Electron transfer in chemistry: 5 Molecules-level electronics ; imaging and information ; energy and the environment
Gespeichert in:
| Format: | Buch |
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| Sprache: | English |
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Weinheim [u.a.]
Wiley-VCH
2001
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| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XLVII, 800 S. Ill., graph. Darst. |
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| 245 | 1 | 0 | |a Electron transfer in chemistry |n 5 |p Molecules-level electronics ; imaging and information ; energy and the environment |c Vincenzo Balzani (ed.) |
| 264 | 1 | |a Weinheim [u.a.] |b Wiley-VCH |c 2001 | |
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| 650 | 4 | |a Oxidation-reduction reaction | |
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Datensatz im Suchindex
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| adam_text | VINCENZO BALZANI (ED.) ELECTRON TRANSFER IN CHEMISTRY ^ MOLECULES-LEVEL
ELECTRONICS IMAGING AND INFORMATION ENERGY AND THE ENVIRONMENT
WILEY-VCH WEINHEIM * NEW YORK * CHICHESTER BRISBANE * SINGAPORE *
TORONTO CONTENTS XLI VOLUME V PART 1 MOLECULAR-LEVEL ELECTRONICS 1 A.
PRASANNA DE SILVA (ED.) 1 WIRES BASED ON METAL COMPLEXES 3 JEAN-PIERRE
LAUNAY AND CHRISTOPHE COUDRET 1.1 INTRODUCTION 3 1.2 BIMETALLIC METAL
COMPLEXES AS MODELS OF MOLECULAR WIRES 4 1.3 SYNTHETIC STRATEGIES 6
1.3.1 REDOX CENTERS 7 1.3.2 CONJUGATED BRIDGES 12 1.4 THEORY 20 1.4.1
OUTLINE OF THE THEORETICAL TREATMENT OF MIXED-VALENCE COMPOUNDS 20 1.4.2
PROCESSES RELATED TO THE V^ COUPLING 22 1.5 REVIEW OF THE DIFFERENT
STUDIES 26 1.5.1 INTERVALENCE ELECTRON TRANSFER 26 1.5.2 ELECTRON
TRANSFER THROUGH A MONOLAYER AT AN ELECTRODE 33 1.5.3 EXCITED-STATE
ELECTRON TRANSFER 34 1.5.4 DEXTER-TYPE ENERGY TRANSFER 35 1.5.5 OTHER
EFFECTS 36 1.6 CONCLUSIONS 38 1.6.1 THE DECAY LAW 38 1.6.2
CYCLOMETALLATED COMPOUNDS 42 1.6.3 PUZZLING COMPOUNDS 43 1.6.4
MIXED-VALENCE COMPLEXES AND METAL/MOLECULE/METAL NANOJUNCTIONS 43
REFERENCES 44 2 APPROACHES TO AN OPTICALLY CONTROLLED MOLECULAR SWITCH
48 AARON S. LUKAS AND MICHAEL R. WASIELEWSKI 2. 1 INTRODUCTION 48 2.2
SYSTEMS CONSISTING OF SINGLE MOLECULES 50 2.2.1 TWO-LEVEL SYSTEMS 50 2.3
PHOTOCHROMIC SYSTEMS 51 2.3.1 PHOTOISOMERIZATIONS 52 2.3.2 OPEN-CLOSED
RING SYSTEMS 55 2.3.3 PHOTOREARRANGEMENTS 59 2.4 ELECTRON TRANSFER BASED
SYSTEMS 59 2.4.1 INTERMOLECULAR ELECTRON TRANSFER 60 2.4.2
INTRAMOLECULAR ELECTRON TRANSFER 61 2.5 ENERGY TRANSFER BASED SYSTEMS 73
2.6 CONCLUSIONS AND FUTURE PROSPECTS 88 ACKNOWLEDGMENT 89 REFERENCES 89
CONTENTS 3 PHOTONIC WIRES CONTAINING METAL COMPLEXES 97 LUISA DE COLA
AND PETER BELSER 3.1 INTRODUCTION 97 3.2 CHOICE AND ASSEMBLY OF THE
COMPONENTS FOR PHOTOACTIVE SYSTEMS 98 3.3 INTERCOMPONENT PHOTOINDUCED
PROCESSES 100 3.4 WHAT IS A MOLECULAR WIRE? 103 3.5 SYSTEMS CONTAINING
SATURATED SPACERS 104 3.6 SYSTEMS CONTAINING CONJUGATED SPACERS 109
3.6.1 POLYENE-BRIDGED BIMETALLIC COMPOUNDS 109 3.6.2 OLIGOYNE-BRIDGED
BIMETALLIC COMPOUNDS 111 3.6.3 PHENYLENE-BRIDGED BIMETALLIC COMPOUNDS
114 3.6.4 OTHER CONJUGATED SYSTEMS 119 3.7 MODULATION OF THE ELECTRONIC
INTERACTIONS IN DINUCLEAR COMPLEXES 123 3.8 CONCLUSIONS 130
ABBREVIATIONS 132 REFERENCES 132 4 RECTIFIERS 137 ALAN C. BRADY AND J.
