The organometallic chemistry of the transition metals:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
New York [u.a.]
Wiley
2001
|
| Ausgabe: | 3. ed. |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XV, 534 S. Ill. |
| ISBN: | 0471184233 |
Internformat
MARC
| LEADER | 00000nam a2200000 c 4500 | ||
|---|---|---|---|
| 001 | BV014093874 | ||
| 003 | DE-604 | ||
| 005 | 20021217 | ||
| 007 | t | ||
| 008 | 020116s2001 a||| |||| 00||| eng d | ||
| 020 | |a 0471184233 |9 0-471-18423-3 | ||
| 035 | |a (OCoLC)44084018 | ||
| 035 | |a (DE-599)BVBBV014093874 | ||
| 040 | |a DE-604 |b ger |e rakwb | ||
| 041 | 0 | |a eng | |
| 049 | |a DE-20 |a DE-703 |a DE-384 |a DE-29T |a DE-355 |a DE-188 |a DE-11 | ||
| 082 | 0 | |a 547.056 |2 21 | |
| 084 | |a VH 9700 |0 (DE-625)147384:253 |2 rvk | ||
| 100 | 1 | |a Crabtree, Robert H. |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a The organometallic chemistry of the transition metals |c Robert H. Crabtree |
| 250 | |a 3. ed. | ||
| 264 | 1 | |a New York [u.a.] |b Wiley |c 2001 | |
| 300 | |a XV, 534 S. |b Ill. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 650 | 4 | |a Organotransition metal compounds | |
| 650 | 0 | 7 | |a Übergangsmetallorganische Verbindungen |0 (DE-588)4417301-5 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Übergangsmetallkomplexe |0 (DE-588)4131837-7 |2 gnd |9 rswk-swf |
| 689 | 0 | 0 | |a Übergangsmetallkomplexe |0 (DE-588)4131837-7 |D s |
| 689 | 0 | 1 | |a Übergangsmetallorganische Verbindungen |0 (DE-588)4417301-5 |D s |
| 689 | 0 | |8 1\p |5 DE-604 | |
| 689 | 1 | 0 | |a Übergangsmetallkomplexe |0 (DE-588)4131837-7 |D s |
| 689 | 1 | |5 DE-604 | |
| 856 | 4 | 2 | |m OEBV Datenaustausch |q application/pdf |u http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009655326&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |3 Inhaltsverzeichnis |
| 999 | |a oai:aleph.bib-bvb.de:BVB01-009655326 | ||
| 883 | 1 | |8 1\p |a cgwrk |d 20201028 |q DE-101 |u https://d-nb.info/provenance/plan#cgwrk | |
Datensatz im Suchindex
| _version_ | 1804128960392462336 |
|---|---|
| adam_text | CONTENTS PREFACE XI LIST OF ABBREVIATIONS XIII 1 INTRODUCTION 1 1. 1
WERNER COMPLEXES 2 1.2 THE TRANS EFFECT 6 1.3 SOFT VERSUS HARD LIGANDS 7
1.4 THE CRYSTAL FIELD 8 1.5 THE LIGAND FIELD 13 1.6 BACK BONDING 15 1.7
ELECTRONEUTRALITY 18 1.8 TYPES OF LIGAND 20 2 GENERAL PROPERTIES OF
ORGANOMETALLIC COMPLEXES 28 2.1 THE 18-ELECTRON RULE 29 2.2 LIMITATIONS
OF THE 18-ELECTRON RULE 34 2.3 ELECTRON COUNTING IN REACTIONS 36 2.4
OXIDATION STATE 37 2.5 COORDINATION NUMBER AND GEOMETRY 40 2.6 EFFECTS
OF COMPLEXATION 43 2.7 DIFFERENCES BETWEEN METALS 45 2.8
INNER/OUTER-SPHERE COORDINATION 47 VI CONTENTS 3 METAL ALKYLS, ARYLS,
AND HYDRIDES AND RELATED CR-BONDED LIGANDS 51 3.1 TRANSITION METAL
ALKYLS AND ARYLS 51 3.2 RELATED A-BONDED LIGANDS 64 3.3 METAL HYDRIDE
COMPLEXES 68 3.4 SIGMA COMPLEXES 70 3.5 BOND STRENGTHS FOR CLASSICAL
A-BONDING LIGANDS 74 4 CARBONYLS, PHOSPHINE COMPLEXES, AND LIGAND
SUBSTITUTION REACTIONS 80 4.1 METAL COMPLEXES OF CO, RNC, CS, AND NO 80
4.2 PHOSPHINES AS LIGANDS 91 4.3 DISSOCIATIVE SUBSTITUTION 96 4.4 THE
ASSOCIATIVE MECHANISM 100 4.5 REDOX EFFECTS, THE I MECHANISM, AND
REARRANGEMENTS IN SUBSTITUTION 102 4.6 PHOTOCHEMICAL SUBSTITUTION 106
4.7 STERIC AND SOLVENT EFFECTS IN SUBSTITUTION 109 5 COMPLEXES OF
JR-BOUND LIGANDS 115 5.1 ALKENE AND ALKYNE COMPLEXES 115 5.2 ALLYL
COMPLEXES 121 5.3 DIENE COMPLEXES 125 5.4 CYCLOPENTADIENYL COMPLEXES 129
