The essential guide to environmental chemistry:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English German |
| Veröffentlicht: |
Chichester [u.a.]
Wiley
2001
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | X, 256 S. Ill., graph. Darst. |
| ISBN: | 0471899542 |
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Datensatz im Suchindex
| _version_ | 1804128886188933120 |
|---|---|
| adam_text | Titel: The essential guide to environmental chemistry
Autor: Schwedt, Georg
Jahr: 2001
Contents
Preface xiv
Introduction 1
1 Material Cycles
1.1 Geochemical cycles
1.1.1 Environmental areas 2
1.1.2 Endogenous and exogenous material
cycles 2
1.1.3 The geological material cycle 4
1.1.4 The crust-ocean machine 4
1.1.5 The Earth as a biogeochemical
factory 6
1.2 The carbon cycle
1.2.1 Mineralisation and biosynthesis 8
1.3 The nitrogen cycle
1.3.1 The global nitrogen cycle 10
1.3.2 Anthropogenic effects 10
1.3.3 Ammonification, nitrification,
denitrification 12
1.4 The sulphur cycle
1.4.1 The global sulphur cycle 14
1.4.2 The biochemical sulphur cycle 14
1.4.3 Environmentally relevant sulphur
compounds 16
1.4.4 Emissions and transformations 16
1.5 The phosphorus cycle
1.5.1 The giobal phosphorus cycle 18
1.5.2 The biogeochemical phosphorus
cycle 18
1.6 Metal cycles
1.6.1 The global anthropogenous
cycle 20
1.6.2 The geochemical cycle 20
1.6.3 The biogeochemical cycle 20
1.7 Special cycles
1.7.1 Cycles of environmental
chemicals 22
1.7.2 Interrelationships among the C. S, P.
N and O cycles 24
1.7.3 Bacterial and biochemical cycles in
the sedimentation of a lake 24
1.7.4 Anthropogenously related surface
material flow 26
1.7.5 Material cycles with links to the
environment 26
1.7.6 The ecologically orientated material
cycle 28
2 The Atmosphere
2.1 Physicochemical processes
2.1.1 Global energy balance 30
2.1.2 Composition of the atmosphere 30
2.1.3 Basic physicochemical
processes 32
2.1.4 Box model of atmospheric
chemistry 32
2.1.5 Linking the carbon and oxygen
cycles 34
2.1.6 Role of carbon dioxide 34
2.1.7 General behaviour of trace elements
in the atmosphere 36
2.1.8 Cycle of atmospheric aerosol
particles 36
2.2 Ecological photochemistry
2.2.1 Chemistry and photochemistry 38
2.2.2 Emission and deposition under
different weather conditions 38
2.2.3 Catalytic cycles of atmospheric ozone
chemistry 40
2.2.4 Ozone: formation and
decomposition 42
2.2.5 Ozone and the catalytic NO,
cycles 42
2.2.6 Photochemistry of the OH
radical 44
2.2.7 Scheme of the catalytic HO,
cycles 44
Contents
2.2.8 Scheme of halogen photochemistry in
the atmosphere 46
2.2.9 The global atmospheric chlorine
cycle 46
2.2.10 Scheme of the catalytic ClOr
cycle 46
2.2.11 Splitting of
chlorofluoromethanes 46
2.3 Air pollution from combustion
2.3.! Sources of air pollution 48
2.3.2 Quantification of air pollutants
according to source 48
2.3.3 Emissions from burning
vegetation 48
2.3.4 Nitrogen oxide: formation and
lowering of levels 50
2.4 Anthropogenous pollutants and
their effects
2.4.1 Anthropogenous emissions in West
Germany in 1984 52
2.4.2 Immissions near ground level 52
2.4.3 Pollutant flows during waste
incineration 54
2.4.4 Waste incineration in Germany 54
2.4.5 Acid formation from NOt
and SO2 56
2.4.6 Air pollution as a stress factor in the
ecosystem of a forest 56
2.4.7 Deposition of fine particles in the
human respiratory tract 58
2.4.8 Points of attack in the respiratory
tract dependent on water
solubility 58
2.4.9 Effects of CO in the
bloodstream 58
2.4.10 Sources of pollution in living and
working environments 60
2.5 Principles of air quality control
