The defect chemistry of metal oxides:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
New York [u.a.]
Oxford Univ. Press
2000
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | X, 294 S. graph. Darst. |
| ISBN: | 0195110145 |
Internformat
MARC
| LEADER | 00000nam a2200000 c 4500 | ||
|---|---|---|---|
| 001 | BV013214179 | ||
| 003 | DE-604 | ||
| 005 | 20010201 | ||
| 007 | t | ||
| 008 | 000620s2000 d||| |||| 00||| eng d | ||
| 020 | |a 0195110145 |9 0-19-511014-5 | ||
| 035 | |a (OCoLC)43114281 | ||
| 035 | |a (DE-599)BVBBV013214179 | ||
| 040 | |a DE-604 |b ger |e rakwb | ||
| 041 | 0 | |a eng | |
| 049 | |a DE-703 | ||
| 050 | 0 | |a QD181.O1 | |
| 082 | 0 | |a 548/.8 |2 21 | |
| 084 | |a UQ 2400 |0 (DE-625)146493: |2 rvk | ||
| 084 | |a VE 9350 |0 (DE-625)147153:253 |2 rvk | ||
| 100 | 1 | |a Smyth, Donald M. |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a The defect chemistry of metal oxides |c D. M. Smyth |
| 264 | 1 | |a New York [u.a.] |b Oxford Univ. Press |c 2000 | |
| 300 | |a X, 294 S. |b graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 650 | 4 | |a Crystals |x Defects | |
| 650 | 4 | |a Metallic oxides | |
| 650 | 0 | 7 | |a Metalloxide |0 (DE-588)4169619-0 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Gitterbaufehler |0 (DE-588)4125030-8 |2 gnd |9 rswk-swf |
| 689 | 0 | 0 | |a Metalloxide |0 (DE-588)4169619-0 |D s |
| 689 | 0 | 1 | |a Gitterbaufehler |0 (DE-588)4125030-8 |D s |
| 689 | 0 | |5 DE-604 | |
| 856 | 4 | 2 | |m HEBIS Datenaustausch |q application/pdf |u http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009003279&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |3 Inhaltsverzeichnis |
| 999 | |a oai:aleph.bib-bvb.de:BVB01-009003279 | ||
Datensatz im Suchindex
| _version_ | 1804127969431519232 |
|---|---|
| adam_text | Contents
Preface ix
1 Introduction 1
Reference 3
2 A Few Useful Crystal Structures 4
Introduction 4
Close-Packed Structures 6
Structures for Eight-Coordinate Cations 13
Structures for Ternary Compounds 16
Conclusion 20
References 20
Problems 20
3 Lattice Defects and the Law of Mass Action 21
Introduction 21
Lattice Defects as Part of the Equilibrium State 22
The Law of Mass Action 26
Another View of Mass Action 28
Lattice Disorder in Elemental Solids 30
Summary 32
References 33
4 Intrinsic Ionic Disorder 34
Lattice Defects and Reference States 34
Conservation Rules 36
Defect Notation 37
Major Types of Intrinsic Ionic Disorder 38
General Comments on Intrinsic Ionic Disorder 48
References 55
Problems 55
v
vi • Contents
5 Extrinsic Ionic Disorder 57
Introduction 57
The AgCl-CdCl2 System 58
The CaF2-CaO System 62
The Ti02~Nb20s System 63
Summary of Important Points 64
Schematic Representation of Defect Concentrations 65
Summary of Extrinsic Ionic Disorder 72
References 73
Problems 73
6 Defect Complexes and Associates 75
Introduction 75
Complexes Containing an Impurity Center and
an Ionic Defect 76
Intrinsic Ionic Defect Associates 82
The Effect of Impurities on the Concentrations of Defect
Complexes and Associates 85
References 89
7 Ionic Transport 91
Introduction 91
Basic Concepts of Diffusion 91
Ionic Conduction in Crystalline Solids 95
Intrinsic and Extrinsic Ionic Conduction 100
Fast Ion Conductors 112
References 117
8 Intrinsic Electronic Disorder 118
Introduction 118
The Development of Energy Bands 118
The Mass-Action Approach 121
The Fermi Function 123
Holes, Waves, and Effective Masses 126
Electronic Conductivity 129
Hopping Mechanisms 132
The Band Structure of Compounds 133
Chemistry and the Band Gap 134
Summary 137
References 137
Contents • vii
9 Extrinsic Electronic Disorder 138
Introduction 138
Interactions with the Gaseous Ambient 138
The Choice of Compensating Defect 141
The Chemical Consequences of Electronic Compensation 145
The Interactions of Impurity Centers with Electrons and
Holes 146
The Situation for Compounds 156
Summary 161
References 161
10 Intrinsic Nonstoichiometry 162
Introduction 162
