Organic electronic materials: conjugated polymers and low molecular weight organic solids
Gespeichert in:
| Format: | Buch |
|---|---|
| Sprache: | English |
| Veröffentlicht: |
Berlin [u.a.]
Springer
2001
|
| Schriftenreihe: | Springer series in materials science
41 |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | Literaturangaben |
| Beschreibung: | XVIII, 448 S. Ill., graph. Darst. |
| ISBN: | 3540667210 9783540667216 |
Internformat
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| 245 | 1 | 0 | |a Organic electronic materials |b conjugated polymers and low molecular weight organic solids |c R. Farchioni ... (eds.) |
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| 300 | |a XVIII, 448 S. |b Ill., graph. Darst. | ||
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Datensatz im Suchindex
| _version_ | 1804128369865916416 |
|---|---|
| adam_text | R. FARCHIONI G. GROSSO (EDS.) ORGANIC ELECTRONIC MATERIALS CONJUGATED
POLYMERS AND LOW MOLECULAR WEIGHT ORGANIC SOLIDS WITH 200 FIGURES
SPRINGER CONTENTS PART I CONJUGATED POLYMERS 1 INTRODUCTION TO
ELECTRONIC POLYMERS: INFLUENCE OF NANOSTRUCTURE ON ELECTRONIC PHENOMENA
A.J. EPSTEIN 3 1.1 INTRODUCTION 3 1.2 INHOMOGENEOUS STRUCTURE OF
ELECTRONIC POLYMERS 7 1.2.1 PRISTINE AND IODINE-DOPED TRANS-(CH) X 7
1.2.2 POLYANILINE 9 1.2.3 PF^-DOPED POLYPYRROLE 12 1.3 SEMICONDUCTING
POLYMERS 13 1.3.1 FLUORESCENCE PROPERTIES OF SOLUTIONS 16 1.3.2
FLUORESCENCE OF SOLID SAMPLES: AGGREGATE FORMATION 18 1.3.3
TIME-RESOLVED LUMINESCENCE 23 1.3.4 MORPHOLOGY 26 1.4 CONDUCTING
POLYMERS 27 1.4.1 MODELS FOR ELECTRICAL CONDUCTIVITY 27 1.4.2 ELECTRICAL
CONDUCTIVITY OF CONDUCTING POLYMERS 30 1.4.3 SUMMARY 32 REFERENCES 33 2
THEORETICAL STUDIES OF ELECTRONIC PROPERTIES OF CONJUGATED POLYMERS M.
SPRINGBORG, *. SCHMIDT, H. MEIDER AND L. DE MARIA 39 2.1 INTRODUCTION 39
2.2 METHODS OF CALCULATION 44 2.2.1 HARTREE-FOCK- OR
DENSITY-FUNCTIONAL-BASED METHODS 44 2.2.2 INFINITE OR FINITE SYSTEMS 48
2.2.3 CRYSTALS OR CHAINS 49 2.3 PERIODIC SYSTEMS 50 2.3.1 TRANS- AND
CIS-POLYACETYLENE: STRUCTURE AND BAND STRUCTURES 50 2.3.2 CONJUGATED
POLYMERS BASED ON C, H, O, N, AND S ATOMS. . 54 2.3.3 INCORPORATING
METAL ATOMS 63 X CONTENTS 2.3.4 POLYSILANES 64 2.3.5 MX-CHAIN COMPOUNDS
66 2.4 BREAKING THE SYMMETRY 67 2.4.1 SOLITONS AND POLARONS 68 2.4.2
MODEL PARAMETERS 74 2.4.3 CHARGED CHAINS 76 2.4.4 SUBSTITUTIONS:
PERIODIC AND ISOLATED 77 2.4.5 DE FIELDS: POLARIZABILITIES AND
HYPERPOLARIZABILITIES 78 2.4.6 AC FIELDS: NON-LINEAR OPTICS 83 2.5
CONCLUSIONS 85 REFERENCES 86 3 RECURSIVE ALGORITHMS FOR POLYMERIC CHAINS
R. FARCHIONI, G. GROSSO AND P. VIGNOLO 89 3.1 INTRODUCTION 89 3.2 THE
TIGHT-BINDING METHOD 90 3.3 DECIMATION TECHNIQUE AND RENORMALIZATION
METHOD 91 3.3.1 ILLUSTRATIVE EXAMPLES OF THE RENORMALIZATION METHOD 92
