Cation binding by humic substances:
"Humic substances are highly abundant organic compounds formed in soils and sediments by the decay of dead plants, microbes and animals. This book focuses on the important binding properties of these compounds that regulate the chemical reactivity and bioavailability of hydrogen and metal ions...
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Cambridge
Cambridge University Press
2002
|
| Ausgabe: | 1. publ. |
| Schriftenreihe: | Cambridge environmental chemistry series
12 |
| Schlagworte: | |
| Online-Zugang: | Publisher description Table of contents Inhaltsverzeichnis |
| Zusammenfassung: | "Humic substances are highly abundant organic compounds formed in soils and sediments by the decay of dead plants, microbes and animals. This book focuses on the important binding properties of these compounds that regulate the chemical reactivity and bioavailability of hydrogen and metal ions in the natural environment." "This comprehensive account of cation binding by humic matter is a valuable resource for advanced undergraduate and graduate students, environmental scientists, ecologists and geochemists."--BOOK JACKET. |
| Beschreibung: | Includes bibliographical references (p. [391]-421) and index |
| Beschreibung: | X, 434 S. graph. Darst. |
| ISBN: | 0521621461 |
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| 650 | 7 | |a Bioquímica |2 larpcal | |
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Datensatz im Suchindex
| _version_ | 1804129430584426496 |
|---|---|
| adam_text | CATION BINDING BY HUMIC SUBSTANCES EDWARD TIPPING CENTRE FOR ECOLOGY AND
HYDROLOGY, WINDERMERE, UK CAMBRIDGE UNIVERSITY PRESS CONTENTS O O O O O
O O O O O O O O O O O O O O PREFACE IX 1 INTRODUCTION / 2 HUMIC
SUBSTANCES - A BRIEF REVIEW 4 2.1 NATURAL ORGANIC MATTER AND HUMIC
SUBSTANCES 4 2.2 ISOLATION AND CLASSIFICATION OF HUMIC SUBSTANCES 6 2.3
FORMATION AND DECOMPOSITION OF HUMIC SUBSTANCES 10 2.4 CHEMICAL AND
PHYSICAL PROPERTIES OF HUMIC SUBSTANCES 13 2.5 ENVIRONMENTAL
CONCENTRATIONS OF HUMIC SUBSTANCES 24 2.6 HUMIC SUBSTANCES - ACCIDENT OR
DESIGN? 30 3 ENVIRONMENTAL SOLUTION AND SURFACE CHEMISTRY 32 3.1
SOLUTIONS AND SOLUTES 32 3.2 NATURAL PARTICULATE MATTER 34 , 3.3
PHYSICO-CHEMICAL INTERACTIONS IN ENVIRONMENTAL AQUEOUS SYSTEMS 37 3.4
EQUILIBRIUM AND KINETICS 44 3.5 CHEMICAL SPECIATION 45 3.6 CALCULATION
OF EQUILIBRIUM CONCENTRATIONS 46 4 PROTON DISSOCIATION FROM WEAK ACIDS
52 4.1 ACIDS AND BASES 52 4.2 BUFFERING 55 4.3 KINETICS 55 4.4 DIPROTIC
ACIDS 57 4.5 EXTENSION TO HIGHER POLYPROTIC ACIDS 59 4.6 ELECTROSTATIC
INTERACTIONS AMONG SITES 61 4.7 PROTON DISSOCIATION FROM WELL-DEFINED
POLYMERS 73 4.8 PROTON DISSOCIATION FROM HUMIC SUBSTANCES 76 VI CONTENTS
5 METAL-LIGAND INTERACTIONS 77 5.1 COORDINATION 77 5.2 CHEMICAL
EQUILIBRIA INVOLVING METAL IONS, PROTONS AND SIMPLE WEAK ACID LIGANDS 86
5.3 MULTISITE LIGANDS 98 5.4 ELECTROSTATIC INTERACTIONS 99 5.5 RESULTS
WITH WELL-DEFINED MACROMOLECULES 99 6 METHODS FOR MEASURING CATION
BINDING BY HUMIC SUBSTANCES 103 6.1 THE HUMIC SAMPLE 103 6.2
