Atmospheric degradation mechanism of organic sulfur compounds:
Gespeichert in:
| Hauptverfasser: | , |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Wuppertal
Berg. Univ. Gesamthochsch., PC
2002
|
| Schriftenreihe: | Bericht / Bergische Universität, Gesamthochschule Wuppertal, Fachbereich 9, Physikalische Chemie
57 |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | II, 123 S. graph. Darst. |
Internformat
MARC
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| 100 | 1 | |a Benter, Thorsten |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a Atmospheric degradation mechanism of organic sulfur compounds |c Th. Benter ; Cecilia Arsene |
| 264 | 1 | |a Wuppertal |b Berg. Univ. Gesamthochsch., PC |c 2002 | |
| 300 | |a II, 123 S. |b graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 490 | 1 | |a Bericht / Bergische Universität, Gesamthochschule Wuppertal, Fachbereich 9, Physikalische Chemie |v 57 | |
| 650 | 7 | |a Abbaureaktion |2 gtt | |
| 650 | 7 | |a Atmosphäre / Chemie |2 gtt | |
| 650 | 7 | |a Schwefelorganische Verbindungen |2 gtt | |
| 650 | 0 | 7 | |a Abbaureaktion |0 (DE-588)4136352-8 |2 gnd |9 rswk-swf |
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| 689 | 0 | 1 | |a Atmosphäre |0 (DE-588)4003397-1 |D s |
| 689 | 0 | 2 | |a Abbaureaktion |0 (DE-588)4136352-8 |D s |
| 689 | 0 | |5 DE-604 | |
| 700 | 1 | |a Arsene, Cecilia |e Verfasser |4 aut | |
| 810 | 2 | |a Bergische Universität, Gesamthochschule Wuppertal, Fachbereich 9, Physikalische Chemie |t Bericht |v 57 |w (DE-604)BV001823295 |9 57 | |
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| 943 | 1 | |a oai:aleph.bib-bvb.de:BVB01-009764390 | |
Datensatz im Suchindex
| _version_ | 1807682975659196416 |
|---|---|
| adam_text |
CONTENTS
1
INTRODUCTION
.
1
1.1
SULPHUR-CONTAINING
COMPOUNDS
IN
THE
ATMOSPHERE
.
1
1.2
DIMETHYL
SULPHIDE
IN
THE
ATMOSPHERE
.4
1.2.1
SOURCES
AND
SINKS
OF
DIMETHYL
SULPHIDE
IN
THE
ATMOSPHERE
.
4
1.2.2
CHEMICAL
TRANSFORMATION
OF
DIMETHYL
SULPHIDE:
STATE
OF
ART
.
6
1.2.3
AEROSOL
FORMING
POTENTIAL
OF
DIMETHYL
SULPHIDE
.
9
1.3
AIMS
OF
THE
PRESENT
WORK
.
10
2
EXPERIMENTAL
SECTION
.
11
2.1
DESCRIPTION
OF
THE
REACTOR
.
11
2.2
MEASUREMENT
PROCEDURE
.
13
2.3
DATA
ANALYSIS
.
15
3
PRODUCT
STUDY
OF
THE
PHOTO-OXIDATION
OF
DIMETHYL
SULPHIDE
IN
NO
X
FREE
SYSTEMS
.
21
3.1
RESULTS
.
21
3.1.1
FT-IR
ANALYSIS
OF
STABLE
PRODUCTS
.22
3.1.2
IDENTIFICATION
OF
METHANE
SULPHINIC
ACID
(MSIA),
METHANE
SULPHONIC
ACID
(MSA)
AND
SULPHURIC
ACID
(H
2
SO
4
)
BY
ION
CHROMATOGRAPHY
(IC)
.
30
3.2
DISCUSSION
.
33
3.2.1
DIMETHYL
SULPHOXIDE
(DMSO)
FORMATION
.
33
3.2.2
DIMETHYL
SULPHONE
(DMSO2)
FORMATION
.
35
3.2.3
SULPHUR
DIOXIDE
(SO^
FORMATION
.
36
3.2.4
METHANE
SULPHONIC
ACID
(MSA)
FORMATION
IN
THE
GAS
PHASE
.
38
3.2.5
METHANE
THIOL
FORMATE
(MTF)
PRODUCTION
.
40
3.2.6
CARBONYL
SULPHIDE
(OCS)
FORMATION
.
41
3.2.7
DISCUSSION
OF
THE
ION
CHROMATOGRAPHIC
DATA
.
43
3.3
SUMMARY
OF
RESULTS
AND
CONCLUSIONS
.
44
4
PRODUCT
STUDY
OF
THE
PHOTO-OXIDATION
OF
DIMETHYL
SULPHIDE
IN
THE
PRESENCE
OF
NO
X
.
49
4.1
RESULTS
.
49
4.2
DISCUSSION
.
58
4.2.1
DIMETHYL
SULPHOXIDE
(DMSO)
AND
DIMETHYL
SULPHONE
(DMSOJ)
FORMATION
.
58
4.2.2
SULPHUR
DIOXIDE
(SOJ)
FORMATION
.
62
4.2.3
METHANE
SULPHONIC
ACID
(MSA)
AND
METHANE
SULPHONYL
PEROXY
NITRATE
(MSPN)
FORMATION
.
63
4.2.4
FORMATION
OF
CARBONYL
SULPHIDE
(OCS)
IN
THE
PRESENCE
OF
NO
X
.
66
4.3
SUMMARY
OF
RESULTS
AND
CONCLUSIONS
.
68
5
PRODUCT
STUDY
OF
THE
PHOTO-OXIDATION
OF
DIMETHYL
SULPHOXIDE
.
