Small angle neutron scattering investigation on the emulsification efficiency of amphiphilic block copolymer in microemulsions:
Gespeichert in:
| 1. Verfasser: | |
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| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
2001
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| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | Münster, Univ., Diss., 2001 |
| Beschreibung: | II, 111 S. Ill., graph. Darst. |
Internformat
MARC
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| 100 | 1 | |a Endo, Hitoshi |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a Small angle neutron scattering investigation on the emulsification efficiency of amphiphilic block copolymer in microemulsions |c vorgelegt von Hitoshi Endo |
| 264 | 1 | |c 2001 | |
| 300 | |a II, 111 S. |b Ill., graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
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| 500 | |a Münster, Univ., Diss., 2001 | ||
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Datensatz im Suchindex
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CONTENTS
2 EXPERIMENTS 5
2.1 SAMPLES. 5
2.1.1 POLYMER SYNTHESIS. 5
2.1.2 SURFACTANT SYNTHESIS . 8
2.1.3 DENSITY MEASUREMENT AND DEUTERATION DEGREE. 10
2.2 MICROEMULSIONS. 13
2.2.1 TERNARY MICROEMULSIONS. 13
2.2.2 PHASE BEHAVIORS OF MICROEMULSIONS. 14
2.2.3 PREPARATION OF THE MICROEMULSIONS . 15
2.3 SMALL ANGLE NEUTRON SCATTERING. 18
2.3.1 GENERAL BASIS OF NEUTRON SCATTERING. 18
2.3.2 PARTIAL SCATTERING FUNCTIONS IN TERNARY AND QUATERNARY
FLUID MIXTURES.20
2.3.3 DOUBLE CONTRAST VARIATION METHOD.23
2.3.4 BACKGROUND SUBTRACTION.25
2.3.5 RAW DATA TREATMENT .27
2.3.6 RESOLUTION EFFECT .29
3 THEORY 31
3.1 PHASE BEHAVIOR.31
3.1.1 THE MEMBRANE THEORY AND PREDICTING THE PHASE BEHAVIOR 31
3.1.2 MEMBRANE DECORATED BY POLYMER.33
3.1.3 THE POLYMER FRACTION $,54/2 35
3.2 THEORETICAL MODELS FOR THE SCATTERING FUNCTIONS.36
3.2.1 GINZBURG-LANDAU APPROACH AND THE SCATTERING FUNCTION 37
3.2.2 GAUSSIAN-RANDOM-FIELD MODEL .38
3.2.3 DETERMINATION OF BENDING RIGIDITY FROM SANS AND SPA
TIAL RENORMALIZATION.40
3.2.4 POLYMER-FILM SCATTERING AND POLYMER SCATTERING . 41
1
BIBLIOGRAFISCHE INFORMATIONEN
HTTP://D-NB.INFO/964774402
II
CONTENTS
3.2.5 ASYMPTOTIC BEHAVIOR.44
4 EXPERIMENTAL RESULTS AND DISCUSSION 47
4.1 PHASE DIAGRAMS.47
4.2 SMALL ANGLE NEUTRON SCATTERING. 52
4.2.1 RESULTS UNDER BULK CONTRAST. 52
4.2.2 MEASURING BENDING RIGIDITY IN BICONTINUOUS MICROEMUL
SIONS . 55
4.2.3 RESULTS UNDER POLYMER CONTRAST.60
5 CONCLUSIONS 67
APPENDIX 71
A SINGULAR VALUE DECOMPOSITION 71
B
SPP(Q) FOR ASYMMETRIC BLOCK COPOLYMER 75
C VARIATIONAL APPROACH TO SPONGE PHASES 77
D APPLICATION OF TWO-DIMENSIONAL CONTRAST VARIATION
METHODS - DEPENDENCE ON A POLYMER CONCENTRATION 85
D.L INTRODUCTION. 85
D.2 CONTRAST VARIATION ANALYSIS. 85
D.3 ANALYSES OF SFP AND SPP .99
D.3.1 DEPENDENCE OF THE POLYMER CONCENTRATION .99
D.3.2 ANALYSES OF SPP.102
D.4 SUMMARY .104
REFERENCES 105
ACKNOWLEDGMENTS 109
CURRICULUM VITAE
111 |
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| illustrated | Illustrated |
| indexdate | 2024-10-09T18:04:50Z |
| institution | BVB |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-009820406 |
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| physical | II, 111 S. Ill., graph. Darst. |