2.5.1 Techniques for cleaning
exhaust air 62
2.5.2 Comparison of different dust particle
separation systems 64
2.5.3 Thermal decomposition of organic
materials 64
2.5.4 Formation and thermal
decomposition of chlorinated
dibenzodioxins and
dibenzofurans 64
2.5.5 Combination process for cleaning
exhaust gas 66
2.5.6 Catalytic NOV reduction 66
2.5.7 Desulphurisation processes 66
2.5.8 Simultaneous processes for
desulphurisation and denitration of
exhaust gas 68
2.5.9 Adsorption plant for solvent
recovery 68
2.5.10 Construction of a biological
gas-washing plant 68
2.5.11 Automobile exhaust and its
cleaning 70
2.5.12 Landfill gases and low-pollution
combustion 72
3 Water
3.1 The Earth s water cycle
3.1.1 The hydrological cycle 74
3.1.2 Box model for water chemistry 74
3.1.3 Distribution of water by volume 74
3.1.4 Quantitative water content of
the Earth 76
3.1.5 Average water content in
Germany 76
3.1.6 Interactions between water and
land 78
3.1.7 Food chain and material cycle in
bodies of water 80
3.1.8 Quantified material cycle in the open
sea 80
3.1.9 Water cycle with anthropogenic
influences 82
Contents
VII
3.1.10 Water cycle in the area of
water—soil-vegetation 82
3.1.11 pH-pE diagrams with atmospheric
influences 84
3.1.12 Carbon species in bodies of
water 84
3.2 Chemistry in bodies of water
3.2.1 Equilibrium diagrams of some
molecule/ion systems 86
3.2.2 Carbonate species in rainwater 86
3.2.3 Ca2~ and HCO3 ions in rivers 86
3.2.4 Solubility of aluminium species 88
3.2.5 Species partition of Al-hydroxo
complexes 88
3.2.6 Equilibria between nitrate and
ammonium ions 88
3.2.7 Conversion of ammonium in running
waters 88
3.2.8 pE-pH diagram for iron species 90
3.2.9 Concentration-pE diagrams for
chlorine species 90
3.2.10 Genesis of rainwater 92
3.2.11 Pathways of emitted acid producers
and their effects on animals in
water 92
3.2.12 Emission and transport processes of
trace metals in riverbeds 94
3.2.13 Cycles and reactions of metals in
bodies of water 94
3.2.14 Reactions of metal ions in a lake 96
3.2.15 Areas of existence of metal—aquo
complexes, water hydroxo and oxo
complexes 96
3.3 Processes for the preparation of
drinking water
3.3.1 Preparation of Danube River water
for use as drinking water 98
3.3.2 Classical processes for the
preparation of drinking water 100
3.3.3 Electrodialysis in a three-chamber
cell 100
3.3.4 Desalination of water by reverse
osmosis 100
3.4 Basic principles of waste water
chemistry and sewage treatment
3.4.1 Local treatment plant as a direct
discharger 102
3.4.2 Layout of a mechanical-biological
water treatment plant 102
3.4.3 Composition of sewage and its
possible treatment 104
3.4.4 Variations in the amount of municipal
sewage 104
3.4.5 Biochemical oxygen demand,
BOD 104
3.4.6 Anaerobic degradation of organic
materials 106
3.4.7 Basic principles of anaerobic
purification processes 106
3.4.8 Kinetics of flocculation and
filtration 108
3.4.9 Effectiveness of chemicals in water
technology 108
3.4.10 Precipitation-pH ranges of metals
110
3.4.11 Sewage treatment plant with
precipitation of phosphate 110
3.4.12 Sludge formation and BOD 112
3.4.13 Oxygen consumption for metabolic
processes 112
3.4.14 Elimination of phosphate 112
3.4.15 Nitrogen conversion during sewage
treatment 114
3.4.16 Denitrification process 114
3.4.17 Waste water treatment in the
metal-working (automobile)
industry 116
3.4.18 Mechanical-biological—chemical
sewage treatment plant with sludge
treatment 116
VIII
Contents
4 Soil
4.1 Basic principles of soil science
4.1.1 The soil in the environment of the
