Transformation processes in minerals:
Gespeichert in:
| Format: | Buch |
|---|---|
| Sprache: | English |
| Veröffentlicht: |
Washington, DC
Mineralogical Soc. of America
2000
|
| Schriftenreihe: | Reviews in mineralogy and geochemistry
39 |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | X, 361 S. Ill., graph. Darst., Kt. |
| ISBN: | 0939950510 |
Internformat
MARC
| LEADER | 00000nam a2200000 cb4500 | ||
|---|---|---|---|
| 001 | BV013377209 | ||
| 003 | DE-604 | ||
| 007 | t | ||
| 008 | 001009s2000 abd| |||| 00||| eng d | ||
| 020 | |a 0939950510 |9 0-939950-51-0 | ||
| 035 | |a (OCoLC)247906580 | ||
| 035 | |a (DE-599)BVBBV013377209 | ||
| 040 | |a DE-604 |b ger |e rakwb | ||
| 041 | 0 | |a eng | |
| 049 | |a DE-12 |a DE-355 |a DE-703 |a DE-29 |a DE-B16 |a DE-19 | ||
| 082 | 0 | |a 549.12 | |
| 084 | |a UQ 6000 |0 (DE-625)146531: |2 rvk | ||
| 245 | 1 | 0 | |a Transformation processes in minerals |c eds.: Simon A. T. Redfern ... |
| 264 | 1 | |a Washington, DC |b Mineralogical Soc. of America |c 2000 | |
| 300 | |a X, 361 S. |b Ill., graph. Darst., Kt. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 490 | 1 | |a Reviews in mineralogy and geochemistry |v 39 | |
| 650 | 4 | |a Mineral - Mineralchemie - Phase <Thermodynamik> - Phasenumwandlung - Kongress - Cambridge | |
| 650 | 0 | 7 | |a Phasenumwandlung |0 (DE-588)4132140-6 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Mineral |0 (DE-588)4074836-4 |2 gnd |9 rswk-swf |
| 655 | 7 | |0 (DE-588)4143413-4 |a Aufsatzsammlung |2 gnd-content | |
| 689 | 0 | 0 | |a Phasenumwandlung |0 (DE-588)4132140-6 |D s |
| 689 | 0 | 1 | |a Mineral |0 (DE-588)4074836-4 |D s |
| 689 | 0 | |5 DE-604 | |
| 700 | 1 | |a Redfern, Simon A. T. |e Sonstige |4 oth | |
| 830 | 0 | |a Reviews in mineralogy and geochemistry |v 39 |w (DE-604)BV013377203 |9 39 | |
| 856 | 4 | 2 | |m HBZ Datenaustausch |q application/pdf |u http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009124202&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |3 Inhaltsverzeichnis |
Datensatz im Suchindex
| _version_ | 1805078147789488128 |
|---|---|
| adam_text |
TABLE OF CONTENTS
2 Rigid Unit Modes in Framework Structures:
Theory, Experiment and Applications
Martin T. Dove, Kostya O. Trachenko,
Matthew G. Tucker, David A. Keen
INTRODUCTION.1
FLEXIBILITY OF NETWORK STRUCTURES: SOME BASIC PRINCIPLES.3
Engineering principles.3
The role of symmetry.4
THE SPECTRUM OF RIGID UNIT MODES IN SILICATES.5
The "split-atom" method.5
Three-dimensional distribution of RUMs.6
"Density of states" approach.7
Framework structures containing octahedra.8
EXPERIMENTAL OBSERVATIONS 1: MEASUREMENTS OF DIFFUSE
SCATTERING IN ELECTRON DIFFRACTION.9
EXPERIMENTAL OBSERVATIONS 2:
INELASTIC NEUTRON SCATTERING MEASUREMENTS.10
Single crystal measurements.10
Measurements on polycrystalline samples.11
EXPERIMENTAL OBSERVATIONS 3:
STRUCTURE MODELLING USING NEUTRON DIFFUSE
SCATTERING DATA FROM POLYCRYSTALLINE SAMPLES.12
Total scattering measurements.12
The Reverse Monte Carlo method.13
Application of RMC modelling to the phase transition in cristobalite.15
Application of RMC modelling to the phase transition in quartz.19
APPLICATIONS OF THE RIGID UNIT MODE (RUM) MODEL.23
Displacive phase transitions.23
Theory of the transition temperature.25
Negative thermal expansion.26
Localised deformations in zeolites.27
RUMs in network glasses.28
CONCLUSIONS.28
ACKNOWLEDGMENTS.30
REFERENCES.30
2 Strain and Elasticity
at Structural Phase Transitions in Minerals
