Adsorption and desorption behavior of nitric monoxide in Zeolites Na-A, Na-ZSM-5, and H-ZSM-5: a multi-frequency electron paramagnetic resonance study
Gespeichert in:
| 1. Verfasser: | |
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| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
2001
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| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | Leipzig, Univ., Diss., 2001 |
| Beschreibung: | 84, 6 Bl. Ill., graph. Darst. |
Internformat
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| 100 | 1 | |a Rudolf, Thomas |d 1971- |e Verfasser |0 (DE-588)123407265 |4 aut | |
| 245 | 1 | 0 | |a Adsorption and desorption behavior of nitric monoxide in Zeolites Na-A, Na-ZSM-5, and H-ZSM-5 |b a multi-frequency electron paramagnetic resonance study |c von Thomas Rudolf |
| 264 | 1 | |c 2001 | |
| 300 | |a 84, 6 Bl. |b Ill., graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 500 | |a Leipzig, Univ., Diss., 2001 | ||
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| 650 | 0 | 7 | |a Desorption |0 (DE-588)4149190-7 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Stickstoffmonoxid |0 (DE-588)4183282-6 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Zeolith |0 (DE-588)4067660-2 |2 gnd |9 rswk-swf |
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Datensatz im Suchindex
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CONTENTS
1 INTRODUCTION.4
1.1 FREE NO MOLECULES.7
1.2 ADSORBED NITRIC MONOXIDE.14
1.2.1 EPR SPIN HAMILTONIAN.14
1.2.2 THE G TENSOR OF THE NO ADSORPTION COMPLEX.15
1.2.3 ENDOR SPIN HAMILTONIAN.16
1.3 THE ANALYSIS OF THE EPR SPECTRA.18
1.4 ANALYSIS OF THE ENDOR SPECTRA.22
2 EXPERIMENTAL.24
2.1 NANOPOROUS ZEOLITES NA-A, NA-ZSM-5, H-ZSM-5.24
2.2 PREPARATION OF THE SAMPLES.27
2.3 EXPERIMENTAL SETUP.30
3 MULTI-FREQUENCY EPR AND ENDOR OF NO ADSORBED ON NA-A, NA-ZSM-5, AND
H-ZSM-5.33
3.1 RESULTS.33
3.1.1 X, Q, AND W BAND EPR ON THE SYSTEMS NA-A/NO, NA-ZSM-5/NO.33
3.1.2 THE SMALL EFFECT OF MISSING INTENSITIES IN THE EPR AND FIELD-SWEPT
ESE SPECTRA.40
3.1.3 X AND W B AND ENDOR ON THE SYSTEM NA-A/NO.44
3.1.4 X AND Q BAND EPR ON THE SYSTEM H-ZSM-5/NO.48
3.1.5 X BAND ENDOR ON H-ZSM-5/NO.51
3.2 DISCUSSION.55
3.2.1 THE NO ADSORPTION COMPLEXES IN NA-A AND NA-ZSM-5.55
3.2.2 SPIN DENSITY DISTRIBUTION WITHIN THE NO COMPLEX AND LEWIS
ACIDITY.57
3.2.3 STRUCTURE OF THE AF-NO ADSORPTION COMPLEX.58
4 NITRIC MONOXIDE ADSORPTION-DESORPTION BEHAVIOR MAINTAINED BY EPR.60
4.1 RESULTS.60
4.1.1 EPR OF GASEOUS NO.60
4.1.2 EPR OF DESORBED NO IN NA-A, NA-ZSM-5, AND H-ZSM-5.62
4.1.3 EPR BEHAVIOR OF NO ADSORBED ON NA-A, NA-ZSM-5, AND H-ZSM-5.68
4.2 DISCUSSION.73
5 CONCLUSIONS.76
6 ACKNOWLEDGEMENTS.80
7 REFERENCES.81
3
BIBLIOGRAFISCHE INFORMATIONEN
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| indexdate | 2024-10-09T18:06:20Z |
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| language | English |
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| physical | 84, 6 Bl. Ill., graph. Darst. |
