM
COMPLEXES
WITH
BIDENTATE
PNN-LIGANDS:
APPLICATION
IN
ETHENE
OLIGOMERIZATION
43
2.4.1
2.4.2
2.5
SYNTHESIS
AND
CHARACTERIZATION
44
ETHENE
OLIGOMERIZATION
REACTIONS
46
APPLICATION
OF
STERICALLY
DEMANDING
BIS(PHOSPHINO)
COMPLEXES
IN
ETHENE
HOMOPOLYMERIZATION
47
2.5.1
SYNTHESIS
AND
COMPLEXATION
OF
ETHENE
BRIDGED
BIS(PHOSPHINE)
LIGANDS
47
2.5.2
2.5.3
2.5.4
2.6
2.7
SOLID
STATE
STRUCTURES
49
NMR
STUDIES
ON
THE
PALLADIUM
DICHLORO
SPECIES
52
INFLUENCE
OF
SUBSTITUTION
ON
ETHENE
POLYMERIZATION
REACTIONS
52
CONCLUSION
55
REFERENCES
56
3
HIGHLY
ACTIVE
ETHENE
POLYMERIZATION
CATALYSTS
WITH
UNUSUAL
IMINE
LIGANDS
59
GERRIT
A.
LUINSTRA,
JOACHIM
QUEISSER,
BENNO
BILDSTEIN,
HANS-HELMUT
GORTZ,
CHRISTOPH
AMORT,
MICHAEL
MALAUN,
ALEXANDER
KRAJETE,
GERALD
WEME,
MARC
O.
KRISTEN,
NORBERT
HUBER,
AND
CHRISTOPH
GEMERT
3.1
3.2
3.2.1
3.2.1.1
INTRODUCTION
59
LIGAND
AND
METAL
COMPLEX
SYNTHESIS
62
DIIMINE
SYSTEMS
62
[N,N]
DIIMINES
CONTAINING
PERIPHERAL
N-HETEROAROMATIC
SUBSTITUENTS
62
3.2.1.2
3.2.1.3
3.2.1.4
1,2-DIIMINE
LIGANDS
WITH
N-HETARYL
SUBSTITUENTS
64
NICKEL
COMPLEXES
WITH
N-HETARYL
1,2-DIIMINE
LIGANDS
65
DIIMINE
NICKEL
AND
PALLADIUM
COMPLEXES
WITH
2,6-DIBROMOPHENYL
GROUPS
67
3.2.2
DIIMINE
PYRIDINE
SYSTEMS
71
CONTENTS
I
VII
3.2.2.1
3.2.2.2
3.2.3
3.2.3.1
3.2.4
3.3
3.3.1
3.3.2
3.3.3
3.3.4
3.3.5
3.4
3.5
3.6
4
4.1
4.2
4.2.1
4.2.2
4.2.3
4.2.3.1
4.2.3.2
4.2.3.3
4.2.3.4
4.2.3.5
4.2.3.6
4.2.3.7
4.2.3.8
4.2.3.9
4.2.3.10
4.2.3.11
4.3
4.3.1
4.3.1.1
4.3.1.2
4.4
[N,N,N]
BIS(IMINO)PYRIDINE
IRON
AND
COBALT
COMPLEXES
WITH
PERIPHERAL
N-HETEROAROMATIC
SUBSTITUENTS
71
N-HALOGENOARYL-CONTAINING
TRIDENTATE
LIGANDS
AND
THEIR
FE
COMPLEXES
75
SALICYLIMINE
SYSTEMS
75
[N,O]
SALICYLIMINE
NICKEL
COMPLEXES
CONTAINING
PERIPHERAL
N-HETEROAROMATIC
SUBSTITUENTS
75
ETHANOL
IMINE
LIGANDS
AND
THEIR
NICKEL
COMPLEXES
79
POLYMERIZATION
PERFORMANCE
82
DIIMINE
NI
COMPLEXES
WITH
PERIPHERAL
N-HETEROAROMATIC
SUBSTITUENTS
83
DIIMINEPYRIDINE
IRON
AND
COBALT
COMPLEXES
WITH
PERIPHERAL
N-HETEROAROMATIC
SUBSTITUENTS
84
DIIMINE
PALLADIUM
AND
IMINE
PYRIDINE
IRON
COMPLEXES
WITH
HALOGENOPHENYL
IMINE
LIGANDS
87
SALICYLIMINE
NI
COMPLEXES
91
HYDROXYIMINE
NI
COMPLEXES
91
CONCLUDING
REMARKS
95
ACKNOWLEDGEMENTS
95
REFERENCES
95
CYCLOALIPHATIC
POLYMERS
VIA
LATE
TRANSITION
METAL
CATALYSIS
101
BRIAN
L.
