Self-assembly of block copolymers in external fields:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
2002
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | Bayreuth, Univ., Diss., 2002. - Auch als Online-Diss. mit der URL: http://nbn-resolving.de/urn:nbn:de:bvb:703-opus-132 |
| Beschreibung: | IV, 182 S. Ill., graph. Darst. |
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| 100 | 1 | |a Böker, Alexander |d 1973- |e Verfasser |0 (DE-588)124266835 |4 aut | |
| 245 | 1 | 0 | |a Self-assembly of block copolymers in external fields |c vorgelegt von Alexander Böker |
| 264 | 1 | |c 2002 | |
| 300 | |a IV, 182 S. |b Ill., graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 500 | |a Bayreuth, Univ., Diss., 2002. - Auch als Online-Diss. mit der URL: http://nbn-resolving.de/urn:nbn:de:bvb:703-opus-132 | ||
| 650 | 0 | 7 | |a Blockcopolymere |0 (DE-588)4146026-1 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Struktur |0 (DE-588)4058125-1 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Elektrisches Feld |0 (DE-588)4014211-5 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Domänenstruktur |0 (DE-588)4334475-6 |2 gnd |9 rswk-swf |
| 655 | 7 | |0 (DE-588)4113937-9 |a Hochschulschrift |2 gnd-content | |
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| 689 | 0 | 1 | |a Struktur |0 (DE-588)4058125-1 |D s |
| 689 | 0 | |5 DE-604 | |
| 689 | 1 | 0 | |a Blockcopolymere |0 (DE-588)4146026-1 |D s |
| 689 | 1 | 1 | |a Elektrisches Feld |0 (DE-588)4014211-5 |D s |
| 689 | 1 | |5 DE-604 | |
| 689 | 2 | 0 | |a Blockcopolymere |0 (DE-588)4146026-1 |D s |
| 689 | 2 | 1 | |a Domänenstruktur |0 (DE-588)4334475-6 |D s |
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| 943 | 1 | |a oai:aleph.bib-bvb.de:BVB01-010084868 | |
Datensatz im Suchindex
| _version_ | 1807319684889968640 |
|---|---|
| adam_text |
TABLE
OF
CONTENTS
1.
INTRODUCTION
1
1.1.
MICROPHASE
SEPARATION
OF
BLOCK
COPOLYMERS
2
1.1.1.
THEORETICAL
MODELS
FOR
PHASE
SEPARATION
IN
AB
DIBLOCK
COPOLYMERS
3
1.2.
SURFACE-INDUCED
MICRODOMAIN
STRUCTURES
IN
THIN
BLOCK
COPOLYMER
FILMS
9
1.3.
ALIGNMENT
OF
BLOCK
COPOLYMER
MICROSTRUCTURES
9
1.3.1.
SHEAR
ALIGNMENT
10
1.3
2.
ELECTRIC
FIELD
ALIGNMENT
11
1.3.2.1.
ELECTROTHERMODYNAMICS
OF
MICROPHASE-SEPARATED
BLOCK
COPOLYMERS
11
1.4.
STRUCTURE
OF
THIS
THESIS
16
2.
METHODS
20
2.1.
SYNTHESIS
20
2.1.1.
ANIONIC
POLYMERIZATION
20
2.1.2.
FUNDAMENTALS
OF
ANIONIC
POLYMERIZATION
21
2
1
2.1.
MOLECULAR
WEIGHT
DISTRIBUTION
AND
MECHANISM
21
2.1.2.2.
KINETICS
24
2.2.
CHARACTERIZATION
25
2.2
1.
SCANNING
FORCE
MICROSCOPY
(SFM)
25
2
2.2.
TRANSMISSION
ELECTRON
MICROSCOPY
(TEM)
26
2.2.2.1.
FUNDAMENTALS
OF
TRANSMISSION
ELECTRON
MICROSCOPY
26
2.2.2.2.
STAINING
OF
POLYMER
SAMPLES
28
2.2.23.
RADIATION
DAMAGE
29
2.2.3.
SMALL-ANGLE
X-RAY
SCATTERING
(SAXS)
29
2.23.1.
FUNDAMENTALS
OF
SCATTERING
29
2.23.2.
SMALL-ANGLE
X-RAY
SCATTERING
ON
MICROPHASE-SEPARATED
BLOCK
COPOLYMERS
32
2.2.33.
SETUP
OF
SYNCHROTRON-SAXS
BEAMLINE
(ID02A,
ESRF,
GRENOBLE)
32
3.
NANOSCOPIC
SURFACE
PATTERNS
FROM
FUNCTIONAL
ABC
TRIBLOCK
COPOLYMERS
38
3.1.
INTRODUCTION
39
3.2.
EXPERIMENTAL
SECTION
40
3.2.1.
SOLVENTS
AND
MATERIALS
40
3.2.2.
SYNTHESIS
OF
2-[(TRIMETHYLSILYL)OXY]ETHYL
METHACRYLATE
(TMS-HEMA)
41
3.2.3.
