Environmental organic chemistry:
Gespeichert in:
| Hauptverfasser: | , , |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
New York [u.a.]
Wiley
2003
|
| Ausgabe: | 2. ed. |
| Schriftenreihe: | Wiley-interscience
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XIII, 1313 S. graph. Darst. |
| ISBN: | 0471350532 0471357502 |
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Datensatz im Suchindex
| _version_ | 1804129406034116608 |
|---|---|
| adam_text | ENVIRONMENTAL ORGANIC CHEMISTRY SECOND EDITION RENE P. SCHWARZENBACH
PHILIP M. GSCHWEND DIETER M. IMBODEN WILEY-INTERSCIENCE A JOHN WILEY &
SONS, INC., PUBLICATION CONTENTS PREFACE XI PARTI INTRODUCTION 1 GENERAL
TOPIC AND OVERVIEW 1.1 INTRODUCTION / 4 1.2 ASSESSING ORGANIC CHEMICALS
IN THE ENVIRONMENT: 1 3 1.3 THE NEEDS AND THE TASKS / 6 WHAT IS THIS
BOOK ALL ABOUT? / 8 2 AN INTRODUCTION TO ENVIRONMENTAL ORGANIC CHEMICALS
2.1 INTRODUCTION/ 14 2.2 THE MAKEUP OF ORGANIC COMPOUNDS /14 2.3
CLASSIFICATION, NOMENCLATURE, AND EXAMPLES OF ENVIRONMENTAL ORGANIC
CHEMICALS / 31 2.4 QUESTIONS AND PROBLEMS/51 13 PART II EQUILIBRIUM
PARTITIONING BETWEEN GASEOUS, LIQUID, AND SOLID PHASES 55 57 3
PARTITIONING: MOLECULAR INTERACTIONS AND THERMODYNAMICS 3.1 INTRODUCTION
/ 59 3.2 MOLECULAR INTERACTIONS DETERMINING THE PARTITIONING OF ORGANIC
COMPOUNDS BETWEEN DIFFERENT PHASES / 59 3.3 USING THERMODYNAMIC
FUNCTIONS TO QUANTIFY MOLECULAR ENERGIES / 73 3.4 USING THERMODYNAIMC
FUNCTIONS TO QUANTIFY EQUILIBRIUM PARTITIONING / 84 3.5 USING PARTITION
CONSTANTS/COEFFICIENTS TO ASSESS THE EQUILIBRIUM DISTRIBUTION OF NEUTRAL
ORGANIC COMPOUNDS IN MULTIPHASE SYSTEMS / 93 3.6 QUESTIONS AND PROBLEMS
/ 95 VI 4 VAPOR PRESSURE 97 4.1 INTRODUCTION / 98 4.2 THEORETICAL
BACKGROUND / 98 4.3 MOLECULAR INTERACTIONS GOVERNING VAPOR PRESSURE /110
4.4 AVAILABILITY OF EXPERIMENTAL VAPOR PRESSURE DATA AND ESTIMATION
METHODS /118 4.5 QUESTIONS AND PROBLEMS /126 5 ACTIVITY COEFFICIENT AND
SOLUBILITY IN WATER 133 5.1 INTRODUCTION/135 5.2 THERMODYNAMIC
CONSIDERATIONS /135 5.3 MOLECULAR INTERPRETATION OF THE EXCESS FREE
ENERGY OF ORGANIC COMPOUNDS IN AQUEOUS SOLUTIONS /142 5.4 EFFECT OF
TEMPERATURE AND SOLUTION COMPOSITION ON AQUEOUS SOLUBILITY AND ACTIVITY
COEFFICIENT/154 5.5 AVAILABILITY OF EXPERIMENTAL DATA; METHODS FOR
ESTIMATION OF AQUEOUS ACTIVITY COEFFICIENT AND AQUEOUS SOLUBILITY / 172
5.6 QUESTIONS AND PROBLEMS /175 6 AIR-ORGANIC SOLVENT AND AIR-WATER
PARTITIONING 181 6.1 INTRODUCTION/182 6.2 THERMODYNAMIC CONSIDERATIONS /
183 6.3 AIR-ORGANIC SOLVENT PARTITIONING / 185 6.4 AIR-WATER
PARTITIONING/197 6.5 QUESTIONS AND PROBLEMS / 208 7 ORGANIC LIQUID-WATER
PARTITIONING 213 7.1 INTRODUCTION/ 214 7.2 THERMODYNAMIC CONSIDERATIONS
