Polymers derived from isobutylene: synthesis, properties, application
Gespeichert in:
Hauptverfasser: | , , |
---|---|
Format: | Buch |
Sprache: | English |
Veröffentlicht: |
Utrecht ; Boston ; Köln ; Tokyo
VSP
2001
|
Ausgabe: | 1. publ. |
Schriftenreihe: | New concepts in polymer science
|
Schlagworte: | |
Online-Zugang: | Inhaltsverzeichnis |
Beschreibung: | Literaturangaben |
Beschreibung: | IX, 372 S. graph. Darst. : 25 cm |
ISBN: | 9067643351 |
Internformat
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035 | |a (OCoLC)47869284 | ||
035 | |a (DE-599)BVBBV013748073 | ||
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100 | 1 | |a Sangalov, Jurij A. |e Verfasser |4 aut | |
245 | 1 | 0 | |a Polymers derived from isobutylene |b synthesis, properties, application |c Yu. A. Sangalov, K. S. Minsker and G. E. Zaikov |
250 | |a 1. publ. | ||
264 | 1 | |a Utrecht ; Boston ; Köln ; Tokyo |b VSP |c 2001 | |
300 | |a IX, 372 S. |b graph. Darst. : 25 cm | ||
336 | |b txt |2 rdacontent | ||
337 | |b n |2 rdamedia | ||
338 | |b nc |2 rdacarrier | ||
490 | 0 | |a New concepts in polymer science | |
500 | |a Literaturangaben | ||
650 | 7 | |a Butène |2 ram | |
650 | 7 | |a Polybutènes |2 ram | |
650 | 4 | |a Polybutenes | |
650 | 0 | 7 | |a Polyisobutene |0 (DE-588)4175214-4 |2 gnd |9 rswk-swf |
650 | 0 | 7 | |a Isobuten |0 (DE-588)4162474-9 |2 gnd |9 rswk-swf |
650 | 0 | 7 | |a Polymerisation |0 (DE-588)4046704-1 |2 gnd |9 rswk-swf |
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689 | 0 | 1 | |a Polymerisation |0 (DE-588)4046704-1 |D s |
689 | 0 | |5 DE-604 | |
689 | 1 | 0 | |a Polyisobutene |0 (DE-588)4175214-4 |D s |
689 | 1 | |5 DE-604 | |
700 | 1 | |a Minsker, Karl S. |e Verfasser |4 aut | |
700 | 1 | |a Zajkov, Gennadij E. |d 1935- |e Verfasser |0 (DE-588)109480775 |4 aut | |
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adam_text |
CONTENTS
FOREWORD
XI
AUTHORS
'
PREFACE
XIII
P
ART
I.
S
CIENTIFIC
AND
TECHNOLOGICAL
ASPECTS
OF
ISOBUTYLENE
PRODUCTION
CHAPTER
1.
PROPERTIES
AND
PRODUCTION
OF
ISOBUTYLENE
1.1.
PHYSICAL
PROPERTIES
1
1.2.
CHEMICAL
PROPERTIES
3
1.3.
METHODS
OF
ISOBUTYLENE
PRODUCTION
13
1.4.
PRODUCTION
OF
ISOBUTYLENE
IN
INDUSTRY
17
1.5.
SPECIAL
METHODS
OF
ISOBUTYLENE
PRODUCTION
24
1.6.
ANALYSIS
OF
ISOBUTYLENE
25
REFERENCES
TO
CHAPTER
1
29
CHAPTER
2.
ISOBUTYLENE
POLYMERIZATION
2.1.
GENERAL
IDEAS
OF
POLYMERIZATION.
CATALYSTS
32
2.2.
POLYMERIZATION
MECHANISM
60
2.2.1.
INITIATION
60
2.2.2.
CHAIN
PROPAGATION
77
2.2.3.
LIMITING
OF
THE
CHAIN
PROPAGATION
87
2.3.
PROBLEMS
OF
CATIONIC
POLYMERIZATION
OF
ISOBUTYLENE
101
2.3.1.
MOLECULAR
ENGINEERING
101
2.3.2.
FEATURES
OF
FAST
POLYMERIZATION
PROCESSES
103
2.3.3.
PROBLEMS
OF
KINETICS
OF
FAST
POLYMERIZATION
PROCESSES
104
2.4.
KINETIC
FEATURES
OF
ISOBUTYLENE
POLYMERIZATION
106
REFERENCES
TO
CHAPTER
2
115
CHAPTER
3.
MACROKINETICS
OF
ISOBUTYLENE
POLYMERIZATION
3.1.
MODELING
OF
ISOBUTYLENE
POLYMERIZATION
AS
A
FAST
CHEMICAL
REACTION
126
3.2.
MACROSCOPIC
FEATURES
OF
ISOBUTYLENE
POLYMERIZATION.
