Sequenced reactive barriers for groundwater remediation:
Gespeichert in:
| Format: | Buch |
|---|---|
| Sprache: | English |
| Veröffentlicht: |
Boca Raton [u.a.]
Lewis
2000
|
| Schriftenreihe: | AATDF monographs
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | 730 S. zahlr. graph. Darst., Kt. |
| ISBN: | 1566704464 |
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| 245 | 1 | 0 | |a Sequenced reactive barriers for groundwater remediation |c ed. by Stephanie Fiorenza ... Authors: James F. Barker ... |
| 264 | 1 | |a Boca Raton [u.a.] |b Lewis |c 2000 | |
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Datensatz im Suchindex
| _version_ | 1804127742626627584 |
|---|---|
| adam_text | Titel: Sequenced reactive barriers for groundwater remediation
Autor: Fiorenza, Stephanie
Jahr: 2000
Contents
Parti
Executive Summary.................................................................................................................3
Chapter 1 Introduction and Technology Review
1.1 Rationale for the Current Research.........................................................................................7
1.2 Goals and Approach.................................................................................................................9
1.2.1 Borden Experiment.......................................................................................................9
1.2.2 The Alameda Experiment...........................................................................................13
1.3 Description of the Study Sites...............................................................................................14
1.3.1 Selection of the Site Location: CFB Borden Experiment.........................................14
1.3.2 Background Geochemistry: CFB Borden...................................................................16
1.3.3 Selection of the Site Location: Alameda Experiment................................................17
1.3.4 Background Geochemistry: Alameda.........................................................................17
1.4 Technology Review................................................................................................................17
1.4.1 Granular Iron for Reductive Dechlorination..............................................................17
1.4.2 Nutrient Injection Wall (NIW) for Anaerobic Biodegradation..................................18
1.4.3 ORC™ for Delivering Oxygen to Aquifers...............................................................19
1.4.4 Biosparging for Oxygen Delivery to an Aquifer.......................................................19
1.5 Organization of This Report..................................................................................................20
Chapter 2 Sequential In Situ Treatment Using Granular Iron and ORC™ — Gate 1 CFB
Borden Experiment
2.1 Introduction............................................................................................................................23
2.1.1 Technology Process Description................................................................................23
2.1.2 Coupling of Technologies...........................................................................................25
2.2 Field Demonstration...............................................................................................................26
2.2.1 Experimental Design...................................................................................................26
2.2.2 Groundwater Sampling Program................................................................................29
2.2.3 Results.........................................................................................................................29
2.3 Additional Investigations.......................................................................................................57
2.3.1 pH Tolerance of the ORC™.......................................................................................57
2.3.2 Iron Surface Investigations.........................................................................................60
2.4 Performance Data Evaluation................................................................................................63
2.4.1 Mass Balance and Removal Efficiencies....................................................................63
2.4.2 Design Limitations......................................................................................................66
2.5 Waste Management................................................................................................................68
2.6 Conclusions............................................................................................................................68
2.7 Recommendations for Future Studies....................................................................................69
Chapter 3 Intrinsic Remediation — Gate 2, CFB Borden
3.1 Introduction............................................................................................................................73
3.2 Technology Process Description............................................................................................76
3.3 Field Demonstration...............................................................................................................76
3.3.1 Experimental Set-Up...................................................................................................77
3.3.2 Groundwater Sampling Program................................................................................77
3.4 Results ................................................................................................................................7?
3.4.1 Background Groundwater Chemistry.........................................................................78
3.4.2 Laboratory Microcosm Studies..................................................................................78
3.4.3 Hydraulic Conditions..................................................................................................78
3.4.4 Plume Generation.......................................................................................................82
3.4.5 Redox and General Chemical Conditions..................................................................83
3.4.6 Behavior of Target Organics.......................................................................................83
3.5 Performance Data Evaluation................................................................................................94
3.6 Waste Management................................................................................................................96
3.7 Conclusions............................................................................................................................96
3.8 Recommendations for Future Studies/Needs........................................................................96
Chapter 4 Sequential Anaerobic/Aerobic Bioremediation — Gate 3 CFB Borden
4.1 Technology Process Description..........................................................................................101
4.1.1 Enhanced Anaerobic Bioremediation.......................................................................101
4.1.2 Enhanced Aerobic Bioremediation...........................................................................102
4.1.3 Coupling of Technologies.........................................................................................102
4.2 Field Demonstration.............................................................................................................103
4.2.1 Experimental Design.................................................................................................103
4.2.2 Sampling Program....................................................................................................108
4.3 Results ..............................................................................................................................109
4.3.1 Background Conditions............................................................................................109
4.3.2 Hydraulic Conditions................................................................................................110
4.3.3 Plume Generation.....................................................................................................110