5.5 COMPLEXES OF ARENES AND OTHER ALICYCLIC LIGANDS 137 5.6 METALACYCLES
AND ISOELECTRONIC AND ISOLOBAL REPLACEMENT 141 5.7 STABILITY OF POLYENE
AND POLYENYL COMPLEXES 144 6 OXIDATIVE ADDITION AND REDUCTIVE
ELIMINATION 149 6.1 CONCERTED ADDITIONS 152 6.2 S,V2 REACTIONS 156 6.3
RADICAL MECHANISMS 157 6.4 IONIC MECHANISMS 160 6.5 REDUCTIVE
ELIMINATION 161 6.6 A-BOND METATHESIS 167 6.7 OXIDATIVE COUPLING AND
REDUCTIVE CLEAVAGE 168 7 INSERTION AND ELIMINATION 174 7.1 REACTIONS
INVOLVING CO 175 7.2 INSERTIONS INVOLVING AIKENES 182 7.3 OTHER
INSERTIONS 187 7.4 A, FT, Y, AND 8 ELIMINATION 188 CONTENTS VII 8
NUCLEOPHILIC AND ELECTROPHILIC ADDITION AND ABSTRACTION 197 8.1
NUCLEOPHILIC ADDITION TO CO 200 8.2 NUCLEOPHILIC ADDITION TO POLYENE AND
POLYENYL LIGANDS 202 8.3 NUCLEOPHILIC ABSTRACTION IN HYDRIDES, ALKYLS,
AND ACYLS 210 8.4 ELECTROPHILIC ADDITION 211 8.5 ELECTROPHILIC
ABSTRACTION OF ALKYL GROUPS 214 8.6 SINGLE-ELECTRON TRANSFER PATHWAYS
217 8.7 REACTIONS OF ORGANIC FREE RADICALS WITH METAL COMPLEXES 218 9
HOMOGENEOUS CATALYSIS 222 9.1 ALKENE ISOMERIZATION 226 9.2 ALKENE
HYDROGENATION 228 9.3 ALKENE HYDROFORMYLATION 240 9.4 THE HYDROCYANATION
OF BUTADIENE 244 9.5 ALKENE HYDROSILATION AND HYDROBORATION 247 9.6
COUPLING REACTIONS 249 9.7 SURFACE AND SUPPORTED ORGANOMETALLIC
CATALYSIS 252 10 PHYSICAL METHODS IN ORGANOMETALLIC CHEMISTRY 259 10.1
ISOLATION 259 10.2 H NMR SPECTROSCOPY 260 10.3 13 C NMR SPECTROSCOPY
264 10.4 3I P NMR SPECTROSCOPY 266 10.5 DYNAMIC NMR 268 10.6 SPIN
SATURATION TRANSFER 272 10.7 T AND THE NUCLEAR OVERHAUSER EFFECT (NOE)
273 10.8 ISOTOPIC PERTURBATION OF RESONANCE 278 10.9 IR SPECTROSCOPY 280
10.10 CRYSTALLOGRAPHY 283 10.11 OTHER METHODS 285 11 CARBENES,
METATHESIS, AND POLYMERIZATION 292 11. 1 CARBENES 292 11.2 METAL
CARBYNES 308 11.3 BRIDGING CARBENES AND CARBYNES 311 11.4 ALKENE
METATHESIS 313 11.5 DIMERIZATION, OLIGOMERIZATION, AND POLYMERIZATION OF
ALKENES 318 11.6 MULTIPLE BONDS TO HETEROATOMS 329 VIII CONTENTS 12
APPLICATIONS OF ORGANOMETALLIC CHEMISTRY 338 12.1 CO ACTIVATION 338 12.2
CO 2 ACTIVATION 345 12.3 ALKANE ACTIVATION 349 12.4 C*F BOND ACTIVATION
358 12.5 ORGANOMETALLIC MATERIALS AND POLYMERS 361 13 CLUSTERS AND THE
METAL-METAL BOND 368 13.1 STRUCTURES 369 13.2 THE ISOLOBAL ANALOGY 382
13.3 SYNTHESIS 386 13.4 REACTIONS 389 13.5 GIANT CLUSTERS 396 13.6 GIANT
MOLECULES 400 14 APPLICATIONS TO ORGANIC SYNTHESIS 406 14.1 METAL ALKYLS
ARYLS, AND HYDRIDES 406 14.2 REDUCTION, OXIDATION, AND CONTROL OF
STEREOCHEMISTRY 418 14.3 PROTECTION AND DEPROTECTION 423 14.4 REDUCTIVE
ELIMINATION AND COUPLING REACTIONS 426 14.5 INSERTION REACTIONS 433 14.6
NUCLEOPHILIC ATTACK ON A LIGAND 435 14.7 CARBENE REACTIONS 444 15
OXIDATION AND HIGH-OXIDATION-STATE COMPLEXES 454 15.1 MAGNETISM 456 15.2
POLYALKYLS 461 15.3 POLYHYDRIDES 467 15.4 CYCLOPENTADIENYL COMPLEXES 469
15.5 ALKYNE COMPLEXES 471 16 BIOORGANOMETALLIC CHEMISTRY 476 16.1
INTRODUCTION 476 16.2 COENZYME B !2 481 16.3 NITROGEN FIXATION 487 16.4
THE NICKEL ENZYMES 494 16.5 OTHER ENZYMES 500 16.6 BIOMEDICAL
APPLICATIONS 502 CONTENTS IX USEFUL TEXTS ON ALLIED TOPICS 506 MAJOR
REACTION TYPES 509 SOLUTIONS TO PROBLEMS 511 INDEX 525
|
| any_adam_object | 1 |
| author | Crabtree, Robert H. |
| author_facet | Crabtree, Robert H. |
| author_role | aut |
| author_sort | Crabtree, Robert H. |
| author_variant | r h c rh rhc |
| building | Verbundindex |
| bvnumber | BV014093874 |
| classification_rvk | VH 9700 |
| ctrlnum | (OCoLC)44084018 (DE-599)BVBBV014093874 |
