Arsenic and arsenic compounds:
Gespeichert in:
| Format: | Buch |
|---|---|
| Sprache: | English |
| Veröffentlicht: |
Geneva
World Health Organization
2001
|
| Ausgabe: | 2. ed. |
| Schriftenreihe: | Environmental health criteria
224 |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | Mit einer Zsfassung in franz. und span. Sprache |
| Beschreibung: | XXVIII, 521 S. Ill., graph. Darst. |
| ISBN: | 9241572248 |
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Datensatz im Suchindex
| _version_ | 1804129066274521088 |
|---|---|
| adam_text | ENVIRONMENTAL HEALTH CRITERIA FOlf ty ** *
ARSENIC AND ARSENIC COMPOUNDS WO I
PREAMBLE xiii
ABBREVIATIONS xxv
1. SUMMARY 1
1.1 Properties and analytical procedures 1
1.2 Sources and occurrence of arsenic in the environment.. 1
1.3 Environmental transport and distribution 2
1.4 Environmental levels and human exposure 3
1.5 Kinetics and metabolism 4
1.6 Effects on laboratory animals and in vitro systems 6
1.7 Effects on human health 7
1.8 Effects on other organisms in the environment 8
2. PROPERTIES AND ANALYTICAL PROCEDURES 9
2.1 Identity 9
2.2 Chemical and physical properties of arsenic
compounds 9
2.3 Analytical procedures 15
2.4 Sample preparation and treatment 17
2.4.1 Sampling and collection 17
2.4.2 Oxidative digestion 17
2.4.3 Extraction 17
2.4.4 Supercritical fluid extraction 18
2.5 Macro measurement 18
2.6 Colorimetric methods 19
2.7 Methods for total inorganic arsenic 19
2.8 Atomic spectrometry 20
2.9 ICP methodologies 22
2.10 Voltammetry 22
2.11 Radiochemical methods 23
2.12 X ray spectroscopy 24
iii
2.13 Hyphenated techniques 24
I. SOURCES AND OCCURRENCE OF ARSENIC
IN THE ENVIRONMENT 28
3.1 Natural sources 28
3.2 Sources of environmental pollution 30
3.2.1 Industry 30
3.2.2 Past agricultural use 31
3.2.3 Sewage sludge 32
3.3 Uses 32
1. ENVIRONMENTAL TRANSPORT AND
DISTRIBUTION 34
4.1 Transport and distribution between media 34
4.1.1 Air 34
4.1.2 Freshwater and sediment 35
4.1.3 Estuarine and marine water and sediment 41
4.1.4 Soil 44
4.2 Biotransformation 48
4.2.1 Oxidation and reduction 49
4.2.2 Methylation 51
4.2.3 Degradation 54
4.2.3.1 Abiotic degradation 54
4.2.3.2 Biodegradation 55
4.2.4 Bioaccumulation 57
4.2.4.1 Microorganisms 57
4.2.4.2 Macroalgae 59
4.2.4.3 Aquatic invertebrates 60
4.2.4.4 Fish 62
4.2.4.5 Terrestrial plants 63
4.2.4.6 Terrestrial invertebrates 65
4.2.4.7 Birds 65
5. ENVIRONMENTAL LEVELS AND HUMAN
EXPOSURE 67
5.1 Environmental levels 67
5.1.1 Air 67
5.1.2 Precipitation 72
5.1.3 Surface water 72
5.1.4 Groundwater 75
5.1.5 Sediment 81
5.1.6 Sewage sludge 85
5.1.7 Soil 85
5.1.8 Biota 91
5.1.8.1 Freshwater 91
5.1.8.2 Marine 93
5.1.8.3 Terrestrial 95
5.2 General population exposure 98
5.2.1 Air 98
5.2.2 Food and beverages 99
5.2.3 Drinking water 102
5.2.4 Soil 103
5.2.5 Miscellaneous exposures 104
5.3 Occupational exposures 104
5.4 Total human intake of arsenic from all
environmental pathways 108
6. KINETICS AND METABOLISM IN LABORATORY
ANIMALS AND HUMANS 112
