Verfügbarkeit: Phase separation in soft matter physics

Phase separation in soft matter physics: micellar solutions, microemulsions, critical phenomena

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Bibliographische Detailangaben
Hauptverfasser:	Chabibullaev, Pulat K. (VerfasserIn), Saidov, Abdulla A. (VerfasserIn)
Format:	Buch
Sprache:	English
Veröffentlicht:	Berlin [u.a.] Springer 2003
Schriftenreihe:	Springer series in solid-state sciences 138
Schlagworte:	Critical phenomena > (Physics) Phase transformations > (Statistical physics) Soft condensed matter Phasenumwandlung Mehrstoffsystem Kritisches Phänomen Lösung > Chemie
Online-Zugang:	Inhaltsverzeichnis
Beschreibung:	Literaturverz. S.169 - 180
Beschreibung:	IX, 180 S. graph. Darst. : 24 cm
ISBN:	3540438904

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Datensatz im Suchindex

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adam_text	CONTENTS 1. INTRODUCTION .............................................. 1 2. ACOUSTIC SPECTROSCOPY OF IDEAL SOLUTIONS .................. 7 2.1 DENSITY . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8 2.2 VISCOSITY . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8 2.3 ULTRASOUND VELOCITY, COMPRESSIBILITY, AND HEAT CAPACITY . . . . 12 2.4 ULTRASONIC ABSORPTION . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14 3. PHASE-SEPARATING SOLUTIONS ............................... 23 3.1 HYDROGEN BONDS IN SOLUTIONS WITH LOWER PHASE-SEPARATION CRITICAL POINT . . . . . . . . . . . . . . . . 23 3.2 PHASE DIAGRAMS OF PHASE-SEPARATING SOLUTIONS. ORDER PARAMETER . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 25 3.3 PHASE DIAGRAMS OF BINARY SOLUTIONS WITH ONE CRITICAL POINT . 27 3.4 BINARY AND TERNARY SOLUTIONS WITH CLOSED PHASE-SEPARATION REGION . . . . . . . . . . . . . . . . . . . . . 27 4. DYNAMICS OF STATES CLOSE TO CRITICAL ...................... 37 4.1 LOW FREQUENCY ACOUSTIC SPECTROSCOPY OF WEAKLY ABSORBING LIQUIDS. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 37 4.2 ACOUSTIC SPECTROSCOPY OF CRITICAL SOLUTIONS WITH LOW SOUND ABSORPTION . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 39 4.3 ACOUSTIC PERTURBATION AND CORRELATION RADIUS OF FLUCTUATIONS IN THE VICINITY OF A CRITICAL POINT . . . . . . . . . . . 43 4.4 CHEMICAL REACTIONS IN NEAR-CRITICAL STATES . . . . . . . . . . . . . . . . 45 4.5 KINETICS OF MONO- AND BIMOLECULAR REACTIONS CLOSE TO A PHASE-SEPARATION CRITICAL POINT . . . . . . . . . . . . . . . . . 46 5. PHYSICS OF SOLUTIONS WITH DOUBLE CRITICAL POINT ........... 53 5.1 THEORY OF SOLUTIONS WITH DOUBLE CRITICAL POINT . . . . . . . . . . . . . 54 5.2 RAYLEIGH SCATTERING OF LIGHT . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 55 5.3 DYNAMICS OF NEAR-CRITICAL STATES OF SOLUTIONS WITH A DCP . . . 62 5.4 SHEAR VISCOSITY . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 63 5.5 SOUND PROPAGATION . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 67 VIII CONTENTS 6. MICELLIZATION AS A PHASE TRANSITION ....................... 71 6.1 CONCEPTUAL EXPERIMENTS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 71 6.2 ELECTRONIC STRUCTURE OF HYDROCARBON CHAINS OF MOLECULES . . . . 75 6.3 FLUCTUON MODEL OF MICELLIZATION . . . . . . . . . . . . . . . . . . . . . . . . . . 77 6.4 GREEN FUNCTION METHOD . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 80 6.5 81 6.6 CRITICAL MICELLIZATION CONCENTRATION. . . . . . . . . . . . . . . . . . . . . . . 84 6.7 88 6.8 PHASE TRANSITIONS AT MICELLIZATION IN SOLUTIONS OF IONIC MOLECULES . . . . . . . . . . . . . . . . . . . . . . . . . . . 90 6.9 KINETICS OF MICELLAR AND PRE-MICELLAR ASSOCIATIONS . . . . . . . . . . 93 6.10 MICELLIZATION UNDER INTENSIFICATION OF MOLECULAR MASS TRANSFER . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 101 6.11 MICELLIZATION IN THE ELECTRIC FIELD OF CHARGED ADMIXTURES . . . 105 7. FLUCTUATION MECHANISM OF FORCED SPINODAL DECOMPOSITION ........................ 113 7.1 SPINODAL DECOMPOSITION AS A MODEL FOR MICROEMULSION FORMATION . . . . . . . . . . . . . . . . . . 113 7.2 NON-EQUILIBRIUM STATES IN PHASE-SEPARATING BINARY LIQUIDS AND EXTERNAL PERTURBATIONS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 119 7.2.1 VARIABLE ELECTRIC FIELD . . . . . . . . . . . . . . . . . . . . . . . . . . . . 121 7.2.2 ULTRASOUND . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 122 7.2.3 THERMAL ACTION . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 122 7.2.4 OPTOTHERMAL INFLUENCE . . . . . . . . . . . . . . . . . . . . . . . . . . . . 123 7.2.5 NOISE FIELD . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 123 7.2.6 TURBULENCE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 124 7.2.7 SHEAR FLOW . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 124 7.2.8 CENTRIFUGAL FORCES . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 125 7.2.9 STIRRING . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 126 7.3 EXTERNAL PERTURBATION AND SPINODAL DECOMPOSITION . . . . . . . . . 128 7.3.1 HEATING OF A SYSTEM WITHOUT STIRRING . . . . . . . . . . . . . . . 129 7.3.2 HEATING OF A SYSTEM BY STIRRING . . . . . . . . . . . . . . . . . . . . 131 7.4 STATISTICAL ACCOUNT OF AN EXTERNAL STIRRING FIELD . . . . . . . . . . . . 133 8. WEAK STIRRING AND ABSOLUTE INSTABILITY PHENOMENA ....... 139 8.1 SINGULARITY IN THE HEAT CAPACITY IN FORCED SPINODAL DECOMPOSITION . . . . . . . . . . . . . . . . . . . . . . . . 139 8.2 EXTENDING THE REGION OF ABSOLUTE INSTABILITY . . . . . . . . . . . . . . . 142 8.3 INITIAL STAGE KINETICS OF FORCED SPINODAL DECOMPOSITION . . . . . 145 9. MICROHETEROPHASE RELAXATION STATE ....................... 147 9.1 RELAXATION STATE NEAR THE BOUNDARY OF ABSOLUTE INSTABILITY UNDER WEAK PERTURBATION . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 147 MICELLIZATION AS A PHASE TRANSITION OF FINITE TYPE .......... HUCKEL*S METHOD OF MOLECULAR ORBITALS ................... CONTENTS IX 9.3 THERMAL RELAXATION EFFECTS IN THE CELLULAR STRUCTURE . . . . . . . . 152 10. TRANSITION FROM EMULSION TO MICROEMULSION .............. 155 10.1 MICROEMULSION STRUCTURE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 155 10.2 POLYCHRONAL RELAXATION PROCESSES AND DISPERSION ON THE INTERFACE . . . . . . . . . . . . . . . . . . . . . . . . . . 158 10.3 STABLE MICROHETEROPHASE STATE ON THE INTERFACE OF WEAKLY DISSOLVED LIQUIDS . . . . . . . . . . . . . . . 161 10.4 CONCLUSION . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 166 9.2 SURFACE TENSION ENERGY AND HEAT ABSORPTION EFFECT . . . . . . . . 150 REFERENCES .................................................... 169
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spelling	Chabibullaev, Pulat K. Verfasser aut Phase separation in soft matter physics micellar solutions, microemulsions, critical phenomena Pulat K. Khabibullaev ; Abdulla A. Saidov Berlin [u.a.] Springer 2003 IX, 180 S. graph. Darst. : 24 cm txt rdacontent n rdamedia nc rdacarrier Springer series in solid state sciences 138 Physics and astronomy online library Literaturverz. S.169 - 180 Critical phenomena (Physics) Phase transformations (Statistical physics) Soft condensed matter Phasenumwandlung (DE-588)4132140-6 gnd rswk-swf Mehrstoffsystem (DE-588)4132152-2 gnd rswk-swf Kritisches Phänomen (DE-588)4165788-3 gnd rswk-swf Lösung Chemie (DE-588)4036159-7 gnd rswk-swf Lösung Chemie (DE-588)4036159-7 s Mehrstoffsystem (DE-588)4132152-2 s Phasenumwandlung (DE-588)4132140-6 s Kritisches Phänomen (DE-588)4165788-3 s DE-604 Saidov, Abdulla A. Verfasser aut Springer series in solid-state sciences 138 (DE-604)BV000016582 138 SWB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=010022047&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis
spellingShingle	Chabibullaev, Pulat K. Saidov, Abdulla A. Phase separation in soft matter physics micellar solutions, microemulsions, critical phenomena Springer series in solid-state sciences Critical phenomena (Physics) Phase transformations (Statistical physics) Soft condensed matter Phasenumwandlung (DE-588)4132140-6 gnd Mehrstoffsystem (DE-588)4132152-2 gnd Kritisches Phänomen (DE-588)4165788-3 gnd Lösung Chemie (DE-588)4036159-7 gnd
subject_GND	(DE-588)4132140-6 (DE-588)4132152-2 (DE-588)4165788-3 (DE-588)4036159-7
title	Phase separation in soft matter physics micellar solutions, microemulsions, critical phenomena
title_auth	Phase separation in soft matter physics micellar solutions, microemulsions, critical phenomena
title_exact_search	Phase separation in soft matter physics micellar solutions, microemulsions, critical phenomena
title_full	Phase separation in soft matter physics micellar solutions, microemulsions, critical phenomena Pulat K. Khabibullaev ; Abdulla A. Saidov
title_fullStr	Phase separation in soft matter physics micellar solutions, microemulsions, critical phenomena Pulat K. Khabibullaev ; Abdulla A. Saidov
title_full_unstemmed	Phase separation in soft matter physics micellar solutions, microemulsions, critical phenomena Pulat K. Khabibullaev ; Abdulla A. Saidov
title_short	Phase separation in soft matter physics
title_sort	phase separation in soft matter physics micellar solutions microemulsions critical phenomena
title_sub	micellar solutions, microemulsions, critical phenomena
topic	Critical phenomena (Physics) Phase transformations (Statistical physics) Soft condensed matter Phasenumwandlung (DE-588)4132140-6 gnd Mehrstoffsystem (DE-588)4132152-2 gnd Kritisches Phänomen (DE-588)4165788-3 gnd Lösung Chemie (DE-588)4036159-7 gnd
topic_facet	Critical phenomena (Physics) Phase transformations (Statistical physics) Soft condensed matter Phasenumwandlung Mehrstoffsystem Kritisches Phänomen Lösung Chemie
url	http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=010022047&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA
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