litho-, hydro- and atmosphere 118
4.1.2 Components of the litho-, bio-,
hydro- and atmosphere 118
4.1.3 Interrelationships among types of
rock 120
4.1.4 Types of rock 120
4.1.5 Soil granulation classes 122
4.1.6 Clod structures of soil 122
4.1.7 Soil horizons 124
4.1.8 The four physical states of soil 124
4.2 Physico- and biogeochemical
processes
4.2.1 Soil functions 126
4.2.2 Soil components 126
4.2.3 Composition of arable land 126
4.2.4 Relationship between water tension
and water content: pF graphs 128
4.2.5 Volumes of water, air and substances
as a factor of soil type 128
4.2.6 Oxygen and carbon dioxide content
in the air in soil 128
4.2.7 Formation, transformation and
decomposition of clay minerals 130
4.2.8 Arrangement of elements in two- and
three-layered clay minerals 130
4.2.9 Structural types of silicates 130
4.2.10 Weathering of potash feldspar to
form clay minerals 132
4.2.11 Clay minerals as polyfunctional
exchangers 132
4.2.12 Diagenesis and humification 134
4.2.13 Soil and humus 134
4.2.14 Biogenesis of humic substances 138
4.2.15 Synthesis of humic substances 138
4.2.16 Structural model of a humic
system 138
4.2.17 Dynamic processes in the soil 140
4.2.18 Weathering and gas exchange 140
4.3 Metals and acid rain
4.3 .1 Potassium dynamics in the soil 142
4.3.2 Balancing out heavy metals in the
upper soil layer 142
4.3 .3 Soil pH and uptake of metals 142
4.3.4 Transport and activity of melting
salts 144
4.3. .5 Transport pathways of lead 144
4.3.6 Formation of lead emission in
airborne particles 146
4.3. .7 Frequency distribution of lead and
cadmium in garden soils 146
4.3. .8 Standardised lead levels in the AP soil
horizon near a non-ferrous heavy
metal emitter 148
4.3. 9 Accumulation of heavy metals 148
4.3. 10 Behaviour of heavy metals in the
soil 150
4.3. 11 Mobilisation of heavy metals with
various extraction agents 152
4.3. 12 Deposition of acid rain 154
4.3. 13 Influence of acid rain on the
ecosystem of the forests 154
4.3. 14 Processes in the soil 154
4.3.15 Acid rain as the cause of new-type
forest decline 156
4.3.16 Effects of acid emissions on Cologne
Cathedral 158
4.4 Organic contaminants
4.4.1 Example of an impacted industrial
area 160
4.4.2 Behaviour of pollutants in the
soil 162
4.4.3 Distribution of chlorinated
hydrocarbons in soil atmosphere 162
4.4.4 Behaviour of pesticides in the
soil 162
4.4.5 Amounts of measurable materials in
impacted soil 164
Contents
4.4.6 Summation curves of oxygen
consumption in soil contaminated
with oil 164
4.5 Methods for soil remediation
4.5.1 Emission pathways from a hazardous
waste site 166
4.5.2 Soil remediation procedures 166
4.5.3 Counterflow extraction with
solvents 168
4.5.4 Thermal hazardous waste site
remediation 168
4.5.5 Biological hazardous waste site
remediation 170
4.5.6 Remediation of contaminated
groundwater and of soil
atmosphere 170
4.6 Chemistry and technology in
landfills
4.6.1 Construction of a landfill 172
4.6.2 Sources of groundwater
contamination risk near a
landfill 172
4.6.3 Development of the waste volume
and its composition 172
4.6.4 Anaerobic decomposition processes
in landfills 174
4.6.5 Flow process of a waste fermentation
plant 176
4.6.6 Removal and use of landfill gas 176
5 Environmental
Chemistry of Selected
Xenobiotics and Heavy
Metals
5.1 Pathways of pollutants, food chains
and properties of materials
5.1.1 Pollutant pathways in
ecosystems 178
5.1.2 Basic principles of pollutant
distribution and transformation 178
5.1.3 Food chain and energy flow 180
5.1.4 Food pyramid 180
5.1.5 Food chain network 180
5.1.6 Materials properties and
