Nonequilibrium nondissipative thermodynamics: with application to low-pressure diamond synthesis
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Berlin [u.a.]
Springer
2002
|
| Schriftenreihe: | Springer series in chemical physics
68 |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XII, 254 S. Ill., graph. Darst. |
| ISBN: | 354042802X |
Internformat
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Datensatz im Suchindex
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| adam_text | JI-TAO WANG NONEQUILIBRIUM NONDISSIPATIVE THERMODYNAMICS WITH
APPLICATION TO LOW-PRESSURE DIAMOND SYNTHESIS WITH 114 FIGURES SPRINGER
CONTENTS 1. CLASSICAL THERMODYNAMICS 1 1.1 BASIC LAWS OF CLASSICAL
THERMODYNAMICS 1 1.2 CLASSICAL EQUILIBRIUM THERMODYNAMICS 4 1.3
NONEQUILIBRIUM THERMODYNAMICS IN CLASSICAL THERMODYNAMICS 8 1.4 CRITERIA
OF CHANGE DIRECTION AND LIMITATION . : 10 1.5 RELATIONSHIP BETWEEN GIBBS
FREE ENERGY AND TEMPERATURE OR PRESSURE 11 1.6 CHEMICAL POTENTIAL AND
ITS RELATIONSHIP WITH TEMPERATURE AND PRESSURE 13 1.7 CHANGE OF GIBBS
FREE ENERGY IN CHEMICAL REACTIONS 17 1.8 LIMITATION TO THE APPLICABILITY
OF CLASSICAL THERMODYNAMICS 21 2. FUNDAMENTALS OF MODERN THERMODYNAMICS
23 2.1 MODERN FORMULATION OF BASIC THERMODYNAMIC LAWS 24 2.2 SOME BASIC
CONCEPTS IN NONEQUILIBRIUM THERMODYNAMICS 26 2.2.1 IRREVERSIBILITY OF
CHANGE WITH TIME 27 2.2.2 EQUILIBRIUM STATE, STATIONARY STATE AND
NONEQUILIBRIUM STATE 27 2.2.3 REVERSIBLE AND IRREVERSIBLE PROCESSES 28
2.3 ASSUMPTION OF LOCAL EQUILIBRIUM 29 2.4 CALCULATION OF ENTROPY 31 2.5
SYSTEMATIZATION OF MODERN THERMODYNAMICS 35 2.6 ONSAGER S RECIPROCITY
RELATION 40 2.7 ENTROPY PRODUCTION MINIMIZATION PRINCIPLE 45 2.8
PRIGOGINE S DISSIPATIVE STRUCTURES 47 2.8.1 BENARD S PATTERN 47 2.8.2
LASER EMISSION 48 2.8.3 CHEMICAL OSCILLATION 51 X CONTENTS 3.
HIGH-PRESSURE SYNTHESIS AND LOW-PRESSURE VAPOR GROWTH OF DIAMOND SEEDS
53 3.1 EARLY HISTORY OF DIAMOND SYNTHESIS 53 3.2 THERMODYNAMIC
PREDICTIONS 55 3.3 SUCCESS OF THE HIGH-PRESSURE PROCESS 57 3.4 EARLY
EXPLORATION OF LOW-PRESSURE VAPOR GROWTH OF DIAMOND SEEDS 64 3.5
THERMODYNAMIC CONDITIONS FOR CRYSTAL GROWTH FROM THE VAPOR PHASE 65
3.5.1 SUPERSATURATION DEGREE 65 3.5.2 NUCLEATION BARRIER 66 3.6 DIAMOND
SEED GROWTH FROM THE VAPOR PHASE 71 4. ACTIVATED LOW-PRESSURE DIAMOND
GROWTH FROM THE VAPOR PHASE 75 4.1 SUCCESS OF ACTIVATED LOW-PRESSURE
VAPOR GROWTH PROCESS ... 75 4.2 SETUP OF ACTIVATED LOW-PRESSURE GROWTH
FROM THE VAPOR PHASE 79 4.3 PREFERENTIAL ETCHING KINETIC MODEL OF SAH 85
4.4 KINETIC CONTROL MODEL 86 4.5 SOME THERMODYNAMIC THEORETICAL MODELS
OF THE 1980S 89 4.5.1 QUASIEQUILIBRIUM MODEL 90 4.5.2 SURFACE REACTION
THERMODYNAMIC MODEL 94 4.5.3 DEFECT-INDUCED STABILIZATION MODEL 96 5.
