Medicinal natural products: a biosynthetic approach
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Chichester [u.a.]
Wiley
2002
|
| Ausgabe: | 2. ed. |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XII, 507 S. Ill. |
| ISBN: | 0471496413 0471496405 |
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| 245 | 1 | 0 | |a Medicinal natural products |b a biosynthetic approach |c Paul M. Dewick |
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| 650 | 4 | |a Biological Products | |
| 650 | 4 | |a Biosynthesis | |
| 650 | 4 | |a Herbal Medicine | |
| 650 | 4 | |a Natural products | |
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Datensatz im Suchindex
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| adam_text | CONTENTS
1 ABOUT THIS BOOK, AND HOW TO USE IT 1
The Subject 1
The Aim 1
The Approach 2
The Topics 2
Be Selective 2
To Learn, or to Understand? 3
Conventions Regarding Acids, Bases, and Ions 3
Nomenclature 3
Some Common Abbreviations 4
Further Reading 4
2 SECONDARY METABOLISM: THE BUILDING BLOCKS AND CONSTRUCTION
MECHANISMS 7
Primary and Secondary Metabolism 7
The Building Blocks 8
The Construction Mechanisms 12
Alkylation Reactions: Nucleophilic Substitution 12
Alkylation Reactions: Electrophilic Addition 13
Wagner Meerwein Rearrangements 15
Aldol and Claisen Reactions 15
Schiff Base Formation and the Mannich Reaction 18
Transamination 20
Decarboxylation Reactions 20
Oxidation and Reduction Reactions 24
Dehydrogenases 24
Oxidases 25
Mono oxygenases 25
Dioxygenases 27
Amine Oxidases 28
Baeyer— Villiger Oxidations 28
Phenolic Oxidative Coupling 28
Glycosylation Reactions 29
Some Vitamins Associated with the Construction Mechanisms 30
Vitamin Bj, Vitamin B2, Vitamin Bs, Vitamin B(,, Vitamin B12, Vitamin H
Further Reading 33
3 THE ACETATE PATHWAY: FATTY ACIDS AND POLYKETIDES 35
Saturated Fatty Acids 36
Unsaturated Fatty Acids 40
Fixed Oils and Fats, Evening Primrose Oil
Acetylenic Fatty Acids 47
Branched Chain Fatty Acids 48
Echinacea
viii CONTENTS
Prostaglandins 51
Prostaglandins, Isoprostanes
Thromboxanes 58
Thromboxanes
Leukotrienes 58
Leukotrienes
Aromatic Polyketides 60
Cyclization: Simple Phenols 61
Structural Modifications: Anthraquinones 63
Senna, Cascara, Frangula, Allied Drugs, Hypericum/St John s Wort
C Alkylation Reactions 72
Mycophenolic Acid, Khellin and Cromoglicate
Phenolic Oxidative Coupling 76
Griseofulvin
Oxidative Cleavage of Aromatic Rings 78
Starter Groups Other Than Acetate 79
Poison Ivy and Poison Oak, Aflatoxins, Cannabis, Tetracy dines, Anthracydine
Antibiotics
Macrolides and Polyethers 92
Extender Groups other than Malonate 92
Macrolide Antibiotics, Avermectins, Polyene Antifungals, Tacrolimus and Sirolimus,
Ansa Macrolides
Cyclization Through Diels Alder Reactions HI
Mevastatin and other Statins
Genetic Manipulation of the Acetate Pathway H4
Further Reading 117
4 THE SHIKIMATE PATHWAY: AROMATIC AMINO ACIDS AND
PHENYLPROPANOIDS 121
Aromatic Amino Acids and Simple Benzoic Acids 121
Folk Acid (Vitamin Bg), Chloramphenicol
Cinnamic Acids 130
Lignans and Lignin 132
Podophyllum
Phenylpropenes 135
Volatile Oils Containing Principally Aromatic Compounds
Benzoic Acids from C6C3 Compounds 141
Coumarins 142
