Nanoparticles and the environment:
Gespeichert in:
| Format: | Buch |
|---|---|
| Sprache: | English |
| Veröffentlicht: |
Washington, DC
Mineralogical Soc. of America
2001
|
| Schriftenreihe: | Reviews in mineralogy and geochemistry
44 |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XIV, 349 S. Ill., graph. Darst. |
| ISBN: | 0939950561 |
Internformat
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Datensatz im Suchindex
| _version_ | 1805083653149032448 |
|---|---|
| adam_text |
MIINIEIRAIL(Q)OT NANOPARTICLES AND THE ENVIRONMENT EDITORS: JLLLIAN F.
BANFIELD DEPARTMENT OF GEOLOGY & GEOPHYSICS UNIVERSITY OF WISCONSIN
MADISON, WISCONSIN ALEXANDRA NAVROTSKY L^A DEPARTMENT OF CHEMICAL
IGINEERING & MATERIALS SCIENCE UNIVERSITY OF CALIFORNIA-DAVIS 2002 A
20320 COVER: COLORIZED, HIGH-RESOLUTION TRANSMISSION ELECTRON MICROSCOPE
LATTICE-FRINGE IMAGE OF SEVEN NANOPARTICLES OF UO 2 PRODUCED BY THE
ACTIVITY OF SULFATE-REDUCING BACTERIA. NOTE THAT THE LARGEST URANINITE
PARTICLE IS 3 NM IN DIAMETER (SUZUKI AND BANFIELD, IN PREPARATION).
GRAPHIC PROVIDED BY JILL BANIFIELD, YOHEY SUZUKI, AND MARY DIMAN. SERIES
EDITOR FOR MSA: PAUL H. RIBBE VIRGINIA POLYTECHNIC INSTITUTE AND STATE
UNIVERSITY BLACKSBURG, VIRGINIA REVIEWS IN MINERALOGY AND GEOCHEMISTRY
VOLUME 44 TABLE OF CONTENTS 1 NANOPARTICLES IN THE ENVIRONMENT JILLIAN
F. BANFIELD, HENGZHONG ZHANG INTRODUCTION .-. 1 NANOPARTICLES IN
NATURAL SYSTEMS: WHERE DO THEY COME FROM? 2 EXAMPLE: PREDOMINANTLY
INORGANIC NANOPARTICLE FORMATION IN ACID DRAINAGE 3 OTHER INORGANIC
PATHWAYS FOR FORMATION OF NANOPARTICLES 5 NANOPARTICLE FORMATION VIA
BIOLOGICAL PATHWAYS 6 EXAMPLE: IRON-OXIDIZING MICROBES AND NANOPARTICLE
FORMATION IN AMD SYSTEMS 6 EXAMPLE: NANOPARTICLES FORMED BY MICROBES IN
ANOXIC REGIONS OF AMD SYSTEMS 10 OTHER EXAMPLES OF BIOLOGICAL PATHWAYS
THAT LEAD TO NANOPARTICLES IN THE ENVIRONMENT 14 MICROBES, NANOPARTICES,
AND MINERALOGICAL BIOSIGNATURES 16 NANOPARTICLES: HOW AND WHY ARE THEY
DIFFERENT? 16 INTRODUCTION 16 SURFACE FREE ENERGY AND SURFACE STRESS 19
SURFACE ENERGY AND PARTICLE SIZE 20 SURFACE "PRESSURE" AND STRUCTURAL
RESPONSES IN NANOPARTICLES 21 THERMODYNAMICS OF NANOPARTICLE SYSTEMS. 22
MINIMIZATION OF THE TOTAL FREE ENERGY BY PHASE TRANSFORMATION 23
EXAMPLES OF PHASE STABILITY IN NANOPARTICLE SYSTEMS 29 PARTICLE SIZE AND
SURFACE ADSORPTION 35 NANOPARTICLES AND ORGANICS 36 KINETICS IN
NANOPARTICLE SYSTEMS 37 BRIEF REVIEW OF KINETIC MODELS FOR MACROSCOPIC