REACTION COUPLING MODEL 99 5.1 CHEMICAL PUMP MODEL 99 5.1.1 MECHANISM OF
THE CHEMICAL PUMP 100 5.1.2 CHEMICAL PUMP REACTION 103 5.2 CALCULATION
OF THE CHEMICAL PUMP EFFECT 104 5.3 REACTION COUPLING MODEL 109 5.4
THERMODYNAMIC DATA FOR ACTIVATED GRAPHITE 112 5.5 NEW CONCEPT OF
NONEQUILIBRIUM (STATIONARY) PHASE DIAGRAMS 116 5.6 NONEQUILIBRIUM
NONDISSIPATION PRINCIPLE 119 5.7 CALCULATION OF NONEQUILIBRIUM PHASE
DIAGRAMS 122 5.8 SOME RESULTS AND DISCUSSIONS 125 5.9 MORPHOLOGY OF
DIAMOND CRYSTALS AND ORIENTATION OF DIAMOND FILMS 132 CONTENTS XI 6.
NONEQUILIBRIUM PHASE DIAGRAMS OF C-H, C-O AND OTHER BINARY SYSTEMS 139
6.1 T-X NONEQUILIBRIUM PHASE DIAGRAMS FOR C-H BINARY SYSTEMS 139 6.2
T-P-X NONEQUILIBRIUM PHASE DIAGRAMS FOR C-H AND C-0 BINARY SYSTEMS 146
6.3 NONEQUILIBRIUM PHASE DIAGRAMS FOR OTHER BINARY SYSTEMS 150 7.
NONEQUILIBRIUM PHASE DIAGRAMS OF C-H-O AND OTHER TERNARY SYSTEMS 153 7.1
BACHMANN S EMPIRICAL PHASE DIAGRAM FOR THE C-H-0 SYSTEM 154 7.2
PROJECTIVE NONEQUILIBRIUM PHASE DIAGRAMS FOR C-H-0 SYSTEMS 157 7.3
INFLUENCES OF T AND P RANGES ON C-H-0 TERNARY PHASE DIAGRAMS 161 7.4
CROSS-SECTIONAL NONEQUILIBRIUM PHASE DIAGRAMS FOR C-H-0 TERNARY SYSTEMS
165 7.5 NONEQUILIBRIUM PHASE DIAGRAMS FOR C-H-X TERNARY SYSTEMS 169 8.
FURTHER DISCUSSIONS ON SOME DEBATES 173 8.1 COUPLED REACTION IN
BIOCHEMISTRY 174 8.2 THE SEVENTY-YEAR CONTROVERSY ABOUT REACTION
COUPLING IN CHEMISTRY 178 8.3 QUANTITATIVE VERIFICATION OF REACTION
COUPLING IN INANIMATE SYSTEMS 185 8.4 REACTION BARRIER IN SYNTHETIC
DIAMOND PROCESSES 195 8.4.1 UNIFIED BARRIER MODEL 195 8.4.2
THERMODYNAMIC COUPLING EFFECT AND CATALYTIC EFFECT . 196 8.4.3 ANALYSIS
OF CALCULATED RESULTS AND CONCLUSIONS 203 8.5 OTHER THERMODYNAMIC
DISCUSSIONS ON ACTIVATED CVD DIAMOND 209 8.5.1 CHARGED CLUSTER MODEL 209
8.5.2 OTHER THERMODYNAMIC DISCUSSIONS 211 9. OTHER APPLICATIONS AND
SUMMARY 213 9.1 NONEQUILIBRIUM PHASE DIAGRAMS FOR THE ACTIVATED CVD CBN
PROCESS 213 9.2 MODERN THERMODYNAMICS FOR BELOUSOV-ZHABOTINSKY REACTIONS
217 9.3 A CHARACTERISTIC OF LIFE: DRAWING NEGATIVE ENTROPY FROM ITS
ENVIRONMENT 219 XII CONTENTS 9.4 SOME SIMILARITIES OF REACTION COUPLING
IN BIOLOGICAL AND INANIMATE SYSTEMS 224 9.5 SOME CONCLUSIONS, FURTHER
DEVELOPMENT AND PROSPECTS 228 REFERENCES 237 INDEX 251
|
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| indexdate | 2024-07-09T18:58:34Z |
| institution | BVB |
| isbn | 354042802X |
| language | English |
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| physical | XII, 254 S. Ill., graph. Darst. |
| publishDate | 2002 |
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| series | Springer series in chemical physics |
| series2 | Springer series in chemical physics |
