Electron transfer in chemistry: 1 Principles and theories, methods and techniques
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2001
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| Beschreibung: | LXXX, 592 S. Ill., graph. Darst. |
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| 245 | 1 | 0 | |a Electron transfer in chemistry |n 1 |p Principles and theories, methods and techniques |c Vincenzo Balzani (ed.) |
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| adam_text | VINCENZO BALZANI (ED.) ELECTRON TRANSFER IN CHEMISTRY 1 PRINCIPLES AND
THEORIES METHODS AND TECHNIQUES WILEY-VCH WEINHEIM * NEW YORK *
CHICHESTER BRISBANE * SINGAPORE * TORONTO CONTENTS VOLUME I FOREWORD V
PREFACE IX ABOUT THE EDITORS LV LIST OF AUTHORS LXVII PART 1 PRINCIPLES
AND THEORIES 1 PIOTR PIOTROWIAK (ED.) 1 ELECTRON TRANSFER: THEORETICAL
MODELS AND COMPUTATIONAL IMPLEMENTATION 3 MARSHALL D. NEWTON 1.1
INTRODUCTION 3 1.2 KINETIC SCHEINES 7 1.3 RATE-CONSTANT MODELS 10 1.3.1
SYSTEM HAMILTONIAN AND ELECTRONIC STATES 10 1.3.2 DIABATIC ENERGY
SURFACES 13 1.3.3 TST MODELS 16 1.3.4 ROLE OF SOLVENT DYNAMICS 23 1.4
COUPLING ELEMENTS 26 1.4.1 BASIC PROPERTIES 26 1.4.2 COMPARISON OF
THERMAL AND OPTICAL PROCESSES 30 1.4.3 PATHWAY ANALYSIS OF T TF 34 1.5
APPLICATIONS OF THEORY 38 1.5.1 COMPARISONS BASED ON EXPERIMENTAL DATA
38 1.5.2 COMPUTATIONAL STUDIES 44 XIV CONTENTS 1.6 CONCLUDING REMARKS 57
ACKNOWLEDGMENTS 58 REFERENCES 58 2 ADIABATIC VERSUS NON-ADIABATIC
ELECTRON TRANSFER 64 HITOSHI SUMI 2. 1 ADIABATIC- VERSUS STATIC-COUPLING
SCHEME 64 2.2 NON-ADIABATIC LIMIT 69 2.2.1 SINGLE-MODE MODEL 69 2.2.2
ATOM-TUNNELING REGIME 72 2.2.3 SEMICLASSICAL AND CLASSICAL REGIMES 74
2.2.4 MULTIMODE MODEL 77 2.3 ADIABATIC LIMIT 78 2.3.1 SEMICLASSICAL
REGIME 78 2.3.2 ATTEMPT FREQUENCY 80 2.4 FROM THE ADIABATIC TO THE
NON-ADIABATIC LIMIT 83 2.4.1 ADIABATICITY PARAMETER 83 2.4.2 BETWEEN THE
ADIABATIC AND THE NON-ADIABATIC LIMIT 86 2.5 FURTHER DEVELOPMENT 91
2.5.1 LARGE-ENERGY-QUANTUM INTRAMOLECULAR MODES 91 2.5.2 ELECTRON
TRANSFER TO OR FROM A CONTINUUM OF FREE STATES 95 2.5.3
SOLVENT-FLUCTUATION-CONTROLLED REGIME 97 APPENDICES 104 APPENDIX A:
DIRECT DERIVATION OF EQUATION 23 104 APPENDIX B: WIGNER DISTRIBUTION
FUNCTION 104 REFERENCES 107 3 SINGLE- AND MULTI-ELECTRON TRANSFER
PROCESSES 109 SPIROS S. SKOURTIS AND DAVID N. BERATAN 3.1 INTRODUCTION