environmental behaviour 182
5.1.7 Ecochemical materials
properties 184
5.1.8 Fundamental processes of material
transfer between atmosphere and
ocean 184
5.2 General decomposition pathways
5.2.1 Reaction enthalpies for
decomposition reactions of
biomass 186
5.2.2 Reductive (anaerobic) reactions of
xenobiotics 186
5.2.3 Bacterial decomposition of aromatic
compounds 188
5.2.4 Decomposition of aromatic nitro
compounds 188
5.3 Hydrocarbons: PAHs and PCBs
5.3.1 Formation of chlorinated compounds
during combustion processes 190
5.3.2 Decomposition of alkanes in the
troposphere 190
5.3.3 Mechanisms for PAH decomposition
in prokaryotes and eukaryotes 192
5.3.4 Elimination pathways during the
biochemical decomposition of PAHs
in the soil 192
5.3.5 Ways of distributing polychlorinated
biphenyls (PCBs) 194
5.3.6 Bioaccumulation of PCBs 194
5.3.7 Decomposition of PCBs 194
5.4 Dibenzodioxins and dibenzofurans
5.4.1 Sources and pathways of dioxins 196
5.4.2 Contaminants in commercial
chlorophenol products 196
5.4.3 Structural formulas and toxicity
equivalents 198
Contents
5.4.4 Formation and intake by humans 198
5.5 Pesticides and tensides
5.5.1 Behaviour of pesticides in the
soil 200
5.5.2 Persistence of pesticides in soils 200
5.5.3 Biotic decomposition of ethene
bisthiocarbamates 200
5.5.4 Decomposition of parathion in
cattle 202
5.5.5 Microbial decomposition of
parathion 202
5.5.6 Decomposition of herbicides
containing aromatic nitrogen 204
5.5.7 Decomposition of straight-chained
alkylbenzene sulphonates
(tensides) 204
5.6 Heavy metals and their species
5.6.1 Heavy metal species in natural bodies
of water 206
5.6.2 Concentration and activity 206
5.6.3 Chromium species in tannery waste
water 206
5.6.4 Mercury spider : applications and
activity 208
5.6.5 Environmental chemistry of
mercury 208
5.6.6 Ecochemical reactions of arsenic 210
5.6.7 Transformations of arsenic species in
the ocean 210
Problem- and Activity-
Oriented Environmental
Analysis
Environmental analysis - strategies
and concepts
Mobile on-site analysis 212
Rapid-test procedures 212
Conceptional environmental
analysis 214
6.1.4 Risk assessment during examination
of hazardous waste sites 216
6.1.5 Water studies near landfills 218
6.1.6 Strategies for the analysis of
contaminated soils 220
6.1.7 Luminescent bacteria test for
activity-related analysis of
contaminants 222
6.1.8 Outline for pesticide analysis in
environmental samples 224
6.1.9 Modern sample preparation for soils
contaminated with PCBs 224
6.1.10 Analytical methods for hydrocarbons
and PAHs in soils 226
6.1.11 Sample processing and determination
of pesticides 226
6.2 Ecotoxicological concepts for
evaluating risk
6.2.1 Flowchart for rapidly classifying
chemicals 228
6.2.2 Developing an environmental risk
profile 230
6.2.3 Exposure analysis based on the Unit
World fugacity model 232
6.2.4 Evaluation of monitoring data 232
6.2.5 Risk evaluation according to the E4
Chem model 234
6.2.6 The EXTND submodel for exposure
analysis 234
6.2.7 The OECD standard environmental
model 234
6.2.8 Compartments and processes in an
environment model 236
6.2.9 Activity analysis using a computer
study 236
Bibliography 238
Index 240
|
| any_adam_object | 1 |
| author | Schwedt, Georg 1943- |
| author_GND | (DE-588)120302233 |
| author_facet | Schwedt, Georg 1943- |
| author_role | aut |
| author_sort | Schwedt, Georg 1943- |
| author_variant | g s gs |
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| bvnumber | BV014028215 |
| classification_rvk | AR 25000 VN 9202 |
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| dewey-full | 628 |