SOLIDS 37 KINETICS OF AMORPHOUS-TO-NANOCRYSTALLINE TRANSFORMATIONS 38
KINETICS OF CRYSTALLINE TRANSFORMATIONS INVOLVING NANOPARTICLES 39
CRYSTAL GROWTH OF NANOCRYSTALLINE PARTICLES 41 AGGREGATION AND
NUCLEATION 44 POSSIBLE GALVANIC INTERACTIONS IN NANOPARTICLE MIXTURES .:
46 MICROSTRUCTURE DEVELOPMENT IN NANOCRYSTALS 47 SOME RESEARCH
OPPORTUNITIES AND CHALLENGES 48 ACKNOWLEDGMENTS ".:.- 51 REFERENCES 51
2 NANOCRYSTALS AS MODEL SYSTEMS FOR PRESSURE-INDUCED STRUCTURAL PHASE
TRANSITIONS KEREN JACOBS, A. PAUL ALIVISATOS INTRODUCTION 59
SINGLE-STRUCTURAL DOMAIN 60 SURFACE EFFECTS AND SHAPE CHANGE 62
THERMODYNAMIC SMEARING 62 TRANSFORMATION KINETICS: ACTIVATION VOLUME 65
TRANSFORMATION MECHANISM 68 ACTIVATION VOLUME 69 ACTIVATION ENERGY
(ENTHALPIC BARRIER) 70 ENTROPIC FACTOR (ENTROPIC BARRIER) 70 TEMPERATURE
DEPENDENCE 70 ACKNOWLEDGMENTS 71 REFERENCES 71 IX 3 THERMOCHEMISTRY OF
NANOMATERIALS ALEXANDRA NAVROTSKY INTRODUCTION 73 THERMODYNAMIC ISSUES
74 METHODS FOR DETERMINING NANOPARTICLE ENERGETICS 77 EQUILIBRIUM
MEASUREMENTS 77 CALORIMETRIC MEASUREMENTS 77 COMPUTATION, SIMULATION,
AND MODELING 79 SPECIFIC SYSTEMS 79 ALUMINUM OXIDES AND OXYHYDROXIDES 79
IRON OXIDES AND OXYHYDROXIDES 83 MANGANESE OXIDES 84 TITANIUM OXIDE 85
ZIRCONIUM OXIDE 89 MAGNESIUM ALUMINATE 91 SILICA 92 INTERFACES,
DISLOCATIONS, AND NANOCOMPOSITES 95 MIXED HYDROXIDES AND
HYDROXYCARBONATES: FROM SURFACE ADSORBATES TO NANOPARTICLES TO BULK
PHASES 96 FUTURE DIRECTIONS AND UNANSWERED QUESTIONS 98 ACKNOWLEDGMENTS
99 REFERENCES 99 4 STRUCTURE, AGGREGATION AND CHARACTERIZATION OF
NANOPARTICLES GLENN A. WAYCHUNAS INTRODUCTION 105 STRUCTURAL ASPECTS OF
NATURAL NANOMATERIALS 105 DEFINITIONS 105 GROWTH AND AGGREGATION
PROCESSES 106 GROWTH PROCESSES 106 INORGANIC VS. ORGANIC (ENZYMATIC) 106
NUCLEATION AND GROWTH 107 CLASSICAL NUCLEATION THEORY (CNT) -. 107
HOMOGENEOUS NUCLEATION 107 HETEROGENEOUS NUCLEATION 108 PROBLEMS WITH
CLASSICAL MODELS 109 DYNAMICAL NUCLEATION PROCESSES: SMOLUCHOWSKI'S
APPROACH 109 CLASSICAL GROWTH MECHANISMS VS. AGGREGATION PROCESSES 110
CLASSICAL GROWTH MECHANISMS AND LAWS 110 GROWTH TOPOLOGIES ILL INORGANIC
VS. BIOLOGICALLY PRODUCED CRYSTALLITES 113 HOW DO THESE GROWTH
CONSIDERATIONS APPLY TO NANOPARTICLES AND NANOCRYSTALS? 115 AGGREGATION
MECHANISMS.; 117 PARTICLE-PARTICLE INTERACTION FORCES 117 ELECTRICAL
DOUBLE LAYER, DERJAGUIN APPROXIMATION AND DLVO THEORY 119 AGGREGATION
KINETICS AND KERNELS IN THE SMOLUCHOWSKI EQUATION 122 FRACTAL DIMENSIONS