DETERMINATION OF PROTON BINDING BY POTENTIOMETRY 104 6.3 ANALYTICAL
DETERMINATION OF ACID GROUP CONTENTS 108 6.4 DIRECT MEASUREMENT OF
EQUILIBRIUM METAL BINDING - PRINCIPLES 110 6.5 SEPARATION METHODS TO
QUANTIFY EQUILIBRIUM METAL BINDING 113 6.6 COMPETITION METHODS 119 6.7
ELECTROCHEMICAL TECHNIQUES 121 6.8 SPECTROSCOPIC METHODS 123 6.9
MEASUREMENT OF THE KINETICS OF METAL-HUMIC INTERACTIONS 126 7
QUANTITATIVE RESULTS WITH ISOLATED HUMIC SUBSTANCES 128 7.1 PROTON
DISSOCIATION 128 7.2 EQUILIBRIUM BINDING OF METAL IONS 136 7.3 KINETICS
OF METAL ION BINDING 151 8 CATION BINDING SITES IN HUMIC SUBSTANCES 157
8.1 PROTON-DISSOCIATING GROUPS 157 8.2 BINDING SITES FOR METALS -
INFORMATION FROM BINDING STUDIES 759 8.3 INFORMATION FROM SPECTROSCOPY
162 8.4 VISCOMETRY 169 8.5 SUMMARY 169 9 PARAMETERISED MODELS OF
CATION-HUMIC INTERACTIONS 171 9.1 OVERVIEW AND PHILOSOPHY 171 9.2 MODELS
THAT DESCRIBE THE BINDING OF A SINGLE CATION 173 9.3 SIMPLER MODELS THAT
INCLUDE COMPETITION 183 9.4 THE SITE HETEROGENEITY/POLYELECTROLYTE
MODELS OF MARINSKY AND COLLEAGUES 192 9.5 MODELLING ELECTROSTATIC
EFFECTS IN HUMIC SUBSTANCES 194 9.6 HUMIC ION-BINDING MODELS V AND VI
201 9.7 THE NICA AND NICCA MODELS 206 9.8 SUMMARY 209 CONTENTS VII 10
APPLICATIONS OF COMPREHENSIVE PARAMETERISED MODELS 210 10.1 INTERACTIONS
WITH PROTONS 210 10.2 BINDING OF SINGLE METAL CATIONS INTERPRETED WITH
MODEL V 216 10.3 BINDING OF SINGLE METAL CATIONS INTERPRETED WITH MODEL
VI 220 10.4 APPLICATION OF THE NICCA MODEL 229 10.5 METAL BINDING AS A
FUNCTION OF IONIC STRENGTH 235 10.6 NON-SPECIFIC BINDING 240 10.7
COMPETITION BETWEEN METALS 240 10.8 PROTON-METAL EXCHANGE 246 10.9
COMPARISON OF THE NICCA-DONNAN MODEL AND MODEL VI 249 10.10 APPLICATIONS
OF THE MODELS TO FIELD SITUATIONS 251 11 PREDICTIVE MODELLING 253 11.1
ELECTROSTATIC INTERACTIONS 253 11.2 BINDING SITES 254 11.3 PROSPECTS FOR
PREDICTIVE MODELLING 260 12 CATION-HUMIC BINDING AND OTHER
PHYSICO-CHEMICAL PROCESSES 262 12.1 THE CONFORMATION OF HUMIC MATTER 262
12.2 AGGREGATION OF HUMIC SUBSTANCES 266 12.3 ADSORPTION OF HUMIC
SUBSTANCES BY MINERAL SURFACES 270 12.4 BINDING OF ORGANIC CATIONS BY
HUMIC SUBSTANCES 278 12.5 COLLOID STABILITY 278 12.6 DISSOLUTION OF
MINERALS 282 12.7 FORMATION OF MINERAL PRECIPITATES 285 12.8 OTHER
PROCESSES 287 12.9 CONCLUDING REMARKS 287 13 CATION BINDING BY HUMIC
SUBSTANCES IN NATURAL WATERS 288 13.1 CHEMICAL SPECIATION CALCULATIONS
288 13.2 INTERACTIONS WITH MAJOR IONS AND PROTONS 290 13.3 INTERACTIONS
OF HUMIC SUBSTANCES WITH MAJOR CATIONS 301 13.4 COMPETITION 308 13.5
INTERACTIONS OF HEAVY METALS WITH HUMIC SUBSTANCES IN NATURAL WATERS 315
13.6 MODELLING HEAVY METAL SPECIATION IN NATURAL WATERS 320 13.7
INTERACTIONS WITH METALLIC RADIONUCLIDES 331 13.8 BINDING BY DISSOLVED
HUMIC MATTER COMPARED TO ADSORPTION BY SUSPENDED PARTICULATES 331 VIII
CONTENTS 14 CATION BINDING BY HUMIC SUBSTANCES IN SOILS AND SEDIMENTS
334 14.1 COMPONENTS OF THE SOIL SYSTEM 335 14.2 SORPTION OF MAJOR
CATIONS BY ORGANIC-RICH ACID SOILS 339 14.3 SORPTION OF MAJOR CATIONS BY
