Applied homogeneous catalysis with organometallic compounds: a comprehensive handbook ; in three volumes 3 Developments
Gespeichert in:
| Format: | Buch |
|---|---|
| Sprache: | English |
| Veröffentlicht: |
Weinheim
Wiley-VCH
2002
|
| Ausgabe: | 2., completely rev. and enlarged ed. |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XVIII S., S. 1034 - 1450 graph. Darst. |
| ISBN: | 3527304347 |
Internformat
MARC
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| 020 | |a 3527304347 |9 3-527-30434-7 | ||
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| 082 | 0 | |a 541.395 | |
| 245 | 1 | 0 | |a Applied homogeneous catalysis with organometallic compounds |b a comprehensive handbook ; in three volumes |n 3 |p Developments |c ed. by Boy Cornils ... |
| 250 | |a 2., completely rev. and enlarged ed. | ||
| 264 | 1 | |a Weinheim |b Wiley-VCH |c 2002 | |
| 300 | |a XVIII S., S. 1034 - 1450 |b graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 650 | 7 | |a Catalyse homogène |2 ram | |
| 650 | 7 | |a Composés organométalliques |2 ram | |
| 700 | 1 | |a Cornils, Boy |e Sonstige |4 oth | |
| 773 | 0 | 8 | |w (DE-604)BV014160016 |g 3 |
| 856 | 4 | 2 | |m DNB Datenaustausch |q application/pdf |u http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009705595&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |3 Inhaltsverzeichnis |
| 943 | 1 | |a oai:aleph.bib-bvb.de:BVB01-009705595 | |
Datensatz im Suchindex
| _version_ | 1816444713926918144 |
|---|---|
| adam_text |
CONTENTS
VOLUME
1:
APPLICATIONS
1
INTRODUCTION
(B.
CORNILS,
W.A.
HERRMANN)
.
1
INTRODUCTION
.
3
HISTORICAL
GLOSSARY
.
16
2
APPLIED
HOMOGENEOUS
CATALYSIS
.
29
2.1
CARBON
MONOXIDE
AND
SYNTHESIS
GAS
CHEMISTRY
.
31
2.1.1
HYDROFORMYLATION
(OXO
SYNTHESIS,
ROELEN
REACTION)
(C.D.
FROHNING,
C.W.
KOHLPAINTNER,
H.-W.
BOHNEN)
.
31
2.1.1.1
INTRODUCTION
.
31
2.1.1.2
FUNDAMENTAL
PRINCIPLES
.
34
2.1.1.3
KINETICS,
MECHANISM,
AND
PROCESS
PARAMETERS
.
45
2.1.1.4
COMMERCIAL
APPLICATIONS
.
61
2.1.1.5
RECENT
DEVELOPMENTS
.
85
2.1.2
CARBONYLATIONS
.
104
2.1.2.1
SYNTHESIS
OF
ACETIC
ACID
AND
ACETIC
ACID
ANHYDRIDE
FROM
METHANOL
(P.
TORRENCE)
.
104
2.1.2.2
SYNTHESIS
OF
PROPIONIC
AND
OTHER
ACIDS
(A.
HOHN)
.
136
2.1.2.3
CARBONYLATION
OF
BENZYL-X
AND
ARYL-X
COMPOUNDS
(M.
BELLER)
.
145
2.1.2.4
AMIDOCARBONYLATION
(J.
F.
KNIFTON)
.
156
2.1.2.5
OXIDATIVE
CARBONYLATION
(A.
KLAUSENER,
J.-D.
JENTSCH)
.
.
.
164
2.1.2.6
OTHER
CARBONYLATIONS
(M.
BELLER,
A.M.
TAFESH)
.
182
2.2
HYDROGENATION
(H
BRUNNER)
.
195
2.2.1
HOMOGENEOUS
HYDROGENATION
.
195
2.2.1.1
THE
HYDROGEN
MOLECULE
.
195
2.2.1.2
CLASSICAL
TRANSITION
METAL
HYDRIDES
.
195
2.2.1.3
NONCLASSICAL
DIHYDROGEN
COMPLEXES
.
196
2.2.1.4
HOMOGENEOUS
HYDROGENATION
OF
ORGANIC
SUBSTRATES
.
198
2.2.1.5
ENANTIOSELECTIVE
HYDROGENATION
OF
PROCHIRAL
SUBSTRATES
.
.
.
200
VI
CONTENTS
2.2.1.6
ISOLATED
CATALYSTS
VERSUS
IN-SITU
CATALYSTS
.
203
2.2.1.7
TRANSFER
HYDROGENATION
.
204
2.2.1.8
HYDROGENOLYSIS
.
204
2.2.1.9
MECHANISMS
.
205
2.2.1.10
INDUSTRIAL
APPLICATIONS
.
209
2.2.2
COMMERCIAL
ENANTIOSELECTIVE
HYDROGENATION
.
210
2.3
REACTIONS
OF
UNSATURATED
COMPOUNDS
.
213
2.3.1
POLYMERIZATION,
OLIGOMERIZATION,
AND
COPOLYMERIZATION
OF
OLEFINS
.
213
2.3.1.1
CHEMICAL
BACKGROUND
(W.
KAMINSKY,
M.
ARNDT-ROSENAU)
.
.
213
2.3.1.2
CHEMICAL
ENGINEERING
AND
APPLICATIONS
(L.
L.
BOHM)
.
230
2.3.1.3
OLIGOMERIZATION
OF
ETHYLENE
TO
HIGHER
LINEAR
A-OLEFINS
(D.
VOGT)
.
240
2.3.1.4
DIMERIZATION
AND
CODIMERIZATION
(H.
OLIVIER-BOURBIGOU,
L.
SAUSSINE)
.
253
2.3.1.5
EVOLUTION
OF
THE
SYNTHESIS
OF
GROUP
4
METALLOCENE
CATALYST
COMPONENTS
TOWARD
INDUSTRIAL
PRODUCTION
(C.
FRITZE,
P.
MULLER,
L.
RESCONI)
.
265
2.3.2
REACTIONS
OF
OTHER
UNSATURATED
COMPOUNDS
.
274
2.3.2.1
REACTIONS
OF
ALKYNES
(J.
HENKELMANN,
J.-D.
ARNDT,
R.
KESSINGER)
.