Dicoumarol and Warfarin, Psoralens
Styrylpyrones 147
Kava
Flavonoids and Stilbenes 149
Flavonolignans 151
Silybum marianum
Isoflavonoids 154
Phyto oestrogens, Derris and Lonchocarpus
Terpenoid Quinones 158
Vitamin E, Vitamin K
Further Reading 164
CONTENTS ix
5 THE MEVALONATE AND DEOXYXYLULOSE PHOSPHATE PATHWAYS:
TERPENOIDS AND STEROIDS 167
Hemiterpenes (C5) 172
Monoterpenes (Cio) 172
Volatile Oils Containing Principally Terpenoid Compounds
Irregular Monoterpenes 186
Pyrethrins
Iridoids (Ci0) 187
Valerian
Sesquiterpenes (Ci5) 191
Feverfew, Chamomile and Matricaria, Artemisia annua and Artemisinin, Gossypol,
Trichothecenes
Diterpenes (C2o) 203
Taxus brevifolia and Taxol (Paclitaxel), Ginkgo biloba, Forskolin
Sesterterpenes (C2s) 212
Triterpenes (C30) 212
Triterpenoid Saponins 219
Liquorice, Quillaia, Ginseng
Modified Triterpenoids 225
Tetraterpenes (C40) 226
Vitamin A
Higher Terpenoids 231
Steroids 232
Stereochemistry 232
Cholesterol 233
Cholesterol
Steroidal Saponins 237
Dioscorea, Fenugreek, Sisal, Sarsaparilla, Yucca
Cardioactive Glycosides 241
Digitalis purpurea, Digitalis lanata, Strophanthus, Convallaria, Squill, Toxic Plants
Phytosterols 252
Soya Bean Sterols, Fusidic Acid
Vitamin D 257
Vitamin D
Bile Acids 260
Bile Acids
Adrenocortical Hormones/Corticosteroids 262
Semi Synthesis of Corticosteroids 264
Corticosteroid Drugs
Progestogens 267
Progestogen Drugs
Oestrogens
Oestrogen Drugs, Aromatase Inhibitors, Oestrogen Receptor Antagonists
Androgens 282
Androgen Drugs
Further Reading 285
x CONTENTS
6 ALKALOIDS 291
Alkaloids Derived from Ornithine 292
Pyrrolidine and Tropane Alkaloids 292
Belladonna, Stramonium, Hyosycamus, Duboisia, Allied Drugs, Hyoscyamine,
Hyoscine and Atropine, Coca
Pyrrolizidine Alkaloids 305
Alkaloids Derived from Lysine 307
Piperidine Alkaloids 307
Lobelia 308
Quinolizidine Alkaloids 309
Indolizidine Alkaloids 310
Alkaloids Derived from Nicotinic Acid 311
Pyridine Alkaloids 311
Vitamin B3, Tobacco, Areca
Alkaloids Derived from Ttyrosine 315
Phenylethylamines and Simple Tetrahydroisoquinoline Alkaloids 315
Catecholamines, Areca, Lophophora, Curare
Modified Benzyltetrahydroisoquinoline Alkaloids 327
Opium 329
Phenethylisoquinoline Alkaloids 341
Colchicum
Terpenoid Tetrahydroisoquinoline Alkaloids 343
Ipecacuanha
Amaryllidaceae Alkaloids 345
Galanthamine
Alkaloids Derived from Tryptophan 346
Simple Indole Alkaloids 347
5 Hydroxytryptamine (Serotonin), Psilocybe
Simple P Carboline Alkaloids 349
Terpenoid Indole Alkaloids 350
Rauwolfia, Catharanthus, Iboga, Nux vomica, Ellipticine
Quinoline Alkaloids 359
Cinchona, Camptothecin
Pyrroloindole Alkaloids 365
Physostigma
Ergot Alkaloids 368
Ergot, Morning Glories
Alkaloids Derived from Anthranilic Acid 376
Quinazoline Alkaloids 377
Quinoline and Acridine Alkaloids 377
Alkaloids Derived from Histidine 379
Imidazole Alkaloids 379
Pilocarpus
Alkaloids Derived by Animation Reactions 381
Acetate derived Alkaloids 381
Conium maculatum
Phenylalanine derived Alkaloids 382
Ephedra, Khat
Terpenoid Alkaloids 385
Aconite
CONTENTS xi
Steroidal Alkaloids 388
Solanum Alkaloids
Purine Alkaloids 394
Caffeine, Theobromine, and Theophylline, Coffee, Tea, Cola, Cocoa, Mate Tea,
Guarana
Saxitoxin and Tetrodotoxin 396
Saxitoxin, Tetrodotoxin