MINERAL SOILS 347 14.4 SORPTION OF TRACE CATIONS BY SOIL SOLIDS 352 14.5
DISSOLVED ORGANIC MATTER (DOM) IN SOIL SOLUTION 359 14.6 COLLOIDS IN
SOIL AND AQUIFER POREWATERS 371 14.7 CATION-HUMIC INTERACTIONS IN
SEDIMENTS 371 15 RESEARCH NEEDS 380 15.1 RESEARCH NEEDS FOR ISOLATED
HUMIC MATERIALS 380 15.2 RESEARCH NEEDS IN FIELD STUDIES 385 15.3
CATION-HUMIC INTERACTIONS IN CATCHMENTS 387 REFERENCES 391 INDEX 422
|
| any_adam_object | 1 |
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| discipline | Geowissenschaften Biologie Chemie Geographie |
| edition | 1. publ. |
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| id | DE-604.BV014682465 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T19:05:01Z |
| institution | BVB |
| isbn | 0521621461 |
| language | English |
| lccn | 2001043867 |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-009959012 |
| oclc_num | 48046054 |
| open_access_boolean | |
| owner | DE-703 DE-M49 DE-BY-TUM DE-634 |
| owner_facet | DE-703 DE-M49 DE-BY-TUM DE-634 |
| physical | X, 434 S. graph. Darst. |
| publishDate | 2002 |
| publishDateSearch | 2002 |
| publishDateSort | 2002 |
| publisher | Cambridge University Press |
| record_format | marc |
| series | Cambridge environmental chemistry series |
| series2 | Cambridge environmental chemistry series |
| spelling | Tipping, Edward Verfasser aut Cation binding by humic substances Edward Tipping 1. publ. Cambridge Cambridge University Press 2002 X, 434 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Cambridge environmental chemistry series 12 Includes bibliographical references (p. [391]-421) and index "Humic substances are highly abundant organic compounds formed in soils and sediments by the decay of dead plants, microbes and animals. This book focuses on the important binding properties of these compounds that regulate the chemical reactivity and bioavailability of hydrogen and metal ions in the natural environment." "This comprehensive account of cation binding by humic matter is a valuable resource for advanced undergraduate and graduate students, environmental scientists, ecologists and geochemists."--BOOK JACKET. Acides humiques - Dérivés Bioquímica larpcal Cations Húmus larpcal Ligands (Biochimie) - Fixation - Modèles mathématiques Química ambiental larpcal Mathematisches Modell Humic acid Derivatives Ligand binding (Biochemistry) Mathematical models Umweltgeochemie (DE-588)4404136-6 gnd rswk-swf Kation (DE-588)4163478-0 gnd rswk-swf Ligand (DE-588)4035711-9 gnd rswk-swf Physikalische Chemie (DE-588)4045959-7 gnd rswk-swf Chemische Bindung (DE-588)4009843-6 gnd rswk-swf Huminstoff (DE-588)4026165-7 gnd rswk-swf Wechselwirkung (DE-588)4064937-4 gnd rswk-swf Mathematisches Modell (DE-588)4114528-8 gnd rswk-swf Huminsäuren (DE-588)4160791-0 gnd rswk-swf Huminsäuren (DE-588)4160791-0 s Wechselwirkung (DE-588)4064937-4 s Kation (DE-588)4163478-0 s Mathematisches Modell (DE-588)4114528-8 s DE-604 Chemische Bindung (DE-588)4009843-6 s Physikalische Chemie (DE-588)4045959-7 s Umweltgeochemie (DE-588)4404136-6 s 1\p DE-604 