3.4 THE RECURSION METHOD AND THE CONTINUED FRACTION REPRESENTATION OF
THE GREEN S FUNCTION 96 3.4.1 ILLUSTRATIVE EXAMPLES OF THE RECURSION
METHOD 98 3.5 GREEN S FUNCTION AND DENSITY OF STATES 102 3.5.1
ILLUSTRATIVE EXAMPLE: GREEN S FUNCTION FOR THE INFINITE, CONSTANT LINEAR
CHAIN 104 3.6 EFFECTIVE TIGHT-BINDING HAMILTONIANS AND ELECTRONIC STATES
FOR CONJUGATED POLYMERS 106 3.7 TRANSMITTIVITY OF POLYMERIC CHAINS ILL
3.7.1 SCATTERING BY A SINGLE IMPURITY EMBEDDED IN A PERFECT CHAIN ILL
3.7.2 SCATTERING BY A DIMER IMPURITY EMBEDDED IN A PERFECT CHAIN 113
3.7.3 TRANSMISSION THROUGH TWO INTERACTING CHAINS 114 3.8 EFFECTS OF
DISORDER ON THE ELECTRONIC STATES 120 3.9 CONCLUSIONS 124 REFERENCES 124
4 PHOTOPHYSICS OF CONDUCTING POLYMERS E.M. CONWELL 127 4.1 INTRODUCTION
127 4.2 EXCITATIONS CREATED BY LIGHT 128 4.2.1 POLARONS 128 4.2.2
SINGLET EXCITONS 131 4.2.3 BIEXCITONS 134 CONTENTS XI 4.2.4 TRIPLET
EXCITONS 134 4.2.5 BIPOLARONS 134 4.2.6 EXCIMERS 135 4.2.7 AGGREGATES
135 4.2.8 POLARON PAIRS 136 4.2.9 SOLITONS 136 4.3 OPTICAL
ABSORPTION-THEORY AND EXPERIMENT 137 4.3.1 EXPERIMENTAL DATA 137 4.3.2
THEORY OF OPTICAL ABSORPTION IN PPV 138 4.4 PROPERTIES OF THE LOWEST
LYING SINGLET EXCITON 142 4.4.1 VIBRONIC STRUCTURE 142 4.4.2
LOCALIZATION ENERGY 143 4.4.3 DECAY DUE TO PHOTOOXIDATION 143 4.4.4
DISSOCIATION IN HIGH ELECTRIC FIELDS 143 4.5 EXCITATIONS INVOLVING
INTERCHAIN INTERACTIONS 144 4.5.1 PHOTOINDUCED ABSORPTION IN PPV AND ITS
DERIVATIVES 144 4.5.2 DEBATE ABOUT POLARON PAIRS 145 4.5.3 DISCOVERY OF
EXCIMERS IN PPV DERIVATIVES 146 4.5.4 STRUCTURES OF MEH-PPV AND CN-PPV
147 4.5.5 EFFECT OF HIGH-INTENSITY IRRADIATION 148 4.5.6 EXCIMERS IN
MEH-PPV 148 4.5.7 THE CASE OF PPV 149 4.5.8 POLARON PAIRS IN OTHER
POLYMERS 150 4.5.9 SOME PROPERTIES OF EXCIMERS 153 4.5.10 AGGREGATES 154
4.5.11 FACTORS AFFECTING THE FORMATION OF POLARON PAIRS, EXCIMERS AND
AGGREGATES 155 4.6 SINGLE CHAIN EXCITATIONS OTHER THAN SINGLET EXCITONS
157 4.6.1 BIPOLARONS 157 4.6.2 TRIPLET EXCITONS 158 4.6.3 BIEXCITONS 160
4.7 PHOTOCONDUCTIVITY 160 4.7.1 PHOTOGENERATION IN PPV AND ITS
DERIVATIVES 161 4.7.2 TRANSIENT VERSUS STEADY-STATE PHOTOCONDUCTIVITY IN
PPV AND ITS DERIVATIVES 164 4.7.3 PHOTOGENERATION AND PHOTOCONDUCTIVITY
IN L-PPP 165 4.7.4 PHOTOGENERATION OF SOLITONS AND POLARONS AND
PHOTOCONDUCTION IN TRANS-POLYACETYLENE 167 4.7.5 PHOTOCONDUCTIVITY IN
TRANS-POLYACETYLENE 168 4.8 LASER ACTION 170 REFERENCES 174 XII CONTENTS
5 PHOTOELECTRON SPECTROSCOPY STUDIES ON THE ELECTRONIC AND CHEMICAL
STRUCTURES OF CONJUGATED POLYMERS M. FAHLMAN AND W.R. SALANECK 181 5.1
INTRODUCTION 181 5.2 CONJUGATED POLYMERS 182 5.3 PHOTOELECTRON
SPECTROSCOPY 184 5.3.1 X-RAY PHOTOELECTRON SPECTROSCOPY 186 5.3.2
ULTRAVIOLET PHOTOELECTRON SPECTROSCOPY 187 5.3.3 SYNCHROTRON RADIATION
187 5.4 PRISTINE POLYMERS 188 5.4.1 POLY(P-PHENYLENE VINYLENE)S (PPVS)