NOVEL
FUNDAMENTAL
REGULARITIES
13
5
3.2.1.
ON
EXISTENCE
OF
SEVERAL
MACROSCOPIC
REGIMES
135
3.2.2.
ON
CONNECTION
BETWEEN
GEOMETRICAL
SIZE
OF
THE
REACTION
ZONE
AND
KINETIC
AND
HYDRODYNAMIC
PARAMETERS
139
3.2.3.
INFLUENCE
OF
LINEAR
FLOW
MOTION
RATE
ON
MOLECULAR-MASS
CHARACTERISTICS
OF
RESULTING
POLYMER
144
VIII
CONTENTS
3.2.4.
INFLUENCE
OF
THE
METHOD
OF
CATALYST
TRANSMISSION
ON
MOLECULAR-MASS
CHARACTERISTICS
OF
RESULTING
POLYMER
148
3.3.
HEAT
REGIME
OF
FAST
ISOBUTYLENE
POLYMERIZATION
151
3.3.1.
HEAT
REGIME
OF
POLYMERIZATION
IN
THE
ABSENCE
OF
HEAT
ELIMINATION
151
3.3.2.
HEAT
REGIME
OF
POLYMERIZATION
WITH
REACTION
MASS
BOILING
152
3.3.3.
EFFICIENCY
OF
EXTERNAL
HEAT
ELIMINATION
157
3.4.
OPTIMIZATION
OF
MOLECULAR-MASS
CHARACTERISTICS
OF
POLYMER
IN
FAST
ISOBUTYLENE
POLYMERIZATION.
THE
ZONE
MODEL
160
3.4.1.
ESTIMATION
OF
MOLECULAR-MASS
POLYISOBUTYLENE
CHARACTERISTICS
IN
THE
ABSENCE
OF
HEAT
ELIMINATION
AT
THE
MULTISTAGE
CATALYST
DELIVERY
INTO
THE
REACTING
TURBULENT
ZONE
160
3.4.2.
TWO-ZONE
MODEL
OF
PIPE
TURBULENT
REACTOR
161
3.4.3.
THREE-STAGE
CATALYST
FEEDING
163
3.4.4.
THE
FOUR-STAGE
CATALYST
FEEDING
164
3.4.5.
MULTISTAGE
CATALYST
FEEDING
(THE
REACTOR
WITH
INFINITE
NUMBER
OF
CATALYST
FEEDING
ZONES
WITHOUT
HEAT
ELIMINATION)
164
3.5.
MOLECULAR-MASS
CHARACTERISTICS
OF
RESULTING
POLYMER
UNDER
THE
CONDITION
OF
INTERNAL
HEAT
ELIMINATION
(AT
THE
SACRIFICE
OF
THE
REACTION
MASS
BOILING)
171
3.5.1.
THE
TWO-STAGE
CATALYST
FEEDING
UNDER
INTERNAL
HEAT
ELIMINATION
171
3.5.2.
THREE-STAGE
CATALYST
FEEDING
UNDER
INTERNAL
HEAT
ELIMINATION
172
3.5.3.
FOUR-STAGE
CATALYST
FEEDING
UNDER
INTERNAL
HEAT
ELIMINATION
173
3.5.4.
MULTISTAGE
CATALYST
FEEDING
UNDER
INTERNAL
HEAT
ELIMINATION
173
3.6.
EFFICIENCY
OF
EXTERNAL
HEAT
ELIMINATION
UNDER
CONDITIONS
OF
REACTIVE
TURBULENT
FLOW.
THE
ZONE
MODEL
174
REFERENCES
TO
CHAPTER
3
179
CHAPTER
4.
COPOLYMERIZATION
OF
ISOBUTYLENE
4.1.
SPECIFIC
FEATURES
OF
CATIONIC
COPOLYMERISATION
181
4.2.
REACTIVITY
OF
MONOMERS
IN
COPOLYMERIZATION
WITH
ISOBUTYLENE
185
4.3.
SPECIAL
METHODS
OF
DERIVING
COPOLYMERS
OF
ISOBUTYLENE
193
REFERENCES
TO
CHAPTER
4
200
P
ART
II.
P
OLYMERS
DERIVED
FROM
ISOBUTYLENE
CHAPTER
5.
PROPERTIES
AND
PRODUCTION
OF
POLYISOBUTYLENE
5.1.
PHYSICAL
PROPERTIES
204
5.2.
CHEMICAL
PROPERTIES
209
5.2.1.
POLYISOBUTYLENE
REACTIONS
AT
UNSATURATED
BONDS
211
5.2.2.
POLYISOBUTYLENE
REACTIONS
INVOLVING
THE
MAIN
CHAIN
227
5.3.
ANALYTICAL
CHARACTERISTICS
OF
POLYISOBUTYLENE
242
REFERENCES
TO
CHAPTER
5
247
CHAPTER
6.