OF AN AGGREGATE 123 AGGREGATION TOPOLOGIES 123 SIMULATIONS AND STATE OF
KNOWLEDGE 126 STRUCTURE 126 SCALES OF STRUCTURE 126 SURFACE VS. BULK
STRUCTURE 127 SURFACE FEATURES 128 BULK NANOPARTICLE FEATURES 130
STRUCTURE AND SHAPE/SIZE DETERMINATION 133 ATOMIC STRUCTURE*TEM, X-RAY
SCATTERING AND DIFFRACTION 133 BRAGG PEAK BROADENING I.134 BRAGG
ANALYSIS AND RIETVELD METHOD 134 DEBYE EQUATION AND SCATTERING FROM
SMALL CRYSTALLITES 137 SHORT RANGE ORDER: X-RAY ABSORPTION SPECTROSCOPY
(XANES AND EXAFS) 142 DISORDER PROBLEMS IN EXAFS ANALYSIS. 147
EMPIRICAL AND AB INITIO XANES ANALYSIS 148 DETERMINATION OF PARTICLE
SIZE DISTRIBUTIONS 152 RATE OF GROWTH/AGGREGATION EXPERIMENTS WITH SAXS
153 SMALL-ANGLE NEUTRON SCATTERING (SANS) 154 LIGHT SCATTERING
TECHNIQUES 155 "INDIRECT" STRUCTURAL METHODS 156 OPTICAL SPECTROSCOPY
(IR, VISIBLE, UV, RAMAN, LUMINESCENCE, LIBD) 156 SOFT X-RAY SPECTROSCOPY
158 MOSSBAUER/NMR SPECTROSCOPY 159 SOME OUTSTANDING ISSUES 160 CAN
CRYSTAL CHEMISTRY SYSTEMATICS BE APPLIED TO NANOPARTICLES? 160 CAN WE
MEANINGFULLY COMPARE NANOPARTICLE SURFACES WITH BULK CRYSTAL SURFACES
(I.E., ARE NANOPARTICLES JUST LIKE SMALL UNITS OF A BULK CRYSTAL
SURFACE)? 160 IS THE LOCAL STRUCTURE OF WATER DIFFERENT NEAR
NANOPARTICLES? IS THIS SIGNIFICANT IN DEFINING NANOPARTICLE SURFACE/BULK
STRUCTURE AND PERHAPS STABILITY? 160 DO HIGHLY DEFECTIVE STRUCTURES HAVE
ASPECTS IN COMMON WITH NANOPARTICLES? FOR EXAMPLE: DO "NANOPOROUS
MATERIALS" HAVE SIMILARITIES TO CLUSTERED NANOPARTICLES EITHER
STRUCTURALLY OR ENERGETICALLY? 161 OUTSTANDING PROBLEMS THAT NEED TO BE
ADDRESSED 161 REFERENCES *. 162 5 AQUEOUS ALUMINUM POLYNUCLEAR COMPLEXES
AND NANOCLUSTERS: A REVIEW WILLIAM H. CASEY, BRIAN L. PHILLIPS, GERHARD
FURRER INTRODUCTION :.-.*. 167 METHODS FOR DETERMINING STRUCTURES 168
X-RAY DIFFRACTION ;. 168 NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY ! 168
POTENTIOMETRY : ; 169 STRUCTURES ;, 169 ALUMINUM MONOMERS 1 169 ALUMINUM
DIMERS 169 BAKER-FIGGIS KEGGIN-LIKE STRUCTURES 173 THE FLAT ALUMINUM
TRIDECAMERS 174 AL, 0 POLYOXOCATIONS 175 REACTIVITIES OF KEGGIN-LIKE
ALUMINUM POLYOXOCATIONS 178 RATES OF OXYGEN-ISOTOPIC EXCHANGE IN
E-KEGGIN MOLECULES 178 DECOMPOSITION OF THE E-KEGGIN MOLECULES 183
MECHANISMS OF FORMATION OF THE E-KEGGIN MOLECULES 184 MECHANISMS OF
FORMATION OF THE AL 30 MOLECULES 184 CATALYSIS BY OXIDE NANOCLUSTERS 184
CONCLUSIONS 186 ACKNOWLEDGMENTS 187 REFERENCES 187 XI 6 COMPUTATIONAL
APPROACHES TO NANOMINERALOGY JAMES R. RUSTAD, WITOLD DZWINEL, DAVID A.