ROY SAMBLES 4.1 INTRODUCTION 137 4.2 MOLECULAR CONDUCTION 138 4.3
MOLECULAR RECTIFIER 139 4.4 PRACTICAL INVESTIGATION OF A MOLECULAR
RECTIFIER 145 4.5 THE LANGMUIR-BLODGETT TECHNIQUE 146 4.6 JUNCTION
DESIGN 148 4.7 ELECTRICAL CHARACTERIZATIONS OF LB FILMS 150 4.8 OTHER
TECHNIQUES 154 4.9 CONCLUSIONS 154 REFERENCES 1 54 5 LOGIC GATES 156 A.
PRASANNA DE SILVA, NATHAN D. MCCLENAGHAN, AND COLIN P. MCCOY 5.1
INTRODUCTION 156 5.2 PHOTOCHEMICAL APPROACHES TO MOLECULAR-SCALE LOGIC
157 5.2.1 CHEMICAL/OPTICAL INPUT/OUTPUT 157 5.2.2 ALL-OPTICAL
INPUT/OUTPUT 168 5.3 OTHER APPROACHES TO MOLECULAR-SCALE INFORMATION
PROCESSING 172 5.3.1 MECHANOCHEMICAL APPROACH 172 5.3.2 OLIGONUCLEOTIDE
APPROACH 175 5.3.3 QUANTUM APPROACH 177 5.3.4 ELECTRONIC APPROACH 180 4
CONCLUSION 182 CONTENTS XLIII ACKNOWLEDGEMENTS 182 REFERENCES 182 6
ANTENNAS 186 SEBASTIANO CAMPAGNA, SCOLASTICA SERRONI, FAUSTO PUNTORIERO,
CINZIA DI PIETRO, AND VITTORIO RICEVUTO 6.1 INTRODUCTION 186 6.2 NATURAL
ANTENNAS 188 6.3 ARTIFICIAL ANTENNAS 190 6.3.1 PRINCIPLES OF DESIGN 190
6.3.2 EXAMPLES 193 6.4 CONCLUDING REMARKS 211 REFERENCES 211 7 MEMORIES
215 MASAHIRO IRIE AND KENJI MATSUDA 7.1 INTRODUCTION 215 7.2
IRREVERSIBLE MEMORY MEDIA 216 7.3 REVERSIBLE MEMORY MEDIA 218 7.3.1
DIARYLETHENES 220 7.3.2 FURYL FULGIDE DERIVATIVES 229 7.3.3
PHENOXYNAPHTHACENE QUINONES 235 7.3.4 STILBENE DERIVATIVES 236 7.4
NONDESTRUCTIVE READOUT 237 7.5 NEAR-FIELD MEMORY 239 7.6 CONCLUSIONS 240
REFERENCES 240 8 NONLINEAR OPTICS 243 STEPHAN HOUBRECHTS, ERIC
HENDRICKX, THIERRY VERBTEST, KOEN CLAYS, AND ANDRE PERSOONS 8. 1
INTRODUCTION TO NONLINEAR OPTICS 243 8.1.1 THE BASICS OF NONLINEAR
OPTICS 243 8.1.2 SYMMETRY RESTRICTIONS 245 8.1.3 SYSTEMS OF UNITS 246
8.2 MEASUREMENT TECHNIQUES 247 8.2.1 ELECTRIC-FIELD-INDUCED
SECOND-HARMONIC GENERATION (EFISHG) 247 8.2.2 HYPER-RAYLEIGH SCATTERING
(HRS) 250 8.3 SECOND-ORDER NONLINEAR OPTICAL MOLECULES 252 8.3.1 DIPOLAR
MOLECULAR STRUCTURES 252 8.3.2 RIGID MULTICHROMOPHORIC MOLECULES 255
8.3.3 OCTOPOLAR MOLECULES 264 8.3.4 METALLO-ORGANIC COMPOUNDS 268 8.4
MACROSCOPIC NONLINEARITIES 273 XLIV CONTENTS ACKNOWLEDGMENTS 276
REFERENCES 276 PART 2 IMAGING AND INFORMATION 283 IAN R. GOULD (ED.) 1
ELECTRON TRANSFER PROCESSES IN SILVER HALIDE PHOTOGRAPHY 285 JOHN R.
