Broadband dielectric spectroscopy:
Gespeichert in:
| Format: | Buch |
|---|---|
| Sprache: | English |
| Veröffentlicht: |
Berlin [u.a.]
Springer
2003
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | Hier auch später erschienene, unveränderte Nachdrucke |
| Beschreibung: | XXI, 729 S. graph. Darst. |
| ISBN: | 9783540434078 3540434070 |
Internformat
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| 245 | 1 | 0 | |a Broadband dielectric spectroscopy |c F. Kremer ... (eds.) |
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Datensatz im Suchindex
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|---|---|
| adam_text | F. KREMER * A. SCHOENHALS (EDS.) BROADBAND LELECTNC SPECTROSCOPY WITH 393
FIGURES AND 22 TABLES SJ SPRINGER CONTENTS 1 THEORY OF DIELECTRIC
RELAXATION 1 A. SCHOENHALS, F. KREMER 1.1 INTRODUCTION 1 1.2
ELECTROSTATICS 3 1.3 DIELECTRIC RELAXATION (DIELECTRIC RETARDATION) 10
1.3.1 LINEAR RESPONSE THEORY AND FLUCTUATION DISSIPATION THEOREM . 10
1.3.2 THEORETICAL CONSIDERATIONS (MODELS) 15 1.3.2.1 DEBYE RELAXATION 17
1.3.2.2 MODELS FOR NON-DEBYE RELAXATION 19 APPENDIX 1.1 LINEAR RESPONSE
THEORY 24 APPENDIX 1.2 DERIVATION OF THE KRAMERS/KRONIG-RELATIONSHIPS .
26 APPENDIX 1.3 FLUCTUATION DISSIPATION THEOREM 29 REFERENCES 32 2
BROADBAND DIELECTRIC MEASUREMENT TECHNIQUES (10~ 6 HZ TO 10 12 HZ) 35 F.
