Iron oxides in the laboratory: preparation and characterization
Gespeichert in:
| Hauptverfasser: | , |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Weinheim ; New York ; Chichester ; Brisbane ; Singapore ; Toront
Wiley-VCH
2000
|
| Ausgabe: | 2., completely rev. and extended ed. |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | Literaturverz. S. 165 - 180 |
| Beschreibung: | XVIII, 188 S. Ill., graph. Darst |
| ISBN: | 3527296697 |
Internformat
MARC
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| 245 | 1 | 0 | |a Iron oxides in the laboratory |b preparation and characterization |c U. Schwertmann ; R. M. Cornell |
| 250 | |a 2., completely rev. and extended ed. | ||
| 264 | 1 | |a Weinheim ; New York ; Chichester ; Brisbane ; Singapore ; Toront |b Wiley-VCH |c 2000 | |
| 300 | |a XVIII, 188 S. |b Ill., graph. Darst | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 500 | |a Literaturverz. S. 165 - 180 | ||
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Datensatz im Suchindex
| _version_ | 1804127965996384256 |
|---|---|
| adam_text | Titel: Iron oxides in the laboratory
Autor: Schwertmann, Udo
Jahr: 2000
Contents
Introduction................................................................................1
1 The Iron Oxides..................................................................5
1.1 The Major Iron Oxides ........................................................6
1.2 Less Common or Rare Iron Oxides ......................................10
1.3 Iron Oxides in the Environment............................................13
2 General Preparative Techniques ........................................19
2.1 Quantity of Product..............................................................19
2.2 Treatment after Synthesis......................................................19
2.2.1 Washing ..................................................................19
2.2.2 Drying ....................................................................21
2.2.3 Storage....................................................................21
2.3 Chemical Analysis................................................................22
2.3.1 Total Analysis..........................................................22
2.3.2 Extent of Isomorphous Substitution ..........................23
2.3.3 Impurities................................................................23
2.4 Removal of Iron Oxides from Reaction Vessels......................24
2.5 Purity of Reagents................................................................25
3 IVIethods of Characterization..............................................27
3.1 Introduction ........................................................................27
3.2 Color (A.Schcinost)..............................................................27
3.2.1 Origin of Color........................................................29
3.2.2 Color Measurement..................................................32
3.2.3 Color Systems..........................................................33
3.2.4 Identification of Iron Oxides by Color and Crystal-
Field Bands..............................................................37
VIII Contents
3.3 X-Ray Powder Diffraction.......................... 42
3.4 Microscopy..................................... 42
3.5 Surface Area, Porosity and Fractal Dimensions........... 49
3.6 Acid Oxalate Extraction ........................... 50
3.7 Infrared Spectroscopy ..........................................................51
3.8 Thcrmoanalysis.................................. 53
3.9 Mossbaucr Spectroscopy ......................................................53
4 Synthesis Pathways ............................................................55
4.1 Nuclcation and Crystal Growth ............................................55
4.1.1 Nuclcation ..............................................................55
4.1.2 Crystal Growth ........................................................57
4.1.3 Production of Monodispcrscd Particles......................57
4.1.4 Production of Nanoparticlcs......................................59
4.2 Main Routes of Synthesis ....................................................60
4.2.1 Hydrolysis of Acidic Solutions of Fcin Salts..............60
4.2.2 Transformation of Fcrrihydritc ..................................61
4.2.3 Oxidative Hydrolysis of Fc11 Salts..............................62
4.2.4 Phase Transformations..............................................63
4.2.5 The Gel-Sol Method ................................................63
4.2.6 Hydrothcrmal Precipitation ......................................64
4.2.7 Decomposition of Metal Chelates..............................64
5 Goethite..............................................................................67
5.1 Introduction ........................................................................67
5.2 Pure Goethite from Fcn,Systcms............................................73
5.2.1 Preparation from an Alkaline System (ace. to Bohm,
1925) ......................................................................73
5.2.2 Preparation from an Acid System (ace. to Morup
ctal., 1983)..............................................................74
5.2.3 Preparation From a Cystcine/2-line Ferrihydrite
System (Cornell ct al. 1989) ....................................76
5.3 Pure Goethite from an Fc^Systcm ........................................78
5.4 General Comments ..............................................................83
5.5 Metal (M)-Substitutcd Gocthitcs Fci_xMxOOH......................86
5.5.1 Al-Substitutcd Goethite Fe, _xAlxOOH ......................86
Contents IX
5.5.1.1 Preparation from an Alkaline Fc System..................86
5.5.1.2 Preparation from an FcnSystcm ................................88
5.5.2 Cr-Substitutcd Gocthitc Fe| xCrxOOH ......................89
5.5.3 Mn-Substituted Gocthite Fcj xMnxOOFI....................90
5.5.4 V-Substitutcd Gocthitc Fei_xVxOOH ........................91
6 Lepidocrocite......................................................................93
6.1 Introduction ........................................................................93
6.2 Preparation..........................................................................94
6.3 Other Methods ....................................................................97
7 Feroxyhyte..........................................................................99
7.1 Introduction ........................................................................99
7.2 Preparation..........................................................................99
8 Ferrihydrite........................................................................103
8.1 Introduction ........................................................................103
8.2 6-Line Ferrihydrite ..............................................................104