188 5.4.2 POLYANILINES 193 5.5 METAL/POLYMER INTERFACES 196 5.5.1 METALS
ON POLY(P-PHENYLENE VINYLENE)S 197 5.5.2 METALS ON POLYANILINES 201 5.6
POLYMER/METAL INTERFACES 204 5.6.1 POLY(P-PHENYLENE VINYLENE) ON ITO 204
5.6.2 POLYANILINE ON ITO 206 5.7 SUMMARY 208 REFERENCES 209 PART II LOW
MOLECULAR WEIGHT ORGANIC SOLIDS 6 INTRODUCTION N. KARL 215 6.1 GENERAL
REMARKS 215 6.2 ORGANIC CRYSTALS AND MATERIALS-SCIENCE ASPECTS 219 6.2.1
PURIFICATION 219 6.2.2 GROWTH OF SINGLE CRYSTALS 222 6.2.3 HANDLING,
CUTTING, PHASE ASSIGNMENT, AND ORIENTING OF SINGLE CRYSTALS 225 6.2.4
ASSESSMENT OF SAMPLE QUALITY: DEFECTS AND THEIR CHARACTERIZATION 227 6.3
EXCITED STATES OF ORGANIC CRYSTALS 228 6.4 DYNAMICAL AND TRANSPORT
PROPERTIES OF EXCITED STATES IN CRYSTALS 232 6.5 ORGANIC NON-POLYMERIC
THIN FILMS 235 6.5.1 CURRENT DEVELOPMENTS 235 6.5.2 POSSIBLE FUTURE
TRENDS 236 REFERENCES 236 CONTENTS XIII 7 ELECTRONIC STATES IN ORGANIC
MOLECULAR CRYSTALS V. CAEPEK AND I. MUZIKANTE 241 7.1 INTRODUCTION 241
7.2 MODEL 242 7.3 EIGEN- OR QUASIPARTICLE STATES 249 7.4 EXCITONS 250
7.5 ELECTRON AND HOLE STATES IN OMC 253 7.6 CHARGE-TRANSFER STATES 256
7.7 INFLUENCE OF PHONONS 257 7.8 ESTABLISHING THE ELECTRONIC STATES IN
OMC 264 7.9 PROSPECTS FOR THEORETICAL WORK 265 7.10
CHARGE-CARRIER-TRAPPING STATES IN OMC 266 7.11 EXPERIMENTAL METHODS FOR
TRAPPING STATES IN OMC 273 REFERENCES 280 8 CHARGE-CARRIER MOBILITY IN
ORGANIC CRYSTALS N. KARL 283 8.1 INTRODUCTION 283 8.2 THE CONCEPT OF
CHARGE-CARRIER MOBILITY 285 8.2.1 BASIC CONCEPT 285 8.2.2 TEMPERATURE
DEPENDENCE 287 8.2.3 OHMIC AND HIGH-FIELD NON-LINEAR TRANSPORT 288 8.2.4
THE MOBILITY TENSOR 291 8.3 MEASUREMENT TECHNIQUES 292 8.3.1 THE
TIME-OF-FLIGHT (TOF) METHOD 292 8.3.2 THE ACOUSTO-ELECTRIC TRAVELLING
WAVE (SAW) METHOD 301 8.3.3 THE FIELD EFFECT TRANSISTOR (FET/TFT) METHOD
305 8.3.4 OTHER DIRECT AND INDIRECT METHODS TO DETERMINE MOBILITIES 306
8.4 EXPERIMENTAL RESULTS 310 8.4.1 MAGNITUDE, ANISOTROPY, AND
TEMPERATURE DEPENDENCE OF MOBILITIES 310 8.4.2 MOBILITIES ACROSS PHASE
TRANSITIONS 314 8.4.3 THE ROLE OF PHYSICAL AND CHEMICAL DEFECTS 315
8.4.4 NON-LINEAR TRANSPORT 316 8.4.5 MOBILITIES IN ORGANIC THIN FILMS
317 8.5 CONCLUDING REMARKS 321 REFERENCES 322 9 DIELECTRIC AND
CHARGE-TRANSFER APPROACHES TO EXCITONS R.W. MUNN AND P. PETELENZ 327 9.1
INTRODUCTION 327 9.2 DIELECTRIC THEORY OF EXCITONS 328 9.3 NON-LINEAR
OPTICS 332 XIV CONTENTS 9.4 NON-LOCAL RESPONSE: CHARGE-TRANSFER EXCITONS
334 9.5 HAMILTONIAN DESCRIPTION OF EXCITONS 336 9.6 MIXING OF FRENKEL
AND CHARGE-TRANSFER STATES 340 9.7 ELECTRO-ABSORPTION 342 9.8
PHOTOCONDUCTIVITY 345 9.9 CONCLUDING REMARKS 349 REFERENCES 349 10
EXCITONS IN ORGANIC-BASED MULTILAYERS V.M. AGRANOVICH, G.C. LA ROCCA AND
F. BASSANI 353 10.1 INTRODUCTION 353 10.2 EXCITONS IN ORGANIC-INORGANIC