KREMER, A. SCHOENHALS 2.1 INTRODUCTION 35 2.2 MEASUREMENTS IN THE
FREQUENCY DOMAIN FROM 10 6 HZ TO 10 11 HZ 37 2.2.1 FOURIER CORRELATION
ANALYSIS 37 2.2.2 DIELECTRIC CONVERTERS IN COMBINATION WITH FOURIER
CORRELATION ANALYSIS 39 2.2.3 IMPEDANCE ANALYSIS 41 2.2.4 INTEGRATED
DIELECTRIC ANALYZERS 42 2.2.5 SAMPLES AND SAMPLE CELLS FOR FREQUENCIES
10 MHZ 43 2.2.6 RF REFLECTOMETRY 43 2.2.7 NETWORK ANALYSIS 45 2.2.8
IMPEDANCE AND FREQUENCY RANGES OVERVIEW 46 2.3 MEASUREMENT SYSTEMS IN
THE TIME DOMAIN FROM 10 6 HZ TO 10 10 HZ 48 2.4 QUASIOPTICAL SET-UPS IN
THE FREQUENCY RANGE FROM 10 10 HZ TO 10 12 HZ 51 2.5 CONCLUSIONS 54
REFERENCES 56 CONTENTS ANALYSIS OF DIELECTRIC SPECTRA 59 A. SCHOENHALS,
F. KREMER INTRODUCTION 59 DIPOLAR FLUCTUATIONS 60 1 ANALYSIS OF
DIELECTRIC SPECTRA - MODEL FUNCTIONS 61 2 ANALYSIS OF DIELECTRIC SPECTRA
- MODEL FREE 72 FLUCTUATIONS OF MOBILE CHARGE CARRIERS 81 SEPARATION OF
CHARGES 87 1 MESOSCOPIC SCALE: MAXWELL/WAGNER/SILLARS POLARIZATION 87 2
ELECTRODE POLARIZATION 91 CONCLUSION - HOW TO ANALYZE DIELECTRIC SPECTRA
93 APPENDIX 3.1 FIT PARAMETERS 94 REFERENCES 96 THE SCALING OF THE
DYNAMICS OF GLASSES AND SUPERCOOLED LIQUIDS 99 F. KREMER, A. SCHOENHALS
INTRODUCTION 99 THEORIES DESCRIBING THE SCALING OF THE DYNAMICS IN
GLASS-FORMING SYSTEMS 101 TEMPERATURE DEPENDENCE OF THE DYNAMIC GLASS
TRANSITION . . . 108 SCALING OF THE RELAXATION TIME DISTRIBUTION
FUNCTION OF THE DYNAMIC GLASS TRANSITION 116 SCALING OF THE DYNAMIC
GLASS TRANSITION AND THE SLOW SS-RELAXATION IN POLYETHYLENE
TEREPHTHALATE) (PET) 120 CONCLUSIONS 125 REFERENCES 127 GLASSY DYNAMICS
BEYOND THE A- RELAXATION 131 P. LUNKENHEIMER, A. LOIDL INTRODUCTION 131
DYNAMIC PROCESSES IN GLASS-FORMING MATERIALS 133 BROADBAND DIELECTRIC
SPECTRA OF GLASS-FORMING MATERIALS .... 136 THE EXCESS WING 142 1
SCALING AND DIVERGENT SUSCEPTIBILITY 143 2 THE EXCESS WING - A SS-
RELAXATION? 146 THE HIGH-FREQUENCY RESPONSE 149 1 THE (V)-MINIMUM 149
1.1 PHENOMENOLOGICAL DESCRIPTION 150 1.2 MODE-COUPLING THEORY 152 1.3
OTHER MODELS 157 2 COMPARISON WITH LIGHT AND NEUTRON SCATTERING 158
CONTENTS XV 5.5.3 THE BOSON PEAK 161 5.6 CONCLUSIONS 162 REFERENCES 165
6 MOLECULAR DYNAMICS IN CONFINING SPACE 171 F. KREMER, A. HUWE, A.
SCHOENHALS, S.A. ROEZAHSKI 6.1 INTRODUCTION 171 6.2 H-BOND FORMING AND
VAN-DER-WAALS LIQUIDS IN ZEOLITIC AND NANOPOROUS MEDIA 172 6.2.1 GLYCOLS
IN ZEOLITES AND NANOPOROUS SOL-GEL GLASSES 172 6.2.2 SALOL IN
(LUBRICATED) NANOPOROUS SOL-GEL GLASSES 188 6.3 POLYMERS IN ZEOLITIC AND
NANOPOROUS MEDIA 199 6.3.1 POLY(VINYLETHER) IN MESOPOROUS MCM 199 6.3.2
POLY(PROPYLENE GLYCOL) IN NANOPOROUS SOL-GEL GLASSES 202 6.3.3
POLY(DIMETHYL SILOXANE) IN NANOPOROUS SOL-GEL GLASSES 207 6.4 LIQUID
CRYSTALS IN CONFINING SPACE 210 6.4.1 NEMATIC LIQUID CRYSTALS IN
MESOPOROUS MEMBRANES 210 6.4.2 FERROELECTRIC LIQUID CRYSTALS IN
MESOPOROUS MEMBRANES .... 216 6.5 CONCLUSIONS 220 REFERENCES 222 7
MOLECULAR DYNAMICS IN POLYMER MODEL SYSTEMS 225 A. SCHOENHALS 7.1
INTRODUCTION 225 7.2 THEORETICAL CONSIDERATIONS 227 7.2.1 CONFORMATIONS
OF POLYMERIE CHAINS 227 7.2.2 DIPOLE MOMENTS OF POLYMERIE CHAINS 230
7.2.3 MOTIONAL PROCESSES IN ISOLATED CHAINS 233 7.2.3.1 SEGMENTAL MOTION
233 7.2.3.2 CHAIN MOTION 234 7.3 DIELECTRIC PROPERTIES OF POLYMERS IN
SOLUTION 236 7.3.1 DILUTE SOLUTIONS 236 7.3.1.1 SEGMENTAL MOTION 236
7.3.1.2 CHAIN MOTION 238 7.3.2 CONCENTRATED SOLUTIONS 238 7.3.2.1
SEGMENTAL MOTION 238 7.3.2.2 CHAIN MOTION 239 7.3.3 ROD-LIKE SYSTEMS 240
7.4 DIELECTRIC PROPERTIES OF POLYMERIE SYSTEMS IN THE BULK STATE . . 241
7.4.1 AMORPHOUS POLYMERS 241 7.4.1.1 SS-RELAXATION 242 7.4.1.2 DYNAMIC
GLASS TRANSITION (A-RELAXATION) 244 7.4.1.3 RELATIONSHIP BETWEEN THE SS-
AND THE A-RELAXATION - THE (A/3)-PROCESS 251 XVIII CONTENTS 11.3 THIN
FILMS OF GLASS FORMING POLYMERS 438 11.3.1 POLY(METHYL METHACRYLATE)