274
2.3.2.2
STEREOSPECIFIC
POLYMERIZATION
OF
BUTADIENE
OR
ISOPRENE
(R.
TAUBE,
G.
SYLVESTER)
.
285
2.3.2.3
A
CLEAN
ROUTE
TO
METHACRYLATES
VIA
CARBONYLATION
OF
ALKYNES
(E.
DRENT,
W.
W.
JAGER,
J.
J.
KEIJSPER,
F.G.M.
NIELE)
.
316
2.3.3
METATHESIS
(J.
C.
MOL)
.
328
2.3.3.1
INTRODUCTION
.
328
2.3.3.2
SCOPE
OF
THE
REACTION
.
329
2.3.3.3
REACTION
MECHANISM
AND
CATALYSTS
IN
GENERAL
.
333
2.3.3.4
HOMOGENEOUS
CATALYST
SYSTEMS
.
335
2.3.3.5
INDUSTRIAL
APPLICATIONS
.
339
2.3.3.6
CONCLUSIONS
.
341
2.3.4
THE
ALTERNATING
COPOLYMERIZATION
OF
ALKENES
AND
CARBON
MONOXIDE
(E.
DRENT,
J.A.M.
VAN
BROEKHOVEN,
P.H.M.
BUDZELAAR)
.
.
.
344
2.3.4.1
INTRODUCTION
.
344
2.3.4.2
HISTORY
OF
POLYKETONES
.
344
2.3.4.3
COPOLYMERIZATION
OF
ETHYLENE
AND
CO
.
346
2.3.4.4
SCOPE
OF
OLEFIN/CO
COPOLYMERIZATION
.
356
2.3.4.5
CONCLUSIONS
.
358
CONTENTS
VII
2.3.5
TELOMERIZATION
(HYDRODIMERIZATION)
OF
OLEFINS
(N.
YOSHIMURA)
.
361
2.3.5.1
INTRODUCTION
.
361
2.3.5.2
DEVELOPMENT
OF
TECHNOLOGIES
.
362
2.3.5.3
PROCESS
FOR
THE
MANUFACTURE
OF
1-OCTANOL
.
366
2.3.5.4
DEVELOPMENT
AND
SCOPE
.
366
2.3.6
CYCLOOLIGOMERIZATIONS
AND
CYCLO-CO-OLIGOMERIZATIONS
OF
1,3-DIENES
(G.
WILKE,
A.
ECKERLE)
.
368
2.3.6.1
INTRODUCTION
.
368
2.3.6.2
CYCLODIMERIZATION
AND
CYCLOTRIMERIZATION
OF
BUTADIENE
AND
SUBSTITUTED
1,3-DIENES
.
370
2.3.6.3
CYCLO-CO-OLIGOMERIZATION
OF
1,3-DIENES
WITH
OLEFINS
AND
ALKYNES
.
374
2.3.6.4
MECHANISTIC
CONSIDERATIONS
.
377
2.3.6.5
SUMMARY
.
379
2.3.7
CATALYZED
POLYMERISATION
OF
EPOXY
RESINS
(M.
DORING)
.
.
.
383
2.4
OXIDATIONS
.
386
2.4.1
OXIDATION
OF
OLEFINS
TO
CARBONYL
COMPOUNDS
(WACKER
PROCESS)
(R.
JIRA)
.
386
2.4.1.1
HISTORICAL
AND
ECONOMIC
BACKGROUND
.
386
2.4.1.2
CHEMICAL
BACKGROUND
.
386
2.4.1.3
KINETICS
AND
MECHANISM
.
389
2.4.1.4
TECHNICAL
APPLICATIONS
(WACKER-HOECHST-PROCESSES)
.
397
2.4.1.5
APPLICATION
OF
THE
OLEFIN
OXIDATION
TO
ORGANIC
SYNTHESES
.
.
402
2.4.2
HOMOGENEOUS
OXIDATIVE
ACETOXYLATION
OF
ALKENES
(I.
I.
MOISEEV,
M.N.
VARGAFTIK)
.
406
2.4.2.1
INTRODUCTION
.
406
2.4.2.2
MECHANISTIC
CONSIDERATIONS
.
407
2.4.2.3
GIANT
CLUSTER
CATALYZED
REACTION
.
409
2.4.3
SYNTHESIS
OF
OXIRANES
(R.
A.
SHEIDON)
.
412
2.4.3.1
HISTORICAL
DEVELOPMENT
.
412
2.4.3.2
METAL-CATALYZED
EPOXIDATION
WITH
ALKYL
HYDROPEROXIDES:
KINETICS
AND
MECHANISM
.
413
2.4.3.3
COMMERCIAL
OXIRANE
PROCESSES
.
417
2.4.3.4
SCOPE
AND
APPLICATIONS
IN
ORGANIC
SYNTHESIS
.
419
2.4.3.5
RECENT
DEVELOPMENTS
AND
FUTURE
PROSPECTS
.
421
2.4.4
ALIPHATIC
CARBOXYLIC
ACIDS
VIA
ALIPHATIC
ALDEHYDES
(F.
KOCH)
.
427
2.4.4.1
GENERAL
.
427
2.4.4.2
CATALYSTS
.
428
2.4.4.3
KINETICS
AND
MECHANISM
.
429
2.4.4.4
TECHNICAL
PROCESS
.
430
2.4.4.5
FUTURE
TRENDS
.
431
VIII
CONTENTS
2.4.5
OXIDATION
OF
ARENES
AND
ALKYL-SUBSTITUTED
AROMATIC
COMPOUNDS
.
433
2.4.5.1
OXIDATION
OF
ARENES
TO
QUINONES
(R.
W.
FISCHER)
.
433
2.4.5.2
OXIDATION
OF
ALKYL-SUBSTITUTED
AROMATIC
COMPOUNDS
WITH
AIR
(R.'W.
FISCHER,
F.
ROHRSCHEID)
.
443
2.5
REACTIONS
WITH
HYDROGEN
CYANIDE
(HYDROCYANATION)
(S.
KRILL)
.
468
2.5.1
INTRODUCTION
AND
SCOPE
.
468
2.5.2
MECHANISTIC
ASPECTS
OF
HYDROCYANATION
.
469
2.5.3
HYDROCYANATION
OF
OLEFINS
.
470
2.5.3.1
HYDROCYANATION
OF
NON-ACTIVATED
MONOOLEFINS
.