BUTYL
RUBBER
AND
ITS
DERIVATIVES
6.1.
BUTYL
RUBBER
251
6.1.1.
PHYSICAL
PROPERTIES
251
6.1.2.
CHEMICAL
PROPERTIES
253
6.1.3.
MAIN
AREAS
OF
BUTYL
RUBBER
APPLICATION
256
CONTENTS
IX
6.2.
MODIFIED
BUTYL
RUBBER
262
6.2.1.
CHLORINATED
BUTYL
RUBBER
262
6.2.1.1.
STRUCTURE
AND
PHYSICAL
PROPERTIES
262
6.2.1.2.
CHEMICAL
PROPERTIES
266
6.2.1.3.
AREAS
OF
APPLICATION
270
6.2.2.
BROMATED
BUTYL
RUBBER
272
6.2.2.1.
STRUCTURE
AND
PHYSICAL
PROPERTIES
273
6.2.2.2.
CHEMICAL
PROPERTIES
274
6.2.2.3.
APPLICATION
OF
BROMOBUTYL
RUBBER
275
6.2.3.
OTHER
MODIFIED
BUTYL
RUBBERS
276
6.2.4.
MIXTURES
OF
HALOGENATED
BUTYL
RUBBERS
WITH
OTHER
ELASTOMERS
278
REFERENCES
TO
CHAPTER
6
282
CHAPTER
7.
INDUSTRIAL
PRODUCTION
OF
ISOBUTYLENE
POLYMERS
7.1.
STANDARD
TECHNOLOGIES
FOR
PRODUCTION
OF
OLIGO
AND
POLYISOBUTYLENE
284
7.1.1.
PRODUCTION
OF
HIGH-MOLECULAR
POLY
ISOBUTYLENE
285
7.1.2.
PRODUCTION
OF
MODERATE
AND
LOW-MOLECULAR
POLYISOBUTYLENES
291
7.2.
NEW
GENERATION
OF
RESOURCE
AND
ENERGY
PRESERVING
TECHNOLOGIES
FOR
PRODUCTION
OF
HIGHER
ECOLOGICALLY
FRIENDLY
OLIGO
AND
POLYISOBUTYLENES
296
7.2.1.
MAIN
PREREQUISITES
296
7.2.2.
PRODUCTION
OF
HIGH-MOLECULAR
POLY
ISOBUTYLENE
299
7.2.3.
PRODUCTION
OF
MODERATE
AND
LOW-MOLECULAR
POLYISOBUTYLENES
300
7.3.
SPECIFIC
FEATURES
OF
BUTYL
RUBBER
PRODUCTION
312
7.4.
STANDARD
TECHNOLOGIES
OF
BUTYL
RUBBER
PRODUCTION
315
7.4.1.
MAIN
PREMISES
315
7.4.2.
TECHNOLOGY
OF
PRODUCTION
OF
BUTYL
RUBBER
319
7.5.
NEW
TECHNOLOGIES
IN
PRODUCTION
OF
ECOLOGICALLY
FRIENDLY
BUTYL
RUBBER
322
7.5.1.
SYNTHESIS
OF
HIGH-MOLECULAR
BUTYL
RUBBER
IN
HYDROCARBON
SOLUTION
322
7.5.2.
SYNTHESIS
OF
LOW-MOLECULAR
BUTYL
RUBBER
IN
TURBULENT
PIPES
326
7.6.
STANDARD
PRODUCTION
TECHNOLOGIES
OF
MODIFIED
BUTYL
RUBBERS
327
7.6.1.
MAIN
PREMISES
327
7.6.2.
PRODUCTION
OF
HALOGENATED
BUTYL
RUBBERS
330
7.6.2.1.
CHLOROBUTYL
RUBBER
330
7.6.2.2.
BROMOBUTYL
RUBBER
332
7.7.
NEW
TECHNOLOGY
OF
CHLOROBUTYL
RUBBER
PRODUCTION
IN
SMALL-SCALE
TURBULENT
PIPE
REACTORS
333
7.8.
ECOLOGICAL
ASPECTS
OF
TECHNOLOGY
OF
PRODUCTION
OF
ISOBUTYLENE
POLYMERS
333
REFERENCES
TO
CHAPTER
7
340
CHAPTER
8.
COMPOSITES
AND
FIELD
OF
APPLICATION
SPHERES
OF
POLYISOBUTYLENES
8.1.
MAIN
AREAS
OF
APPLICATION
OF
OLIGO
AND
POLYISOBUTYLENES
343
8.2.
