Scanning electrochemical microscopy:
Gespeichert in:
Format: | Buch |
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Sprache: | English |
Veröffentlicht: |
New York [u.a.]
Dekker
2001
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Schriftenreihe: | Monographs in electroanalytical chemistry and electrochemistry
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Schlagworte: | |
Online-Zugang: | Inhaltsverzeichnis |
Beschreibung: | X, 650 S. Ill., graph. Darst. |
ISBN: | 0824704711 |
Internformat
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Datensatz im Suchindex
_version_ | 1804129164824936448 |
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adam_text | Titel: Scanning electrochemical microscopy
Autor: Bard, Allen J.
Jahr: 2001
CONTENTS
Preface m
Contributors ¡x
1 INTRODUCTION AND PRINCIPLES 1
Allen J. Bard
I. Background of Scanning Electrochemical Microscopy 1
II. Principles of SECM 2
III. Applications of SECM 9
References 15
2 INSTRUMENTATION 17
David O. Wipf
I. Introduction 17
II. Overview of the SECM Apparatus 18
III. Commercial SECM Instrument Implementation 42
IV. Tip Position Modulation Instrumentation 44
V. Constant-Current Mode Instrumentation 44
VI. Experimental Difficulties in Data Acquisition 53
VII. Accessory Equipment for SECM 59
Appendix; Suppliers 66
References 71
vi Contents
3 THE PREPARATION OF TIPS FOR SCANNING
ELECTROCHEMICAL MICROSCOPY 75
Fu-Ren F. Fan and Christophe Démaille
I. Introduction 75
n. Preparation Techniques 75
III. Nondisk Tips and Tip Shape Characterization 104
References 107
SECM IMAGING 111
Fu-Ren F. Fan
I. Introduction 111
II. Principle and Methodology of SEM Imaging 111
III. Images in Solutions 115
IV. Images in Humid Air 124
V. Conclusions and Future Projections 139
References 141
5 THEORY 145
Michael V. Mirkin
I. Introduction 145
II. Feedback Mode of SECM Operation 145
III. Generation/Collection (G/C) Mode of SECM Operation 165
IV. SECM of More Complicated Chemical Systems 170
V. Numerical Solution of SECM Diffusion Problems
Using PDEase2 Program Package 182
List of Symbols 193
References 198
6 HETEROGENEOUS ELECTRON TRANSFER REACTIONS 201
Kai Borgwarth and Jürgen Heinze
I. Introduction 201
II. Principles 203
III. Studies of Heterogeneous Electron Transfer 217
IV. Applications 234
V. Conclusion and Outlook 237
References 238
Contents vii
7 KINETICS OF HOMOGENEOUS REACTIONS COUPLED
TO HETEROGENEOUS ELECTRON TRANSFER 241
Patrick R. Unwin
I. Introduction 241
II. EC¡ Processes 244
III. EC2i Processes 270
IV. ECE/DISP Processes 283
References 297
8 CHARGE-TRANSFER AT THE LIQUID/LIQUID INTERFACE 299
Michael V. Mirkin and Michael Tsionsky
I. Introduction 299
II. Electron Transfer 301
III. Ion Transfer at the ITIES 325
IV. Processes with Coupled Homogeneous Reactions 336
References 339
9 IMAGING MOLECULAR TRANSPORT ACROSS
MEMBRANES 343
Bradley D. Bath, Henry S. White, and Erik R. Scott
I. Introduction 343
II. Principles of Imaging Porous Membranes 346
III. Applications 365
IV. Future Directions 392
References 394
10 POTENTIOMETRIC PROBES 397
Guy Denuault, Géza Nagy, and Klára Tóth
I. Introduction 397
II. Basic Theory 415
III. Properties and Behavior of Ion-Selective Probes 417
IV. Potentiometric Measurements in Scanning Probe
Microscopies Other than SECM 422
V. Potentiometric Measurements in SECM 423
VI. Conclusion 441
References 442
viii Contents
11 BIOLOGICAL SYSTEMS 445
Benjamin R. Horrocks and Günther Wittstock
I. Approaches to Imaging Biological and Biochemical
Systems 445
n. Selected Applications 463
III. Conclusion and Outlook 504
IV. Abbreviations, Acronyms, and Symbols 510
References 512
12 PROBING REACTIONS AT SOLID/LIQUID INTERFACES 521
Julie V. Macpherson and Patrick R. Unwin
I. Introduction 521
n. Measurement of Adsorption/Desorption Kinetics and
Surface Diffusion Rates 523
in. Dissolution Kinetics of Ionic Single Crystals 536
IV. Corrosion Studies 573
V. Conclusions 588
References 590
13 MICRO- AND NANOPATTERNING USING THE
SCANNING ELECTROCHEMICAL MICROSCOPE 593
Daniel Mandler
I. Patterning by the Direct Mode of the SECM 594
n. Patterning by the Feedback Mode of the SECM 603
III. Perspective Approaches 623
References 625
14 CONCLUSIONS AND PROSPECTS 629
Allen J. Bard
I. Combining SECM with Other Techniques 629
II. Novel Interfaces 634
III. Instrumentation Improvements 636
References 637
Index 639
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illustrated | Illustrated |
indexdate | 2024-07-09T19:00:47Z |
institution | BVB |
isbn | 0824704711 |
language | English |
oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-009788777 |
oclc_num | 248247161 |
open_access_boolean | |
owner | DE-703 |
owner_facet | DE-703 |
physical | X, 650 S. Ill., graph. Darst. |
publishDate | 2001 |
publishDateSearch | 2001 |
publishDateSort | 2001 |
publisher | Dekker |
record_format | marc |
series2 | Monographs in electroanalytical chemistry and electrochemistry |
spelling | Scanning electrochemical microscopy ed. by Allen J. Bard ... New York [u.a.] Dekker 2001 X, 650 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Monographs in electroanalytical chemistry and electrochemistry Rastermikroskopie (DE-588)4330329-8 gnd rswk-swf Elektrochemie (DE-588)4014241-3 gnd rswk-swf Rastermikroskopie (DE-588)4330329-8 s Elektrochemie (DE-588)4014241-3 s DE-604 Bard, Allen J. 1933-2024 Sonstige (DE-588)123776368 oth HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009788777&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
spellingShingle | Scanning electrochemical microscopy Rastermikroskopie (DE-588)4330329-8 gnd Elektrochemie (DE-588)4014241-3 gnd |
subject_GND | (DE-588)4330329-8 (DE-588)4014241-3 |
title | Scanning electrochemical microscopy |
title_auth | Scanning electrochemical microscopy |
title_exact_search | Scanning electrochemical microscopy |
title_full | Scanning electrochemical microscopy ed. by Allen J. Bard ... |
title_fullStr | Scanning electrochemical microscopy ed. by Allen J. Bard ... |
title_full_unstemmed | Scanning electrochemical microscopy ed. by Allen J. Bard ... |
title_short | Scanning electrochemical microscopy |
title_sort | scanning electrochemical microscopy |
topic | Rastermikroskopie (DE-588)4330329-8 gnd Elektrochemie (DE-588)4014241-3 gnd |
topic_facet | Rastermikroskopie Elektrochemie |
url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009788777&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
work_keys_str_mv | AT bardallenj scanningelectrochemicalmicroscopy |