470
2.5.3.2
HYDROCYANATION
OF
FUNCTIONALIZED
OLEFINS
.
476
2.5.4
HYDROCYANATION
OF
ALKYNES
.
479
2.5.5
HYDROCYANATION
OF
DIENES
.
481
2.5.5.1
ADIPONITRILE
SYNTHESIS
VIA
HYDROCYANATION
OF
BUTADIENE
.
.
.
481
2.5.5.2
HYDROCYANATION
OF
OTHER
DIENES
.
484
2.5.6
HYDROCYANATION
OF
ALDEHYDES/KETONES
.
485
2.6
HYDROSILYLATION
AND
RELATED
REACTIONS
OF
SILICON
COMPOUNDS
(B.
MARCINIEC)
.
491
2.6.1
HYDROSILYLATION
.
491
2.6.1.1
GENERAL
SCOPE
AND
APPLICATIONS
.
491
2.6.1.2
HOMOGENEOUS
CATALYSTS
.
495
2.6.1.3
IMMOBILIZED
METAL
COMPLEXES
AS
CATALYSTS
.
500
2.6.1.4
PHOTO
AND
PEROXIDE-INITIATED
CATALYSIS
BY
METAL
COMPLEXES
.
501
2.6.2
DEHYDROGENATIVE
COUPLING
REACTIONS
.
502
2.6.2.1
DEHYDROGENATIVE
SILYLATION
OF
ALKENES
AND
ALKYNES
WITH
HYDROSILANES
.
502
2.6.2.2
SILYLATIVE
COUPLING
OF
ALKENES
WITH
VINYLSILANES
.
504
2.6.2.3
DEHYDROCOUPLING
OF
HYDROSILANES
.
505
2.6.3
SILYLCARBONYLATION
.
506
2.7
REACTION
WITH
NITROGEN
COMPOUNDS:
HYDROAMINATION
(R.
TAUBE)
.
513
2.7.1
INTRODUCTION
.
513
2.7.2
GENERAL
MECHANISTIC
ASPECTS
.
513
2.7.3
THE
DIFFERENT
CATALYST
SYSTEMS
.
516
2.7.3.1
CATALYST
SYSTEMS
CONTAINING
ALKALI
METALS
.
516
2.7.3.2
CATALYST
SYSTEMS
CONTAINING
LANTHANIDES
.
518
CONTENTS
IX
2.7.3.3
CATALYST
SYSTEMS
CONTAINING
IRIDIUM
.
520
2.7.3.4
CATALYST
SYSTEMS
CONTAINING
IRON
OR
RUTHENIUM
.
522
2.7.3.5
CATALYST
SYSTEMS
CONTAINING
RHODIUM
.
522
2.7.4
PERSPECTIVES
.
524
2.8
REACTIONS
OF
HYDROCARBONS
AND
OTHER
SATURATED
COMPOUNDS
.
525
2.8.1
OXIDATIONS
.
525
2.8.1.1
HOMOGENEOUS
CATALYSIS
IN
THE
OXIDATION
OF
HYDROCARBONS
TO
ACETIC
ACID
(
C.
C.
HOBBS,
JR.)
.
525
2.8.1.2
SYNTHESIS
OF
DIMETHYL
TEREPHTHALATE/TEREPHTHALIC
ACID
AND
POLY
(ETHYLENE
TEREPHTHALATE)
(D.
A.
SCHIRALDI)
.
544
2.8.2
HALOGENATIONS
(W.A.
HERRMANN,
M.
STOECKL)
.
552
2.8.2.1
INTRODUCTION
.
552
2.8.2.2
SUBSTITUTION
REACTIONS
.
552
2.8.2.3
ADDITION
REACTIONS
.
553
2.9
ASYMMETRIC
SYNTHESES
(R.
NOYORI,
S.
HASHIGUCHI,
T.
YAMANO)
.
557
2.9.1
INTRODUCTION
.
557
2.9.2
PREPARATION
OF
SELECTED
STRUCTURES
.
557
2.9.2.1
TERPENES
.
557
2.9.2.2
CARBOXYLIC
ACIDS
.
559
2.9.2.3
PYRETHROIDS
.
563
2.9.2.4
PROSTAGLANDINS
.
565
2.9.2.5
SIMPLE
SECONDARY
ALCOHOLS
.
565
2.9.2.6
AMINO
ALCOHOLS
AND
RELATED
COMPOUNDS
.
568
2.9.2.7
AMINO
ACIDS
.
572
2.9.2.8
ALKALOIDS
.
574
2.9.2.9
CARBAPENEM
ANTIBIOTICS
.
576
2.9.2.10
SULFOXIDES
.
577
2.9.2.11
1,2-DIOLS
AND
RELATED
COMPOUNDS
.
578
2.9.2.12
MISCELLANEOUS
.
578
2.9.3
CONCLUSIONS
.
580
2.10
FERROCENE
AS
A
GASOLINE
AND
FUEL
ADDITIVE
(WA.
HERRMANN)
.
586
2.10.1
INTRODUCTION
.
586
2.10.2
COMMERCIAL
SYNTHESIS
.
586
2.10.3
THE
GASOLINE
AND
FUEL
ADDITIVE
.
588
2.10.4
RELATED
ANTIKNOCKING
ADDITIVES
.
589
X
CONTENTS
2.11
THE
SUZUKI
CROSS-COUPLING
(W.
A.
HERRMANN)
.
591
2.11.1
INTRODUCTION
.
591
2.11.2
ADVANTAGES
AND
DRAWBACKS
.
591
2.11.3
CATALYSTS,
SUBSTRATES,
CONDITIONS
.
592
2.11.3.1
CURRENT
STATUS
.
592
2.11.3.2
RECENT
CATALYST
IMPROVEMENTS
.
592
2.11.3.3
TWO-PHASE
CATALYSIS
.
595
2.11.3.4
SUZUKI-RELATED
COUPLING
.
595
2.11.4
MECHANISM
.
596
2.11.5
COMMERCIAL
APPLICATION
AND
FURTHER
DEVELOPMENT
.
597
VOLUME
2:
DEVELOPMENTS
3
RECENT
DEVELOPMENTS
IN
HOMOGENEOUS
CATALYSIS
.
599
3.1
DEVELOPMENT
OF
METHODS
.
601
3.1.1
HOMOGENEOUS
CATALYSTS
AND
THEIR
HETEROGENIZATION
OR
IMMOBILIZATION
(B.