| dewey-full | 547.056 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 547 - Organic chemistry |
| dewey-raw | 547.056 |
| dewey-search | 547.056 |
| dewey-sort | 3547.056 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie |
| edition | 3. ed. |
| format | Book |
| fullrecord | <?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01671nam a2200409 c 4500</leader><controlfield tag="001">BV014093874</controlfield><controlfield tag="003">DE-604</controlfield><controlfield tag="005">20021217 </controlfield><controlfield tag="007">t</controlfield><controlfield tag="008">020116s2001 a||| |||| 00||| eng d</controlfield><datafield tag="020" ind1=" " ind2=" "><subfield code="a">0471184233</subfield><subfield code="9">0-471-18423-3</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(OCoLC)44084018</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-599)BVBBV014093874</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-604</subfield><subfield code="b">ger</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1="0" ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="049" ind1=" " ind2=" "><subfield code="a">DE-20</subfield><subfield code="a">DE-703</subfield><subfield code="a">DE-384</subfield><subfield code="a">DE-29T</subfield><subfield code="a">DE-355</subfield><subfield code="a">DE-188</subfield><subfield code="a">DE-11</subfield></datafield><datafield tag="082" ind1="0" ind2=" "><subfield code="a">547.056</subfield><subfield code="2">21</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">VH 9700</subfield><subfield code="0">(DE-625)147384:253</subfield><subfield code="2">rvk</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Crabtree, Robert H.</subfield><subfield code="e">Verfasser</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">The organometallic chemistry of the transition metals</subfield><subfield code="c">Robert H. Crabtree</subfield></datafield><datafield tag="250" ind1=" " ind2=" "><subfield code="a">3. ed.</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="a">New York [u.a.]</subfield><subfield code="b">Wiley</subfield><subfield code="c">2001</subfield></datafield><datafield tag="300" ind1=" " ind2=" "><subfield code="a">XV, 534 S.</subfield><subfield code="b">Ill.</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="b">n</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="b">nc</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Organotransition metal compounds</subfield></datafield><datafield tag="650" ind1="0" ind2="7"><subfield code="a">Übergangsmetallorganische Verbindungen</subfield><subfield code="0">(DE-588)4417301-5</subfield><subfield code="2">gnd</subfield><subfield code="9">rswk-swf</subfield></datafield><datafield tag="650" ind1="0" ind2="7"><subfield code="a">Übergangsmetallkomplexe</subfield><subfield code="0">(DE-588)4131837-7</subfield><subfield code="2">gnd</subfield><subfield code="9">rswk-swf</subfield></datafield><datafield tag="689" ind1="0" ind2="0"><subfield code="a">Übergangsmetallkomplexe</subfield><subfield code="0">(DE-588)4131837-7</subfield><subfield code="D">s</subfield></datafield><datafield tag="689" ind1="0" ind2="1"><subfield code="a">Übergangsmetallorganische Verbindungen</subfield><subfield code="0">(DE-588)4417301-5</subfield><subfield code="D">s</subfield></datafield><datafield tag="689" ind1="0" ind2=" "><subfield code="8">1\p</subfield><subfield code="5">DE-604</subfield></datafield><datafield tag="689" ind1="1" ind2="0"><subfield