4.3.4 Anaerobic Treatment.................................................................................................112
4.3.5 Aerobic Treatment....................................................................................................120
4.4 Performance Summary.........................................................................................................125
4.4.1 Benzoate and Mineral Salt Nutrient Delivery..........................................................125
4.4.2 Nutrient Pulse Mixing..............................................................................................125
4.4.3 Geochemical Conditions and Microbial Habitat......................................................125
4.4.4 Off-gas Production and Composition.......................................................................126
4.4.5 Organic Compounds.................................................................................................127
4.4.6 Comparison to Intrinsic Performance in Gate 2......................................................129
4.4.7 Adverse Interaction between Technologies and Design Limitations.......................130
4.5 Waste Management..............................................................................................................130
4.6 Conclusions..........................................................................................................................130
4.7 Recommendations for Implementation................................................................................131
Chapter 5 In Situ Sequential Treatment of a Mixed Organic Plume Using Granular Iron
and Oxygen Sparging — NAS Alameda
5.1 Technology Process Description..........................................................................................133
5.1.1 Overview...................................................................................................................133
5.1.2 Technology Description............................................................................................133
5.2 Field Site Description..........................................................................................................137
5.2.1 Site 1 History............................................................................................................137
5.2.2 Site 1 Hydrogeology.................................................................................................137
5.2.3 Demonstration Project Site Conditions....................................................................138
5.3 Field Demonstration.............................................................................................................140
5.3.1 Description and Design............................................................................................140
5.3.2 Construction of the Remedial Gate..........................................................................144
5.3.3 Operational Phases of the Experiment.....................................................................146
5.3.4 Media Sampled.........................................................................................................148
5.3.5 Description of the Chemical Data............................................................................148
5.3.6 Results....................................................................................... 149
5.4 Performance Data Evaluation..............................................................................................168
5.4.1 Granular Iron.............................................................................................................168
5.4.2 Biosparge Zone.........................................................................................................169
5.4.3 Overall Performance.................................................................................................171
5.4.4 Adverse Interaction Between Technologies and Design Limitations......................173
5.5 Waste Management..............................................................................................................173
5.6 Conclusions..........................................................................................................................173
5.7 Recommendations for Future Studies..................................................................................174
Chapter 6 Project Overview and Conclusions
6.1 Review of Objectives...........................................................................................................177
6.2 The Borden Experiment.......................................................................................................177
6.2.1 Comparison of Treatment Methods..........................................................................177
6.2.2 Operational Aspects of Gates 1, 2, and 3................................................................188
6.2.3 Lowest Achieved Concentrations of Contaminants.................................................190
6.2.4 Performance Parameters...........................................................................................191
6.3 The Alameda Experiment....................................................................................................193
6.3.1 System Performance and Performance Parameters..................................................193
6.3.2 Remedial Objectives.................................................................................................196
6.4 Selected Recommendations for Technology Application....................................................197
6.4.1 Passive Delivery of Solutes to Aquifers from Wells................................................197
6.4.2 Granular Iron in Removable Cassettes Coupled to ORC™ for Oxygen Delivery .197
6.4.3 Anaerobic and Aerobic Bioremediation Using An NIW and a Biosparge Wall.....197
6.4.4 Granular Iron Coupled to a Biosparge Reactor.......................................................198
6.5 Concluding Remarks............................................................................................................198
Partii
Executive Summary.......................................................................................................203
Chapter 7 Introduction to the Technology Evaluation
7.1 Background..........................................................................................................................205
7.2 Summary of the Technology demonstration.......................................................................206
7.2.1 The Borden Experiment............................................................................................208
7.2.2 The Alameda Experiment.........................................................................................212
7.2.3 Conclusions of the UW-AATDF Experiments.........................................................216
Chapter 8 Application of a Sequential Treatment system at a Hypothetical Site
8.1 Hypothetical Site..................................................................................................................221
8.1.1 Site Location.............................................................................................................221
8.1.2 Plume Dimensions....................................................................................................222
8.2 General System Configuration.............................................................................................222
8.3 Engineering Design..............................................................................................................225
8.3.1 Treatment Objectives................................................................................................225
8.3.2 Site Characterization.................................................................................................225
8.3.3 Treatability Studies...................................................................................................226
8.3.4 Groundwater Flow Modeling...................................................................................228
8.3.5 Determination of SPRB Dimensions........................................................................229
8.4 Installation............................................................................................................................235
