The physical chemistry of natural waters:
Gespeichert in:
1. Verfasser: | |
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Format: | Buch |
Sprache: | English |
Veröffentlicht: |
New York [u.a.]
Wiley
2001
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Schriftenreihe: | Wiley-Interscience series in geochemistry
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Schlagworte: | |
Online-Zugang: | Inhaltsverzeichnis |
Beschreibung: | XIX, 654 S. graph. Darst. |
ISBN: | 0471362786 |
Internformat
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Datensatz im Suchindex
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adam_text | Titel: The physical chemistry of natural waters
Autor: Millero, Frank J.
Jahr: 2001
CONTENTS
Symbols, Physical Constants, and Conversion Factors ix
Introduction xvii
1. Basic Thermodynamic Concepts 1
A. The First Law of Thermodynamics 7
B. The Second Law of Thermodynamics-Entropy 20
C The Relationship Between Entropy and Other State Functions 27
D. Free Energy Functions and Equilibrium Calculations 31
E. The Thermodynamics of Solutions 42
F. Activity and Activity Coefficients 59
G. Nonelectrolyte Solutions 63
H. Strong Electrolytes 69
I. Thermodynamics of Electrolyte Solutions 79
2. Basic Kinetic Concepts 86
A. Transport Properties 86
B. Rate Processes in Solutions 108
3. Ionic Interactions 142
A. Water, the Unique Solvent 142
B. Ion-Water Interactions 149
C. Ion-Ion Interactions 163
D. Excess Properties of Mixing Electrolyte Solutions 194
E. Non-Coulombic Treatments 212
F. Activity Coefficients of Nonelectrolytes in Salt Solution 215
vii
vili CONTENTS
4. Physical Chemical Properties of Natural Waters 243
A. Introduction 243
B. The Composition and Stoichiometry of Seawater 249
C. The Equation of State of Seawater 254
D. Effect of Changes in the Composition of Seawater on the
Density-Salinity Relationship 270
E. The PVT Properties of Lakes, Rivers, and Estuaries 274
F. The Thermochemical Properties of Seawater 277
G. Other Physical Properties of Seawater 300
5. Chemical Equilibria in Natural Waters 315
A. Solubility of Gases 316
B. Dissociation of Acids 323
C. Solid-Liquid Equilibria 347
D. Formation of Metal Ion Pairs in Water 360
E. Effects of Pressure and Temperature on Ionic Equilibria 366
F. Helgeson Equations for Partial Molai Properties 386
6. Estimation of the Thermodynamic Properties of Natural Waters 413
A. Estimation of the Physical Properties of Natural Waters 413
B. Estimation of the Activity Coefficients in Natural Waters 429
C. Estimation of the Partial Molai Properties in Mixed Electrolytes 496
7. The Kinetics of Oxidation and Reduction of Metals in Natural Waters 515
A. Oxidation of Cu(I) with O2 516
B. Oxidation of Cu(I) with H2O2 523
C. Comparisons of the Rates of Oxidation of Cu(I) with O2 and H2O2 528
D. Rates of Reduction of Cu(II) with H2O2 530
E. Oxidation of Fe(II) with O2 540
F. Oxidation of Fe(II) with H,O2 546
G. Comparisons of the Rates of Oxidation of Fe(II) with O2 and H2O2 550
H. Reduction of Fe(III) with Sulfite 552
I. Oxidation of Cr(III) with H2O2 558
J. Reduction of Cr(VI) with Fe(II) 562
K. Reactions of Metals with Superoxide 571
8. The Oxidation of Hydrogen Sulfide in Natural Waters 582
A. Oxidation of H;S with O: 585
B. Effect of Metals on the Oxidation of H,S 590
C. Products from the Oxidation of H2S 593
D. Oxidation of H;SO, with O2 595
E. Kinetic Model for the Oxidation of H2S with O2 598
F. Oxidation of H2S in Anoxic Environments 602
G. Oxidation of H2S by H2O2 606
H. Oxidation of H,S with Fe and Mn Oxides 612
Author Index 633
Subject Index 643
|
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author | Millero, Frank J. |
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indexdate | 2024-07-09T18:55:29Z |
institution | BVB |
isbn | 0471362786 |
language | English |
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physical | XIX, 654 S. graph. Darst. |
publishDate | 2001 |
publishDateSearch | 2001 |
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publisher | Wiley |
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series2 | Wiley-Interscience series in geochemistry |
spelling | Millero, Frank J. Verfasser aut The physical chemistry of natural waters Frank J. Millero New York [u.a.] Wiley 2001 XIX, 654 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Wiley-Interscience series in geochemistry Physikalische Chemie (DE-588)4045959-7 gnd rswk-swf Hydrochemie (DE-588)4072678-2 gnd rswk-swf Wasser (DE-588)4064689-0 gnd rswk-swf Wasser (DE-588)4064689-0 s Physikalische Chemie (DE-588)4045959-7 s DE-604 Hydrochemie (DE-588)4072678-2 s HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009568016&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
spellingShingle | Millero, Frank J. The physical chemistry of natural waters Physikalische Chemie (DE-588)4045959-7 gnd Hydrochemie (DE-588)4072678-2 gnd Wasser (DE-588)4064689-0 gnd |
subject_GND | (DE-588)4045959-7 (DE-588)4072678-2 (DE-588)4064689-0 |
title | The physical chemistry of natural waters |
title_auth | The physical chemistry of natural waters |
title_exact_search | The physical chemistry of natural waters |
title_full | The physical chemistry of natural waters Frank J. Millero |
title_fullStr | The physical chemistry of natural waters Frank J. Millero |
title_full_unstemmed | The physical chemistry of natural waters Frank J. Millero |
title_short | The physical chemistry of natural waters |
title_sort | the physical chemistry of natural waters |
topic | Physikalische Chemie (DE-588)4045959-7 gnd Hydrochemie (DE-588)4072678-2 gnd Wasser (DE-588)4064689-0 gnd |
topic_facet | Physikalische Chemie Hydrochemie Wasser |
url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009568016&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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