Further Reading 398
7 PEPTIDES, PROTEINS, AND OTHER AMINO ACID DERIVATIVES 405
Peptides and Proteins 405
Ribosomal Peptide Biosynthesis 407
Peptide Hormones 410
Thyroid Hormones 410
Thyroxine, Calcitonin
Hypothalamic Hormones 411
Thyrotrophin Releasing Hormone, Luteinizing Hormone Releasing Hormone, Growth
Hormone Releasing Hormone/Factor, Somatostatin
Anterior Pituitary Hormones 413
Corticotropin, Growth Hormone, Prolactin, Gonadotrophins
Posterior Pituitary Hormones 413
Oxytocin, Vasopressin
Pancreatic Hormones 416
Insulin, Glucagon
Interferons 417
Interferons
Opioid Peptides 417
Enzymes 419
Nonribosomal Peptide Biosynthesis 421
Peptide Antibiotics 423
Cycloserine, Polymyxins, Bacitracins, Tyrothricin and Gramicidins, Capreomycin,
Vancomycin and Teicoplanin, Bleomycin, Cyclosporins, Streptogramins,
Dactinomycin
Peptide Toxins 433
Death Cap (Amanita phalloides), Ricin, Botulinum Toxin, Microcystins, Snake Venoms
Modified Peptides: Penicillins, Cephalosporins, and Other 0 Lactams 422
Penicillins 422
Penicillins
Cephalosporins 444
Cephalosporins, Cephamycins, Carbacephems
Other P Lactams 450
Clavulanic Acid, Carbapenems, Monobactams
Cyanogenic Glycosides 455
Glucosinolates 457
Cysteine Sulphoxides 460
Garlic
Further Reading 461
xii CONTENTS
8 CARBOHYDRATES 465
Monosaccharides 465
Oligosaccharides 469
Monosaccharides and Disaccharides, Vitamin C
Polysaccharides 473
Polysaccharides
Aminosugars 477
Aminoglycosides 478
Aminoglycoside Antibiotics, Streptamine containing Antibiotics,
2 Deoxystreptamine containing Antibiotics, Acarbose, Lincomycin and Clindamycin
Further Reading 486
Index 487
|
| any_adam_object | 1 |
| author | Dewick, Paul M. |
| author_facet | Dewick, Paul M. |
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| dewey-ones | 615 - Pharmacology and therapeutics |
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| dewey-search | 615/.321 |
| dewey-sort | 3615 3321 |
| dewey-tens | 610 - Medicine and health |
| discipline | Chemie / Pharmazie Medizin |
| edition | 2. ed. |
| format | Book |
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| geographic | Pharmacognosy |
| geographic_facet | Pharmacognosy |
| id | DE-604.BV013847809 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T18:53:07Z |
| institution | BVB |
| isbn | 0471496413 0471496405 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-009471932 |
| oclc_num | 47074246 |
| open_access_boolean | |
| owner | DE-20 DE-29 DE-29T DE-11 |
| owner_facet | DE-20 DE-29 DE-29T DE-11 |
| physical | XII, 507 S. Ill. |
| publishDate | 2002 |
| publishDateSearch | 2002 |
| publishDateSort | 2002 |
| publisher | Wiley |
| record_format | marc |
| spelling | Dewick, Paul M. Verfasser aut Medicinal natural products a biosynthetic approach Paul M. Dewick 2. ed. Chichester [u.a.] Wiley 2002 XII, 507 S. Ill. txt rdacontent n rdamedia nc rdacarrier Alkaloïden gtt Biosynthese gtt Biosynthèse Eiwitten gtt Farmacochemie gtt Koolwaterstoffen gtt Natuurlijke stoffen gtt Pharmacognosie Produits naturels Steroïden gtt Terpenen gtt Biological Factors biosynthesis Biological Products Biosynthesis Herbal Medicine Natural products Pharmacognosy Plants, Medicinal Naturstoff (DE-588)4041418-8 gnd rswk-swf