Basic concepts for simple and complex liquids:
Saved in:
| Main Authors: | , |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
Cambridge
Cambridge Univ. Press
2003
|
| Edition: | 1. publ. |
| Subjects: | |
| Online Access: | Publisher description Table of contents Inhaltsverzeichnis |
| Physical Description: | XI, 296 S. Ill., graph. Darst. |
| ISBN: | 0521783445 9780521783446 0521789532 9780521789530 |
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MARC
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| 245 | 1 | 0 | |a Basic concepts for simple and complex liquids |c Jean-Louis Barrat and Jean-Pierre Hansen |
| 250 | |a 1. publ. | ||
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| 300 | |a XI, 296 S. |b Ill., graph. Darst. | ||
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Record in the Search Index
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| adam_text | Contents
Preface
page
ix
1
An introduction to liquid matter
1
1.1
Fluid states of simple substances
2
1.2
From simple to complex fluids
7
1.3
Exploring the liquid state
15
1.4
Application
1 :
excluded and free volume
18
1.5
Application
2:
polymer chains and scale
invariance
23
1.6
Applications: numerical experiments
28
Further reading
35
1 Thermodynamics, structure and fluctuations
2
A reminder of thermodynamics
36
2.1
State variables and thermodynamic equilibrium
36
2.2
Link with statistical mechanics
42
2.3
Phase coexistence and interfaces
47
2.4
Application
1:
scaled particle theory
51
2.5
Application
2:
particle insertion
55
2.6
Applications: criticalmicellarconcentration
57
2.7
Application
4:
depletion interactions and solvation forces
62
Further reading
67
3
Equilibrium fluctuations
69
3.1
Gaussian distribution of fluctuations
69
3.2
Density fluctuations in a one-component system
72
3.3
Concentration fluctuations in a mixture
74
3.4
Local order and pair structure
75
3.5
Link with thermodynamics
81
3.6
Static linear response
84
3.7
Application
1 :
dipole
moment fluctuations and dielectric response
85
Contents
3.8 Application 2:
determination of the structure from diffraction
experiments
90
3.9
Applications: form factors of complex objects or molecules
93
3.10
Application
4:
random phase approximation
98
Further reading
106
II Phase transitions
4
Mean field approaches
107
4.1
Lattice models and mean field treatment
107
4.2
Landau theory of phase transitions
115
4.3
Application
1 :
van
der Waals
theory of condensation
126
4.4
Application
2:
Flory-Huggins theory of polymer blends
128
4.5
Application
3:
isotropic-nematic transition
131
4.6
Application
4:
freezing
136
5
Critical fluctuations and scaling
143
5.1
The correlation length
144
5.2
Fluctuations and dimensionality
148
5.3
Scaling ideas
153
5.4
Application
1 :
Ginzburg criterion for polymer blends
157
5.5
Application
2:
scaling laws for polymer solutions
159
5.6
Application
3:
finite size scaling
165
III Interfaces and inhomogeneous fluids
6
Macroscopic description of interfaces
167
6.1
Interfacial
tension and excess quantities
167
6.2
Geometry of curved surfaces
170
6.3
Wetting phenomena
172
6.4
Capillary pressure and capillary condensation
173
6.5
Disjoining pressure and film stability
176
Further reading
178
7
The density functional approach
179
7.1
Variational principle
179
7.2
Some approximate functionals
181
7.3
Application
1 :
the fluid-fluid interface
184
7.4
Application
2:
the adsorbed polymer layer
186
7.5
Application
3:
self-assembly of copolymers
188
7.6
Application
4:
electric double-layers
193
7.7
Application
5:
colloid stability
203
Further reading
212
Contents
8
Curvature and fluctuations
213
8.1
Fluctuations of interfaces and capillary waves
213
8.2
Membranes and curvature moduli
215
8.3
Fluctuations of membranes
217
8.4
Steric interactions between membranes
218
Further reading
219
IV
Dynamics
9
Phenomenological description of transport processes
220
9.1
Fluxes, affinities and transport coefficients
220
9.2
Application
1 :
the diffusion equation
221
9.3
Application
2:
spinodal decomposition
224
Further reading
227
10
Brownian motion, diffusion and the
Langevin
equation
228
10.1
The
Langevin
equation
228
10.2
The Fokker-Planck description
231
10.3
Application
1 :
rotational diffusion
235
10.4
Application
2:
polymer dynamics, Rouse and
reptation
models
239
10.5
Application
3:
barrier crossing
246
10.6
Application
4:
classical nucleation theory
251
Further reading
255
11
Response and correlation functions
257
11.1
Probing dynamical properties at equilibrium
257
11.2
Time dependent correlation functions
258
11.3
Response functions
259
11.4
Fluctuation-dissipation theorem
261
11.5
Application
1 :
collective modes
263
11.6
Application
2:
inelastic scattering of neutrons and light
267
11.7
Application
3:
pulsed field gradient nuclear magnetic resonance
270
Further reading
272
12
Slow relaxations
273
12.1
Memory and viscoelastic effects
273
12.2
Coupling to hydrodynamic modes and long time tails
275
12.3
Critical slowing down
277
12.4
The glass transition
280
Further reading
292
Index
294
|
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| dewey-full | 530.4/2 |
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| discipline | Physik |
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| spelling | Barrat, Jean-Louis 1964- Verfasser (DE-588)124808514 aut Basic concepts for simple and complex liquids Jean-Louis Barrat and Jean-Pierre Hansen 1. publ. Cambridge Cambridge Univ. Press 2003 XI, 296 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Complex fluids Liquids Physik (DE-588)4045956-1 gnd rswk-swf Flüssigkeit (DE-588)4017621-6 gnd rswk-swf Flüssigkeit (DE-588)4017621-6 s Physik (DE-588)4045956-1 s DE-604 Hansen, Jean-Pierre 1942- Verfasser (DE-588)138359059 aut http://www.loc.gov/catdir/description/cam031/2002031051.html Publisher description http://www.loc.gov/catdir/toc/cam031/2002031051.html Table of contents Digitalisierung UB Regensburg application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009940578&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Barrat, Jean-Louis 1964- Hansen, Jean-Pierre 1942- Basic concepts for simple and complex liquids Complex fluids Liquids Physik (DE-588)4045956-1 gnd Flüssigkeit (DE-588)4017621-6 gnd |
| subject_GND | (DE-588)4045956-1 (DE-588)4017621-6 |
| title | Basic concepts for simple and complex liquids |
| title_auth | Basic concepts for simple and complex liquids |
| title_exact_search | Basic concepts for simple and complex liquids |
| title_full | Basic concepts for simple and complex liquids Jean-Louis Barrat and Jean-Pierre Hansen |
| title_fullStr | Basic concepts for simple and complex liquids Jean-Louis Barrat and Jean-Pierre Hansen |
| title_full_unstemmed | Basic concepts for simple and complex liquids Jean-Louis Barrat and Jean-Pierre Hansen |
| title_short | Basic concepts for simple and complex liquids |
| title_sort | basic concepts for simple and complex liquids |
| topic | Complex fluids Liquids Physik (DE-588)4045956-1 gnd Flüssigkeit (DE-588)4017621-6 gnd |
| topic_facet | Complex fluids Liquids Physik Flüssigkeit |
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