YUEN INTRODUCTION 191 MULTISCALE DESCRIPTION OF COMPLEX SURFACES 193
SCALING CONCEPTS 194 WAVELETS AND MULTISCALE DESCRIPTION OF SURFACES AND
INTERFACES 196 MULTISCALE SIMULATION METHODS FOR SOLIDS 199 LARGE-SCALE
MOLECULAR DYNAMICS METHODS 200 COUPLING METHODS 201 TRANSITION STATE
SEARCHING AND KINETIC MONTE CARLO TECHNIQUES 203 MULTISCALE
COMPUTATIONAL METHODS FOR FLUIDS 204 DISSIPATIVE PARTICLE DYNAMICS 205
AGGLOMERATION OF PARTICLES 206 COARSE-GRAINING DISSIPATIVE PARTICLE
DYNAMICS: FLUID PARTICLE MODEL 208 OUTLOOK 211 ACKNOWLEDGMENTS 212
REFERENCES 213 7 MAGNETISM OF EARTH, PLANETARY, AND ENVIRONMENTAL
NANOMATERIALS DENIS G. RANCOURT INTRODUCTION 217 MAGNETISM IN THE EARTH
SCIENCES 217 RELATION TO OTHER BOOKS AND REVIEWS 217 ORGANIZATION AND
FOCUS OF THIS CHAPTER 218 SYMBOLS AND ACRONYMS 219 MAGNETIC
NANOPARTICLES EVERYWHERE 222 HI OUR BRAINS, THE ANIMALS, SPACE,
EVERYWHERE 222 APPLICATIONS OF MAGNETIC NANOPARTICLES 223 TOWARDS
FUNCTION AND MECHANISMS 223 MAGNETISM OF THE CRUST AND SURFACE
ENVIRONMENTS 224 DIAMAGNETIC AND PARAMAGNETIC IONS 224 MAGNETISM FROM
CRUSTAL IONS IN SURFACE MINERALS 224 MAGNETISM FROM CRUSTAL AND SURFACE
MINERALOGY 226 MEASUREMENT METHODS FOR MINERAL MAGNETISM 227 CONSTANT
FIELD (DC) MAGNEFOMETRY 228 ALTERNATING FIELD MAGNETOMETRY (AC
SUSCEPTOMETRY) 229 NEUTRON DIFFRACTION 230 MOSSBAUER SPECTROSCOPY 231
ELECTRON SPIN RESONANCE 232 TYPES OF MAGNETIC ORDER AND UNDERLYING
MICROSCOPIC INTERACTIONS .232 INTRA-ATOMIC INTERACTIONS AND MOMENT
FORMATION 232 INTER-ATOMIC EXCHANGE INTERACTIONS 233 MAGNETIC
ORDER-DISORDER TRANSITIONS 233 COLLINEAR AND NONCOLLINEAR FERROMAGNETISM
234 COLLINEAR AND NONCOLLINEAR ANTIFERROMAGNETISM 235 FERRIMAGNETISM 235
WEAK FERROMAGNETISM, CANTED ANTIFERROMAGNETISM 236 METAMAGNETISM OF
LAYERED MATERIALS : : 236 SPIN GLASSES, CLUSTER GLASSES, AND
MULTI-CONFIGURATION STATES 236 SPIN-ORBIT COUPLING AND
MAGNETO-CRYSTALLINE ENERGY 238 DIPOLE-DIPOLE INTERACTIONS AND MAGNETIC
DOMAINS 239 FROM BULK TO NANOPARTICLE VIA SUPERPARRAMAGNETISM 240
PHENOMENA INDUCED BY SMALL SIZE AND SEQUENCE OF CRITICAL PARTICLE SIZES
240 XII MAGNETO-SENSITIVE FEATURES OF MAGNETIC NANOPARTICLES 244
MICROSCOPIC AND MESOSCOPIC CALCULATIONS OF MAGNETISM IN MATERIALS *. 252
METHODS OF CALCULATION IN SOLID STATE MAGNETISM 252 CALCULATIONS OF
SUPERPARAMAGNETISM AND INTER-PARTICLE INTERACTIONS 257 INTERPLAYS
BETWEEN MAGNETISM AND OTHER SAMPLE FEATURES 258 CHEMISTRY AND STRUCTURE
VIA {^, K,, J^)} 258 CHEMICAL COUPLING TO MAGNETISM IN NANOPARTICLES