FYSON, PETER J. TWIST, AND IAN R. GOULD 1.1 INTRODUCTION 285 1.2
DEVELOPERS 286 1.2.1 INTRODUCTION 286 1.2.2 CHEMICAL DEVELOPMENT 287
1.2.3 COUPLING 335 1.3 BLEACHING/BLEACH-FIXING 336 1.3.1
INTRODUCTION*GENERAL MECHANISMS 336 1.3.2 SOLVENT BLEACHES 338 1.3.3
BLEACH-FIXES 344 1.3.4 DIFFUSION 346 1.3.5 SPECIFIC BLEACHING AGENTS 347
1.3.6 DYE-BLEACHES 354 1.3.7 FIXING AND WASHING 355 1.4 SPECTRAL
SENSITIZATION 355 1.4.1 INTRODUCTION 355 1.4.2 ELECTRONIC PROPERTIES OF
SILVER HALIDES 356 1.4.3 SENSITIZING DYES 357 1.4.4 SENSITIZATION
MECHANISMS 363 1.4.5 KINETIC MEASUREMENTS OF ELECTRON INJECTION 370
1.4.6 SUPERSENSITIZATION 372 REFERENCES 373 2 ELECTROPHOTOGRAPHY 379
DAVID S. WEISS, J. ROBIN COWDERY, AND RALPH H. YOUNG 2.1 INTRODUCTION
379 2.2 ELECTROPHOTOGRAPHIC DEVELOPERS 381 2.3 ORGANIC PHOTORECEPTOR
FABRICATION AND CHARACTERIZATION 383 2.4 CORONA CHARGING 388 2.5 CHARGE
CARRIER GENERATION 390 2.5.1 BACKGROUND AND METHODOLOGIES 390 2.5.2
MODELS 393 2.5.3 ORGANIC PHOTORECEPTORS 398 2.5.4 SUMMARY OF CARRIER
GENERATION MECHANISMS 428 2.6 CHARGE TRANSPORT 429 2.6.1 TYPICAL
MATERIALS 429 2.6.2 CHARGE CARRIER MOBILITY 431 2.6.3 CHEMICAL
DESIDERATA FOR CHARGE-TRANSPORTING MOLECULES 460 CONTENTS XLV 2.7
CONCLUDING REMARKS 462 REFERENCES 463 3 PHOTOREFRACTIVE MATERIALS 472
DAVID P. WEST AND MARK D. RAHN 3.1 THE PHOTOREFRACTIVE EFFECT IN
CRYSTALS AND AMORPHOUS ORGANIC MEDIA 472 3.1.1 SCENARIOS OF POTENTIAL
APPLICATIONS 472 3.1.2 AN OVERVIEW OF THE SEQUENCE OF PROCESSES LEADING
TO PHOTOREFRACTIVITY 473 3.1.3 A HISTORICAL PERSPECTIVE 479 3.2 ELECTRON
TRANSFER IN AMORPHOUS ORGANIC PHOTOREFRACTIVE MEDIA 481 3.2.1 OPTICAL
GENERATION OF BOUND PAIRS 482 3.2.2 DISSOCIATION OF BOUND PAIRS INTO
FREE CHARGES 484 3.2.3 CHOICE OF PHOTOSENSITIZER 484 3.2.4 SPECIFIC
MATERIAL SYSTEMS 488 3.2.5 FULLY FUNCTIONAL AND PERMANENTLY POLED
MATERIALS 494 3.3 CHARGE TRANSPORT PROCESSES IN AMORPHOUS ORGANIC MEDIA
494 3.3.1 TRANSPORT IN DISORDERED MEDIA 495 3.3.2 SPECIFIC EXAMPLES OF
HOLE TRANSPORT MATERIALS FOR ORGANIC PHOTOREFRACTIVES 499 3.3.3 PULSED
EXCITATION AND CHARGE TRAPPING 501 3.4 AN OVERVIEW OF AMORPHOUS ORGANIC
PHOTOREFRACTIVES AND THEIR APPLICATIONS 503 3.4.1 THE ELECTRO-OPTIC
RESPONSE 503 3.4.2 HOLOGRAPHIE OPTICAL DATA STORAGE AND OTHER
APPLICATIONS 508 ACKNOWLEDGEMENTS 513 REFERENCES 513 4 PHOTOINDUCED
ELECTRON TRANSFER INITIATING SYSTEMS FOR FREE-RADICAL POLYMERIZATION 516
JERZY PACZKOWSKI AND DOUGLAS C. NECKERS 4.1 INTRODUCTION 516 4.2 GENERAL
SCHEME 517 4.3 DYE PHOTOINITIATORS-MECHANISMS 519 4.3.1 PHOTOINITIATING