Michael A. Carpenter
INTRODUCTION.35
LATTICE GEOMETRY AND REFERENCE STATES.40
SYMMETRY-ADAPTED STRAIN, SYMMETRY-BREAKING STRAIN,
NON-SYMMETRY-BREAKING STRAIN AND SOME TENSOR FORMALITIES .41
COUPLING BETWEEN STRAIN AND THE ORDER PARAMETER.42
THERMODYNAMIC CONSEQUENCES OF STRAIN/ORDER
PARAMETER COUPLING.51
ELASTIC CONSTANT VARIATIONS.55
ACKNOWLEDGMENTS.61
REFERENCES.61
3 Mesoscopic Twin Patterns in
Ferroelastic and Co-Elastic Minerals
Ekhard K. H. Salje
INTRODUCTION.65
FERROELASTIC TWIN WALLS.66
BENDING OF TWIN WALLS AND FORMATION OF NEEDLE DOMAINS.71
Comparison with experimental observations.72
NUCLEATION OF TWIN BOUNDARIES FOR RAPID TEMPERATURE QUENCH:
COMPUTER SIMULATION STUDIES.74
INTERSECTION OF A DOMAIN WALL WITH THE MINERAL SURFACE.79
REFERENCES.82
41 High-Pressure Structural Phase Transitions
R.J. Angel
INTRODUCTION.85
PRESSURE AND TEMPERATURE.85
SPONTANEOUS STRAIN.87
Experimental methods.°
Fitting high-pressure lattice parameters.°"
Calculating strains."
ELASTICITY.93
OTHER TECHNIQUES.96
ACKNOWLEDGMENTS.96
APPENDIX.97
Fitting the high-symmetry data.9 '
Strain calculation.""
REFERENCES.102
§ Order-Disorder Phase Transitions
Simon A. T. Redfern
INTRODUCTION.105
EQUILIBRIUM AND NON-EQUILIBRIUM THERMODYNAMICS.107
The Bragg-Williams model.108
Landau theory. ' '^
Non-convergent ordering.' '7
Computer modelling of cation ordering.' '7
EXAMPLES OF REAL SYSTEMS.l19
Cation ordering in ilmenite-hematite.' '9
Thermodynamics and kinetics of non-convergent disordering in olivine.123
Modelling non-convergent order-disorder in spinel.125
Bilinear coupling of Q and god in albite.125
The P6/mcc-Cccm transition in pure and K-bearing cordierite:
influence of chemical variation.127
Ferroelasticity and order/disorder in leucite-related frameworks.128
CONCLUSIONS.130
ACKNOWLEDGEMENTS.130
REFERENCES.130
VI
£ Phase Transformations Induced by Solid Solution
Peter J. Heaney
INTRODUCTION. 135
CONCEPTS OF MORPHOTROPISM. 136
A brief historical background. 136
Analogies between morphotropism and polymorphism. 137
PRINCIPLES OF MORPHOTROP1C TRANSITIONS. 140
Types of atomic substitutions.140
Linear dependence of Tc on composition.141
Morphotropic phase diagrams (MPDs). 142
Quantum saturation, the plateau effect, and defect tails. 144
Impurity-induced twinning. 146
Incommensurate phases and solid solutions. 148
CASE STUDIES OF DISPLACIVE TRANSITIONS
INDUCED BY SOLID SOLUTION. 149
Ferroelectric perovskites. 149
Stabilized cubic zirconia. 154
Lead phosphate analogs to palmierite. 155
Cuproscheelite-sanmartinite solid solutions. 158
Substitutions in feldspar frameworks. 160
Stuffed derivatives of quartz. 164
GENERAL CONCLUSIONS. 166
ACKNOWLEDGMENTS. 167
REFERENCES. 167
? Magnetic Transitions in Minerals
Richard J.Harrison
INTRODUCTION. 175
MAGNETIC ORDERING.175
Driving force for magnetic ordering. 175
Classification of ordered (collinear) magnetic structures. 176
Models of magnetic ordering. 176
CATION ORDERING. 179
Non-convergent cation ordering in oxide spinels. 180
Verwey transition in magnetite. 181
Convergent cation ordering in rhombohedral oxides. 181
Magnetic consequences of cation ordering. 181
SELF-REVERSED THERMOREMANENT MAGNETIZATION (SR-TRM). 189
Mechanisms of self reversal.189
Self-reversal in the ilmenite-hematite solid solution. 190
CHEMICAL REMANENT MAGNETIZATION (CRM).195
Principles of CRM.195
TRANSFORMATION OF Y-FeOOH-^Y-Fe2O3^a-Fe2°j.196
CLOSING REMARKS. 198
ACKNOWLEDGMENTS. 198
REFERENCES.198
Vll
$ NMR Spectroscopy of Phase Transitions in Minerals