COMILS,
W.A.
HERRMANN)
.
601
3.1.1.1
IMMOBILIZATION
BY
AQUEOUS
CATALYSTS
(B.
COMILS,
W.A.
HERRMANN)
.
603
3.1.1.2
IMMOBILIZATION
BY
OTHER
LIQUIDS
.
634
3.1.1.2.1
FLUOROUS
PHASES
(I.
T.
HORVATH)
.
634
3.1.1.2.2
NON-AQUEOUS
IONIC
LIQUIDS
(V.P.W.
BOHM)
.
639
3.1.1.3
IMMOBILIZATION
(P.
PANSTER,
S.
WIELAND)
.
646
3.1.1.4
SURFACE
ORGANOMETALLIC
CHEMISTRY
(J.-M.
BASSET,
G.P.
NICCOLAI)
.
664
3.1.1.5
LIGAND-STABILIZED
CLUSTERS
AND
COLLOIDS
(G.
SCHMID)
.
677
3.1.1.6
NEW
GENERATION
OF
RE-IMMOBILIZED
CATALYSTS
(H.
BAHRMANN)
.
684
3.1.1.7
NEW
REACTIONS
(J.
HERWIG)
.
694
3.1.2
MOLECULAR
MODELING
IN
HOMOGENEOUS
CATALYSIS
(R.
SCHMID,
W
HIERINGER,
D.
GLEICH,
T.
STRASSNER)
.
700
3.1.2.1
MOLECULAR
MODELING
TECHNIQUES
(R.
SCHMID)
.
700
3.1.2.2
APPLICATIONS
.
712
3.1.2.2.1
MODELING
OF
HOMOGENEOUS
OLEFIN
POLYMERIZATION
CATALYSTS
(R.
SCHMID)
.
712
CONTENTS
XI
3.1.2.2.2
PALLADIUM-CATALYZED
C-C
COUPLING
REACTIONS:
THE
HECK
REACTION
(W.
HIERINGER)
.
721
3.1.2.2.3
HYDROFORMYLATION
(D.
GLEICH)
.
727
3.1.2.2.4
C-H
ACTIVATION
(T.
STRASSNER)
.
737
3.1.3
HIGH-THROUGHPUT
APPROACHES
TO
HOMOGENEOUS
CATALYSIS
(V.
MURPHY,
H.
W.
TURNER,
T.
WESKAMP)
.
740
3.1.3.1
INTRODUCTION
.
740
3.1.3.2
PRINCIPAL
WORKFLOW
.
741
3.1.3.3
ANALYSIS
IN
HIGH-THROUGHPUT
FORMAT
.
745
3.1.3.4
DATA
MANAGEMENT
AND
SOFTWARE
.
746
3.1.3.5
DISCOVERY
SCREENING
WORKFLOW
FOR
NEW
POLYOLEFIN
CATALYSTS
.
747
3.1.4
CHEMICAL
REACTION
ENGINEERING
ASPECTS
OF
HOMOGENEOUSLY
CATALYZED
PROCESSES
(M.
BAEMS,
P.
CLAUS)
.
748
3.1.4.1
KINETICS
IN
HOMOGENEOUS
CATALYSIS
.
750
3.1.4.2
ASPECTS
OF
CATALYST
RECYCLING
.
759
3.1.5
INTRODUCTION
TO
SELECTED
MULTICOMPONENT
AND
MULTIFUNCTIONAL
CATALYSTS
(D.
HESSE)
.
762
3.1.5.1
INTRODUCTION
.
762
3.1.5.2
ADVANTAGES
IN
THE
USE
OF
MULTICOMPONENT
OR
MULTIFUNCTIONAL
CATALYSTS
.
764
3.1.5.3
PROBLEMS
IN
THE
USE
OF
MULTIFUNCTIONAL
OR
MULTICOMPONENT
CATALYSTS
.
772
3.1.5.4
CONCLUSIONS
.
773
3.1.6
CATALYTIC
CARBON-CARBON
COUPLING
BY
PALLADIUM
COMPLEXES:
HECK
REACTIONS
(W.A.
HERRMANN)
.
775
3.1.6.1
INTRODUCTION
.
775
3.1.6.2
HISTORY
.
775
3.1.6.3
DEFINITION
.
776
3.1.6.4
CATALYSTS
AND
REACTION
CONDITIONS
.
777
3.1.6.5
SCOPE
AND
LIMITATIONS
.
778
3.1.6.6
MECHANISM
.
782
3.1.6.7
CATALYST
DEACTIVATION
.
784
3.1.6.8
INDUSTRIAL
APPLICATIONS
AND
PERSPECTIVES
.
786
3.1.7
CATALYTIC
CYCLOPROPANATION
(A.
F.
NOELS,
A.
DEMONCEAU)
.
.
793
3.1.7.1
INTRODUCTION
.
793
3.1.7.2
TRANSITION
METAL
CATALYZED
CYCLOPROPANATIONS
.
794
3.1.7.3
RECENT
DEVELOPMENTS
AND
APPLICATIONS
.
798
3.1.7.4
CONCLUSION:
IN
SEARCH
OF
NEW
CATALYSTS
.
805
3.1.8
THE
FISCHER-TROPSCH
SYNTHESIS
-
MOLECULAR
MODELS
FOR
HOMOGENEOUS
CATALYSIS?
(W.A.
HERRMANN)
.
808
3.1.8.1
INTRODUCTION
.
808
3.1.8.2
HISTORICAL
AND
ECONOMIC
BACKGROUND
.
809
3.1.8.3
TECHNOLOGICAL
FEATURES
.
811
XII
CONTENTS
3.1.8.4
MECHANISTIC
CONSIDERATIONS
.
811
3.1.8.5
ASSESSMENT
AND
PERSPECTIVES
.
819
3.1.9
ARENE
COUPLING
REACTIONS
(W.
A.
HERRMANN)
.
822
3.1.9.1
INTRODUCTION
.
822
3.1.9.2
ARYL-ARYL
COUPLING
.
823
3.1.9.3
GRIGNARD
CROSS-COUPLING
.
824
3.1.9.4
PHENOL
COUPLING
.
826
3.1.9.5
PERSPECTIVES
.