(PMMA) 438 11.3.2 ATACTIC POLYSTYRENE (A-PS) 452 11.4 THIN FILMS OF
GRAFTED POLYMERS: POLY(Y-BENZYL-L-GLUTAMATE) (PBLG) 462 11.5 CONCLUSIONS
469 REFERENCES 472 12 THE DIELECTRIC PROPERTIES OF SEMICONDUCTING
DISORDERED MATERIALS 475 F. KREMER, S.A. ROEZANSKI 12.1 INTRODUCTION 475
12.2 SIMILARITIES IN THE A. C. CONDUCTIVITY OF SEMICONDUCTING DISORDERED
MATERIALS 480 12.3 RELAXATION AND CHARGE TRANSPORT IN MIXTURES OF
ZWITTERIONIC POLYMERS AND INORGANIC SALTS 483 12.4 CONCLUSIONS 492
REFERENCES 493 13 DIELECTRIC PROPERTIES OF INHOMOGENEOUS MEDIA 495
P.A.M. STEEMAN,]. VAN TURNHOUT 13.1 INTRODUCTION 495 13.2 THEORY 496
13.2.1 TWO-PHASE HETEROGENEOUS MATERIALS 496 13.2.2 HETEROGENEOUS
MATERIALS CONTAINING MORE THAN TWO PHASES . . 501 13.2.3 HETEROGENEOUS
MATERIALS WITH AN INTERFACIAL LAYER 502 13.3 EXPERIMENTAL RESULTS 503
13.3.1 POLYMERIE BLENDS 503 13.3.2 FILLED POLYMERS 508 13.3.3
SEMI-CRYSTALLINE POLYMERS 512 13.3.4 EFFECT OF PROCESSING ON MATERIAL
HOMOGENEITY 516 13.4 CONCLUSIONS 519 REFERENCES 520 14 PRINCIPLES AND
APPLICATIONS OF PULSED DIELECTRIC SPECTROSCOPY AND NONRESONANT
DIELECTRIC HOLE BURNING 523 R. BOEHMER, G. DIEZEMANN 14.1 INTRODUCTION
523 14.2 THEORETICAL CONCEPTS 525 14.2.1 MACROSCOPIC LINEAR RESPONSE 525
14.2.2 MICROSCOPIC REORIENTATION MODELS 527 CONTENTS XIX 14.2.3
STOCHASTIC DYNAMICS IN MODERATELY LARGE ELECTRIC FIELDS .... 533
14.2.3.1 THE MODEL OF ASYMMETRIE DOUBLE WELL POTENTIALS 534 14.2.3.2 THE
BOX MODEL 540 14.3 EXPERIMENTAL ASPECTS 542 14.4 APPLICATIONS 545 14.4.1
SUPERCOOLED LIQUIDS AND PLASTIC CRYSTALS 545 14.4.1.1 PULSED DIELECTRIC
SPECTROSCOPY 545 14.4.1.2 NONRESONANT SPECTRAL HOLE BURNING 548 14.4.2
ION CONDUCTING GLASSES 552 14.4.3 CRYSTALS WITH FROZEN-IN DISORDER 556
14.5 RELATED EXPERIMENTAL METHODS 559 14.6 CONCLUSIONS 562 APPENDIX 14.1
563 APPENDIX 14.2 564 REFERENCES 566 15 LOCAL DIELECTRIC RELAXATION BY
SOLVATION DYNAMICS 571 R. RICHERT 15.1 INTRODUCTION 571 15.2
EXPERIMENTAL TECHNIQUES 572 15.3 DIELECTRIC ASPECTS OF SOLVATION 576
15.4 SOLVATION DYNAMICS 580 15.4.1 DYNAMIC HETEROGENEITY 583 15.4.2
CONFMED SYSTEMS 587 15.5 SUMMARY 592 REFERENCES 594 16 DIELECTRIC AND
MECHANICAL SPECTROSCOPY - A COMPARISON .... 597 T. PAKULA 16.1
INTRODUCTION 597 16.2 PRINCIPLES OF MECHANICAL ANALYSIS 600 16.3 LINEAR
VISCOELASTIC BEHAVIOUR 602 16.4 EXPERIMENTAL PROCEDURES AND TYPICAL DATA
ANALYSIS 606 16.5 DIFFERENCES IN DATA TREATMENT 610 16.6 TYPICAL
BEHAVIOUR OF POLYMERIE MATERIALS 612 16.6.1 MELTS OF LINEAR POLYMERS 612
16.6.2 BLOCK COPOLYMER SYSTEMS 614 16.6.3 HIGHLY BRANCHED POLYMERS 618
16.7 SUGGESTED ANALYSIS OF MODULUS SPECTRA 619 16.8 CONCLUDING REMARKS
620 REFERENCES 623 XX CONTENTS 17 DIELECTRIC SPECTROSCOPY AND
MULTIDIMENSIONAL NMR - A COMPARISON 625 R. BOEHMER, F. KREMER 17.1
INTRODUCTION 625 17.2 SELECTED NMR METHODS 626 17.2.1 SPIN-RELAXATION
TECHNIQUES 627 17.2.2 STIMULATED TWO-TIME ECHO SPECTROSCOPY 631 17.2.2.1
TRANSLATIONAL DISPLACEMENTS 632 17.2.2.2 REORIENTATIONAL DYNAMICS 636
17.2.3 MULTIDIMENSIONAL TECHNIQUES 638 17.2.3.1 FREQUENCY-DOMAIN
SPECTROSCOPY 638 17.2.3.2 MULTIPLE-TIME CORRELATIONS 641 17.3 COMBINED
DIELECTRIC AND NMR STUDIES: RECENT EXPERIMENTAL EXAMPLES 646 17.3.1
DYNAMICS IN SIMPLE GLASS FORMERS: GLYCEROL VS TOLUENE .... 646 17.3.2
MOTIONAL PROCESSES OF A TRIPHENYLENE-BASED DISCOTIC LIQUID CRYSTAL 652
17.3.3 A- AND /3-RELAXATIONS IN POLY(METHYL METHACRYLATE) 657 17.3.4
DYNAMIC AND SPATIAL HETEROGENEITY IN POLY(VINYL ACETATE) .... 662 17.3.5
2CA(N0 3 ) 2 * 3MN0 3 AS AN EXAMPLE FOR AN ION CONDUCTOR .... 668 17.3.6
SELF-DIFFUSION IN POLYMERIE SYSTEMS 671 17.4 CONCLUDING REMARKS 674
APPENDIX 17.1 675 APPENDIX 17.2 676 REFERENCES 679 18 POLYMER DYNAMICS
BY DIELECTRIC SPECTROSCOPY AND NEUTRON SCATTERING - A COMPARISON 685 A.