Brian L. Phillips
INTRODUCTION.203
NMR SPECTROSCOPY.203
Basic concepts of NMR spectroscopy.204
Chemical shifts.205
Nuclear quadrupole effects.208
Dipole-dipole interactions.2'"
Dynamical effects.21 '
Relaxation rates.21 2
919
Summary.¦" ^
STRUCTURAL PHASE TRANSITIONS.213
rx-ß transition in cristobalite.2 '3
a-ß quartz.218
Cryolite (Na,AlF6).lli
Order Parameters: The PÏ-/Ï transition in anorthite (CaAl2Si2Og).224
Melanophlogite.
INCOMMENSURATE PHASES.227
Sr2SiO4.227
990
Akermanite.
Tridymite.23°
ORDERING/DISORDERING TRANSITIONS.lil
9^2
Si,Al ordering in framework aluminosilicates.iJ
Cation ordering in spinels.
CONCLUSIONS. ACKNOWLEDGMENTS 237
REFERENCES.237
$ Insights into Phase Transformations
from Mössbauer Spectroscopy
Catherine A. McCammon
INTRODUCTION.241
MöSSBAUER PARAMETERS.241
Isomer Shift.243
Quadrupole splitting.
Hyperfine magnetic splitting.
Relative Area.249
INSTRUMENTATION.251
APPLICATIONS.252
Structural transformations.2^3
Electronic transitions.255
Magnetic transitions.2
CONCLUDING REMARKS.256
REFERENCES.256
APPENDIX.259
Worked example: Incommensurate-normal phase transformation
in Fe-doped akermanite.259
APPENDIX REFERENCES.263
vm
HD Hard Mode Spectroscopy of Phase Transitions
Ulli Bismayer
INTRODUCTION.265
THE ANALYSIS OF PHONON SPECTRA.266
IR powder spectra.266
Raman spectra.267
EXAMPLES OF SHORT-RANGE ORDER IN
STRUCTURAL PHASE TRANSITIONS.269
Precursor in Pb3(PO4)2.269
Phase transitions in synthetic titanite, natural titanite and malayaite.272
ACKNOWLEDGMENTS.281
REFERENCES.281
II H Synchrotron Studies of Phase Transformations
John B. Parise
INTRODUCTION AND OVERVIEW.285
OVERVIEW: DIFFRACTION AND SPECTROSCOPIC TECHNIQUES
FOR STUDYING TRANSITIONS.286
Overview of the diffraction-based science from bulk samples.288
SYNCHROTRON RADIATION SOURCES.289
General characteristics.289
Properties of undulators, wigglers and bending magnets.290
Access.292
Web resources.294
DIFFRACTION STUDIES AT SYNCHROTRON SOURCES.294
General considerations.294
Diffraction from single- and from micro-crystals.294
Powder diffraction studies.296
Energy-dispersive (ED) studies.299
Tools for the collection and analysis of powder diffraction data.300
PHASE TRANSITIONS AND SYNCHROTRON RADIATION:
CASE STUDIES.301
Time resolved diffraction studies.301
Multiple simultaneous techniques—
a more complete picture of the phase transition.306
ACKNOWLEDGMENTS.308
REFERENCES.310
U 2 Radiation-Induced Amorphization
Rodney C. Ewing, Alkiviathes Meldrum
LuMin Wang, ShiXin Wang
INTRODUCTION.319
History and applications.319
MECHANISMS OF RADIATION DAMAGE.320
EXPERIMENTAL METHODS.322
Minerals containing U and Th.322
Actinide-doping.323
Charged-particle irradiation.323
IX
RADIATION DAMAGE IN MINERALS.326
Zircon.326
Monazite.332
Thorite and huttonite.334
Pyrochlore and zirconolite.334
Perovskite.337
Titanite.338
Apatite.339
Olivine and spinel.341
MODELS OF RADIATION DAMAGE MECHANISMS.342
Direct impact vs. defect accumulation models.342
A modified model of direct impact amorphization.345
Temperature-dependence of the amorphization dose.346
The effects of ion mass and energy.347
SUSCEPTIBILITY TO RADIATION-INDUCED AMORPHIZATION.348
GEOLOGIC APPLICATIONS.350
ACKNOWLEDGMENTS.353
REFERENCES.354 |
| any_adam_object | 1 |
| building | Verbundindex |
| bvnumber | BV013377209 |
| classification_rvk | UQ 6000 |
| ctrlnum | (OCoLC)247906580 (DE-599)BVBBV013377209 |
| dewey-full | 549.12 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 549 - Mineralogy |
| dewey-raw | 549.12 |