8.3 2-Line Ferrihydrite ..............................................................105
8.4 Ferrihydritcs with a Range of Crystallinitics..........................110
9 Akaganeite..........................................................................113
9.1 Introduction ........................................................................113
9.2 Preparation by Hydrolysis of an Acidic FcCI3 Solution
(Somatoids) ........................................................................113
9.3 Preparation by Hydrolysis of a Partially Neutralized FcCl3
Solution (Rod-like Crystals)..................................................118
9.4 Si-containing Akaganeite......................................................118
10 Hematite ............................................................................121
10.1 Introduction ........................................................................121
10.2 Preparation by Forced Hydrolysis of Fc1 Salt Solutions .... 122
10.3 Preparation by Transformation of 2-Line Ferrihydrite ............126
10.4 Monodispcrsc Hematites of Different Crystal Shapes ............129
10.5 Other Methods ....................................................................132
X Contents
10.6 Al-substitutcd Hematite........................................................*33
10.7 Coated Hematite..................................................................134
11 Magnetite ..........................................................................135
11.1 Introduction ........................................................................133
11.2 Preparation by Oxidation of a Fc Solution............................135
11.3 Cation-substituted Magnetites ..............................................140
12 Maghemitc..........................................................................141
12.1 Introduction ........................................................................141
12.2 Preparation..........................................................................141
13 Green Rusts........................................................................143
13.1 Introduction ........................................................................143
13.2 Preparation..........................................................................143
14 Schwertmannite..................................................................147
14.1 Introduction ........................................................................147
14.2 Preparation..........................................................................148
15 Coating of Si02 Sand (Quartz; Cristobalite) with Iron
Oxides................................................................................153
15.1 Introduction ........................................................................153
15.2 Preparation..........................................................................154
16 An Experimental Lecture for Students on the Formation
of Iron Oxides ....................................................................157
16.1 Introduction ........................................................................157
16.2 Demonstration; Synthesis oflron Oxides..............................158
16.3 Lecture: Processes by which Iron Oxides Form......................159
16.4 Video: Iron in a Landscape ..................................................162
References..................................................................................165
Acknowledgement ............................................................181
lnd« ..........................................................................................183
|
| any_adam_object | 1 |
| author | Schwertmann, Udo 1927-2016 Cornell, Rochelle M. |
| author_GND | (DE-588)122323114 |
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| dewey-ones | 546 - Inorganic chemistry |
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| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie Agrar-/Forst-/Ernährungs-/Haushaltswissenschaft / Gartenbau Geographie |
| edition | 2., completely rev. and extended ed. |
| format | Book |
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| id | DE-604.BV013211301 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T18:41:44Z |
| institution | BVB |
| isbn | 3527296697 |
| language | English |
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| physical | XVIII, 188 S. Ill., graph. Darst |
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| spelling | Schwertmann, Udo 1927-2016 Verfasser (DE-588)122323114 aut Iron oxides in the laboratory preparation and characterization U. Schwertmann ; R. M. Cornell 2., completely rev. and extended ed. Weinheim ; New York ; Chichester ; Brisbane ; Singapore ; Toront Wiley-VCH 2000 XVIII, 188 S. Ill., graph. Darst txt rdacontent n rdamedia nc rdacarrier Literaturverz. S. 165 - 180 Oxydes de fer ram Iron oxides Bodenkunde (DE-588)4007379-8 gnd rswk-swf Eisenhydroxide (DE-588)4151544-4 gnd rswk-swf Präparative Chemie (DE-588)4047006-4 gnd rswk-swf Eisenoxide (DE-588)4151589-4 gnd rswk-swf Eisenoxide (DE-588)4151589-4 s Präparative Chemie (DE-588)4047006-4 s DE-604 Bodenkunde (DE-588)4007379-8 s Eisenhydroxide (DE-588)4151544-4 s 1\p DE-604 Cornell, Rochelle M. Verfasser aut HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009001093&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | Schwertmann, Udo 1927-2016 Cornell, Rochelle M. Iron oxides in the laboratory preparation and characterization Oxydes de fer ram Iron oxides Bodenkunde (DE-588)4007379-8 gnd Eisenhydroxide (DE-588)4151544-4 gnd Präparative Chemie (DE-588)4047006-4 gnd Eisenoxide (DE-588)4151589-4 gnd |
| subject_GND | (DE-588)4007379-8 (DE-588)4151544-4 (DE-588)4047006-4 (DE-588)4151589-4 |
| title | Iron oxides in the laboratory preparation and characterization |
| title_auth | Iron oxides in the laboratory preparation and characterization |
| title_exact_search | Iron oxides in the laboratory preparation and characterization |
| title_full | Iron oxides in the laboratory preparation and characterization U. Schwertmann ; R. M. Cornell |
| title_fullStr | Iron oxides in the laboratory preparation and characterization U. Schwertmann ; R. M. Cornell |
| title_full_unstemmed | Iron oxides in the laboratory preparation and characterization U. Schwertmann ; R. M. Cornell |
| title_short | Iron oxides in the laboratory |
| title_sort | iron oxides in the laboratory preparation and characterization |
| title_sub | preparation and characterization |
| topic | Oxydes de fer ram Iron oxides Bodenkunde (DE-588)4007379-8 gnd Eisenhydroxide (DE-588)4151544-4 gnd Präparative Chemie (DE-588)4047006-4 gnd Eisenoxide (DE-588)4151589-4 gnd |
| topic_facet | Oxydes de fer Iron oxides Bodenkunde Eisenhydroxide Präparative Chemie Eisenoxide |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009001093&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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