ARBE, J. COLMENERO, D. RICHTER 18.1 INTRODUCTION 685 18.2 QUASIELASTIC
NEUTRON SCATTERING 686 18.2.1 NEUTRON CROSS SECTIONS AND CORRELATION
FUNCTIONS 686 18.2.2 NEUTRON INSTRUMENTATION 688 18.2.2.1 TIME OF FLIGHT
SPECTROMETER 688 18.2.2.2 BACKSCATTERING INSTRUMENT 689 18.2.2.3 SPIN
ECHO SPECTROMETER 690 18.2.3 RELATION TO DIELECTRIC SPECTROSCOPY 692
18.3. DYNAMIC STRUCTURE FACTORS FOR THE A- AND SS-PROCESS 695 18.3.1
LOCAL PROCESSES 695 18.3.2 DIFFUSIVE (Q DISPERSIVE) PROCESSES 697 18.3.3
MERGING OF THE A- AND /3-PROCESSES 699 18.4. EXPERIMENTAL EXAMPLES 699
18.4.1 POLYBUTADIENE AS A SHOWCASE 699 CONTENTS XXI 18.4.2 COMBINED
DIELECTRIC AND NEUTRON INVESTIGATIONS OF THE/3-PROCESS 703 18.4.3
A-PROCESS ON POLYBUTADIENE 705 18.4.3.1 TEMPERATURE DEPENDENCE 705
18.4.3.2 Q-DEPENDENCE 706 18.4.3.3 MERGING OFOC- AND /3-PROCESSES 707
18.5. CONCLUSIONS 714 REFERENCES 717 FOR FURTHER READING 719 SUBJECT
INDEX 721
|
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| id | DE-604.BV014392958 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T19:02:21Z |
| institution | BVB |
| isbn | 9783540434078 3540434070 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-009852500 |
| oclc_num | 51710302 |
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| owner_facet | DE-355 DE-BY-UBR DE-384 DE-M49 DE-BY-TUM DE-29T DE-91G DE-BY-TUM DE-83 |
| physical | XXI, 729 S. graph. Darst. |
| publishDate | 2003 |
| publishDateSearch | 2003 |
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| publisher | Springer |
| record_format | marc |
| spelling | Broadband dielectric spectroscopy F. Kremer ... (eds.) Berlin [u.a.] Springer 2003 XXI, 729 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Hier auch später erschienene, unveränderte Nachdrucke Impedanzspektroskopie (DE-588)4161400-8 gnd rswk-swf Impedanzspektroskopie (DE-588)4161400-8 s DE-604 Kremer, Friedrich 1949- Sonstige (DE-588)1045057894 oth GBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009852500&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Broadband dielectric spectroscopy Impedanzspektroskopie (DE-588)4161400-8 gnd |
| subject_GND | (DE-588)4161400-8 |
| title | Broadband dielectric spectroscopy |
| title_auth | Broadband dielectric spectroscopy |
| title_exact_search | Broadband dielectric spectroscopy |
| title_full | Broadband dielectric spectroscopy F. Kremer ... (eds.) |
| title_fullStr | Broadband dielectric spectroscopy F. Kremer ... (eds.) |
| title_full_unstemmed | Broadband dielectric spectroscopy F. Kremer ... (eds.) |
| title_short | Broadband dielectric spectroscopy |
| title_sort | broadband dielectric spectroscopy |
| topic | Impedanzspektroskopie (DE-588)4161400-8 gnd |
| topic_facet | Impedanzspektroskopie |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009852500&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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