827
3.1.10
TAILORING
OF
CATALYSTS:
A-HETEROCYCLIC
CARBENES
AS
AN
EXAMPLE
OF
CATALYST
DESIGN
(W.
A.
HERRMANN,
K.
DENK,
C.
W.
K.
GSTOTTMAYR)
.
829
3.1.10.1
INTRODUCTION
.
829
3.1.10.2
LIGAND
DESIGN
FOR
A-HETEROCYCLIC
CARBENES
(NHC)
.
829
3.1.10.3
CATALYTIC
APPLICATIONS
.
832
3.1.11
MICELLAR
CATALYSIS
(G.
OEHME)
.
835
3.1.11.1
INTRODUCTION
.
835
3.1.11.2
EXAMPLES
OF
MICELLAR-PROMOTED
REACTIONS
.
837
3.1.11.3
REACTIONS
IN
REVERSE
MICELLES
.
839
3.11.1.4
LIMITS
AND
NEW
DEVELOPMENTS
.
840
3.1.12
SULFUR
IN
HOMOGENEOUS
CATALYSIS
(P
KALCK,
P.
SERP)
.
842
3.1.12.1
INTRODUCTION
.
842
3.1.12.2
SULFUR
IN
CARBONYLATION
REACTIONS
.
843
3.1.12.3
SULFUR
IN
HYDROGENATION,
ISOMERIZATION,
AND
RELATED
REACTIONS
.
845
3.1.12.4
SULFUR
IN
CARBON-CARBON
COUPLING
REACTIONS
.
846
3.1.12.5
MISCELLANEOUS
REACTIONS
.
847
3.1.12.6
CONCLUSIONS
.
848
3.1.13
HOMOGENEOUS
CATALYSIS
USING
SUPERCRITICAL
FLUIDS
(W.
LEITNER)
.
852
3.1.13.1
INTRODUCTION
.
852
3.1.13.2
SINGLE-PHASE
CATALYSIS
USING
SCFS
AS
SOLVENTS
.
854
3.1.13.3
MULTIPHASE
CATALYSIS
USING
SCFS
AS
SOLVENTS
.
862
3.1.13.4
CONCLUSIONS
AND
OUTLOOK
.
867
3.2
SPECIAL
CATALYSTS
AND
PROCESSES
.
872
3.2.1
BIOCATALYSIS
AND
ENZYME-ANALOGOUS
PROCESSES
(C.
SCHULTZ,
H.
GROGER,
C.
DINKEL,
K.
DRAUZ,
H.
WALDMANN)
.
872
3.2.1.1
INTRODUCTION
.
872
3.2.1.2
EXAMPLES
OF
ENZYMATIC
CONVERSIONS
.
873
3.2.1.3
ENZYME-ANALOGOUS
CATALYSTS
.
886
3.2.1.4
COMMERCIAL
APPLICATIONS
.
887
3.2.1.5
OUTLOOK
.
906
CONTENTS
XHI
3.2.2
TEMPLATE
OR
HOST/GUEST
RELATIONS
(F.
VOGTLE,
R.
HOSS,
M.
HANDEL)
.
911
3.2.2.1
INTRODUCTION
.
912
3.2.2.2
METAL
CATIONS
AS
TEMPLATES
.
913
3.2.2.3
NEUTRAL
MOLECULES
AS
(SUPRAMOLECULAR)
TEMPLATES
.
914
3.2.2.4
COVALENT
MOLECULES
AS
TEMPLATES
.
922
3.2.2.5
KINETIC
AND
THERMODYNAMIC
TEMPLATE
EFFECTS
.
926
3.2.2.6
POSITIVE
AND
NEGATIVE
TEMPLATES
.
928
3.2.2.7
SELF-ORGANIZATION
.
928
3.2.2.8
FURTHER
DEVELOPMENTS
AND
APPLICATIONS
.
935
3.2.2.9
CONCLUSIONS
AND
OUTLOOK
.
937
3.2.3
MEMBRANE
REACTORS
IN
HOMOGENEOUS
CATALYSIS
(U.
KRAGL,
C.
DREISBACH)
.
941
3.2.3.1
INTRODUCTION
.
941
3.2.3.2
CLASSIFICATION
AND
EXAMPLES
OF
MEMBRANE
REACTORS
.
942
3.2.3.3
MEMBRANE
REACTORS
FOR
HOMOGENEOUSLY
SOLUBLE
CATALYSTS
.
.
947
3.2.3.4
SUMMARY
AND
OUTLOOK
.
950
3.2.4
PHASE-TRANSFER
CATALYSIS
AND
RELATED
SYSTEMS
(Y.
GOLDBERG,
H.
ALPER)
.
953
3.2.4.1
INTRODUCTION
.
953
3.2.4.2
HOMOGENEOUS
TRANSITION-METAL
CATALYZED
REACTIONS
UNDER
PHASE-TRANSFER
CONDITIONS
.
954
3.2.4.3
TRANSITION-METAL
CONTAINING
PHASE-TRANSFER
AGENTS
AND
THEIR
USE
IN
SYNTHESIS
.
968
3.2.4.4
CONCLUSIONS
.
969
3.2.5
RARE
EARTH
METALS
IN
HOMOGENEOUS
CATALYSIS
(R.
ANWANDER)
.
974
3.2.5.1
INTRODUCTION
.
974
3.2.5.2
CATALYTIC
POTENTIAL
.
976
3.2.5.3
PRECATALYSTS
.
977
3.2.5.4
CARBON-CARBON
BOND-FORMING
REACTIONS
.
978
3.2.5.5
CARBON-HETEROELEMENT
BOND-FORMING
REACTIONS
.
997
3.2.5.6
CATALYST
STRUCTURE
.
1005
3.2.5.7
PERSPECTIVES
.
1007
3.2.6
RECENT
PROGRESS
IN
SPECIAL
PHOSPHORUS-CONTAINING
AUXILIARIES
FOR
HOMOGENEOUS
ENANTIOSELECTIVE
CATALYSIS
(F.
AGBOSSOU-NIEDERCOM)
.
1014
3.2.6.1
INTRODUCTION
.
1014
3.2.6.2
MONOPHOSPHINES
.
1015
3.2.6.3
BI(DI,BIS)PHOSPHINES
.
1020
3.2.6.4
HETEROFUNCTIONALIZED
MULTIDENTATE
P-CONTAINING
CHIRAL
AUXILIARIES
.