BLOCK
COPOLYMERIZATIONS
41
33.
METHODS
42
3.4.
RESULTS
AND
DISCUSSION
46
3.4.1.
BULK
MORPHOLOGY
OF
ABC
BLOCK
COPOLYMERS
46
3.4.2.
THIN
FILMS
OF
ABC
BLOCK
COPOLYMERS
46
3.4.3.
ULTRATHIN
FILMS
50
3.4.3.1.
ANNEALED
ULTRATHIN
FILMS
55
3.4.3.2.
CONCENTRATION
DEPENDENCE
OF
PATTERN
FORMATION
57
3.4.4.
SCALING
ANALYSIS
60
3.4.4.1.
STRIPED
PATTERNS
61
3.4.4.2
ISLAND-LIKE
PATTERNS
62
3.5.
CONCLUSION
67
4.
WETTING
OF
CHEMICALLY
NANOPATTERNED
MODEL
SURFACES
71
4.1.
INTRODUCTION
72
4.2.
EXPERIMENTAL
SECTION
73
4.2.1.
MATERIALS
AND
METHODS
73
4.2.2.
SAMPLE
PREPARATION
73
43.
RESULTS
74
4.3.1.
STABILITY
OF
POLYSTYRENE
FILMS
ON
A
TRIBLOCK
COPOLYMER
MODEL
SURFACE
75
4.3.1.1.
ANNEALING
75
4.3.1.2.
SOLVENT
VAPOR
TREATMENT
76
4.4.
DISCUSSION
79
4.5.
CONCLUSION
79
5.
LARGE
SCALE
DOMAIN
ALIGNMENT
OF
A
BLOCK
COPOLYMER
FROM
SOLUTION
USING
ELECTRIC
FIELDS
83
5.1.
INTRODUCTION
84
5.2.
EXPERIMENTAL
SECTION
85
53.
RESULTS
88
5.3.1.
FILMS
CAST
AT
ZERO
ELECTRIC
FIELD
88
5.3.2.
FILMS
CAST
IN
THE
PRESENCE
OF
AN
ELECTRIC
FIELD
88
5.4.
DISCUSSION
90
5.5.
CONCLUSION
97
N
6.
MICROSCOPIC
MECHANISMS
OF
ELECTRIC
FIELD
INDUCED
ALIGNMENT
OF
BLOCK
COPOLYMER
MICRODOMAINS
101
6.1.
INTRODUCTION
102
6.2.
EXPERIMENTAL
SECTION
103
6
2.1.
SYNTHESIS
103
6.2.2.
SAMPLE
PREPARATION
103
6.2.3.
VISCOSITY
MEASUREMENTS
104
6.2.4.
SYNCHROTRON
SMALL-ANGLE
X-RAY
SCATTERING
(SYNCHROTRON-SAXS)
104
6.2.5.
TRANSMISSION
ELECTRON
MICROSCOPY
(TEM)
104
6.2.6.
CALCULATION
OF
ORDER
PARAMETERS
105
63.
RESULTS
106
6.3.1.
CONCENTRATION
DEPENDENCE
OF
STRUCTURE
FORMATION
106
6
3.2.
REORIENTATION
BEHAVIOR
OF
PS-D-PI
IN
TOLUENE
108
6.3.3.
KINETICS
AND
MECHANISM
OF
MICROPHASE
ORIENTATION
109
6.3.3.1.
CONCENTRATION
DEPENDENCE
109
6.3.3.2.
ELECTRIC
FIELD
STRENGTH
DEPENDENCE
111
6
3.3
3.
TEMPERATURE
DEPENDENCE
113
6.4.
DISCUSSION
115
6.5.
CONCLUSION
127
7.
THE
INFLUENCE
OF
PHASE
SEPARATION
AND
DIELECTRIC
CONTRAST
ON
THE
ELECTRIC
FIELD
INDUCED
ORIENTATION
OF
LAMELLAR
AC
AND
ABC
BLOCK
COPOLYMER
SOLUTIONS
132
7.1.
INTRODUCTION
133
7.2.
EXPERIMENTAL
SECTION
133
73.
RESULTS
134
7.3.1.
CONCENTRATION
DEPENDENCE
OF
THE
MICRODOMAIN
STRUCTURE
IN
SOLUTION
134
7.3.2.
REORIENTATION
BEHAVIOR
OF
PS-6-PHEMA-6-PMMA
IN
THF
136
7.3.3.
KINETICS
OF
MICROPHASE
ORIENTATION
137
7.3.3.
1.
CONCENTRATION
DEPENDENCE
137
7.3.3.2.
ELECTRIC
FIELD
STRENGTH
DEPENDENCE
139
7.3.3.3.
KINETIC
BEHAVIOR
OF
PS-6-PMMA
DIBLOCK
COPOLYMER
142
7.4.
DISCUSSION
143
7.5.
CONCLUSION
152
III
8.