| dewey-search | 549.12 |
| dewey-sort | 3549.12 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie Physik |
| format | Book |
| fullrecord | <?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>00000nam a2200000 cb4500</leader><controlfield tag="001">BV013377209</controlfield><controlfield tag="003">DE-604</controlfield><controlfield tag="007">t</controlfield><controlfield tag="008">001009s2000 abd| |||| 00||| eng d</controlfield><datafield tag="020" ind1=" " ind2=" "><subfield code="a">0939950510</subfield><subfield code="9">0-939950-51-0</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(OCoLC)247906580</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-599)BVBBV013377209</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-604</subfield><subfield code="b">ger</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1="0" ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="049" ind1=" " ind2=" "><subfield code="a">DE-12</subfield><subfield code="a">DE-355</subfield><subfield code="a">DE-703</subfield><subfield code="a">DE-29</subfield><subfield code="a">DE-B16</subfield><subfield code="a">DE-19</subfield></datafield><datafield tag="082" ind1="0" ind2=" "><subfield code="a">549.12</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">UQ 6000</subfield><subfield code="0">(DE-625)146531:</subfield><subfield code="2">rvk</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Transformation processes in minerals</subfield><subfield code="c">eds.: Simon A. T. Redfern ...</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="a">Washington, DC</subfield><subfield code="b">Mineralogical Soc. of America</subfield><subfield code="c">2000</subfield></datafield><datafield tag="300" ind1=" " ind2=" "><subfield code="a">X, 361 S.</subfield><subfield code="b">Ill., graph. Darst., Kt.</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="b">n</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="b">nc</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="490" ind1="1" ind2=" "><subfield code="a">Reviews in mineralogy and geochemistry</subfield><subfield code="v">39</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Mineral - Mineralchemie - Phase <Thermodynamik> - Phasenumwandlung - Kongress - Cambridge</subfield></datafield><datafield tag="650" ind1="0" ind2="7"><subfield code="a">Phasenumwandlung</subfield><subfield code="0">(DE-588)4132140-6</subfield><subfield code="2">gnd</subfield><subfield code="9">rswk-swf</subfield></datafield><datafield tag="650" ind1="0" ind2="7"><subfield code="a">Mineral</subfield><subfield code="0">(DE-588)4074836-4</subfield><subfield code="2">gnd</subfield><subfield code="9">rswk-swf</subfield></datafield><datafield tag="655" ind1=" " ind2="7"><subfield code="0">(DE-588)4143413-4</subfield><subfield code="a">Aufsatzsammlung</subfield><subfield code="2">gnd-content</subfield></datafield><datafield tag="689" ind1="0" ind2="0"><subfield code="a">Phasenumwandlung</subfield><subfield code="0">(DE-588)4132140-6</subfield><subfield code="D">s</subfield></datafield><datafield tag="689" ind1="0" ind2="1"><subfield code="a">Mineral</subfield><subfield code="0">(DE-588)4074836-4</subfield><subfield code="D">s</subfield></datafield><datafield tag="689" ind1="0" ind2=" "><subfield code="5">DE-604</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Redfern, Simon A. T.