6.1 Inorganic arsenic 112
6.1.1 Absorption 112
6.1.1.1 Respiratory deposition and
absorption 112
6.1.1.2 Gastrointestinal absorption 115
6.1.1.3 Dermal absorption 123
6.1.1.4 Placental transfer 124
6.1.2 Distribution 125
6.1.2.1 Fate of inorganic arsenic in blood. 125
6.1.2.2 Tissue distribution 128
6.1.3 Metabolic transformation 134
6.1.3.1 Animal studies 136
6.1.3.2 Human studies 143
6.1.4 Elimination and excretion 146
6.1.4.1 Animal studies 146
6.1.4.2 Human studies 147
6.1.5 Retention and turnover 148
6.1.5.1 Animal studies 148
6.1.5.2 Human studies 149
6.1.6 Reaction with body components 149
2 Organic arsenic compounds 150
6.2.1 Absorption 150
6.2.1.1 Respiratory deposition and
absorption 150
6.2.1.2 Gastrointestinal absorption 150
6.2.1.3 Dermal absorption 152
6.2.1.4 Placental transfer 153
6.2.2 Distribution 153
6.2.2.1 Fate of organic arsenic in blood.... 153
6.2.2.2 Tissue distribution 154
6.2.3 Metabolic transformation 157
6.2.3.1 Animal studies 157
6.2.3.2 Human studies 159
6.2.4 Elimination and excretion 159
6.2.4.1 Animal studies 159
6.2.4.2 Human studies 163
6.2.5 Retention and turnover 163
6.3 Biomarkers of arsenic exposure 164
6.3.1 Arsenic in hair and nails 164
6.3.2 Blood arsenic 166
6.3.3 Arsenic and metabolites in urine 166
. EFFECTS ON LABORATORY MAMMALS AND
IN VITRO TEST SYSTEMS 168
7.1 Inorganic arsenic 168
7.1.1 Single exposure 168
7.1.1.1 Acute toxicity data 168
7.1.2 Short term exposure 172
7.1.2.1 Oral 172
7.1.2.2 Inhalation 172
7.1.2.3 Dermal 173
7.1.2.4 Parenteral 173
7.1.3 Long term exposure 173
7.1.3.1 Oral 173
7.1.3.2 Inhalation 174
7.1.3.3 Dermal 174
7.1.4 Skin and eye irritation; sensitization 174
7.1.4.1 Contact sensitivity 174
7.1.5 Reproductive toxicity, embryotoxicity, and
teratogenicity 174
7.1.5.1 In vivo embryo and fetal toxicity.. 174
7.1.5.2 In vitro embryo and fetal toxicity. 176
7.1.5.3 Teratogenicity 176
7.1.5.4 Gene expression 181
7.1.5.5 Induction of heat shock proteins... 181
7.1.5.6 Male reproductive toxicity 183
7.1.6 Genotoxicity and related end points 184
7.1.6.1 Bacteria 184
7.1.6.2 Mammalian cells 184
7.1.6.3 Human cells 187
7.1.6.4 In vivo genotoxicity 188
7.1.6.5 Mechanism of genotoxicity 189
7.1.6.6 Resistance/hypersensitivity to
arsenic cytotoxicity 192
7.1.7 Carcinogenicity 193
7.1.7.1 Pulmonary carcinogenicity 193
7.1.7.2 Skin rumorigenicity 197
7.1.7.3 Long term study in monkeys 197
7.1.7.4 Long term study in mice 198
7.1.8 Other special studies 199
7.1.8.1 Cardiovascular system 199
7.1.8.2 Nervous system 201
7.1.8.3 Skin 202
7.1.8.4 Immune system 205
7.1.8.5 Haem biosynthesis and urinary
excretion of porphyrins 207
7.1.8.6 Apoptosis 208
7.1.9 Factors modifying toxicity; toxicity of
metabolites 209
7.1.9.1 Interactions with other
compounds 209
7.1.9.2 Biological role of arsenic 212
7.1.9.3 Induction of proteins 212
7.1.10 Potential mechanisms of toxicity mode of
action 215
7.1.10.1 Toxicity of trivalent inorganic
arsenic 215
7.1.10.2 Toxicity of pentavalent inorganic
arsenic 216