1024
3.2.6.5
IMMOBILIZATION
AND
RECYCLING
.
1025
3.2.6.6
CONCLUSIONS
.
1027
XIV
CONTENTS
VOLUME
3:
DEVELOPMENTS
(CONTINUED)
3.2.7
HOMOLOGATION
(H.
BAHRMANN)
.
1034
3.2.7.1
HISTORICAL
BACKGROUND
.
1034
3.2.7.2
CHEMICAL
BASICS
AND
APPLICATIONS
.
1035
3.2.7.3
MECHANISM
OF
REACTION
.
1040
3.2.7.4
TECHNICAL
APPLICATIONS
.
1042
3.2.7.5
FUTURE
PROSPECTS
.
1044
3.2.8
HOMOGENEOUS
ELECTROCATALYSIS
(D.
ASTRUC)
.
1046
3.2.8.1
INTRODUCTION
.
1046
3.2.8.2
ELECTRON-TRANSFER-CHAIN
(ETC)
CATALYZED
REACTIONS
.
1047
3.2.8.3
ATOM-TRANSFER-CHAIN
(ATC)
CATALYSIS
.
1055
3.2.8.4
CONCLUSIONS
.
1057
3.2.9
HOMOGENEOUS
PHOTOCATALYSIS
(A.
HEUMANN,
M.
CHANON)
.
.
1060
3.2.9.1
DEFINITIONS
.
1060
3.2.9.2
SYNTHESIS
AND
ACTIVATION
-
WHAT
HV
METAL
CATALYSIS
CAN
DO
BETTER?
.
1065
3.2.9.3
CONCLUSION:
WHAT
PHOTOCHEMICAL
TECHNIQUES
CAN
PROVIDE
IN
MECHANISTIC
STUDIES
OF
TRANSITION
METAL
CATALYSIS
.
1074
3.2.10
OLEFINS
FROM
ALDEHYDES
(W.A.
HERRMANN)
.
1078
3.2.10.1
INTRODUCTION
.
1078
3.2.10.2
THE
CATALYTIC
APPROACH
.
1079
3.2.10.3
CATALYSTS
.
1080
3.2.10.4
SCOPE
OF
REACTION,
REAGENTS,
AND
SIDE
REACTIONS
.
1081
3.2.10.5
MECHANISM
.
1082
3.2.10.6
PERSPECTIVES
.1085
3.2.11
WATER-GAS
SHIFT
REACTION
(W.A.
HERRMANN,
M.
MUEHLHOFER)
.
1086
3.2.11.1
INTRODUCTION
.
1086
3.2.11.2
DEFINITION
.
1087
3.2.11.3
MECHANISM
.
1087
3.2.11.4
APPLICATIONS
.
1089
3.2.11.5
THE
ARCO
ETHYLURETHANE
PROCESS
.
1090
3.2.11.6
CATALYTIC
IMPLICATIONS
AND
PERSPECTIVES
.
1091
3.2.12
CATALYTIC
MCMURRY
COUPLING:
OLEFINS
FROM
KETO
COMPOUNDS
(WA.
HERRMANN,
H.
SCHNEIDER)
.
1093
3.2.12.1
INTRODUCTION
.
1093
3.2.12.2
STOICHIOMETRIC
TITANIUM
COMPOUNDS,
OTHER
REAGENTS,
AND
MECHANISTIC
ASPECTS
.
1094
3.2.12.3
CATALYTIC
DEOXYGENATION
.
1096
3.2.12.4
PERSPECTIVES
.
1097
CONTENTS
XV
3.2.13
CATALYTIC
HYDROGENATION
OF
HETEROCYCLIC
SULFUR
AND
NITROGEN
COMPOUNDS
IN
RAW
OILS
(C.
BIANCHINI,
A.
MELI,
F.
VIZZA)
.
.
1099
3.2.13.1
INTRODUCTION
.
1099
3.2.13.2
HYDROGENATION
OF
SULFUR
HETEROCYCLES
.
1100
3.2.13.3
HYDROGENOLYSIS
OF
SULFUR
HETEROCYCLES
.
1106
3.2.13.4
HYDRODESULFURIZATION
IN
DIFFERENT
PHASE
VARIATION
SYSTEMS
.
.
1109
3.2.13.5
HYDROGENATION
OF
NITROGEN
HETEROCYCLES
.
1109
3.2.13.6
HYDROGENOLYSIS
OF
NITROGEN
HETEROCYCLES
.
1116
3.2.13.7
PERSPECTIVES
.
1116
3.2.14
DOUBLE-BOND
ISOMERIZATION
OF
OLEFINS
(W.A.
HERRMANN,
M.
PRINZ)
.
1119
3.2.14.1
INTRODUCTION
.
1119
3.2.14.2
CATALYSTS,
SCOPE,
AND
DEFINITION
.
1120
3.2.14.3
MECHANISTIC
CONSIDERATIONS
.
1121
3.2.14.4
APPLICATIONS
.1124
3.2.14.5
ASYMMETRIC
ISOMERIZATION
.
1125
3.2.14.6
RECENT
DEVELOPMENTS
.
1126
3.2.14.7
PERSPECTIVES
.
1128
3.3
SPECIAL
PRODUCTS
.
1131
3.3.1
ENANTIOSELECTIVE
SYNTHESIS
(H.-U.
BLASER,
B.
PUGIN,
F.
SPINDLER)
.
1131
3.3.1.1
INTRODUCTION
AND
BACKGROUND
.
1131
3.3.1.2
CRITICAL
FACTORS
FOR
THE
TECHNICAL
APPLICATION
OF
HOMOGENEOUS
ENANTIOSELECTIVE
CATALYSTS
.1132
3.3.1.3
STATE-OF-THE-ART
AND
EVALUATION
OF
CATALYTIC
TRANSFORMATIONS
.
1134
3.3.1.4
CONCLUSIONS
AND
PROSPECTS
.1146
3.3.2
DIOLS
VIA
CATALYTIC
DIHYDROXYLATION
(M.
BELLER,
K.B.
SHARPLESS)
.
1149
3.3.2.1
INTRODUCTION
.1149
3.3.2.2
HISTORY
AND
GENERAL
FEATURES
OF
OSMIUM-CATALYZED
DIHYDROXYLATION
REACTIONS
.
1150
3.3.2.3
MECHANISM
OF
OSMIUM-CATALYZED
DIHYDROXYLATIONS
.