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| spelling | Rudolf, Thomas 1971- Verfasser (DE-588)123407265 aut Adsorption and desorption behavior of nitric monoxide in Zeolites Na-A, Na-ZSM-5, and H-ZSM-5 a multi-frequency electron paramagnetic resonance study von Thomas Rudolf 2001 84, 6 Bl. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Leipzig, Univ., Diss., 2001 Adsorption (DE-588)4000536-7 gnd rswk-swf Elektronenspinresonanzspektroskopie (DE-588)4151888-3 gnd rswk-swf Desorption (DE-588)4149190-7 gnd rswk-swf Stickstoffmonoxid (DE-588)4183282-6 gnd rswk-swf Zeolith (DE-588)4067660-2 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Zeolith (DE-588)4067660-2 s Stickstoffmonoxid (DE-588)4183282-6 s Adsorption (DE-588)4000536-7 s Desorption (DE-588)4149190-7 s Elektronenspinresonanzspektroskopie (DE-588)4151888-3 s DE-604 DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009648737&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Rudolf, Thomas 1971- Adsorption and desorption behavior of nitric monoxide in Zeolites Na-A, Na-ZSM-5, and H-ZSM-5 a multi-frequency electron paramagnetic resonance study Adsorption (DE-588)4000536-7 gnd Elektronenspinresonanzspektroskopie (DE-588)4151888-3 gnd Desorption (DE-588)4149190-7 gnd Stickstoffmonoxid (DE-588)4183282-6 gnd Zeolith (DE-588)4067660-2 gnd |
| subject_GND | (DE-588)4000536-7 (DE-588)4151888-3 (DE-588)4149190-7 (DE-588)4183282-6 (DE-588)4067660-2 (DE-588)4113937-9 |
| title | Adsorption and desorption behavior of nitric monoxide in Zeolites Na-A, Na-ZSM-5, and H-ZSM-5 a multi-frequency electron paramagnetic resonance study |
| title_auth | Adsorption and desorption behavior of nitric monoxide in Zeolites Na-A, Na-ZSM-5, and H-ZSM-5 a multi-frequency electron paramagnetic resonance study |
| title_exact_search | Adsorption and desorption behavior of nitric monoxide in Zeolites Na-A, Na-ZSM-5, and H-ZSM-5 a multi-frequency electron paramagnetic resonance study |
| title_full | Adsorption and desorption behavior of nitric monoxide in Zeolites Na-A, Na-ZSM-5, and H-ZSM-5 a multi-frequency electron paramagnetic resonance study von Thomas Rudolf |
| title_fullStr | Adsorption and desorption behavior of nitric monoxide in Zeolites Na-A, Na-ZSM-5, and H-ZSM-5 a multi-frequency electron paramagnetic resonance study von Thomas Rudolf |
| title_full_unstemmed | Adsorption and desorption behavior of nitric monoxide in Zeolites Na-A, Na-ZSM-5, and H-ZSM-5 a multi-frequency electron paramagnetic resonance study von Thomas Rudolf |
| title_short | Adsorption and desorption behavior of nitric monoxide in Zeolites Na-A, Na-ZSM-5, and H-ZSM-5 |
| title_sort | adsorption and desorption behavior of nitric monoxide in zeolites na a na zsm 5 and h zsm 5 a multi frequency electron paramagnetic resonance study |
| title_sub | a multi-frequency electron paramagnetic resonance study |
| topic | Adsorption (DE-588)4000536-7 gnd Elektronenspinresonanzspektroskopie (DE-588)4151888-3 gnd Desorption (DE-588)4149190-7 gnd Stickstoffmonoxid (DE-588)4183282-6 gnd Zeolith (DE-588)4067660-2 gnd |
| topic_facet | Adsorption Elektronenspinresonanzspektroskopie Desorption Stickstoffmonoxid Zeolith Hochschulschrift |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009648737&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT rudolfthomas adsorptionanddesorptionbehaviorofnitricmonoxideinzeolitesnaanazsm5andhzsm5amultifrequencyelectronparamagneticresonancestudy |