Reactive cluster impact dynamics and ion processes investigated by cluster impact mass spectrometry:
Gespeichert in:
| 1. Verfasser: | |
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| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
2000
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| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | München, Techn. Univ., Diss., 2000 |
| Beschreibung: | VI, 161 S. Ill., graph. Darst. |
Internformat
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Datensatz im Suchindex
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CONTENTS
1 MOLECULAR CLUSTERS AS 'TEST TRIBES' - AN INTRODUCTION 1
2 CREATION OF MOLECULAR CLUSTERS 10
2.1 CLUSTER CREATION BY ADIABATIC EXPANSION. 10
2.1.1 ADIABATIC EXPANSIONS. 10
2.1.2 ADJUSTING THE KINETIC ENERGY: SEEDED BEAM TECHNIQUE . . . 15
2.1.3 CONDENSATION IN MOLECULAR BEAMS.7\ . . . . 17
2.1.4 GAS MIXTURES. 21
2.1.5 PULSED ADIABATIC EXPANSION. 26
2.2 EXPERIMENTAL SETUP. 28
2.3 CALIBRATION OF THE PARTICLE NUMBER PER PULSE. 34
3 MOLECULAR CLUSTER IONS 39
3.1 ELECTRON IMPACT IONIZATION. 44
3.2 GAS PULSE CHARACTERIZATION. 47
3.3 CLUSTER SIZE MEASUREMENT: RETARDING FIELD METHOD. 48
4 TIME-OF-FLIGHT MASS SPECTROMETRY OF MOLECULAR CLUSTER IONS 55
4.1 TIME-OF-FLIGHT MASS SPECTROMETRY. 55
4.2 LARGE, PULSED EXTRACTION VOLUMES. 60
4.3 EXPERIMENTAL SETUP. 64
5 CHARGE SEPARATION IN POLAR MOLECULE CLUSTERS -
THE CLUSTERELECTRIC EFFECT 70
5.1 OVERVIEW. 70
5.2 DIPOLE MOMENT - THE ORIGIN OF CHARGE SEPARATION. 74
5.3 MASS ANALYSIS OF THE FRAGMENT IONS. 78
5.4 MICROSCOPIC MODEL.'. 85
5.4.1 ALKALI SURFACE ADSORBATES. 88
5.4.2 THE PICKUP PROCESS. 92
5.4.3 CHARGE DELOCALIZATION. 98
5.4.4 CLUSTER FRAGMENTATION AND INERTIAL CHARGE SEPARATION . 101
V
BIBLIOGRAFISCHE INFORMATIONEN
HTTP://D-NB.INFO/960539107
CONTENTS
6 FAST ELECTRON TRANSFER MECHANISM 107
6.1 ELECTRON DELOCALIZATION IN BULK POLAR SOLVENTS . 107
6.2 SOLVATED METAL ATOMS - OBSERVATIONS IN CLUSTERS. 108
6.3 FAST ELECTRON TRANSFER FIELD-IONIZATION BY POINT-CHARGES. ILL
7 THE CLUSTERELECTRIC EFFECT IN DISGUISE 118
7.1 THE SF4 SYSTEM: ION-MOLECULE REACTIONS. 118
7.2 THE NH3 SYSTEM: MISSING ELECTRON AFFINITY. 119
7.3 THE H2O SYSTEM: AUTOPROTOLYSIS. 124
8 APPLICATIONS 127
8.1 APPLICATIONS OF THE CLUSTERELECTRIC EFFECT. 127
8.2 IMPLICATIONS OF CLUSTER IMPACT MASS SPECTROMETRY . 132
9 SUMMARY AND OUTLOOK 135
A REPRINT OF NATURE 400 544-547 (1999) 138
\
REFERENCES 143
VI |
| any_adam_object | 1 |
| author | Gebhardt, Christoph R. 1969- |
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| author_facet | Gebhardt, Christoph R. 1969- |
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| classification_tum | CHE 165d PHY 546d PHY 115d PHY 536d |
| ctrlnum | (OCoLC)645490231 (DE-599)BVBBV013478870 |
| discipline | Physik Chemie |
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| id | DE-604.BV013478870 |
| illustrated | Illustrated |
| indexdate | 2024-10-09T18:10:11Z |
| institution | BVB |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-009199091 |
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| physical | VI, 161 S. Ill., graph. Darst. |
| publishDate | 2000 |
| publishDateSearch | 2000 |
| publishDateSort | 2000 |
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| spelling | Gebhardt, Christoph R. 1969- Verfasser (DE-588)122620402 aut Reactive cluster impact dynamics and ion processes investigated by cluster impact mass spectrometry Christoph R. Gebhardt 2000 VI, 161 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier München, Techn. Univ., Diss., 2000 Massenspektrometrie (DE-588)4037882-2 gnd rswk-swf Clusterion (DE-588)4148106-9 gnd rswk-swf Molekülcluster (DE-588)4198994-6 gnd rswk-swf Polares Molekül (DE-588)4174979-0 gnd rswk-swf Chemische Reaktion (DE-588)4009853-9 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Polares Molekül (DE-588)4174979-0 s Molekülcluster (DE-588)4198994-6 s Clusterion (DE-588)4148106-9 s Chemische Reaktion (DE-588)4009853-9 s Massenspektrometrie (DE-588)4037882-2 s DE-604 DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009199091&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Gebhardt, Christoph R. 1969- Reactive cluster impact dynamics and ion processes investigated by cluster impact mass spectrometry Massenspektrometrie (DE-588)4037882-2 gnd Clusterion (DE-588)4148106-9 gnd Molekülcluster (DE-588)4198994-6 gnd Polares Molekül (DE-588)4174979-0 gnd Chemische Reaktion (DE-588)4009853-9 gnd |
| subject_GND | (DE-588)4037882-2 (DE-588)4148106-9 (DE-588)4198994-6 (DE-588)4174979-0 (DE-588)4009853-9 (DE-588)4113937-9 |
| title | Reactive cluster impact dynamics and ion processes investigated by cluster impact mass spectrometry |
| title_auth | Reactive cluster impact dynamics and ion processes investigated by cluster impact mass spectrometry |
| title_exact_search | Reactive cluster impact dynamics and ion processes investigated by cluster impact mass spectrometry |
| title_full | Reactive cluster impact dynamics and ion processes investigated by cluster impact mass spectrometry Christoph R. Gebhardt |
| title_fullStr | Reactive cluster impact dynamics and ion processes investigated by cluster impact mass spectrometry Christoph R. Gebhardt |
| title_full_unstemmed | Reactive cluster impact dynamics and ion processes investigated by cluster impact mass spectrometry Christoph R. Gebhardt |
| title_short | Reactive cluster impact dynamics and ion processes investigated by cluster impact mass spectrometry |
| title_sort | reactive cluster impact dynamics and ion processes investigated by cluster impact mass spectrometry |
| topic | Massenspektrometrie (DE-588)4037882-2 gnd Clusterion (DE-588)4148106-9 gnd Molekülcluster (DE-588)4198994-6 gnd Polares Molekül (DE-588)4174979-0 gnd Chemische Reaktion (DE-588)4009853-9 gnd |
| topic_facet | Massenspektrometrie Clusterion Molekülcluster Polares Molekül Chemische Reaktion Hochschulschrift |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009199091&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT gebhardtchristophr reactiveclusterimpactdynamicsandionprocessesinvestigatedbyclusterimpactmassspectrometry |