</subfield><subfield code="e">Sonstige</subfield><subfield code="4">oth</subfield></datafield><datafield tag="830" ind1=" " ind2="0"><subfield code="a">Reviews in mineralogy and geochemistry</subfield><subfield code="v">39</subfield><subfield code="w">(DE-604)BV013377203</subfield><subfield code="9">39</subfield></datafield><datafield tag="856" ind1="4" ind2="2"><subfield code="m">HBZ Datenaustausch</subfield><subfield code="q">application/pdf</subfield><subfield code="u">http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009124202&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA</subfield><subfield code="3">Inhaltsverzeichnis</subfield></datafield></record></collection> |
| genre | (DE-588)4143413-4 Aufsatzsammlung gnd-content |
| genre_facet | Aufsatzsammlung |
| id | DE-604.BV013377209 |
| illustrated | Illustrated |
| indexdate | 2024-07-20T06:24:28Z |
| institution | BVB |
| isbn | 0939950510 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-009124202 |
| oclc_num | 247906580 |
| open_access_boolean | |
| owner | DE-12 DE-355 DE-BY-UBR DE-703 DE-29 DE-B16 DE-19 DE-BY-UBM |
| owner_facet | DE-12 DE-355 DE-BY-UBR DE-703 DE-29 DE-B16 DE-19 DE-BY-UBM |
| physical | X, 361 S. Ill., graph. Darst., Kt. |
| publishDate | 2000 |
| publishDateSearch | 2000 |
| publishDateSort | 2000 |
| publisher | Mineralogical Soc. of America |
| record_format | marc |
| series | Reviews in mineralogy and geochemistry |
| series2 | Reviews in mineralogy and geochemistry |
| spelling | Transformation processes in minerals eds.: Simon A. T. Redfern ... Washington, DC Mineralogical Soc. of America 2000 X, 361 S. Ill., graph. Darst., Kt. txt rdacontent n rdamedia nc rdacarrier Reviews in mineralogy and geochemistry 39 Mineral - Mineralchemie - Phase <Thermodynamik> - Phasenumwandlung - Kongress - Cambridge Phasenumwandlung (DE-588)4132140-6 gnd rswk-swf Mineral (DE-588)4074836-4 gnd rswk-swf (DE-588)4143413-4 Aufsatzsammlung gnd-content Phasenumwandlung (DE-588)4132140-6 s Mineral (DE-588)4074836-4 s DE-604 Redfern, Simon A. T. Sonstige oth Reviews in mineralogy and geochemistry 39 (DE-604)BV013377203 39 HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009124202&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Transformation processes in minerals Reviews in mineralogy and geochemistry Mineral - Mineralchemie - Phase <Thermodynamik> - Phasenumwandlung - Kongress - Cambridge Phasenumwandlung (DE-588)4132140-6 gnd Mineral (DE-588)4074836-4 gnd |
| subject_GND | (DE-588)4132140-6 (DE-588)4074836-4 (DE-588)4143413-4 |
| title | Transformation processes in minerals |
| title_auth | Transformation processes in minerals |
| title_exact_search | Transformation processes in minerals |
| title_full | Transformation processes in minerals eds.: Simon A. T. Redfern ... |
| title_fullStr | Transformation processes in minerals eds.: Simon A. T. Redfern ... |
| title_full_unstemmed | Transformation processes in minerals eds.: Simon A. T. Redfern ... |
| title_short | Transformation processes in minerals |
| title_sort | transformation processes in minerals |
| topic | Mineral - Mineralchemie - Phase <Thermodynamik> - Phasenumwandlung - Kongress - Cambridge Phasenumwandlung (DE-588)4132140-6 gnd Mineral (DE-588)4074836-4 gnd |
| topic_facet | Mineral - Mineralchemie - Phase <Thermodynamik> - Phasenumwandlung - Kongress - Cambridge Phasenumwandlung Mineral Aufsatzsammlung |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009124202&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| volume_link | (DE-604)BV013377203 |
| work_keys_str_mv | AT redfernsimonat transformationprocessesinminerals |