HETEROSTRUCTURES 354 10.2.1 STRONG COUPLING: HYBRID EXCITONS 355 10.2.2
WEAK COUPLING: FOERSTER ENERGY TRANSFER 369 10.3 EXCITONS AT
DONOR-ACCEPTOR INTERFACES 382 10.3.1 COLD PHOTOCONDUCTIVITY 382 10.3.2
ALL-OPTICAL NONLINEARITIES 383 10.3.3 PHOTOVOLTAIC MECHANISM 385 10.4
CONCLUSIONS 387 REFERENCES 388 11 EXCITONS AND ENERGY TRANSFER IN DOPED
LUMINESCENT MOLECULAR ORGANIC MATERIALS V. BULOVIC, M.A. BALDO AND S.R.
FORREST 391 11.1 OVERVIEW 391 11.2 BACKGROUND 393 11.2.1 EXCITED STATES
OF A MOLECULE 393 11.2.2 ELECTRONIC TRANSITIONS BETWEEN ENERGY STATES OF
A SINGLE MOLECULE 394 11.2.3 EXCITONS 398 11.2.4 ELECTRONIC ENERGY
TRANSFER 401 11.2.5 EXCITON TRANSPORT 403 11.3 ORGANIC LIGHT-EMITTING
DEVICES 405 11.3.1 OPERATING PRINCIPLES 405 11.3.2 DOPED OLEDS 406 11.4
EXAMPLES OF FOERSTER ENERGY TRANSFER 407 11.4.1 WHITE OLEDS BASED ON
INTERLAYER SEQUENTIAL ENERGY TRANSFER 407 11.4.2 SOLID-STATE SOLVATION
EFFECT 411 11.5 EXAMPLES OF DEXTER ENERGY TRANSFER 422 11.5.1 PTOEP
PHOSPHORESCENCE 422 11.5.2 TRIPLET DIFFUSION 424 11.5.3 1*(***)*
PHOSPHORESCENCE 426 11.5.4 TRIPLET-TRIPLET ANNIHILATION 428 CONTENTS XV
11.6 COMBINED FOERSTER AND DEXTER ENERGY TRANSFER 432 11.6.1
SINGLET-TO-TRIPLET EXCITON RATIO IN ELECTRICALLY EXCITED THIN FILMS 432
11.6.2 PHOSPHOR-SENSITIZED FLUORESCENCE 435 11.7 CONCLUDING REMARKS 439
REFERENCES 439 INDEX 443
|
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| id | DE-604.BV013568341 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T18:48:09Z |
| institution | BVB |
| isbn | 3540667210 9783540667216 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-009267337 |
| oclc_num | 248078087 |
| open_access_boolean | |
| owner | DE-703 DE-29T DE-355 DE-BY-UBR DE-M347 DE-1102 DE-20 DE-634 DE-83 DE-11 DE-19 DE-BY-UBM |
| owner_facet | DE-703 DE-29T DE-355 DE-BY-UBR DE-M347 DE-1102 DE-20 DE-634 DE-83 DE-11 DE-19 DE-BY-UBM |
| physical | XVIII, 448 S. Ill., graph. Darst. |
| publishDate | 2001 |
| publishDateSearch | 2001 |
| publishDateSort | 2001 |
| publisher | Springer |
| record_format | marc |
| series | Springer series in materials science |
| series2 | Springer series in materials science Physics and astronomy online library |
| spelling | Organic electronic materials conjugated polymers and low molecular weight organic solids R. Farchioni ... (eds.) Berlin [u.a.] Springer 2001 XVIII, 448 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Springer series in materials science 41 Physics and astronomy online library Literaturangaben Konjugierte Polymere - Elektronische Eigenschaft Organischer Festkörper - Oligomere - Elektronische Eigenschaft Conducting polymers Organic conductors Konjugierte Polymere (DE-588)4236284-2 gnd rswk-swf Organischer Festkörper (DE-588)4172779-4 gnd rswk-swf Elektronische Eigenschaft (DE-588)4235053-0 