| dewey-hundreds | 600 - Technology (Applied sciences) |
| dewey-ones | 628 - Sanitary engineering |
| dewey-raw | 628 |
| dewey-search | 628 |
| dewey-sort | 3628 |
| dewey-tens | 620 - Engineering and allied operations |
| discipline | Chemie / Pharmazie Allgemeines Bauingenieurwesen Umwelt |
| format | Book |
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| id | DE-604.BV014028215 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T18:56:22Z |
| institution | BVB |
| isbn | 0471899542 |
| language | English German |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-009605201 |
| oclc_num | 247904528 |
| open_access_boolean | |
| owner | DE-355 DE-BY-UBR DE-M49 DE-BY-TUM DE-12 DE-634 DE-83 DE-11 |
| owner_facet | DE-355 DE-BY-UBR DE-M49 DE-BY-TUM DE-12 DE-634 DE-83 DE-11 |
| physical | X, 256 S. Ill., graph. Darst. |
| publishDate | 2001 |
| publishDateSearch | 2001 |
| publishDateSort | 2001 |
| publisher | Wiley |
| record_format | marc |
| spelling | Schwedt, Georg 1943- Verfasser (DE-588)120302233 aut Taschenatlas der Umweltchemie The essential guide to environmental chemistry Georg Schwedt Chichester [u.a.] Wiley 2001 X, 256 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Wörterbuch (DE-588)4066724-8 gnd rswk-swf Umweltanalytik (DE-588)4282985-9 gnd rswk-swf Analytische Chemie (DE-588)4129906-1 gnd rswk-swf Umwelt (DE-588)4061616-2 gnd rswk-swf Ökologische Chemie (DE-588)4135167-8 gnd rswk-swf Atlas (DE-588)4143303-8 gnd rswk-swf Umwelt (DE-588)4061616-2 s Analytische Chemie (DE-588)4129906-1 s 1\p DE-604 Ökologische Chemie (DE-588)4135167-8 s Wörterbuch (DE-588)4066724-8 s 2\p DE-604 Atlas (DE-588)4143303-8 s 3\p DE-604 Umweltanalytik (DE-588)4282985-9 s 4\p DE-604 HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009605201&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 2\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 3\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 4\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | Schwedt, Georg 1943- The essential guide to environmental chemistry Wörterbuch (DE-588)4066724-8 gnd Umweltanalytik (DE-588)4282985-9 gnd Analytische Chemie (DE-588)4129906-1 gnd Umwelt (DE-588)4061616-2 gnd Ökologische Chemie (DE-588)4135167-8 gnd Atlas (DE-588)4143303-8 gnd |
| subject_GND | (DE-588)4066724-8 (DE-588)4282985-9 (DE-588)4129906-1 (DE-588)4061616-2 (DE-588)4135167-8 (DE-588)4143303-8 |
| title | The essential guide to environmental chemistry |
| title_alt | Taschenatlas der Umweltchemie |
| title_auth | The essential guide to environmental chemistry |
| title_exact_search | The essential guide to environmental chemistry |
| title_full | The essential guide to environmental chemistry Georg Schwedt |
| title_fullStr | The essential guide to environmental chemistry Georg Schwedt |
| title_full_unstemmed | The essential guide to environmental chemistry Georg Schwedt |
| title_short | The essential guide to environmental chemistry |
| title_sort | the essential guide to environmental chemistry |
| topic | Wörterbuch (DE-588)4066724-8 gnd Umweltanalytik (DE-588)4282985-9 gnd Analytische Chemie (DE-588)4129906-1 gnd Umwelt (DE-588)4061616-2 gnd Ökologische Chemie (DE-588)4135167-8 gnd Atlas (DE-588)4143303-8 gnd |
| topic_facet | Wörterbuch Umweltanalytik Analytische Chemie Umwelt Ökologische Chemie Atlas |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009605201&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT schwedtgeorg taschenatlasderumweltchemie AT schwedtgeorg theessentialguidetoenvironmentalchemistry |