ELECTRIC
FIELD
INDUCED
ALIGNMENT
OF
HIGH
MOLECULAR
WEIGHT
AB
AND
ABC
BLOCK
COPOLYMERS
WITH
HIGH
DIELECTRIC
CONTRAST
155
8.1.
INTRODUCTION
156
8.2.
EXPERIMENTAL
SECTION
156
8.2.1.
SYNTHESIS
156
83.
RESULTS
AND
DISCUSSION
157
8.3.1.
POLYSTYRENE-FE-POLY(2-VINYL
PYRIDINE)
S50V
J07G
157
8.3.1.1.
CONCENTRATION
DEPENDENCE
OF
THE
MICRODOMAIN
STRUCTURE
IN
SOLUTION
157
8.3.1.2.
REORIENTATION
BEHAVIOR
158
8.3.1.3.
KINETICS
OF
MICROPHASE
ORIENTATION
161
8.3.2.
POLYSTYRENE-D-POLY(RERR-BUTYL
METHACRYLATE)
S
5
O
T$
O
100
166
8.3.3.
POLYSTYRENE-D-POLY(2-VINYLPYRIDINE)-B-POLY(TERT-BUTYL
METHACRYLATE)
S
2
7V
!5
T
3
,
M
AND
S
I
6
V
2
|T
6
,
II
!
168
8.4.
CONCLUSION
172
9.
SUMMARY/ZUSAMMENFASSUNG
175
10.
LIST
OF
PUBLICATIONS
181 |
| any_adam_object | 1 |
| author | Böker, Alexander 1973- |
| author_GND | (DE-588)124266835 |
| author_facet | Böker, Alexander 1973- |
| author_role | aut |
| author_sort | Böker, Alexander 1973- |
| author_variant | a b ab |
| building | Verbundindex |
| bvnumber | BV014963118 |
| classification_rvk | UV 9900 VC 7600 |
| ctrlnum | (OCoLC)643229056 (DE-599)BVBBV014963118 |
| discipline | Chemie / Pharmazie Physik |
| format | Book |
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| genre | (DE-588)4113937-9 Hochschulschrift gnd-content |
| genre_facet | Hochschulschrift |
| id | DE-604.BV014963118 |
| illustrated | Illustrated |
| indexdate | 2024-08-14T00:12:42Z |
| institution | BVB |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-010084868 |
| oclc_num | 643229056 |
| open_access_boolean | |
| owner | DE-703 DE-12 |
| owner_facet | DE-703 DE-12 |
| physical | IV, 182 S. Ill., graph. Darst. |
| publishDate | 2002 |
| publishDateSearch | 2002 |
| publishDateSort | 2002 |
| record_format | marc |
| spelling | Böker, Alexander 1973- Verfasser (DE-588)124266835 aut Self-assembly of block copolymers in external fields vorgelegt von Alexander Böker 2002 IV, 182 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Bayreuth, Univ., Diss., 2002. - Auch als Online-Diss. mit der URL: http://nbn-resolving.de/urn:nbn:de:bvb:703-opus-132 Blockcopolymere (DE-588)4146026-1 gnd rswk-swf Struktur (DE-588)4058125-1 gnd rswk-swf Elektrisches Feld (DE-588)4014211-5 gnd rswk-swf Domänenstruktur (DE-588)4334475-6 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Blockcopolymere (DE-588)4146026-1 s Struktur (DE-588)4058125-1 s DE-604 Elektrisches Feld (DE-588)4014211-5 s Domänenstruktur (DE-588)4334475-6 s DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=010084868&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Böker, Alexander 1973- Self-assembly of block copolymers in external fields Blockcopolymere (DE-588)4146026-1 gnd Struktur (DE-588)4058125-1 gnd Elektrisches Feld (DE-588)4014211-5 gnd Domänenstruktur (DE-588)4334475-6 gnd |
| subject_GND | (DE-588)4146026-1 (DE-588)4058125-1 (DE-588)4014211-5 (DE-588)4334475-6 (DE-588)4113937-9 |
| title | Self-assembly of block copolymers in external fields |
| title_auth | Self-assembly of block copolymers in external fields |
| title_exact_search | Self-assembly of block copolymers in external fields |
| title_full | Self-assembly of block copolymers in external fields vorgelegt von Alexander Böker |
| title_fullStr | Self-assembly of block copolymers in external fields vorgelegt von Alexander Böker |
| title_full_unstemmed | Self-assembly of block copolymers in external fields vorgelegt von Alexander Böker |
| title_short | Self-assembly of block copolymers in external fields |
| title_sort | self assembly of block copolymers in external fields |
| topic | Blockcopolymere (DE-588)4146026-1 gnd Struktur (DE-588)4058125-1 gnd Elektrisches Feld (DE-588)4014211-5 gnd Domänenstruktur (DE-588)4334475-6 gnd |
| topic_facet | Blockcopolymere Struktur Elektrisches Feld Domänenstruktur Hochschulschrift |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=010084868&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT bokeralexander selfassemblyofblockcopolymersinexternalfields |