Pflanzeninhaltsstoff (DE-588)4139067-2 gnd rswk-swf Pharmazeutische Biologie (DE-588)4045693-6 gnd rswk-swf Biosynthese (DE-588)4006902-3 gnd rswk-swf Pharmazeutische Chemie (DE-588)4132158-3 gnd rswk-swf Heilpflanzen (DE-588)4024076-9 gnd rswk-swf Biosynthese (DE-588)4006902-3 s Naturstoff (DE-588)4041418-8 s Pharmazeutische Biologie (DE-588)4045693-6 s DE-604 Pharmazeutische Chemie (DE-588)4132158-3 s 1\p DE-604 Heilpflanzen (DE-588)4024076-9 s Pflanzeninhaltsstoff (DE-588)4139067-2 s 2\p DE-604 3\p DE-604 HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009471932&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 2\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 3\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | Dewick, Paul M. Medicinal natural products a biosynthetic approach Alkaloïden gtt Biosynthese gtt Biosynthèse Eiwitten gtt Farmacochemie gtt Koolwaterstoffen gtt Natuurlijke stoffen gtt Pharmacognosie Produits naturels Steroïden gtt Terpenen gtt Biological Factors biosynthesis Biological Products Biosynthesis Herbal Medicine Natural products Pharmacognosy Plants, Medicinal Naturstoff (DE-588)4041418-8 gnd Pflanzeninhaltsstoff (DE-588)4139067-2 gnd Pharmazeutische Biologie (DE-588)4045693-6 gnd Biosynthese (DE-588)4006902-3 gnd Pharmazeutische Chemie (DE-588)4132158-3 gnd Heilpflanzen (DE-588)4024076-9 gnd |
| subject_GND | (DE-588)4041418-8 (DE-588)4139067-2 (DE-588)4045693-6 (DE-588)4006902-3 (DE-588)4132158-3 (DE-588)4024076-9 |
| title | Medicinal natural products a biosynthetic approach |
| title_auth | Medicinal natural products a biosynthetic approach |
| title_exact_search | Medicinal natural products a biosynthetic approach |
| title_full | Medicinal natural products a biosynthetic approach Paul M. Dewick |
| title_fullStr | Medicinal natural products a biosynthetic approach Paul M. Dewick |
| title_full_unstemmed | Medicinal natural products a biosynthetic approach Paul M. Dewick |
| title_short | Medicinal natural products |
| title_sort | medicinal natural products a biosynthetic approach |
| title_sub | a biosynthetic approach |
| topic | Alkaloïden gtt Biosynthese gtt Biosynthèse Eiwitten gtt Farmacochemie gtt Koolwaterstoffen gtt Natuurlijke stoffen gtt Pharmacognosie Produits naturels Steroïden gtt Terpenen gtt Biological Factors biosynthesis Biological Products Biosynthesis Herbal Medicine Natural products Pharmacognosy Plants, Medicinal Naturstoff (DE-588)4041418-8 gnd Pflanzeninhaltsstoff (DE-588)4139067-2 gnd Pharmazeutische Biologie (DE-588)4045693-6 gnd Biosynthese (DE-588)4006902-3 gnd Pharmazeutische Chemie (DE-588)4132158-3 gnd Heilpflanzen (DE-588)4024076-9 gnd |
| topic_facet | Alkaloïden Biosynthese Biosynthèse Eiwitten Farmacochemie Koolwaterstoffen Natuurlijke stoffen Pharmacognosie Produits naturels Steroïden Terpenen Biological Factors biosynthesis Biological Products Biosynthesis Herbal Medicine Natural products Pharmacognosy Plants, Medicinal Naturstoff Pflanzeninhaltsstoff Pharmazeutische Biologie Pharmazeutische Chemie Heilpflanzen |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009471932&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT dewickpaulm medicinalnaturalproductsabiosyntheticapproach |