109 3.2 SINGLE-ELECTRON TRANSFER REACTIONS 109 3.3 MULTI-ELECTRON
TRANSFER REACTIONS 120 3.4 CONCLUSIONS 123 ACKNOWLEDGMENTS 123
REFERENCES 124 4 ELECTRON TRANSFER AT ELECTRODES AND INTERFACES 126
DANIEL VANMAEKELBERGH 4.1 SCOPE 126 4.2 OPEN ELECTRON SYSTEMS 127 4.2.1
THE ELECTROCHEMICAL POTENTIAL 127 4.2.2 ELECTRONIC EQUILIBRIUM BETWEEN
TWO PHASES 129 4.2.3 DEVIATIONS FROM EQUILIBRIUM 131 4.3 THE ELECTRONIC
STRUCTURE OF SOLIDS 132 4.3.1 FREE AND INDEPENDENT ELECTRONS 133 4.3.2
THE SOMMERFELD MODEL FOR FREE ELECTRONS IN A METALLIC PHASE 134 CONTENTS
XV 4.3.3 OCCUPATION OF THE ELECTRON-ENERGY LEVELS 137 4.3.4 THE ORIGIN
OF ENERGY BANDS 137 4.3.5 METALS, SEMICONDUCTORS AND INSULATORS 140
4.3.6 EXTRINSIC SEMICONDUCTORS 141 4.4 ELECTRON-ENERGY LEVELS
CORRESPONDING TO A REDOX SYSTEM 142 4.4.1 THE ELECTROCHEMICAL POTENTIAL
OF A DISSOLVED REDOX SYSTEM 143 4.4.2 THE FLUCTUATING-ENERGY-LEVEL MODEL
PROPOSED BY GERISCHER 144 4.5 INTERFACIAL STRUCTURE 149 4.5.1 METAL
SURFACES 150 4.5.2 PHYSISORPTION AND CHEMISORPTION 154 4.5.3 THE
METAL/SOLUTION INTERFACE 155 4.5.4 THE SEMICONDUCTOR/SOLUTION INTERFACE
158 4.6 ELECTRON TUNNELING 161 4.6.1 THE PROBABILITY OF ELECTRON
TUNNELING 161 4.6.2 INTERFACIAL ELECTRON TUNNELING BETWEEN TWO METALS
163 4.6.3 EXPERIMENTAL TUNNELING SPECTROSCOPY 165 4.7 ELECTROCHEMICAL
REACTIONS: KINETICS AND MECHANISM 167 4.7.1 THE DIVERSITY OF
ELECTROCHEMICAL PROCESSES 167 4.7.2 ELECTROCHEMICAL ION TRANSFER AND
ELECTROCHEMICAL ELECTRON TRANSFER (ECIT AND ECET) 169 4.7.3 CURRENT
DENSITY VS OVERPOTENTIAL: EXPERIMENTAL RESULTS 170 4.7.4 A HEURISTIC
TREATMENT OF ELECTROCHEMICAL KINETICS 171 4.8 ELECTRON TRANSFER BETWEEN
A METAL AND A SIMPLE REDOX SYSTEM 176 4.8.1 COMPARISON BETWEEN
ELECTROCHEMICAL ELECTRON TUNNELING AND TUNNELING BETWEEN TWO METALS 176
4.8.2 CURRENT DENSITY AS A FUNCTION OF OVERPOTENTIAL 1 7 7 4.8.3 MARCUS,
GERISCHER AND THE PHENOMENOLOGICAL RATE EQUATIONS 181 4.9 COMPARISON OF
ELECTRON TRANSFER AT A SEMICONDUCTOR WITH ELECTRON TRANSFER AT A METAL
ELECTRODE 182 REFERENCES 187 5 PROTON-COUPLED ELECTRON TRANSFER 189
SHARON HAMMES-SCHIFFER 5.1 INTRODUCTION 189 5.2 CONTINUUM THEORY FOR
SINGLE-CHARGE TRANSFER 191 5.2.1 SINGLE-ELECTRON TRANSFER 192 5.2.2
SINGLE-PROTON TRANSFER 195 5.3 MULTISTATE CONTINUUM THEORY FOR
PROTON-COUPLED ELECTRON TRANSFER 198 5.3.1 FOUR-STATE FORMULATION 198