SPECIFIC
AND
NEW
FIELDS
OF
APPLICATION
OF
POLYISOBUTYLENES
AND
COMPOSITES
DERIVED
FROM
THEM
354
REFERENCES
TO
CHAPTER
8
361
SUBJECT
INDEX
364 |
any_adam_object | 1 |
author | Sangalov, Jurij A. Minsker, Karl S. Zajkov, Gennadij E. 1935- |
author_GND | (DE-588)109480775 |
author_facet | Sangalov, Jurij A. Minsker, Karl S. Zajkov, Gennadij E. 1935- |
author_role | aut aut aut |
author_sort | Sangalov, Jurij A. |
author_variant | j a s ja jas k s m ks ksm g e z ge gez |
building | Verbundindex |
bvnumber | BV013748073 |
callnumber-first | T - Technology |
callnumber-label | TP1180 |
callnumber-raw | TP1180.P56 |
callnumber-search | TP1180.P56 |
callnumber-sort | TP 41180 P56 |
callnumber-subject | TP - Chemical Technology |
classification_rvk | UV 2100 |
ctrlnum | (OCoLC)47869284 (DE-599)BVBBV013748073 |
dewey-full | 668.4/23 |
dewey-hundreds | 600 - Technology (Applied sciences) |
dewey-ones | 668 - Technology of other organic products |
dewey-raw | 668.4/23 |
dewey-search | 668.4/23 |
dewey-sort | 3668.4 223 |
dewey-tens | 660 - Chemical engineering |
discipline | Chemie / Pharmazie Physik |
edition | 1. publ. |
format | Book |
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id | DE-604.BV013748073 |
illustrated | Illustrated |
indexdate | 2024-08-13T00:15:01Z |
institution | BVB |
isbn | 9067643351 |
language | English |
oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-009398064 |
oclc_num | 47869284 |
open_access_boolean | |
owner | DE-703 |
owner_facet | DE-703 |
physical | IX, 372 S. graph. Darst. : 25 cm |
publishDate | 2001 |
publishDateSearch | 2001 |
publishDateSort | 2001 |
publisher | VSP |
record_format | marc |
series2 | New concepts in polymer science |
spelling | Sangalov, Jurij A. Verfasser aut Polymers derived from isobutylene synthesis, properties, application Yu. A. Sangalov, K. S. Minsker and G. E. Zaikov 1. publ. Utrecht ; Boston ; Köln ; Tokyo VSP 2001 IX, 372 S. graph. Darst. : 25 cm txt rdacontent n rdamedia nc rdacarrier New concepts in polymer science Literaturangaben Butène ram Polybutènes ram Polybutenes Polyisobutene (DE-588)4175214-4 gnd rswk-swf Isobuten (DE-588)4162474-9 gnd rswk-swf Polymerisation (DE-588)4046704-1 gnd rswk-swf Isobuten (DE-588)4162474-9 s Polymerisation (DE-588)4046704-1 s DE-604 Polyisobutene (DE-588)4175214-4 s Minsker, Karl S. Verfasser aut Zajkov, Gennadij E. 1935- Verfasser (DE-588)109480775 aut DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009398064&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
spellingShingle | Sangalov, Jurij A. Minsker, Karl S. Zajkov, Gennadij E. 1935- Polymers derived from isobutylene synthesis, properties, application Butène ram Polybutènes ram Polybutenes Polyisobutene (DE-588)4175214-4 gnd Isobuten (DE-588)4162474-9 gnd Polymerisation (DE-588)4046704-1 gnd |
subject_GND | (DE-588)4175214-4 (DE-588)4162474-9 (DE-588)4046704-1 |
title | Polymers derived from isobutylene synthesis, properties, application |
title_auth | Polymers derived from isobutylene synthesis, properties, application |
title_exact_search | Polymers derived from isobutylene synthesis, properties, application |
title_full | Polymers derived from isobutylene synthesis, properties, application Yu. A. Sangalov, K. S. Minsker and G. E. Zaikov |
title_fullStr | Polymers derived from isobutylene synthesis, properties, application Yu. A. Sangalov, K. S. Minsker and G. E. Zaikov |
title_full_unstemmed | Polymers derived from isobutylene synthesis, properties, application Yu. A. Sangalov, K. S. Minsker and G. E. Zaikov |
title_short | Polymers derived from isobutylene |
title_sort | polymers derived from isobutylene synthesis properties application |
title_sub | synthesis, properties, application |
topic | Butène ram Polybutènes ram Polybutenes Polyisobutene (DE-588)4175214-4 gnd Isobuten (DE-588)4162474-9 gnd Polymerisation (DE-588)4046704-1 gnd |
topic_facet | Butène Polybutènes Polybutenes Polyisobutene Isobuten Polymerisation |
url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009398064&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
work_keys_str_mv | AT sangalovjurija polymersderivedfromisobutylenesynthesispropertiesapplication AT minskerkarls polymersderivedfromisobutylenesynthesispropertiesapplication AT zajkovgennadije polymersderivedfromisobutylenesynthesispropertiesapplication |