.". 258 STRUCTURAL COUPLING TO MAGNETISM IN NANOPARTICLES 259
MAGNETIC AND RELATED TRANSITIONS AFFECTED BY PARTICLE SIZE 260 DEFINING
THE SIZE EFFECT QUESTION 260 CLASSIC ORDER-DISORDER, SPIN FLOPS,
ELECTRONIC LOCALIZATION, AND PERCOLATION 261 FRUSTRATION AND
MAGNETO-STRAIN EFFECTS 261 MAGNETO-VOLUME EFFECTS 261 EXOTIC EFFECTS AND
TRANSITIONS 262 OVERVIEW OF RECENT DEVELOPMENTS 262 MAIN RECENT
DEVELOPMENTS IN MAGNETIC NANOPARTICLE SYSTEMS 262 MEASUREMENTS ON SINGLE
MAGNETIC NANOPARTICLES 263 SYNTHETIC MODEL SYSTEMS OF MAGNETIC
NANOPARTICLES 264 INTER-PARTICLE INTERACTIONS AND COLLECTIVE BEHAVIOR
265 NOTEWORTHY ATTEMPTS AT DEALING WITH NANOPARTICLE COMPLEXITY 266
INTERPRETING THE MOSSBAUER SPECTRA OF NANOPARTICLE SYSTEMS 269 NEEDED
AREAS OF DEVELOPMENT 271 EXAMPLES: CLUSTERS, BUGS, METEORITES, AND LOESS
273 TWO-DIMENSIONAL NANOMAGNETISM OF LAYER SILICATES AND LAYERED
MATERIALS 273 ABIOTIC AND BIOTIC HYDROUS FERRIC OXIDE AND SORBED-FE ON
BACTERIAL CELL WALLS 274 HYDROXYHEMATITE, NANOHEMATITE, AND THE MORIN
TRANSITION 275 MINERAL MAGNETISM OF LOESS/PALEOSOL DEPOSITS 275
SYNTHETIC AND METEORITIC NANOPHASE FE-NI AND EARTH'S GEODYNAMO 276 NEW
DIRECTIONS: ENVIRONMENTAL MODELLING 277 ACKNOWLEDGMENTS 278 REFERENCES
278 8 -. ATMOSPHERIC NANOPARTICLES C. ANASTASIO, S. T. MARTIN
INTRODUCTION [ 293 BACKGROUND CONCEPTS L ; 294 SIZE DISTRIBUTIONS OF
ATMOSPHERIC PARTICLES 294 SOURCES AND SINKS OF ATMOSPHERIC PARTICLES 296
VISIBILITY REDUCTION 298 RADIATIVE FORCING AND CLIMATE CHANGE 299 HEALTH
EFFECTS 301 CHEMICAL REACTIONS OF ATMOSPHERIC PARTICLES 303 NUCLEATION :
307 THEORETICAL TREATMENT OF CRITICAL GERM FORMATION 308 CHEMICAL
COMPOSITION OF CRITICAL GERM 310 NEW PARTICLE FORMATION IN THE
ATMOSPHERE 311 PRIMARY EMISSIONS 315 GROWTH 317 CHARACTERIZATION 319
NUMBER CONCENTRATIONS 319 CHEMICAL COMPOSITION 319 MORPHOLOGY 324 XLLL
PROPERTIES 325 MOTION 325 HYGROSCOPIC BEHAVIOR 326 CHEMICAL REACTIVITY
331 OUTLOOK 336 ACKNOWLEDGMENTS 337 REFERENCES 338 XIV |
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| dewey-search | 553.6/1 |
| dewey-sort | 3553.6 11 |
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| discipline | Chemie / Pharmazie Geologie / Paläontologie Physik |
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| oclc_num | 248141804 |
| open_access_boolean | |
| owner | DE-703 DE-355 DE-BY-UBR DE-19 DE-BY-UBM DE-20 DE-12 DE-29 DE-B16 |
| owner_facet | DE-703 DE-355 DE-BY-UBR DE-19 DE-BY-UBM DE-20 DE-12 DE-29 DE-B16 |