5.3.2 TWO-STATE FORMULATION 201 5.3.3 INCORPORATION OF INNER-SPHERE
REORGANIZATION 207 5.3.4 EXTENSION TO MORE THAN TWO CHARGE-TRANSFER
REACTIONS 208 5.4 APPLICATIONS OF PROTON-COUPLED ELECTRON TRANSFER IN
SOLUTION 209 5.4.1 CALCULATION OF INPUT QUANTITIES 209 5.4.2
PROTON-COUPLED ELECTRON TRANSFER THROUGH ASYMMETRIE SALT BRIDGES 209 XVI
CONTENTS 5.5 FUNDAMENTAL PRINCIPLES OF PROTON-COUPLED ELECTRON TRANSFER
212 5.6 FUTURE DIRECTIONS 213 ACKNOWLEDGMENTS 213 REFERENCES 213 6
RELATIONSHIP BETWEEN ELECTRON AND ELECTRONIC EXCITATION TRANSFER 215
PIOTR PIOTROWIAK 6.1 INTRODUCTION 215 6.2 SINGLET ENERGY TRANSFER 217
6.3 TRIPLET ENERGY TRANSFER 223 6.4 SUMMARY 232 ACKNOWLEDGMENTS 233
REFERENCES 234 7 CHARGE-TRANSFER EXCITED STATES OF TRANSITION METAL
COMPLEXES 238 JOHN F. ENDICOTT 7. 1 DEFMITIONS AND GENERAL CONCEPTS 238
7.1.1 BASIC CONCEPTS 238 7.1.2 THE IDEALIZED LIMIT OF WEAK D/A
ELECTRONIC COUPLING (LWEC) .... 239 7.2 CHARGE-TRANSFER ABSORPTION
SPECTROSCOPY 241 7.2.1 THE ENERGIES OF CHARGE-TRANSFER ABSORPTIONS 241
7.2.2 CHARGE-TRANSFER EXCITED-STATE TERMS AND ASSIGNMENTS 244 7.2.3 THE
ANALYSIS OF SPECTROSCOPIC ABSORPTION BANDS 245 7.3 CHARGE-TRANSFER
EMISSION SPECTROSCOPY 247 7.3.1 THE INTERPRETATION OF CHARGE-TRANSFER
EMISSION SPECTRA 248 7.4 THE CLASSIFICATION OF CHARGE-TRANSFER
ABSORPTION BANDS 248 7.5 THE ELECTRONIC STATES GENERATED BY
CHARGE-TRANSFER ABSORPTIONS ... 248 7.5.1 THE FRANCK-CONDON STATE IN
TRANSITION METAL COMPLEXES 249 7.5.2 THE VIBRATIONALLY EQUILIBRATED
EXCITED STATES (VEQES) 249 7.6 EXCITED-STATE RELAXATION PROCESSES 249
7.6.1 VIBRATIONALLY EQUILIBRATED EXCITED STATES RELAXATION PROCESSES 250
7.6.2 UPPER-EXCITED-STATE ELECTRONIC-STATE RELAXATION 251 7.7
OBSERVATIONS ON THE WEAK ELECTRONIC COUPLING LIMIT: LON-PAIR
CHARGE-TRANSFER ABSORPTION BANDS 252 7.7.1 THE CORRELATION OF OBSERVED
LON-PAIR CHARGE-TRANSFER ENERGIES WITH EXPERIMENTAL ELECTRON-TRANSFER
PARAMETERS 252 ELECTRONIC COUPLING IN LON-PAIR CHARGE-TRANSFER SYSTEMS
253 LON-PAIR CHARGE-TRANSFER ABSORPTION BAND WIDTHS 256 LIGAND-TO-METAL
CHARGE-TRANSFER (LMCT) ABSORPTION BANDS 257 ENERGY CORRELATIONS FOR
SIMPLE SYSTEMS: M IIT (NH3) 5 (X~) COMPLEXES 257 MORE COMPLEX
LIGAND-TO-METAL CHARGE-TRANSFER (LMCT) SYSTEMS. 259 LIGAND-TO-METAL
CHARGE-TRANSFER (LMCT) BAND SHAPES AND INTENSITIES 261 7.9
METAL-TO-LIGAND CHARGE-TRANSFER (MLCT) ABSORPTION BAND ENERGIES 261