Nonstoichiometry in Pure Crystalline Compounds 163
Nonstoichiometry and Equilibrium Defect Concentrations 167
The Hypothetical Compound MX with Schottky Disorder 167
Summary of the Kröger-Vmk Diagram for MX 174
Conclusion of the Discussion of MX 184
A More Complex Kröger-Vink Diagram 185
Summary of the Kröger-Vink Diagrams for Intrinsic
Nonstoichiometry 193
Enthalpy Relationships 193
Conclusion 194
Reference 194
Problems 194
11 Extrinsic Nonstoichiometry 197
Introduction 197
A Simple Example: Donor-Doped MX 198
Enthalpy Relationships 205
A More Complex Example: Acceptor-Doped M2O3 207
General Considerations 210
Nonstoichiometric Reactions in the Impurity-Controlled
Region 214
Problems 215
12 Titanium Dioxide 217
Introduction 217
The Amount of Nonstoichiometry 220
The Equilibrium Electrical Conductivity of Undoped UO2 222
The Seebeck Coefficient of Undoped TiC 2 228
Ionic Conduction in Ti02 228
viii • Contents
The Effect of Dopants on TiC 2 230
General Comments on the Defect Chemistry ofTiC 2 235
References 237
Problems 238
13 Cobalt Oxide and Nickel Oxide 239
Introduction 239
Cobaltous Oxide, CoO 240
Nickelous Oxide, NiO 247
Summary 252
References 252
14 Barium Titanate 253
Introduction 253
General Expectations 255
The Equilibrium Conductivity of Undoped BaTiOs 256
Insulating Properties of BaTiO3 262
Acceptor-Doped BaTiOs 268
Ionic Conduction in BaTiOs 271
Donor-Doped BaTiOs 275
Trivalent Dopants in BaTiOs 278
Summary 281
References 281
15 Order versus Disorder 283
Block Structures 287
Summary 288
References 289
|
| any_adam_object | 1 |
| author | Smyth, Donald M. |
| author_facet | Smyth, Donald M. |
| author_role | aut |
| author_sort | Smyth, Donald M. |
| author_variant | d m s dm dms |
| building | Verbundindex |
| bvnumber | BV013214179 |
| callnumber-first | Q - Science |
| callnumber-label | QD181 |
| callnumber-raw | QD181.O1 |
| callnumber-search | QD181.O1 |
| callnumber-sort | QD 3181 O1 |
| callnumber-subject | QD - Chemistry |
| classification_rvk | UQ 2400 VE 9350 |
| ctrlnum | (OCoLC)43114281 (DE-599)BVBBV013214179 |
| dewey-full | 548/.8 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 548 - Crystallography |
| dewey-raw | 548/.8 |
| dewey-search | 548/.8 |
| dewey-sort | 3548 18 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie Physik |
| format | Book |
| fullrecord | <?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01433nam a2200397 c 4500</leader><controlfield tag="001">BV013214179</controlfield><controlfield tag="003">DE-604</controlfield><controlfield tag="005">20010201 </controlfield><controlfield tag="007">t</controlfield><controlfield tag="008">000620s2000 d||| |||| 00||| eng d</controlfield><datafield tag="020" ind1=" " ind2=" "><subfield code="a">0195110145</subfield><subfield code="9">0-19-511014-5</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(OCoLC)43114281</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-599)BVBBV013214179</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-604</subfield><subfield code="b">ger</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1="0" ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="049" ind1=" " ind2=" "><subfield code="a">DE-703</subfield></datafield><datafield tag="050" ind1=" " ind2="0"><subfield code="a">QD181.O1</subfield></datafield><datafield tag="082" ind1="0" ind2=" "><subfield code="a">548/.8</subfield><subfield code="2">21</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">UQ 2400</subfield><subfield code="0">(DE-625)146493:</subfield><subfield code="2">rvk</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">VE 9350</subfield><subfield code="0">(DE-625)147153:253</subfield><subfield code="2">rvk</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Smyth, Donald M.</subfield><subfield code="e">Verfasser</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">The defect chemistry of metal oxides</subfield><subfield code="c">D. M. Smyth</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="a">New York [u.a.]