73
5.1
RESULTS
.
74
5.1.1
IDENTIFICATION
OF
METHANE
SULPHINIC
ACID
(MSIA)
AND
METHANE
SULPHONIC
ACID
(MSA)
BY
ION
CHROMATOGRAPHY
(IC)
.74
5.1.2
IDENTIFICATION
OF
PRODUCTS
FORMED
IN
THE
GAS-PHASE
BY
FT-IR
.
78
5.1.2.1
PRODUCTS
IDENTIFIED
IN
THE
PHOTO-OXIDATION
OF
DMSO
IN
THE
ABSENCE
OF
NO
X
.
78
5.1.2.2
PRODUCTS
IDENTIFIED
IN
THE
PHOTO-OXIDATION
OF
DMSO
IN
THE
PRESENCE
OF
NO
X
.
80
5.2
DISCUSSION
.
83
5.2.1
FORMATION
OF
METHANE
SULPHINIC
ACID
(MSIA).
83
5.2.2
PRODUCT
FORMATION
FROM
DMSO
PHOTO-OXIDATION
IN
THE
ABSENCE
OF
NO
X
.
84
5.2.3
PRODUCT
FORMATION
FROM
DMSO
PHOTO-OXIDATION
IN
THE
PRESENCE
OF
NO
X
.
86
5.5
SUMMARY
OF
RESULTS
AND
CONCLUSIONS
.
88
6
GENERAL
CONCLUSIONS
.
93
APPENDIX
A
ION
CHROMATOGRAPHIC
ANALYSIS
.
99
APPENDIX
B
GAS
PHASE
INFRARED
SPECTRUM
OF
METHANE
SULPHINIC
ACID
(TENTATIVE
ASSIGNMENT)
.
103
APPENDIX
C
GASES
AND
CHEMICALS
.
105
APPENDIX
D
ABBREVIATION
.
107
REFERENCES
.
109
II |
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| author | Benter, Thorsten Arsene, Cecilia |
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| illustrated | Illustrated |
| indexdate | 2024-08-18T00:27:05Z |
| institution | BVB |
| language | English |
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| physical | II, 123 S. graph. Darst. |
| publishDate | 2002 |
| publishDateSearch | 2002 |
| publishDateSort | 2002 |
| publisher | Berg. Univ. Gesamthochsch., PC |
| record_format | marc |
| series2 | Bericht / Bergische Universität, Gesamthochschule Wuppertal, Fachbereich 9, Physikalische Chemie |
| spelling | Benter, Thorsten Verfasser aut Atmospheric degradation mechanism of organic sulfur compounds Th. Benter ; Cecilia Arsene Wuppertal Berg. Univ. Gesamthochsch., PC 2002 II, 123 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Bericht / Bergische Universität, Gesamthochschule Wuppertal, Fachbereich 9, Physikalische Chemie 57 Abbaureaktion gtt Atmosphäre / Chemie gtt Schwefelorganische Verbindungen gtt Abbaureaktion (DE-588)4136352-8 gnd rswk-swf Atmosphäre (DE-588)4003397-1 gnd rswk-swf Schwefelorganische Verbindungen (DE-588)4180419-3 gnd rswk-swf Schwefelorganische Verbindungen (DE-588)4180419-3 s Atmosphäre (DE-588)4003397-1 s Abbaureaktion (DE-588)4136352-8 s DE-604 Arsene, Cecilia Verfasser aut Bergische Universität, Gesamthochschule Wuppertal, Fachbereich 9, Physikalische Chemie Bericht 57 (DE-604)BV001823295 57 DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009764390&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Benter, Thorsten Arsene, Cecilia Atmospheric degradation mechanism of organic sulfur compounds Abbaureaktion gtt Atmosphäre / Chemie gtt Schwefelorganische Verbindungen gtt Abbaureaktion (DE-588)4136352-8 gnd Atmosphäre (DE-588)4003397-1 gnd Schwefelorganische Verbindungen (DE-588)4180419-3 gnd |
| subject_GND | (DE-588)4136352-8 (DE-588)4003397-1 (DE-588)4180419-3 |
| title | Atmospheric degradation mechanism of organic sulfur compounds |
| title_auth | Atmospheric degradation mechanism of organic sulfur compounds |
| title_exact_search | Atmospheric degradation mechanism of organic sulfur compounds |
| title_full | Atmospheric degradation mechanism of organic sulfur compounds Th. Benter ; Cecilia Arsene |
| title_fullStr | Atmospheric degradation mechanism of organic sulfur compounds Th. Benter ; Cecilia Arsene |
| title_full_unstemmed | Atmospheric degradation mechanism of organic sulfur compounds Th. Benter ; Cecilia Arsene |
| title_short | Atmospheric degradation mechanism of organic sulfur compounds |
| title_sort | atmospheric degradation mechanism of organic sulfur compounds |
| topic | Abbaureaktion gtt Atmosphäre / Chemie gtt Schwefelorganische Verbindungen gtt Abbaureaktion (DE-588)4136352-8 gnd Atmosphäre (DE-588)4003397-1 gnd Schwefelorganische Verbindungen (DE-588)4180419-3 gnd |
| topic_facet | Abbaureaktion Atmosphäre / Chemie Schwefelorganische Verbindungen Atmosphäre |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009764390&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| volume_link | (DE-604)BV001823295 |
| work_keys_str_mv | AT benterthorsten atmosphericdegradationmechanismoforganicsulfurcompounds AT arsenececilia atmosphericdegradationmechanismoforganicsulfurcompounds |