| physical | XIV, 349 S. Ill., graph. Darst. |
| publishDate | 2001 |
| publishDateSearch | 2001 |
| publishDateSort | 2001 |
| publisher | Mineralogical Soc. of America |
| record_format | marc |
| series | Reviews in mineralogy and geochemistry |
| series2 | Reviews in mineralogy and geochemistry |
| spelling | Nanoparticles and the environment ed.: Jillian F. Banfield ... Washington, DC Mineralogical Soc. of America 2001 XIV, 349 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Reviews in mineralogy and geochemistry 44 Meio ambiente larpcal Nanopartículas larpcal Umwelt Clay minerals Nanoparticles Nanoparticles Environmental aspects Nanopartikel (DE-588)4333369-2 gnd rswk-swf Umwelt (DE-588)4061616-2 gnd rswk-swf (DE-588)4143413-4 Aufsatzsammlung gnd-content Nanopartikel (DE-588)4333369-2 s DE-604 Umwelt (DE-588)4061616-2 s Banfield, Jillian F. Sonstige oth Reviews in mineralogy and geochemistry 44 (DE-604)BV013377203 44 GBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009661060&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Nanoparticles and the environment Reviews in mineralogy and geochemistry Meio ambiente larpcal Nanopartículas larpcal Umwelt Clay minerals Nanoparticles Nanoparticles Environmental aspects Nanopartikel (DE-588)4333369-2 gnd Umwelt (DE-588)4061616-2 gnd |
| subject_GND | (DE-588)4333369-2 (DE-588)4061616-2 (DE-588)4143413-4 |
| title | Nanoparticles and the environment |
| title_auth | Nanoparticles and the environment |
| title_exact_search | Nanoparticles and the environment |
| title_full | Nanoparticles and the environment ed.: Jillian F. Banfield ... |
| title_fullStr | Nanoparticles and the environment ed.: Jillian F. Banfield ... |
| title_full_unstemmed | Nanoparticles and the environment ed.: Jillian F. Banfield ... |
| title_short | Nanoparticles and the environment |
| title_sort | nanoparticles and the environment |
| topic | Meio ambiente larpcal Nanopartículas larpcal Umwelt Clay minerals Nanoparticles Nanoparticles Environmental aspects Nanopartikel (DE-588)4333369-2 gnd Umwelt (DE-588)4061616-2 gnd |
| topic_facet | Meio ambiente Nanopartículas Umwelt Clay minerals Nanoparticles Nanoparticles Environmental aspects Nanopartikel Aufsatzsammlung |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009661060&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| volume_link | (DE-604)BV013377203 |
| work_keys_str_mv | AT banfieldjillianf nanoparticlesandtheenvironment |