1152
3.3.2.4
SCOPE
AND
LIMITATION
OF
ASYMMETRIC
DIHYDROXYLATION
.
.
.
1153
3.3.2.5
SELECTED
APPLICATIONS
OF
OSMIUM-CATALYZED
DIHYDROXYLATIONS
1159
3.3.3
HYDROVINYLATION
(P.
W
JOLLY,
G.
WILKE)
.1164
3.3.3.1
INTRODUCTION
.1164
3.3.3.2
THE
CATALYST
.
1165
3.3.3.3
THE
PRODUCT
.
1169
3.3.3.4
THE
MECHANISM
.
1178
3.3.3.5
OUTLOOK
.
1184
3.3.3.6
POSTSCRIPT
.
1185
XVI
CONTENTS
3.3.4
CARBON
DIOXIDE
AS
A
CJ
BUILDING
BLOCK
(E.
DINJUS,
R.
FOMIKA,
S.
FITTER,
T.
ZEVACO)
.
1189
3.3.4.1
INTRODUCTION
.
1189
3.3.4.2
CATALYTIC
C-C
BOND-FORMING
REACTIONS
.
1191
3.3.4.3
TRANSITION
METAL
CATALYZED
FORMATION
OF
FORMIC
ACID
AND
ITS
DERIVATIVES
FROM
CO
2
AND
H
2
.
1196
3.3.4.4
CATALYZED
FORMATION
OF
ORGANIC
CARBONATES
.
1205
3.3.4.5
SUMMARY
AND
OUTLOOK
.
1208
3.3.5
REDUCTIVE
CARBONYLATION
OF
NITRO
COMPOUNDS
(M.
DUGAL,
D.
KOCH,
G.
NABERFELD,
C.
SIX)
.
1214
3.3.5.1
INTRODUCTORY
REMARKS
.
1214
3.3.5.2
SYNTHESIS
OF
ISOCYANATES
.
1214
3.3.5.3
THERMODYNAMICS,
KINETICS,
AND
MECHANISM
.
1218
3.3.5.4
OUTLOOK
.
1223
3.3.6
NEW
APPROACHES
IN
C-H
ACTIVATION
OF
ALKANES
(A.
SEN)
.
.
1226
3.3.6.1
INTRODUCTION
.
1226
3.3.6.2
RADICAL
PATHWAYS
.
1227
3.3.6.3
OXIDATIVE
ADDITION
PATHWAYS
.
1229
3.3.6.4
ELECTROPHILIC
PATHWAYS
.
1231
3.3.6.5
CONCLUSIONS
.
1238
3.3.7
PAUSON-KHAND
REACTION
(W.
A.
HERRMANN)
.
1241
3.3.7.1
INTRODUCTION
.
1241
3.3.7.2
THE
CATALYTIC
OPTION
.
1242
3.3.7.3
RELATED
REACTIONS
.
1244
3.3.7.4
STEREOSELECTIVE
PKRS
AND
HETERO-REACTIONS
.
1245
3.3.7.5
DEGENERATE
(INTERMITTENT)
AND
DOMINO
PK
REACTIONS
.
1246
3.3.7.6
SUBSTITUTION
EFFECTS,
SELECTIVITY,
AND
MECHANISM
.
1247
3.3.7.7
COMMERCIAL
PERSPECTIVES
.
1249
3.3.7.8
OUTLOOK
.
1250
3.3.8
CYCLOOLIGOMERIZATION
OF
ALKYNES
(H.
BONNEMANN,
W
BRIJOUX)
.
1252
3.3.8.1
INTRODUCTION
.
1252
3.3.8.2
SURVEY
OF
THE
CATALYSTS
.
1253
3.3.8.3
FIVE
AND
SIX-MEMBERED
HETEROCYCLES
.
1254
3.3.8.4
SIX
AND
EIGHT-MEMBERED
CARBOCYCLES
.
1261
3.3.9
CHEMICALS
FROM
RENEWABLE
RESOURCES
(J.
P.
ZOLLER)
.
1268
3.3.9.1
INTRODUCTION
AND
GENERAL
DEVELOPMENTS
.
1268
3.3.9.2
"
OLEO
CHEMISTRY
"
.
1268
3.3.9.3
THE
CHEMISTRY
OF
CARBOHYDRATES
.1271
3.3.9.4
THE
CHEMISTRY
OF
STARCH
.
1271
3.3.10
SPECIAL
REACTIONS
IN
HOMOGENEOUS
AQUEOUS
SYSTEMS
.
1274
3.3.10.1
SYNTHESIS
OF
POLYMERS
(B.
M.
NOVAK)
.
1274
3.3.10.2
HOMOGENEOUS
CATALYSIS
IN
LIVING
CELLS
(L.
VIGH,
F.
JOO)
.
.
1283
CONTENTS
XVII
3.3.11
CYCLIC
HYDROCARBONS
FROM
DIAZOALKANES
(W.
A.
HERRMANN,
HORST
SCHNEIDER)
.
1290
3.3.11.1
INTRODUCTION
.
1290
3.3.11.2
SCOPE
AND
DEFINITION
.
1290
3.3.11.3
MECHANISTIC
CONSIDERATIONS
.
1291
3.3.11.4
CATALYTIC
CYCLIZATION
.
1292
3.3.11.5
ENANTIOSELECTIVE
CYCLIZATION
.
1295
3.3.11.6
PERSPECTIVES
.1295
3.3.12
ACROLEIN
AND
ACRYLONITRILE
FROM
PROPENE
(W.A.
HERRMANN)
.
1297
3.3.12.1
INTRODUCTION
.
1297
3.3.12.2
SCOPE
AND
TECHNOLOGICAL
FEATURES
.
1297
3.3.12.3
CATALYST
PRINCIPLES
AND
MECHANISM
.
1298
3.3.12.4
ORGANOMETALLIC
MODELS
.
1300
3.3.12.5
THE
"
AMM(ON)DEHYDROGENATION
"
.
1301
3.3.12.6
PERSPECTIVES
.1303
3.3.13
CHEMISTRY
OF
METHYLTRIOXORHENIUM
(MTO)
.
1304
3.3.13.1
FINE
CHEMICALS
VIA
METHYLTRIOXORHENIUM
AS
CATALYST
(F.E.
KUHN,
M.