Huminstoff (DE-588)4026165-7 s Ligand (DE-588)4035711-9 s 2\p DE-604 Cambridge environmental chemistry series 12 (DE-604)BV004588434 12 http://www.loc.gov/catdir/description/cam022/2001043867.html Publisher description http://www.loc.gov/catdir/toc/cam022/2001043867.html Table of contents GBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009959012&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 2\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | Tipping, Edward Cation binding by humic substances Cambridge environmental chemistry series Acides humiques - Dérivés Bioquímica larpcal Cations Húmus larpcal Ligands (Biochimie) - Fixation - Modèles mathématiques Química ambiental larpcal Mathematisches Modell Humic acid Derivatives Ligand binding (Biochemistry) Mathematical models Umweltgeochemie (DE-588)4404136-6 gnd Kation (DE-588)4163478-0 gnd Ligand (DE-588)4035711-9 gnd Physikalische Chemie (DE-588)4045959-7 gnd Chemische Bindung (DE-588)4009843-6 gnd Huminstoff (DE-588)4026165-7 gnd Wechselwirkung (DE-588)4064937-4 gnd Mathematisches Modell (DE-588)4114528-8 gnd Huminsäuren (DE-588)4160791-0 gnd |
| subject_GND | (DE-588)4404136-6 (DE-588)4163478-0 (DE-588)4035711-9 (DE-588)4045959-7 (DE-588)4009843-6 (DE-588)4026165-7 (DE-588)4064937-4 (DE-588)4114528-8 (DE-588)4160791-0 |
| title | Cation binding by humic substances |
| title_auth | Cation binding by humic substances |
| title_exact_search | Cation binding by humic substances |
| title_full | Cation binding by humic substances Edward Tipping |
| title_fullStr | Cation binding by humic substances Edward Tipping |
| title_full_unstemmed | Cation binding by humic substances Edward Tipping |
| title_short | Cation binding by humic substances |
| title_sort | cation binding by humic substances |
| topic | Acides humiques - Dérivés Bioquímica larpcal Cations Húmus larpcal Ligands (Biochimie) - Fixation - Modèles mathématiques Química ambiental larpcal Mathematisches Modell Humic acid Derivatives Ligand binding (Biochemistry) Mathematical models Umweltgeochemie (DE-588)4404136-6 gnd Kation (DE-588)4163478-0 gnd Ligand (DE-588)4035711-9 gnd Physikalische Chemie (DE-588)4045959-7 gnd Chemische Bindung (DE-588)4009843-6 gnd Huminstoff (DE-588)4026165-7 gnd Wechselwirkung (DE-588)4064937-4 gnd Mathematisches Modell (DE-588)4114528-8 gnd Huminsäuren (DE-588)4160791-0 gnd |
| topic_facet | Acides humiques - Dérivés Bioquímica Cations Húmus Ligands (Biochimie) - Fixation - Modèles mathématiques Química ambiental Mathematisches Modell Humic acid Derivatives Ligand binding (Biochemistry) Mathematical models Umweltgeochemie Kation Ligand Physikalische Chemie Chemische Bindung Huminstoff Wechselwirkung Huminsäuren |
| url | http://www.loc.gov/catdir/description/cam022/2001043867.html http://www.loc.gov/catdir/toc/cam022/2001043867.html http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009959012&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| volume_link | (DE-604)BV004588434 |
| work_keys_str_mv | AT tippingedward cationbindingbyhumicsubstances |