/ 214 7.3 COMPARISON OF DIFFERENT ORGANIC SOLVENT-WATER SYSTEMS / 216
7.4 THE RC-OCTANOL-WATER PARTITION CONSTANT / 223 7.5 DISSOLUTION OF
ORGANIC COMPOUNDS IN WATER FROM ORGANIC LIQUID MIXTURES*EQUILIBRIUM
CONSIDERATIONS (ADVANCED TOPIC) / 235 7.6 QUESTIONS AND PROBLEMS / 239 8
ORGANIC ACIDS AND BASES: ACIDITY CONSTANT AND PARTITIONING BEHAVIOR 245
8.1 INTRODUCTION / 246 8.2 THERMODYNAMIC CONSIDERATIONS / 246 8.3
CHEMICAL STRUCTURE AND ACIDITY CONSTANT / 256 VII 8.4 AVAILABILITY OF
EXPERIMENTAL DATA; METHODS FOR ESTIMATION OF ACIDITY CONSTANTS / 261 8.5
AQUEOUS SOLUBILITY AND PARTITIONING BEHAVIOR OF ORGANIC ACIDS AND BASES
/ 268 8.6 QUESTIONS AND PROBLEMS / 272 9 SORPTION I: GENERAL
INTRODUCTION AND SORPTION PROCESSES INVOLVING ORGANIC MATTER 275 9.1
INTRODUCTION / 277 , 9.2 SORPTION ISOTHERMS, SOLID-WATER DISTRIBUTION
COEFFICIENTS (K ID ), AND THE FRACTION DISSOLVED (/J W ) / 280 9.3
SORPTION OF NEUTRAL ORGANIC COMPOUNDS FROM WATER TO SOLID-PHASE ORGANIC
MATTER (POM) / 291 9.4 SORPTION OF NEUTRAL COMPOUNDS TO DISSOLVED
ORGANIC MATTER (DOM) / 314 9.5 SORPTION OF ORGANIC ACIDS AND BASES TO
NATURAL ORGANIC MATTER (NOM) / 321 9.6 QUESTIONS AND PROBLEMS / 326 10
SORPTION II: PARTITIONING TO LIVING MEDIA - BIOACCUMULATION AND BASELINE
TOXICITY 331 10.1 INTRODUCTION / 333 10.2 PARTITIONING TO DEFINED
BIOMEDIA / 335 10.3 BIOACCUMULATION IN AQUATIC SYSTEMS / 349 10.4
BIOACCUMULATION IN TERRESTRIAL SYSTEMS / 361 10.5 BIOMAGNIFICATION / 366
10.6 BASELINE TOXICITY (NARCOSIS) / 374 10.7 QUESTIONS AND PROBLEMS/381
11 SORPTION III: SORPTION PROCESSES INVOLVING INORGANIC SURFACES 387
11.1 INTRODUCTION/389 11.2 ADSORPTION OF NOHIPNIC ORGANIC COMPOUNDS TO
INORGANIC SURFACES FROM AIR / 391 11.3 SORPTION OF NBNIONIC ORGANIC
COMPOUNDS TO INORGANIC SURFACES IN WATER / 408 11.4 ADSORPTION OF
IONIZED ORGANIC COMPOUNDS FROM AQUEOUS SOLUTIONS TO CHARGED MINERAL
SURFACES / 417 11.5 SURFACE REACTIONS OF ORGANIC COMPOUNDS (ADVANCED
TOPIC) / 441 11.6 QUESTIONS AND PROBLEMS / 448 VU1 PART III
TRANSFORMATION PROCESSES 459 12 THERMODYNAMICS AND KINETICS OF
TRANSFORMATION REACTIONS 461 12.1 INTRODUCTION / 462 12.2 THERMODYNAMICS
OF TRANSFORMATION REACTIONS / 463 12.3 KINETIC ASPECTS OF TRANSFORMATION
REACTIONS / 468 12.4 WELL-MIXED REACTOR OR ONE-BOX MODEL / 482 12.5
QUESTIONS AND PROBLEMS / 486 13 CHEMICAL TRANSFORMATIONS I: HYDROLYSIS
AND REACTIONS INVOLVING OTHER NUCLEOPHILIC SPECIES 489 13.1
INTRODUCTION, OVERVIEW / 491 13.2 NUCLEOPHILIC SUBSTITUTION AND
ELIMINATION AT SATURATED CARBON ATOMS / 495 13.3 HYDROLYTIC REACTIONS OF
CARBOXYLIC AND CARBONIC ACID DERIVATIVES / 513 13.4 HYDRO LYTIC
REACTIONS OF PHOSPHORIC AND THIOPHOSPHORIC ACID ESTERS / 536 13.5