</subfield><subfield code="b">Oxford Univ. Press</subfield><subfield code="c">2000</subfield></datafield><datafield tag="300" ind1=" " ind2=" "><subfield code="a">X, 294 S.</subfield><subfield code="b">graph. Darst.</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="b">n</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="b">nc</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Crystals</subfield><subfield code="x">Defects</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Metallic oxides</subfield></datafield><datafield tag="650" ind1="0" ind2="7"><subfield code="a">Metalloxide</subfield><subfield code="0">(DE-588)4169619-0</subfield><subfield code="2">gnd</subfield><subfield code="9">rswk-swf</subfield></datafield><datafield tag="650" ind1="0" ind2="7"><subfield code="a">Gitterbaufehler</subfield><subfield code="0">(DE-588)4125030-8</subfield><subfield code="2">gnd</subfield><subfield code="9">rswk-swf</subfield></datafield><datafield tag="689" ind1="0" ind2="0"><subfield code="a">Metalloxide</subfield><subfield code="0">(DE-588)4169619-0</subfield><subfield code="D">s</subfield></datafield><datafield tag="689" ind1="0" ind2="1"><subfield code="a">Gitterbaufehler</subfield><subfield code="0">(DE-588)4125030-8</subfield><subfield code="D">s</subfield></datafield><datafield tag="689" ind1="0" ind2=" "><subfield code="5">DE-604</subfield></datafield><datafield tag="856" ind1="4" ind2="2"><subfield code="m">HEBIS Datenaustausch</subfield><subfield code="q">application/pdf</subfield><subfield code="u">http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009003279&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA</subfield><subfield code="3">Inhaltsverzeichnis</subfield></datafield><datafield tag="999" ind1=" " ind2=" "><subfield code="a">oai:aleph.bib-bvb.de:BVB01-009003279</subfield></datafield></record></collection> |
| id | DE-604.BV013214179 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T18:41:47Z |
| institution | BVB |
| isbn | 0195110145 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-009003279 |
| oclc_num | 43114281 |
| open_access_boolean | |
| owner | DE-703 |
| owner_facet | DE-703 |
| physical | X, 294 S. graph. Darst. |
| publishDate | 2000 |
| publishDateSearch | 2000 |
| publishDateSort | 2000 |
| publisher | Oxford Univ. Press |
| record_format | marc |
| spelling | Smyth, Donald M. Verfasser aut The defect chemistry of metal oxides D. M. Smyth New York [u.a.] Oxford Univ. Press 2000 X, 294 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Crystals Defects Metallic oxides Metalloxide (DE-588)4169619-0 gnd rswk-swf Gitterbaufehler (DE-588)4125030-8 gnd rswk-swf Metalloxide (DE-588)4169619-0 s Gitterbaufehler (DE-588)4125030-8 s DE-604 HEBIS Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009003279&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Smyth, Donald M. The defect chemistry of metal oxides Crystals Defects Metallic oxides Metalloxide (DE-588)4169619-0 gnd Gitterbaufehler (DE-588)4125030-8 gnd |
| subject_GND | (DE-588)4169619-0 (DE-588)4125030-8 |
| title | The defect chemistry of metal oxides |
| title_auth | The defect chemistry of metal oxides |
| title_exact_search | The defect chemistry of metal oxides |
| title_full | The defect chemistry of metal oxides D. M. Smyth |
| title_fullStr | The defect chemistry of metal oxides D. M. Smyth |
| title_full_unstemmed | The defect chemistry of metal oxides D. M. Smyth |
| title_short | The defect chemistry of metal oxides |
| title_sort | the defect chemistry of metal oxides |
| topic | Crystals Defects Metallic oxides Metalloxide (DE-588)4169619-0 gnd Gitterbaufehler (DE-588)4125030-8 gnd |
| topic_facet | Crystals Defects Metallic oxides Metalloxide Gitterbaufehler |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009003279&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT smythdonaldm thedefectchemistryofmetaloxides |