DONOR-ACCEPTOR PAIRS WITH ELECTROSTATIC INTERACTION IN THE GROUND STATE
(GROUND-STATE ION PAIR) AND NEUTRAL AFTER PHOTOINDUCED ELECTRON TRANSFER
PROCESS 519 4.3.2 PHOTOINITIATING DONOR-ACCEPTOR PAIR WITHOUT
ELECTROSTATIC INTERACTION IN GROUND STATE AND AFTER AN ELECTRON TRANSFER
538 4.3.3 PHOTOINITIATING DONOR-ACCEPTOR PAIR NEUTRAL IN A GROUND STATE
AND CHARGED AFTER AN ELECTRON TRANSFER (RADICAL-ION PAIR) 545 4.4
KINETICS 568 ACKNOWLEDGMENTS 580 REFERENCES 580 XLVI CONTENTS PART 3
ENERGY AND THE ENVIRONMENT 587 IAN R. GOULD (ED.) 1 SOLAR ENERGY
CONVERSION 589 MICHAEL GRAETZEL AND JACQUES-E. MOSER 1.1 INTRODUCTION AND
SCOPE 589 1.2 EFFICIENCY RESTRICTIONS IN PHOTOCHEMICAL CONVERSION 589
1.2.1 MAXIMUM POWER EXTRACTION 590 1.2.2 LIMITATIONS DUE TO THE ENTROPY
OF LIGHT 591 1.2.3 FURTHER INCREASE OF ENTROPY ON ABSORPTION OR
SCATTERING 592 1.2.4 EFFICIENCY OF ENERGY CONVERSION UNDER POLYCHROMATIC
RADIATION 594 1.3 STATUS OF PHOTOCHEMICAL ENERGY CONVERSION SYSTEMS 595
1.4 MOLECULAR PHOTOVOLTAICS 596 1.4.1 MIMICKING NATURAL PHOTOSYNTHESIS
597 1.4.2 MESOSCOPIC OXIDE SEMICONDUCTOR FILMS 600 1.4.3 PHOTOINDUCED
CHARGE SEPARATION AT THE SOLID/ELECTROLYTE INTERFACE .. 603 1.4.4 CHARGE
SEPARATION IN MOLECULAR PHOTOVOLTAIC DEVICES 623 1 4.5 CHARGE SEPARATION
IN NANOCRYSTALLINE HETEROTRIADS 628 1.4.6 PHOTOVOLTAIC PERFORMANCES OF
DYE-SENSITIZED NANOCRYSTALLINE SOLAR CELLS 634 1.5 WATER CLEAVAGE BY
VISIBLE LIGHT 636 1.5.1 ANALOGS OF PHOTOSYSTEM II OF GREEN PLANTS 637
1.5.2 COLLOIDAL SEMICONDUCTOR SYSTEMS 637 1.5.3 TANDEM SYSTEMS FOR WATER
CLEAVAGE BY VISIBLE LIGHT 638 1.6 FUTURE OUTLOOK AND CONCLUDING REMARKS
639 ACKNOWLEDGMENTS 641 REFERENCES 641 2 BATTERIES 645 CATIA ARBIZZANI,
MARINA MASTRAGOSTINO, AND FRANCESCA SOAVI 2. 1 INTRODUCTION 645 2.2
BASIC ASPECTS 647 2.2.1 THERMODYNAMICS AND ELECTROCHEMICAL KINETICS 650
2.2.2 BATTERY PERFORMANCE 656 2.3 ENERGY CONVERSION SYSTEMS 657 2.3.1
PRIMARY CELLS 657 2.3.2 SECONDARY CELLS 661 2.3.3 SUPERCAPACITORS 668
2.3.4 FUEL CELLS 673 2.4 LITHIUM RECHARGEABLE BATTERIES 676 2.4.1
LITHIUM-METAL BATTERIES 677 2.4.2 LITHIUM-ION BATTERIES 681 2.4.3
INSERTION ELECTRODE MATERIALS 682 2.5 PRESENT STATUS AND FUTURE
PROSPECTS 690 REFERENCES 691 CONTENTS XLVII 3 PRINCIPLES OF
SEMICONDUCTOR-ASSISTED PHOTOCATALYSIS FOR WASTE REMEDIATION 695 MARION
C. THURNAUER, TIJANA RAJH, AND NADA M. DIMITRIJEVIC 3.1 INTRODUCTION 695
3.2 COLLOIDAL SEMICONDUCTORS 696 3.2.1 OPTICAL PROPERTIES OF
SEMICONDUCTORS 696 3.2.2 QUANTIZATION EFFECT 698 3.2.3 SPACE CHARGE
LAYER AND BAND BANDING 699 3.2.4 ENERGY BAND STRUCTURE OF TI0 2 701 3.3