EFFECTS OF DISSOLVED METAL SPECIES AND OF MINERAL OXIDE SURFACES ON
HYDROLYTIC REACTIONS (ADVANCED TOPIC) 1 540 13.6 QUESTIONS AND PROBLEMS
/ 546 14 CHEMICAL TRANSFORMATIONS II: REDOX REACTIONS 555 14.1
INTRODUCTION, OVERVIEW / 556 14.2 THERMODYNAMIC CONSIDERATIONS OF REDOX
REACTIONS / 559 14.3 REACTION PATHWAYS AND KINETICS OF REDOX REACTIONS /
580 14.4 QUESTIONS AND PROBLEMS / 602 15 DIRECT PHOTOLYSIS 611 15.1
INTRODUCTION/ 613 15.2 SOME BASIC PRINCIPLES OF PHOTOCHEMISTRY / 614
15.3 LIGHT ABSORPTION BY ORGANIC CHEMICALS IN NATURAL WATERS / 627 15.4
QUANTUM YIELD AND RATE OF DIRECT PHOTOLYSIS / 641 15.5 EFFECTS OF SOLID
SORBENTS (PARTICLES, SOIL SURFACES) ON DIRECT PHOTOLYSIS / 649 15.6
QUESTIONS AND PROBLEMS / 650 16 INDIRECT PHOTOLYSIS: REACTIONS WITH
PHOTOOXIDANTS IN NATURAL WATERS AND IN THE ATMOSPHERE 655 16.1
INTRODUCTION A656 16.2 INDIRECT PHOTOLYSIS IN SURFACE WATERS / 658 IX
16.3 INDIRECT PHOTOLYSIS IN THE ATMOSPHERE (TROPOSPHERE)* REACTIONS WITH
HYDROXYL RADICAL (HO*) / 672 16.4 QUESTIONS AND PROBLEMS / 683 17
BIOLOGICAL TRANSFORMATIONS 687 17.1 INTRODUCTION / 689 17.2 SOME
IMPORTANT CONCEPTS ABOUT MICROORGANISMS / 694 17.3 BIOCHEMICAL
STRATEGIES OF MICROBIAL ORGANIC CHEMISTS / 702 17.4 RATES OF
BIOTRANSFORMATIONS: UPTAKE / 734 17.5 RATES OF BIOTRANSFORMATIONS:
MICROBIAL GROWTH / 739 17.6 RATES OF BIOTRANSFORMATIONS: ENZYMES / 750
17.7 QUESTIONS AND PROBLEMS / 767 PART IV MODELING TOOLS: TRANSPORT AND
REACTION 775 18 TRANSPORT BY RANDOM MOTION 777 18.1 INTRODUCTION:
ADVECTION AND DIFFUSION / 779 18.2 RANDOM MOTION / 780 18.3 RANDOM
MOTION AT THE MOLECULAR LEVEL: MOLECULAR DIFFUSION COEFFICIENTS / 798
18.4 DIFFUSION IN POROUS MEDIA / 815 18.5 OTHER RANDOM TRANSPORT
PROCESSES IN THE ENVIRONMENT / 825 18.6 QUESTIONS AND PROBLEMS / 828 19
TRANSPORT THROUGH BOUNDARIES 833 19.1 THE ROLE OF BOUNDARIES IN THE
ENVIRONMENT / 83 5 19.2 BOTTLENECK BOUNDARIES / 839 19.3 WALL BOUNDARIES
/ 848 19.4 DIFFUSIVE BOUNDARIES / 866 19.5 SPHERICAL BOUNDARIES
(ADVANCED TOPIC) / 871 19.6 QUESTIONS AND PROBLEMS / 883 20 AIR-WATER
EXCHANGE 887 20.1 INTRODUCTION / 889 20.2 MEASUREMENT OF AIR-WATER
TRANSFER VELOCITIES / 896 20.3 AIR-WATER EXCHANGE MODELS / 906 20.4
AIR-WATER EXCHANGE IN FLOWING WATERS / 921 20.5 INFLUENCE OF SURFACE
FILMS AND CHEMICAL REACTIONS ON AIR-WATER EXCHANGE {ADVANCED TOPIC) I
929 20.6 QUESTIONS AND PROBLEMS / 939 21 BOX MODELS 945 21.1 PRINCIPLES
OF MODELING / 947 21.2 ONE-BOX MODELS/955 21.3 TWO-BOX MODELS / 982 21.4
DYNAMIC PROPERTIES OF LINEAR MULTIDIMENSIONAL MODELS (ADVANCED TOPIC) /
991 21.5 QUESTIONS AND PROBLEMS/1000 22 MODELS IN SPACE AND TIME 1005
22.1 ONE-DIMENSIONAL DIFFUSION/ADVECTION/REACTION MODELS /. 1006 22.2