7.7.2 7.7.3 7.8 7.8.1 7.8.2 7.8.3 CONTENTS XVN 7.9.1 GENERAL COMMENTS
261 7.9.2 METAL-TO-LIGAND CHARGE-TRANSFER (MLCT) EXCITED-STATE
ENERGIES.. 262 7.9.3 BAND SHAPES AND INTENSITIES 265 7.10 EXCITED-STATE
LIFETIMES AND LUMINESCENCE PROPERTIES 265 7.11 PERSPECTIVES AND
CONCLUSIONS 266 ACKNOWLEDGEMENTS 267 REFERENCES 267 8 SYNTHETIC
APPLICATIONS OF PHOTOCATALYTIC OXIDATION AND REDUCTION REACTIONS OF
ORGANIC REACTANTS ON IRRADIATED SEMICONDUCTOR SURFACES 271 MARYE ANNE
FOX 8.1 INTRODUCTION 271 8.2 PRINCIPLES GOVERNING PHOTOELECTROCHEMISTRY
273 8.2.1 REDOX REACTIONS ON IRRADIATED SEMICONDUCTOR SURFACES 273 8.2.2
COMPARISON OF A PHOTOELECTROCHEMICALLY GENERATED ELECTRON-HOLE PAIR AND
A MOLECULARY EXCITED STATE 277 8.2.3 ENERGY CONSIDERATIONS 278 8.2.4
SOLVENT EFFECTS 280 8.2.5 SEMICONDUCTOR STABILITY TOWARD CATALYTIC
CYCLING 281 8.2.6 PHOTOSENSITIZATION 281 8.3 MECHANISM 282 8.4 CHEMICAL
SELECTIVITY THROUGH PHOTOELECTROCHEMICAL ACTIVATION 286 8.4.1 ADSORPTION
AND SURFACE EFFECTS 286 8.4.2 POTENTIAL CONTROL 290 8.4.3 CURRENT
CONTROL 292 8.5 SELECTIVE PHOTOELECTROCHEMICAL TRANSFORMATIONS 293 8.5.1
OXIDATIONS 294 8.5.2 REDUCTIONS 301 8.5.3 CYCLOADDITIONS AND
RETROCYCLOADDITIONS 303 8.5.4 GEOMETRIE ISOMERIZATIONS 304 8.5.5
MISCELLANEOUS REACTIONS 305 8.6 CONCLUSIONS 305 ACKNOWLEDGMENTS 306
REFERENCES 307 9 RADIATIVE CHARGE RECOMBINATION AND
ELECTROCHEMILUMINESCENCE 312 ANN-MARGRET ANDERSSON AND RUSSELL H.
SCHMEHL 9.1 INTRODUCTION 312 9.2 PROCESSES LEADING TO RADIATIVE CHARGE
RECOMBINATION 313 9.2.1 ANNIHILATION OF ANION AND CATION RADICALS 313
9.2.2 EXCIMER AND EXCIPLEX EMISSION 314 9.2.3 REACTIONS OF RADICAL IONS
WITH OTHER REAGENTS 316 9.2.4 CHEMICALLY INDUCED ELECTRON-EXCHANGE
LUMINESCENCE 317 9.3 KINETIC ASPECTS 319 9.4 EXPERIMENTAL
CONSIDERATIONS: TECHNIQUES AND MOLECULAR SYSTEMS .. 323 XVNI CONTENTS
9.4.1 GENERATION AND CHARACTERIZATION OF REACTIVE SPECIES 323 9.4.2
MOLECULAR SYSTEMS 328 9.5 APPLICATIONS 331 9.5.1 SENSORS FOR ORGANIC
SUBSTRATES EMPLOYING [RU(BPY)3] 2+ AND DERIVATIVES 331 9.5.2 SENSORS
EMPLOYING OTHER ECL CHROMOPHORES 335 9.5.3 DEVICE APPLICATIONS 337 9.6
SUMMARY 338 ACKNOWLEDGMENTS 338 REFERENCES 338 10 ELECTRON TRANSFER
REACTIONS IN ORGANIC CHEMISTRY 342 STEPHEN F. NEBEN 10.1 INTRODUCTION
342 10.2 INNER- AND OUTER-SPHERE ELECTRON TRANSFER REACTIONS 343 10.3
BOND CLEAVAGE 347 10.3.1 REDUCTIVE CLEAVAGE OF SINGLE BONDS 347 10.3.2