gnd rswk-swf Oligomere (DE-588)4212195-4 gnd rswk-swf Konjugierte Polymere (DE-588)4236284-2 s Elektronische Eigenschaft (DE-588)4235053-0 s DE-604 Organischer Festkörper (DE-588)4172779-4 s Oligomere (DE-588)4212195-4 s Farchioni, Riccardo 1964- Sonstige (DE-588)122763785 oth Springer series in materials science 41 (DE-604)BV000683335 41 GBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009267337&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Organic electronic materials conjugated polymers and low molecular weight organic solids Springer series in materials science Konjugierte Polymere - Elektronische Eigenschaft Organischer Festkörper - Oligomere - Elektronische Eigenschaft Conducting polymers Organic conductors Konjugierte Polymere (DE-588)4236284-2 gnd Organischer Festkörper (DE-588)4172779-4 gnd Elektronische Eigenschaft (DE-588)4235053-0 gnd Oligomere (DE-588)4212195-4 gnd |
| subject_GND | (DE-588)4236284-2 (DE-588)4172779-4 (DE-588)4235053-0 (DE-588)4212195-4 |
| title | Organic electronic materials conjugated polymers and low molecular weight organic solids |
| title_auth | Organic electronic materials conjugated polymers and low molecular weight organic solids |
| title_exact_search | Organic electronic materials conjugated polymers and low molecular weight organic solids |
| title_full | Organic electronic materials conjugated polymers and low molecular weight organic solids R. Farchioni ... (eds.) |
| title_fullStr | Organic electronic materials conjugated polymers and low molecular weight organic solids R. Farchioni ... (eds.) |
| title_full_unstemmed | Organic electronic materials conjugated polymers and low molecular weight organic solids R. Farchioni ... (eds.) |
| title_short | Organic electronic materials |
| title_sort | organic electronic materials conjugated polymers and low molecular weight organic solids |
| title_sub | conjugated polymers and low molecular weight organic solids |
| topic | Konjugierte Polymere - Elektronische Eigenschaft Organischer Festkörper - Oligomere - Elektronische Eigenschaft Conducting polymers Organic conductors Konjugierte Polymere (DE-588)4236284-2 gnd Organischer Festkörper (DE-588)4172779-4 gnd Elektronische Eigenschaft (DE-588)4235053-0 gnd Oligomere (DE-588)4212195-4 gnd |
| topic_facet | Konjugierte Polymere - Elektronische Eigenschaft Organischer Festkörper - Oligomere - Elektronische Eigenschaft Conducting polymers Organic conductors Konjugierte Polymere Organischer Festkörper Elektronische Eigenschaft Oligomere |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009267337&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| volume_link | (DE-604)BV000683335 |
| work_keys_str_mv | AT farchioniriccardo organicelectronicmaterialsconjugatedpolymersandlowmolecularweightorganicsolids |