TURBULENT DIFFUSION/1019 22.3 HORIZONTAL DIFFUSION: TWO-DIMENSIONAL
MIXING / 1030 22.4 DISPERSION (ADVANCED TOPIC) / 1038 22.5 QUESTIONS AND
PROBLEMS / 1044 PARTV ENVIRONMENTAL SYSTEMS AND CASE STUDIES 1049 23
PONDS, LAKES, AND OCEANS 1051 23.1 LINEAR ONE-BOX MODELS OF LAKES,
PONDS, AND OCEANS / 1054 23.2 THE ROLE OF PARTICLES AND THE
SEDIMENT-WATER INTERFACE / 1059 23.3 TWO-BOX MODELS OF LAKES/1075 23.4
ONE-DIMENSIONAL CONTINUOUS LAKE MODELS (ADVANCED TOPIC) 1 1082 23.5
QUESTIONS AND PROBLEMS /1093 24 RIVERS 1101 24.1 TRANSPORT AND REACTION
IN RIVERS /1102 24.2 TURBULENT MIXING AND DISPERSION IN RIVERS /1120
24.3 A LINEAR TRANSPORT/REACTION MODEL FOR RIVERS /1130 24.4 QUESTIONS
AND PROBLEMS / 1141 25 GROUNDWATER 1147 25.1 GROUNDWATER HYDRAULICS/1148
25.2 TIME-DEPENDENT INPUT INTO AN AQUIFER (ADVANCED TOPIC) /1160 25.3
SORPTION AND TRANSFORMATIONS /1170 25.4 QUESTIONS AND PROBLEMS / 1179
APPENDIX 1185 BIBLIOGRAPHY 1213 INDEX (SUBJECT INDEX, COMPOUND INDEX,
LIST OF ILLUSTRATIVE EXAMPLES) 1255
|
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| author_facet | Schwarzenbach, René P. Gschwend, Philip M. 1951- Imboden, Dieter M. 1943- |
| author_role | aut aut aut |
| author_sort | Schwarzenbach, René P. |
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| ctrlnum | (OCoLC)237597717 (DE-599)BVBBV014641251 |
| discipline | Chemie / Pharmazie Allgemeines Chemie Umwelt |
| edition | 2. ed. |
| format | Book |
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| genre | 1\p (DE-588)4123623-3 Lehrbuch gnd-content |
| genre_facet | Lehrbuch |
| id | DE-604.BV014641251 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T19:04:37Z |
| institution | BVB |
| isbn | 0471350532 0471357502 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-009943115 |
| oclc_num | 237597717 |
| open_access_boolean | |
| owner | DE-703 DE-12 DE-1046 DE-19 DE-BY-UBM DE-384 DE-29 DE-91 DE-BY-TUM DE-634 DE-188 |
| owner_facet | DE-703 DE-12 DE-1046 DE-19 DE-BY-UBM DE-384 DE-29 DE-91 DE-BY-TUM DE-634 DE-188 |
| physical | XIII, 1313 S. graph. Darst. |
| publishDate | 2003 |
| publishDateSearch | 2003 |
| publishDateSort | 2003 |
| publisher | Wiley |
| record_format | marc |
| series2 | Wiley-interscience |
| spelling | Schwarzenbach, René P. Verfasser aut Environmental organic chemistry René P. Schwarzenbach ; Philip M. Gschwend ; Dieter M. Imboden 2. ed. New York [u.a.] Wiley 2003 XIII, 1313 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Wiley-interscience Physikalische Chemie (DE-588)4045959-7 gnd rswk-swf Organische Verbindungen (DE-588)4043816-8 gnd rswk-swf Ökologische Chemie (DE-588)4135167-8 gnd rswk-swf Physikalisch-chemische Eigenschaft (DE-588)4369521-8 gnd rswk-swf Umwelt (DE-588)4061616-2 gnd rswk-swf Organische Chemie (DE-588)4043793-0 gnd rswk-swf 1\p (DE-588)4123623-3 Lehrbuch gnd-content Ökologische Chemie (DE-588)4135167-8 s Organische Chemie (DE-588)4043793-0 s DE-604 Physikalische Chemie (DE-588)4045959-7 s Organische Verbindungen (DE-588)4043816-8 s Umwelt (DE-588)4061616-2 s 2\p DE-604 Physikalisch-chemische Eigenschaft (DE-588)4369521-8 s 3\p DE-604 4\p DE-604 Gschwend, Philip M. 1951- Verfasser (DE-588)136129900 aut Imboden, Dieter M. 1943- Verfasser (DE-588)172164672 aut HEBIS Datenaustausch Darmstadt application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009943115&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 2\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 3\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 4\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | Schwarzenbach, René P. Gschwend, Philip M. 1951- Imboden, Dieter M. 1943- Environmental organic chemistry Physikalische Chemie (DE-588)4045959-7 gnd Organische Verbindungen (DE-588)4043816-8 gnd Ökologische Chemie (DE-588)4135167-8 gnd Physikalisch-chemische Eigenschaft (DE-588)4369521-8 gnd Umwelt (DE-588)4061616-2 gnd Organische Chemie (DE-588)4043793-0 gnd |
| subject_GND | (DE-588)4045959-7 (DE-588)4043816-8 (DE-588)4135167-8 (DE-588)4369521-8 (DE-588)4061616-2 (DE-588)4043793-0 (DE-588)4123623-3 |
| title | Environmental organic chemistry |
| title_auth | Environmental organic chemistry |
| title_exact_search | Environmental organic chemistry |
| title_full | Environmental organic chemistry René P. Schwarzenbach ; Philip M. Gschwend ; Dieter M. Imboden |
| title_fullStr | Environmental organic chemistry René P. Schwarzenbach ; Philip M. Gschwend ; Dieter M. Imboden |
| title_full_unstemmed | Environmental organic chemistry René P. Schwarzenbach ; Philip M. Gschwend ; Dieter M. Imboden |
| title_short | Environmental organic chemistry |
| title_sort | environmental organic chemistry |
| topic | Physikalische Chemie (DE-588)4045959-7 gnd Organische Verbindungen (DE-588)4043816-8 gnd Ökologische Chemie (DE-588)4135167-8 gnd Physikalisch-chemische Eigenschaft (DE-588)4369521-8 gnd Umwelt (DE-588)4061616-2 gnd Organische Chemie (DE-588)4043793-0 gnd |
| topic_facet | Physikalische Chemie Organische Verbindungen Ökologische Chemie Physikalisch-chemische Eigenschaft Umwelt Organische Chemie Lehrbuch |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009943115&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT schwarzenbachrenep environmentalorganicchemistry AT gschwendphilipm environmentalorganicchemistry AT imbodendieterm environmentalorganicchemistry |