GOODALL
INTRODUCTION
101
THE
ADDITION
POLYMERIZATION
OF
CYCLIC
OLEFINS
104
CYCLOPROPENES
AND
CYCLOBUTENES
104
CYCLOPENTENE
104
NORBORNENES
105
NATURE
AND
SCOPE
OF
THE
CATALYST
107
REACTION
INJECTION
MOLDING
(RIM)
OF
NORBORNENES
108
CATALYST
SYNTHESIS
AND
POLYMERIZATION
OF
NORBOMENE
109
ON
THE
MECHANISM
OF
INITIATION
110
POLY(NORBORNENE)
MICROSTRUCTURE
112
ON
THE
MECHANISM
OF
PROPAGATION
AND
CHAIN
TRANSFER
113
ISOLATION
AND
CHARACTERIZATION
OF
NORBOMENE
OLIGOMERS
119
CONTROL
OF
GLASS
TRANSITION
TEMPERATURE
123
MULTI-COMPONENT
CATALYST
SYSTEMS
125
POLYMERIZATION
OF
NORBOMENES
CONTAINING
FUNCTIONAL
GROUPS
137
POLYMER
PROPERTIES
AND
APPLICATIONS
139
THE
COPOLYMERIZATION
OF
NORBOMENES
WITH
ACYCLIC
MONOMERS
144
COPOLYMERS
WITH
A-OLEFINS
144
NICKEL
CATALYSTS
145
PALLADIUM
CATALYSTS
147
REFERENCES
150
VIII
CONTENTS
5
WELL-DEFINED
TRANSITION
METAL
CATALYSTS
FOR
METATHESIS
POLYMERIZATION
155
MICHAEL
R.
BUCHMEISER
5.1
5.2
5.2.1
5.2.2
5.2.2.1
5.2.2.2
5.2.2.3
5.2.3
5.2.3.1
5.2.4
5.2.4.1
5.2.4.2
5.2.4.3
5.2.5
5.3
5.4
INTRODUCTION
155
TRANSITION
METAL
ALKYLIDENES
156
GROUP
IVA
AND
VA
TRANSITION
METAL-BASED
INITIATORS
156
GROUP
VI
TRANSITION
METAL-BASED
INITIATORS
157
CHROMIUM-BASED
INITIATORS
157
TUNGSTEN-BASED
INITIATORS
157
MOLYBDENUM-BASED
INITIATORS
161
GROUP
VIIA
TRANSITION
METAL-BASED
INITIATORS
170
RHENIUM-BASED
INITIATORS
170
GROUP
VIIIA
TRANSITION
METAL-BASED
INITIATORS
170
RUTHENIUM-BASED
INITIATORS
170
REACTIVITY
OF
RUTHENIUM-BASED
INITIATORS
171
LIGAND
AND
STRUCTURAL
VARIATION
IN
RUTHENIUM-BASED
INITIATORS
174
OSMIUM-BASED
INITIATORS
183
OUTLOOK
183
REFERENCES
183
6
CATALYSIS
IN
ACYCLIC
DIENE
METATHESIS
(ADMET)
POLYMERIZATION
193
STEPHEN
E.
LEHMAN
JR.
AND
KENNETH
B.