BASIC MECHANISMS OF SEMICONDUCTOR-ASSISTED PHOTOCATALYSIS 703 3.3.1
PHOTOGENERATION OF CHARGE PAIRS AND INTRINSIC PROPERTIES OF
SEMICONDUCTORS 703 3.3.2 CHARGE PAIR SEPARATION AND CHARGE CARRIER
TRAPPING 706 3.3.3 CHARGE CARRIER RECOMBINATION AND INTERFACIAL ELECTRON
TRANSFER ... 707 3.3.4 NATURE OF TRAPPING SITES 709 3.3.5 ADSORPTION 709
3.4 ENHANCED CHARGE SEPARATION: ROUTE FOR EFFICIENT PHOTODEGRADATION 712
3.4.1 METALLIZATION OF SEMICONDUCTOR PARTICLES 712 3.4.2 SURFACE
MODIFIKATION 713 3.4.3 DYE SENSITIZATION 714 3.5 RADIATION-INDUCED
CATALYSIS ON SEMICONDUCTOR SURFACES 714 3.6 SUMMARY 716 ACKNOWLEDGMENT
716 REFERENCES 716 INDEX 719
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| indexdate | 2024-07-09T18:46:19Z |
| institution | BVB |
| language | English |
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| physical | XLVII, 800 S. Ill., graph. Darst. |
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| spelling | Electron transfer in chemistry 5 Molecules-level electronics ; imaging and information ; energy and the environment Vincenzo Balzani (ed.) Weinheim [u.a.] Wiley-VCH 2001 XLVII, 800 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Oxidation-reduction reaction Balzani, Vincenzo 1936- Sonstige (DE-588)10907811X oth (DE-604)BV013463647 5 GBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009188984&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Electron transfer in chemistry Oxidation-reduction reaction |
| title | Electron transfer in chemistry |
| title_auth | Electron transfer in chemistry |
| title_exact_search | Electron transfer in chemistry |
| title_full | Electron transfer in chemistry 5 Molecules-level electronics ; imaging and information ; energy and the environment Vincenzo Balzani (ed.) |
| title_fullStr | Electron transfer in chemistry 5 Molecules-level electronics ; imaging and information ; energy and the environment Vincenzo Balzani (ed.) |
| title_full_unstemmed | Electron transfer in chemistry 5 Molecules-level electronics ; imaging and information ; energy and the environment Vincenzo Balzani (ed.) |
| title_short | Electron transfer in chemistry |
| title_sort | electron transfer in chemistry molecules level electronics imaging and information energy and the environment |
| topic | Oxidation-reduction reaction |
| topic_facet | Oxidation-reduction reaction |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009188984&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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