7.1.10.3 Carcinogenicity 217
7.2 Organic arsenic compounds 218
7.2.1 Single exposure 218
7.2.1.1 Acute toxicity data 218
7.2.2 Short term exposure 223
7.2.2.1 Oral 223
7.2.3 Long term exposure 224
7.2.3.1 Oral 224
7.2.3.2 Inhalation 225
7.2.3.3 Dermal 225
7.2.4 Skin and eye irritation; sensitization 225
7.2.5 Reproductive toxicity, embryotoxicity, and
teratogenicity 225
7.2.5.1 In vivo embryo and fetal toxicity.. 225
7.2.5.2 Teratogenicity 226
7.2.6 Genotoxicity and related end points 227
7.2.6.1 Bacteria 227
7.2.6.2 Mammalian cells 227
7.2.6.3 Human cells 227
7.2.6.4 In vivo genotoxicity 228
7.2.6.5 Apoptosis 229
7.2.7 Carcinogenicity 229
7.2.7.1 Bladder 229
7.2.7.2 Promotion 229
7.2.8 Factors modifying toxicity; toxicity of
metabolites 230
7.2.8.1 Interaction withthiols 230
7.2.8.2 Inhibition of GSH reductase 231
7.2.8.3 Induction of proteins 231
7.2.9 Potential mechanisms of toxicity: mode of
action 232
7.2.9.1 Acute toxicity 232
7.2.9.2 Carcinogenicity 233
8. EFFECTS ON HUMANS 234
8.1 Short term effects 234
8.2 Long term effects: historical introduction 235
8.3 Levels of arsenic in drinking water in
epidemiological studies 236
8.4 Vascular diseases 239
8.4.1 Peripheral vascular disease 239
8.4.2 Cardio and cerebrovascular disease 252
8.4.3 Hypertension 257
8.5 Diabetes mellitus 258
8.6 Neurotoxicity 265
8.7 Cancer 267
8.7.1 Exposure via inhalation 267
8.7.1.1 Lung cancer 267
8.7.1.2 Cancer at other sites 283
8.7.2 Exposure via drinking water 285
8.7.3 Dermal effects, including skin cancer 307
8.8 Reproductive toxicity 318
8.9 Genotoxicity and related end points 331
9. EFFECTS ON OTHER ORGANISMS IN THE
ENVIRONMENT 346
9.1 Laboratory experiments 346
9.1.1 Microorganisms 346
9.1.1.1 Water 346
9.1.1.2 Soil 351
9.1.1.3 Bacterial resistance to arsenic 352
9.1.2 Aquatic organisms 353
9.1.2.1 Macroalgae 353
9.1.2.2 Aquatic plants 353
9.1.2.3 Invertebrates 354
9.1.2.4 Vertebrates 363
9.1.3 Terrestrial organisms 374
9.1.3.1 Plants 374
9.1.3.2 Invertebrates 378
9.1.3.3 Vertebrates 379
9.2 Field observations 382
9.2.1 Microorganisms 382
9.2.2 Aquatic organisms 382
9.2.3 Terrestrial organisms 382
9.2.3.1 Plants 382
9.2.3.2 Vertebrates 383
10. EVALUATION OF HUMAN HEALTH RISKS
AND EFFECTS ON THE ENVIRONMENT 385
10.1 Effects on human health 385
10.1.1 Acute effects 385
10.1.2 Vascular effects 385
10.1.3 Diabetes mellitus 386
10.1.4 Neurological effects 386
10.1.5 Cancer of the lung, bladder, and kidney 387
10.1.6 Cancer and precancerous lesions of the
skin 389
10.1.7 Cancer at other sites 389
10.1.8 Reproductive toxicity 390
10.1.9 Genotoxicity 390
10.1.10 Supporting data from experimental studies.. 392
10.1.11 Conclusions 392
10.2 Evaluation of effects on the environment 393
10.2.1 Exposure 393
10.2.2 Effects 396
10.2.3 Environmental modification of toxicity 401
10.2.4 Risk evaluation 401
11. RECOMMENDATIONS FOR FUTURE RESEARCH 404
11.1 Human health 404
11.2 Environmental 405
12. PREVIOUS EVALUATIONS BY INTERNATIONAL
BODIES 406
REFERENCES 407
RESUME 502