WAGENER
6.1
6.2
6.2.1
6.2.2
6.2.3
6.2.4
6.2.5
6.2.6
6.2.7
6.3
6.4
6.5
6.5.1
6.5.2
6.5.2.1
6.5.2.2
6.5.3
6.5.3.1
6.6
6.6.1
6.6.2
6.6.3
6.6.4
6.6.5
INTRODUCTION
193
THE
ADMET
REACTION
195
ADMET:
A
STEP-GROWTH
POLYCONDENSATION
195
FUNCTIONAL
GROUP
TOLERANCE
197
FORMATION
OF
CYCLICS
197
TRANS
METATHESIS
1
98
GENERAL
ADMET
MECHANISM
199
REGIOCHEMICAL
AND
STEREOCHEMICAL
CONSIDERATIONS
201
APPLICATIONS
OF
ADMET
202
CLASSICAL
METATHESIS
CATALYSTS
203
WELL-DEFINED
TUNGSTEN
AND
MOLYBDENUM
CATALYSTS
204
WELL-DEFINED
RUTHENIUM
CATALYSTS
207
EARLY
OBSERVATIONS:
ILL-DEFINED
RUTHENIUM-BASED
CATALYSTS
207
FIRST-GENERATION
GRUBBS
CATALYSTS:
RUC^FPRJ^CHRI
208
SYNTHESIS
AND
ACTIVITY
208
USE
IN
ADMET
210
SECOND-GENERATION
GRUBBS
CATALYSTS:
R
U
C12(NHC)(PR
3
)CHR
I
211
SYNTHESIS
AND
ACTIVITY
211
MECHANISM
OF
ADMET
WITH
GRUBBS
CATALYSTS
214
ROLE
OF
THE
PHOSPHINE
LIGAND:
R
U
C1
2
(PR3)(L)CHR
I
214
ROLE
OF
THE
L
LIGAND:
RUCHFPRSXLJCHRJ
217
ROLE
OF
THE
CARBENE:
THE
SPECIAL
CASE
OF
THE
METHYLIDENE
219
STEREOCHEMICAL
ASPECTS
OF
ADMET
221
CATALYST
DECOMPOSITION
223
CONTENTS
I
IX
6.7
EXPERIMENTAL
CONSIDERATIONS
FOR
ADMET
224
6.7.1
THE
IDEAL
CASE:
BULK
ADMET
WITH
HIGH
VACUUM
224
6.7.2
THE
IDEAL
CASE:
BULK
ADMET
WITH
CARRIER
GAS
224
6.7.3
ADMET
WITH
VOLATILE
MONOMERS
225
6.7.4
VISCOUS
OR
SOLID
MONOMERS
OF
POLYMERS
225
6.8
CONCLUSIONS
AND
OUTLOOK
226
6.9
REFERENCES
226
7
TRANSITION
METAL-CATALYZED
POLYMERIZATION
IN
AQUEOUS
SYSTEMS
231
STEFAN
MERITING
AND
JEROME
P.
CLAVERIE
7.1
INTRODUCTION
231
7.1.1
TRADITIONAL
FREE-RADICAL
POLYMERIZATION
IN
AQUEOUS
SYSTEMS
231
7.1.2
GENERAL
ASPECTS
OF
TRANSITION
METAL-CATALYZED
POLYMERIZATION
IN
AQUEOUS
SYSTEMS
235
7.2
CATALYTIC
OLEFIN
AND
ALKYNE
POLYMERIZATION
IN
AQUEOUS
SYSTEMS
237
7.2.1
HISTORICAL
DEVELOPMENT
237
7.2.2
RECENT
PROGRESSES
IN
CATALYTIC
INSERTION
POLYMERIZATION
OF
OLEFINS
238
7.2.2.1
ALTERNATING
OLEFIN/CARBON
MONOXIDE
COPOLYMERIZATION
239
7.2.2.2
POLYMERIZATION
OF
ETHYLENE
AND
1-OLEFINS
243
7.2.2.3
MISCELLANEOUS
INSERTION
POLYMERIZATIONS
249
7.2.3
RECENT
PROGRESSES
IN
RING
OPENING
METATHESIS
POLYMERIZATION
231
7.2.4
RECENT
PROGRESSES
IN
CATALYTIC
POLYMERIZATION
OF
ALKYNES
254
7.2.4.1
INTRODUCTION
254
7.2.4.2
CATALYTIC
POLYMERIZATION
OF
ALKYNES
IN
AQUEOUS
SYSTEMS
256
7.2.5
SUMMARY
258
7.3
CONTROLLED
FREE-RADICAL
POLYMERIZATION
IN
AQUEOUS
SYSTEMS
WITH
METAL
COMPLEXES
259
7.3.1
GENERAL
FEATURES
OF
ATOM
TRANSFER
RADICAL
POLYMERIZATION
(ATRP)
259
7.3.2
POLYMERIZATION
OF
WATER-SOLUBLE
MONOMERS
BY
ATRP
261
7.3.3
POLYMERIZATION
OF
WATER-INSOLUBLE
MONOMERS
OF
ATRP
264
7.4
POLYMERIZATION
BY
SUZUKI-COUPLING
IN
AQUEOUS
SYSTEMS
266
7.5
CONCLUSIONS
AND
OUTLOOK
268
7.6
REFERENCES
270
8
COPOLYMERIZATION
OF
CARBON
MONOXIDE
WITH
ALKENES
279
GIAMBATTISTA
CONSIGLIO
8.1
INTRODUCTION
279
8.2
COPOLYMERIZATION
CATALYSTS
AND
MECHANISM
280
8.3
STRUCTURE
OF
THE
OLEFIN/CARBON
MONOXIDE
COPOLYMERS
283
8.4
CATALYST
PRECURSORS
FOR
THE
COPOLYMERIZATION
OF
ETHENE
283
8.5
COPOLYMERIZATION
OF
1-OLEFINS
288
8.5.1
COPOLYMERIZATION
OF
STYRENE
(AND
HOMOLOGUES)
288
8.5.2
COPOLYMERIZATION
OF
PROPENE
(AND
OTHER
ALIPHATIC
OLEFINS)
294
8.6
COPOLYMERIZATION
OF
INTERNAL
AND
CYCLIC
OLEFINS
297
8.6.1
CYCLOPOLYMERIZATION
OF
A,-DIENES
299
X
I
CONTENTS
8.7
8.8
CONCLUSIONS
300
REFERENCES
301
9
STRATEGIES
FOR
CATALYTIC
POLYMERIZATION
OF
POLAR
MONOMERS
307
AYUSMAN
SEN
AND
MYEONGSOON
KANG
9.1
9.2
9.3
9.4
INTRODUCTION
307
RESULTS
AND