| spelling | Wang, Ji-Tao Verfasser aut Nonequilibrium nondissipative thermodynamics with application to low-pressure diamond synthesis Ji-Tao Wang Berlin [u.a.] Springer 2002 XII, 254 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Springer series in chemical physics 68 Físico-química larpcal Diamonds, Artificial Nonequilibrium thermodynamics LPCVD-Verfahren (DE-588)4277965-0 gnd rswk-swf Nichtgleichgewichts-Phasenübergang (DE-588)4171732-6 gnd rswk-swf Diamant (DE-588)4012069-7 gnd rswk-swf Synthese (DE-588)4418958-8 gnd rswk-swf Nichtgleichgewichts-Phasenübergang (DE-588)4171732-6 s DE-604 Diamant (DE-588)4012069-7 s Synthese (DE-588)4418958-8 s LPCVD-Verfahren (DE-588)4277965-0 s Springer series in chemical physics 68 (DE-604)BV000000670 68 HEBIS Datenaustausch Darmstadt application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009698293&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Wang, Ji-Tao Nonequilibrium nondissipative thermodynamics with application to low-pressure diamond synthesis Springer series in chemical physics Físico-química larpcal Diamonds, Artificial Nonequilibrium thermodynamics LPCVD-Verfahren (DE-588)4277965-0 gnd Nichtgleichgewichts-Phasenübergang (DE-588)4171732-6 gnd Diamant (DE-588)4012069-7 gnd Synthese (DE-588)4418958-8 gnd |
| subject_GND | (DE-588)4277965-0 (DE-588)4171732-6 (DE-588)4012069-7 (DE-588)4418958-8 |
| title | Nonequilibrium nondissipative thermodynamics with application to low-pressure diamond synthesis |
| title_auth | Nonequilibrium nondissipative thermodynamics with application to low-pressure diamond synthesis |
| title_exact_search | Nonequilibrium nondissipative thermodynamics with application to low-pressure diamond synthesis |
| title_full | Nonequilibrium nondissipative thermodynamics with application to low-pressure diamond synthesis Ji-Tao Wang |
| title_fullStr | Nonequilibrium nondissipative thermodynamics with application to low-pressure diamond synthesis Ji-Tao Wang |
| title_full_unstemmed | Nonequilibrium nondissipative thermodynamics with application to low-pressure diamond synthesis Ji-Tao Wang |
| title_short | Nonequilibrium nondissipative thermodynamics |
| title_sort | nonequilibrium nondissipative thermodynamics with application to low pressure diamond synthesis |
| title_sub | with application to low-pressure diamond synthesis |
| topic | Físico-química larpcal Diamonds, Artificial Nonequilibrium thermodynamics LPCVD-Verfahren (DE-588)4277965-0 gnd Nichtgleichgewichts-Phasenübergang (DE-588)4171732-6 gnd Diamant (DE-588)4012069-7 gnd Synthese (DE-588)4418958-8 gnd |
| topic_facet | Físico-química Diamonds, Artificial Nonequilibrium thermodynamics LPCVD-Verfahren Nichtgleichgewichts-Phasenübergang Diamant Synthese |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009698293&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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