| publishDate | 2001 |
| publishDateSearch | 2001 |
| publishDateSort | 2001 |
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| spelling | Endo, Hitoshi Verfasser aut Small angle neutron scattering investigation on the emulsification efficiency of amphiphilic block copolymer in microemulsions vorgelegt von Hitoshi Endo 2001 II, 111 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Münster, Univ., Diss., 2001 Blockcopolymere (DE-588)4146026-1 gnd rswk-swf Amphiphile Verbindungen (DE-588)4142278-8 gnd rswk-swf Mikroemulsionscopolymerisation (DE-588)4293082-0 gnd rswk-swf Neutronenkleinwinkelstreuung (DE-588)4171646-2 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Blockcopolymere (DE-588)4146026-1 s Amphiphile Verbindungen (DE-588)4142278-8 s Mikroemulsionscopolymerisation (DE-588)4293082-0 s Neutronenkleinwinkelstreuung (DE-588)4171646-2 s DE-604 DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009820406&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Endo, Hitoshi Small angle neutron scattering investigation on the emulsification efficiency of amphiphilic block copolymer in microemulsions Blockcopolymere (DE-588)4146026-1 gnd Amphiphile Verbindungen (DE-588)4142278-8 gnd Mikroemulsionscopolymerisation (DE-588)4293082-0 gnd Neutronenkleinwinkelstreuung (DE-588)4171646-2 gnd |
| subject_GND | (DE-588)4146026-1 (DE-588)4142278-8 (DE-588)4293082-0 (DE-588)4171646-2 (DE-588)4113937-9 |
| title | Small angle neutron scattering investigation on the emulsification efficiency of amphiphilic block copolymer in microemulsions |
| title_auth | Small angle neutron scattering investigation on the emulsification efficiency of amphiphilic block copolymer in microemulsions |
| title_exact_search | Small angle neutron scattering investigation on the emulsification efficiency of amphiphilic block copolymer in microemulsions |
| title_full | Small angle neutron scattering investigation on the emulsification efficiency of amphiphilic block copolymer in microemulsions vorgelegt von Hitoshi Endo |
| title_fullStr | Small angle neutron scattering investigation on the emulsification efficiency of amphiphilic block copolymer in microemulsions vorgelegt von Hitoshi Endo |
| title_full_unstemmed | Small angle neutron scattering investigation on the emulsification efficiency of amphiphilic block copolymer in microemulsions vorgelegt von Hitoshi Endo |
| title_short | Small angle neutron scattering investigation on the emulsification efficiency of amphiphilic block copolymer in microemulsions |
| title_sort | small angle neutron scattering investigation on the emulsification efficiency of amphiphilic block copolymer in microemulsions |
| topic | Blockcopolymere (DE-588)4146026-1 gnd Amphiphile Verbindungen (DE-588)4142278-8 gnd Mikroemulsionscopolymerisation (DE-588)4293082-0 gnd Neutronenkleinwinkelstreuung (DE-588)4171646-2 gnd |
| topic_facet | Blockcopolymere Amphiphile Verbindungen Mikroemulsionscopolymerisation Neutronenkleinwinkelstreuung Hochschulschrift |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009820406&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT endohitoshi smallangleneutronscatteringinvestigationontheemulsificationefficiencyofamphiphilicblockcopolymerinmicroemulsions |