DISCUSSION
307
CONCLUSION
316
REFERENCES
316
SUBJECT
INDEX
319 |
| any_adam_object | 1 |
| building | Verbundindex |
| bvnumber | BV015735881 |
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| ctrlnum | (OCoLC)50615667 (DE-599)BVBBV015735881 |
| dewey-full | 547/.28 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 547 - Organic chemistry |
| dewey-raw | 547/.28 |
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| discipline | Chemie / Pharmazie Chemie |
| format | Book |
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| id | DE-604.BV015735881 |
| illustrated | Illustrated |
| indexdate | 2024-08-23T00:24:05Z |
| institution | BVB |
| isbn | 3527304355 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-010121791 |
| oclc_num | 50615667 |
| open_access_boolean | |
| owner | DE-703 DE-91G DE-BY-TUM DE-19 DE-BY-UBM DE-29T |
| owner_facet | DE-703 DE-91G DE-BY-TUM DE-19 DE-BY-UBM DE-29T |
| physical | XIV, 331 S. Ill., graph. Darst. : 25 cm |
| publishDate | 2003 |
| publishDateSearch | 2003 |
| publishDateSort | 2003 |
| publisher | Wiley-VCH |
| record_format | marc |
| spelling | Late transition metal polymerization catalysis Bernhard Rieger ... (eds.) Weinheim Wiley-VCH 2003 XIV, 331 S. Ill., graph. Darst. : 25 cm txt rdacontent n rdamedia nc rdacarrier Literaturangaben Homogene katalyse gtt Overgangsmetaalcomplexen gtt Polymerisatie gtt Polymerization Transition metal catalysts Katalyse (DE-588)4029921-1 gnd rswk-swf Polymerisation (DE-588)4046704-1 gnd rswk-swf Übergangsmetallkomplexe (DE-588)4131837-7 gnd rswk-swf Übergangsmetallkomplexe (DE-588)4131837-7 s Polymerisation (DE-588)4046704-1 s Katalyse (DE-588)4029921-1 s DE-604 Rieger, Bernhard Sonstige oth DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=010121791&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Late transition metal polymerization catalysis Homogene katalyse gtt Overgangsmetaalcomplexen gtt Polymerisatie gtt Polymerization Transition metal catalysts Katalyse (DE-588)4029921-1 gnd Polymerisation (DE-588)4046704-1 gnd Übergangsmetallkomplexe (DE-588)4131837-7 gnd |
| subject_GND | (DE-588)4029921-1 (DE-588)4046704-1 (DE-588)4131837-7 |
| title | Late transition metal polymerization catalysis |
| title_auth | Late transition metal polymerization catalysis |
| title_exact_search | Late transition metal polymerization catalysis |
| title_full | Late transition metal polymerization catalysis Bernhard Rieger ... (eds.) |
| title_fullStr | Late transition metal polymerization catalysis Bernhard Rieger ... (eds.) |
| title_full_unstemmed | Late transition metal polymerization catalysis Bernhard Rieger ... (eds.) |
| title_short | Late transition metal polymerization catalysis |
| title_sort | late transition metal polymerization catalysis |
| topic | Homogene katalyse gtt Overgangsmetaalcomplexen gtt Polymerisatie gtt Polymerization Transition metal catalysts Katalyse (DE-588)4029921-1 gnd Polymerisation (DE-588)4046704-1 gnd Übergangsmetallkomplexe (DE-588)4131837-7 gnd |
| topic_facet | Homogene katalyse Overgangsmetaalcomplexen Polymerisatie Polymerization Transition metal catalysts Katalyse Polymerisation Übergangsmetallkomplexe |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=010121791&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT riegerbernhard latetransitionmetalpolymerizationcatalysis |