HETEROLYTIC VERSUS HOMOLYTIC BOND-CLEAVAGE REACTIONS 352 10.4
REARRANGEMENTS INITIATED BY BOND CLEAVAGE IN RADICAL CATIONS 354 10.5
ADDITIONS TO SINGLE BONDS OF RADICAL CATIONS 357 10.6 ADDITIONS TO N
SYSTEMS OF RADICAL CATIONS 362 10.7 TRISUBSTITUTED NITROGEN OXIDATIONS
AND AMINIUM RADICAL CATION DEPROTONATIONS 370 10.8 STUDIES FOCUSING ON
ELECTRON TRANSFER KINETICS OF ORGANIC SYSTEMS 373 10.8.1 INTERMOLECULAR
REACTIONS 373 10.8.2 INTRAMOLECULAR REACTIONS: DONOR-BRIDGE-ACCEPTOR
SYSTEMS 376 10.8.3 INTRAMOLECULAR REACTIONS: INTERVALENCE COMPOUNDS 379
REFERENCES 386 PART 2 METHODS AND TECHNIQUES 393 MICHAEL A. J. RODGERS
(ED.) 1 CLASSICAL METHODS 395 ANDREJA BAKAC 1.1 INTRODUCTION 395 1.2
MIXING METHODS 395 1.2.1 MANUAL MIXING 395 1.2.2 RAPID MIXING 397 1.3
RELAXATION METHODS 403 1.3.1 TEMPERATURE JUMP 404 1.3.2 PRESSURE JUMP
406 1.3.3 SPIN-RELAXATION METHODS 407 1.4 HIGH-PRESSURE TECHNIQUES 412
1.5 INDIRECT METHODS AND SPECIAL CASES 414 CONTENTS XIX 1.5.1
COMPETITION KINETICS 414 1.5.2 EXCHANGE REACTIONS 418 ACKNOWLEDGMENTS
419 ABBREVIATIONS 419 REFERENCES 420 2 ELECTROCHEMICAL TECHNIQUES 422
STEEN UTTRUP PEDERSEN AND KIM DAASBJERG 2.1 ELECTROCHEMICAL TECHNIQUES
422 2.1.1 INTRODUCTION 422 2.1.2 HETEROGENEOUS KINETICS 425 2.1.3 MASS
TRANSPORT 427 2.1.4 HOMOGENEOUS KINETICS 429 2.2 POTENTIAL-STEP
EXPERIMENTS 431 2.2.1 CHRONOAMPEROMETRY 431 2.2.2 SAMPLED-CURRENT
VOLTAMMETRY 437 2.2.3 DOUBLE-POTENTIAL-STEP CHRONOAMPEROMETRY 437 2.3
LINEAR SWEEP VOLTAMMETRY AND CYCLIC VOLTAMMETRY 440 2.3.1
CHARGE-TRANSFER REACTIONS 443 2.3.2 NERNSTIAN CHARGE TRANSFER 444 2.3.3
QUASI-REVERSIBLE AND IRREVERSIBLE CHARGE TRANSFER 444 2.3.4 OHMIC DROP
446 2.3.5 COUPLED CHEMICAL REACTIONS 446 2.3.6 MIXED CHARGE TRANSFER AND
KINETIC CONTROL 449 2.4 ULTRA-MICROELECTRODES 451 2.4.1 FAST-TRANSIENT
TECHNIQUES 455 2.4.2 APPLICATIONS OF UME IN RESISTIVE MEDIA AND UNDER
INDUSTRIAL CONDITIONS 458 2.4.3 STEADY-STATE MEASUREMENTS AT UMES FOR
MONITORING SLOW HOMOGENEOUS REACTIONS 462 2.4.4 SENSORS 465 2.5
HYDRODYNAMIC ELECTROCHEMICAL TECHNIQUES 468 2.5.1 PREPARATIVE
ELECTROLYSIS 470 2.5.2 ROTATING DISC ELECTRODE 472 2.6 COMBINATION OF
ELECTROCHEMISTRY AND SPECTROSCOPY 477 2.6.1 TYPE 1 477 2.6.2 TYPE 2 483
2.6.3 TYPE 3 491 2.7 INDIRECT ELECTROLYSIS 491 REFERENCES 499 3
RADIATION-CHEMLCAL TECHNIQUES 503 GEORGE V. BUXTON AND QUINTO G.