code="a">Übergangsmetallkomplexe</subfield><subfield code="0">(DE-588)4131837-7</subfield><subfield code="D">s</subfield></datafield><datafield tag="689" ind1="1" ind2=" "><subfield code="5">DE-604</subfield></datafield><datafield tag="856" ind1="4" ind2="2"><subfield code="m">OEBV Datenaustausch</subfield><subfield code="q">application/pdf</subfield><subfield code="u">http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009655326&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA</subfield><subfield code="3">Inhaltsverzeichnis</subfield></datafield><datafield tag="999" ind1=" " ind2=" "><subfield code="a">oai:aleph.bib-bvb.de:BVB01-009655326</subfield></datafield><datafield tag="883" ind1="1" ind2=" "><subfield code="8">1\p</subfield><subfield code="a">cgwrk</subfield><subfield code="d">20201028</subfield><subfield code="q">DE-101</subfield><subfield code="u">https://d-nb.info/provenance/plan#cgwrk</subfield></datafield></record></collection> |
| id | DE-604.BV014093874 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T18:57:32Z |
| institution | BVB |
| isbn | 0471184233 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-009655326 |
| oclc_num | 44084018 |
| open_access_boolean | |
| owner | DE-20 DE-703 DE-384 DE-29T DE-355 DE-BY-UBR DE-188 DE-11 |
| owner_facet | DE-20 DE-703 DE-384 DE-29T DE-355 DE-BY-UBR DE-188 DE-11 |
| physical | XV, 534 S. Ill. |
| publishDate | 2001 |
| publishDateSearch | 2001 |
| publishDateSort | 2001 |
| publisher | Wiley |
| record_format | marc |
| spelling | Crabtree, Robert H. Verfasser aut The organometallic chemistry of the transition metals Robert H. Crabtree 3. ed. New York [u.a.] Wiley 2001 XV, 534 S. Ill. txt rdacontent n rdamedia nc rdacarrier Organotransition metal compounds Übergangsmetallorganische Verbindungen (DE-588)4417301-5 gnd rswk-swf Übergangsmetallkomplexe (DE-588)4131837-7 gnd rswk-swf Übergangsmetallkomplexe (DE-588)4131837-7 s Übergangsmetallorganische Verbindungen (DE-588)4417301-5 s 1\p DE-604 DE-604 OEBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009655326&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | Crabtree, Robert H. The organometallic chemistry of the transition metals Organotransition metal compounds Übergangsmetallorganische Verbindungen (DE-588)4417301-5 gnd Übergangsmetallkomplexe (DE-588)4131837-7 gnd |
| subject_GND | (DE-588)4417301-5 (DE-588)4131837-7 |
| title | The organometallic chemistry of the transition metals |
| title_auth | The organometallic chemistry of the transition metals |
| title_exact_search | The organometallic chemistry of the transition metals |
| title_full | The organometallic chemistry of the transition metals Robert H. Crabtree |
| title_fullStr | The organometallic chemistry of the transition metals Robert H. Crabtree |
| title_full_unstemmed | The organometallic chemistry of the transition metals Robert H. Crabtree |
| title_short | The organometallic chemistry of the transition metals |
| title_sort | the organometallic chemistry of the transition metals |
| topic | Organotransition metal compounds Übergangsmetallorganische Verbindungen (DE-588)4417301-5 gnd Übergangsmetallkomplexe (DE-588)4131837-7 gnd |
| topic_facet | Organotransition metal compounds Übergangsmetallorganische Verbindungen Übergangsmetallkomplexe |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009655326&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT crabtreeroberth theorganometallicchemistryofthetransitionmetals |