RESUMEN 512
|
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| id | DE-604.BV014187366 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T18:59:13Z |
| institution | BVB |
| institution_GND | (DE-588)308058-4 |
| isbn | 9241572248 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-009724883 |
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| open_access_boolean | |
| owner | DE-12 DE-Er8 |
| owner_facet | DE-12 DE-Er8 |
| physical | XXVIII, 521 S. Ill., graph. Darst. |
| publishDate | 2001 |
| publishDateSearch | 2001 |
| publishDateSort | 2001 |
| publisher | World Health Organization |
| record_format | marc |
| series | Environmental health criteria |
| series2 | Environmental health criteria |
| spelling | Arsenic and arsenic compounds the first and second drafts ... under the coordination of J. Ng ... 2. ed. Geneva World Health Organization 2001 XXVIII, 521 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Environmental health criteria 224 Mit einer Zsfassung in franz. und span. Sprache Arsen (DE-588)4003041-6 gnd rswk-swf Toxizität (DE-588)4078372-8 gnd rswk-swf Umwelttoxikologie (DE-588)4121813-9 gnd rswk-swf Arsenverbindungen (DE-588)4143104-2 gnd rswk-swf Arsen (DE-588)4003041-6 s Umwelttoxikologie (DE-588)4121813-9 s DE-604 Toxizität (DE-588)4078372-8 s Arsenverbindungen (DE-588)4143104-2 s Ng, J. Sonstige oth International Programme on Chemical Safety Sonstige (DE-588)308058-4 oth Environmental health criteria 224 (DE-604)BV000011459 224 HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009724883&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Arsenic and arsenic compounds Environmental health criteria Arsen (DE-588)4003041-6 gnd Toxizität (DE-588)4078372-8 gnd Umwelttoxikologie (DE-588)4121813-9 gnd Arsenverbindungen (DE-588)4143104-2 gnd |
| subject_GND | (DE-588)4003041-6 (DE-588)4078372-8 (DE-588)4121813-9 (DE-588)4143104-2 |
| title | Arsenic and arsenic compounds |
| title_auth | Arsenic and arsenic compounds |
| title_exact_search | Arsenic and arsenic compounds |
| title_full | Arsenic and arsenic compounds the first and second drafts ... under the coordination of J. Ng ... |
| title_fullStr | Arsenic and arsenic compounds the first and second drafts ... under the coordination of J. Ng ... |
| title_full_unstemmed | Arsenic and arsenic compounds the first and second drafts ... under the coordination of J. Ng ... |
| title_short | Arsenic and arsenic compounds |
| title_sort | arsenic and arsenic compounds |
| topic | Arsen (DE-588)4003041-6 gnd Toxizität (DE-588)4078372-8 gnd Umwelttoxikologie (DE-588)4121813-9 gnd Arsenverbindungen (DE-588)4143104-2 gnd |
| topic_facet | Arsen Toxizität Umwelttoxikologie Arsenverbindungen |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009724883&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| volume_link | (DE-604)BV000011459 |
| work_keys_str_mv | AT ngj arsenicandarseniccompounds AT internationalprogrammeonchemicalsafety arsenicandarseniccompounds |