MULAZZANI 3.1 INTRODUCTION 503 3.2 INTERACTION OF IONIZING RADIATION
WITH CONDENSED MATTER 504 XX CONTENTS 3.3 THE RADIATION CHEMISTRY OF
WATER 505 3.3.1 PROPERTIES OF THE PRIMARY RADICALS 507 3.3.2 GENERATION
OF SECONDARY RADICALS 510 3.4 THE RADIATION CHEMISTRY OF ORGANIC LIQUIDS
514 3.5 ONE-ELECTRON REDUCTION AND OXIDATION IN NONAQUEOUS SOLVENTS 515
3.5.1 ALCOHOLS 515 3.5.2 ACETONE 518 3.5.3 ACETONITRILE 518 3.5.4
CHLORINATED HYDROCARBONS 519 3.5.5 2-METHYLTETRAHYDROFURAN AND
2,2,4-TRIMETHYLPENTANE 520 3.5.6 CYCLOHEXANE 521 3.5.7 DIMETHYL
SULFOXIDE 522 3.5.8 AMMONIA 522 3.5.9 SOLVENT MIXTURES 523 3.6 PULSE
RADIOLYSIS 523 3.6.1 HISTORICAL PERSPECTIVE 523 3.7 PULSE RADIOLYSIS
FACILITIES 529 3.7.1 A TYPICAL MODERN PULSE RADIOLYSIS FACILITY 530 3.8
OTHER METHODS OF DETECTION 543 3.8.1 POLAROGRAPHY 543 3.8.2 MICROWAVE
DETECTION 544 3.8.3 MAGNETIC RESONANCE 545 3.9 PICOSECOND PULSE
RADIOLYSIS 546 3.10 DATA CAPTURE AND ANALYSIS 548 3.11 PURIFICATION OF
MATERIALS AND PREPARATION OF SOLUTIONS 549 3.11.1 PURIFICATION OF
SOLVENTS 551 3.12 CONCLUDING REMARKS 552 REFERENCES 552 FURTHER READING
557 4 PHOTOCHEMICAL TECHNIQUES 558 KEVIN HENBEST AND MICHAEL A. J.
RODGERS 4. 1 INTRODUCTION 558 4.2 THE SIGNIFICANCE OF PHOTOEXCITATION
FOR ELECTRON TRANSFER 559 4.2.1 ADVANTAGES OF PHOTOEXCITATION 560 4.3
THE METHODOLOGY OF PHOTOKINETICS 563 4.3.1 INSTRUMENTATION
CONSIDERATIONS 564 4.3.2 EXCITATION SOURCES 564 4.4 DETECTION AND
MEASUREMENT TECHNIQUES 569 4.4.1 OPTICAL ABSORPTION SPECTROMETRY 569
4.4.2 LIGHT-SCATTERING SPECTROMETRY 580 4.4.3 FLUORESCENCE
INSTRUMENTATION 582 4.4.4 FREQUENCY-DOMAIN (PHASE-SHIFT) MEASUREMENTS
586 4.5 CONCLUDING REMARKS 588 ACKNOWLEDGMENTS 588 REFERENCES 588
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| spelling | Electron transfer in chemistry 1 Principles and theories, methods and techniques Vincenzo Balzani (ed.) Weinheim [u.a.] Wiley-VCH 2001 LXXX, 592 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Oxidation-reduction reaction Balzani, Vincenzo 1936- Sonstige (DE-588)10907811X oth (DE-604)BV013463647 1 GBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009188965&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Electron transfer in chemistry Oxidation-reduction reaction |
| title | Electron transfer in chemistry |
| title_auth | Electron transfer in chemistry |
| title_exact_search | Electron transfer in chemistry |
| title_full | Electron transfer in chemistry 1 Principles and theories, methods and techniques Vincenzo Balzani (ed.) |
| title_fullStr | Electron transfer in chemistry 1 Principles and theories, methods and techniques Vincenzo Balzani (ed.) |
| title_full_unstemmed | Electron transfer in chemistry 1 Principles and theories, methods and techniques Vincenzo Balzani (ed.) |
| title_short | Electron transfer in chemistry |
| title_sort | electron transfer in chemistry principles and theories methods and techniques |
| topic | Oxidation-reduction reaction |
| topic_facet | Oxidation-reduction reaction |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009188965&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| volume_link | (DE-604)BV013463647 |
| work_keys_str_mv | AT balzanivincenzo electrontransferinchemistry1 |