GROARKE)
.
1304
3.3.13.2
PILOT-PLANT
SYNTHESIS
OF
MTO
(W.
A.
HERRMANN)
.
1319
3.3.14
ACETOXYLATIONS
AND
OTHER
PALLADIUM-PROMOTED
OR
PALLADIUM-CATALYZED
REACTIONS
(R.
JIRA)
.1323
3.3.14.1
HISTORICAL
AND
ECONOMIC
BACKGROUND
.
1323
3.3.14.2
CHEMICAL
BACKGROUND
.1323
3.3.14.3
KINETICS
AND
MECHANISM
.
1325
3.3.14.4
COMMERCIAL
PROCESSES
.
1329
3.3.14.5
TRANSVINYLATION
.
1331
3.3.14.6
ACETOXYLATION
IN
ORGANIC
SYNTHESIS
.
1332
3.3.14.7
OTHER
PALLADIUM-PROMOTED
OR
PALLADIUM-CATALYZED
REACTIONS
.
1333
3.3.14.8
CONCLUSIONS
.
1336
4
EPILOGUE
.
1341
4.1
HOMOGENEOUS
CATALYSIS
-
QUO
VADIS?
FW
A.
HERRMANN,
B.
CORNILS)
.1343
4.1.1
IMMOBILIZATION
OF
HOMOGENEOUS
CATALYSTS
.1345
4.1.2
COLLOIDAL
ORGANOMETALLIC
CATALYSTS
.
1347
4.1.3
MULTICOMPONENT
AND
MULTIFUNCTIONAL
CATALYSIS
.
1347
4.1.4
STEREOSELECTIVE
CATALYSIS
.
1348
4.1.5
METALS
FROM
STOICHIOMETRIC
REACTIVITY
TO
CATALYTIC
EFFICIENCY
.
1351
XVIII
CONTENTS
4.1.6
MECHANISTIC
KNOWLEDGE
AND
THEORY
-
KEYS
TO
CATALYST
DESIGN
.
1352
4.1.7
CATALYST
PERFORMANCE/NEW
TECHNIQUES
TO
GENERATE
AND
ACTIVATE
CATALYSTS
.
1353
4.1.8
ORGANOMETALLIC
ELECTROCATALYSIS
AND
BIOMIMETIC
CATALYSIS
.
.
1354
4.1.9
NEW
CHEMICAL
FEEDSTOCKS
FOR
HOMOGENEOUS
CATALYSIS
AND
RENEWABLE
RESOURCES
.
1356
4.1.10
CATALYSIS
UNDER
SUPERCRITICAL
CONDITIONS
AND
SUPPORTED
BY
IONIC
LIQUIDS
.
1362
4.1.11
NEW
REACTIONS,
IMPROVED
CATALYSTS
.
1365
4.1.12
A
NEW
GENERATION
OF
CATALYST
LIGANDS
.
1368
4.1.13
RARE
EARTH
CATALYSTS
.
1369
4.1.14
ORGANOMETALLIC
CATALYSTS
FOR
POLYMERS
.
1371
4.1.15
CATALYST
REACTIVATION,
PROCESS,
AND
REACTOR
TECHNOLOGY
.
.
.
1375
4.1.16
FINAL
CLOSURE
.
1375
INDEX
.
1383 |
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| building | Verbundindex |
| bvnumber | BV014160019 |
| ctrlnum | (OCoLC)492521507 (DE-599)BVBBV014160019 |
| dewey-full | 541.395 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 541 - Physical chemistry |
| dewey-raw | 541.395 |
| dewey-search | 541.395 |
| dewey-sort | 3541.395 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie |
| edition | 2., completely rev. and enlarged ed. |
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| id | DE-604.BV014160019 |
| illustrated | Illustrated |
| indexdate | 2024-11-22T17:31:10Z |
| institution | BVB |
| isbn | 3527304347 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-009705595 |
| oclc_num | 492521507 |
| open_access_boolean | |
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| owner_facet | DE-703 DE-29T DE-355 DE-BY-UBR DE-20 DE-19 DE-BY-UBM DE-91G DE-BY-TUM |
| physical | XVIII S., S. 1034 - 1450 graph. Darst. |
| publishDate | 2002 |
| publishDateSearch | 2002 |
| publishDateSort | 2002 |
| publisher | Wiley-VCH |
| record_format | marc |
| spelling | Applied homogeneous catalysis with organometallic compounds a comprehensive handbook ; in three volumes 3 Developments ed. by Boy Cornils ... 2., completely rev. and enlarged ed. Weinheim Wiley-VCH 2002 XVIII S., S. 1034 - 1450 graph. Darst. txt rdacontent n rdamedia nc rdacarrier Catalyse homogène ram Composés organométalliques ram Cornils, Boy Sonstige oth (DE-604)BV014160016 3 DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009705595&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Applied homogeneous catalysis with organometallic compounds a comprehensive handbook ; in three volumes Catalyse homogène ram Composés organométalliques ram |
| title | Applied homogeneous catalysis with organometallic compounds a comprehensive handbook ; in three volumes |
| title_auth | Applied homogeneous catalysis with organometallic compounds a comprehensive handbook ; in three volumes |
| title_exact_search | Applied homogeneous catalysis with organometallic compounds a comprehensive handbook ; in three volumes |
| title_full | Applied homogeneous catalysis with organometallic compounds a comprehensive handbook ; in three volumes 3 Developments ed. by Boy Cornils ... |
| title_fullStr | Applied homogeneous catalysis with organometallic compounds a comprehensive handbook ; in three volumes 3 Developments ed. by Boy Cornils ... |
| title_full_unstemmed | Applied homogeneous catalysis with organometallic compounds a comprehensive handbook ; in three volumes 3 Developments ed. by Boy Cornils ... |
| title_short | Applied homogeneous catalysis with organometallic compounds |
| title_sort | applied homogeneous catalysis with organometallic compounds a comprehensive handbook in three volumes developments |
| title_sub | a comprehensive handbook ; in three volumes |
| topic | Catalyse homogène ram Composés organométalliques ram |
| topic_facet | Catalyse homogène Composés organométalliques |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009705595&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| volume_link | (DE-604)BV014160016 |
| work_keys_str_mv | AT cornilsboy appliedhomogeneouscatalysiswithorganometalliccompoundsacomprehensivehandbookinthreevolumes3 |