8.4.1 Possible Construction Methods................................................................................235
8.4.2 Construction Sequence.............................................................................................235
8.5 Operations and Maintenance Issues....................................................................................236
Chapter 9 Measurement Procedures and Monitoring Program
9.1 Monitoring Plan — SPRB Case A......................................................................................238
9.2 Full-Scale Monitoring Plan — SPRB Case Â....................................................................243
Chapter 10 Cost and Performance
10.1 Capital Cost Estimates.........................................................................................................245
10.1.1 SPRB Capital Cost Estimate....................................................................................245
10.1.2 P T System Capital Cost Estimate.........................................................................245
10.2 Operations, Maintenance, and Monitoring Costs................................................................248
10.2.1 OM M for SPRB.....................................................................................................249
10.2.2 OM M for P T.......................................................................................................249
10.3 Comparison of SPRB Costs to P T Costs.........................................................................249
10.3.1 Cumulative Costs......................................................................................................249
10.3.2 Net Present Value......................................................................................................252
10.4 Factors Affecting Cost Competitiveness of In Situ Treatment...........................................254
10.4.1 Effluent Criteria........................................................................................................254
10.4.2 Construction Methods...............................................................................................255
10.4.3 Dimensions of Treatment Zone for Chlorinated Solvent Removal.........................255
10.4.4 Different Configurations for the Biosparge Zone....................................................256
10.4.5 Effect of Changing Design Criteria on P T Costs.................................................256
10.5 Summary..............................................................................................................................256
Chapter 11 Applicability of SPRB Technology
11.1 Target Chemicals..................................................................................................................259
11.2 Treatment Configurations.....................................................................................................262
11.3 Limitations...........................................................................................................................265
Appendices
Appendix 1 Borden Site Description.....................................................................................269
Appendix 2 Chronology of Borden Activities......................................................................277
Appendix 3 Laboratory Analytical Procedures...................................................................283
Appendix 4 Groundwater Sampling and Field Analysis Methods (Borden)...................333
Appendix 5 Quality Assurance/Quality Control Procedures and Results........................345
Appendix 6 Background Sampling Results (Borden).........................................................363
Appendix 7 Main Tracer Test................................................................................................369
Appendix 8 Water Level/Head Measurements and Potentiometric Surface Plots..........381
Appendix 9 Source Well Evaluation.....................................................................................393
Appendix 10 Aboveground Treatment System Design — Borden......................................413
Appendix 11 Laboratory Microcosm Experiment................................................................417
Appendix 12 Granular Iron Performance Analyses..............................................................449
Appendix 13 Assessment of Bioremediation Efforts in Gate 1............................................463
Appendix 14 Leak Around Cassettes (Gate 1).......................................................................491
Appendix 15 Iron and ORC™ Incompatibility.....................................................................507
Appendix 16 Surface Investigations of Granular Iron.........................................................515
Appendix 17 Gate 3 Modelling - Design Of Nutrient Pulse Delivery.................................525
Appendix 18 Nutrient Pulse Tracer Test................................................................................537
Appendix 19 Redox Status of the Anaerobic Zone of Gate 3..............................................561
Appendix 20 Gate 3 Biosparge Zone Assessment..................................................................575
Appendix 21 Benzoate-Conductivity Comparison................................................................589
Appendix 22 Laboratory Sparging Experiments..................................................................593
Appendix 23 Gate 3 Nutrient Concentrate............................................................................597
Appendix 24 Breakthrough Curve Analysis, Velocity Estimation
and Concentration Averaging...........................................................................601
Appendix 25 Alameda Timeline..............................................................................................607
Appendix 26 Sampling Methods — Alameda........................................................................615
Appendix 27 Tracer Test and In Situ Permeable Flow Sensors —Alameda.....................623
Appendix 28 Oxygen and Carbon Dioxide Sparging Protocol for
the Biosparge Zone............................................................................................637
Appendix 29 Equations Used to Calculate Degradation Rates for Compounds
at Alameda NAS.................................................................................................649
Appendix 30 Plots of Contaminant Distribution in the Remedial Gate
For OP2, Alameda..............................................................................................665
Appendix 31 Aboveground Treatment of Groundwater Extracted
from Remedial Gate, Alameda.........................................................................677
Appendix 32 Numerical Simulations Alameda......................................................................679
Appendix 33 Technology Evaluation — Modeling for Hypothetical Site...........................685
Appendix 34 Technology Evaluation — Calculations For BTEX Degradation.................695
Appendix 35 Supplemental Information on Pump-and-Treat System Costs.....................699
Index..............................................................................................................................................717
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| spelling | Sequenced reactive barriers for groundwater remediation ed. by Stephanie Fiorenza ... Authors: James F. Barker ... Boca Raton [u.a.] Lewis 2000 730 S. zahlr. graph. Darst., Kt. txt rdacontent n rdamedia nc rdacarrier AATDF monographs Eaux souterraines - Épuration ram Membranes (technologie) ram Groundwater Purification Membranes (Technology) Gewässerreinigung (DE-588)4139781-2 gnd rswk-swf Grundwasser (DE-588)4022369-3 gnd rswk-swf Grundwasser (DE-588)4022369-3 s Gewässerreinigung (DE-588)4139781-2 s DE-604 Fiorenza, Stephanie Sonstige oth Barker, James F. Sonstige oth Advanced Applied Technology Demonstration Facility Sonstige (DE-588)1303178-8 oth HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=008887856&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Sequenced reactive barriers for groundwater remediation Eaux souterraines - Épuration ram Membranes (technologie) ram Groundwater Purification Membranes (Technology) Gewässerreinigung (DE-588)4139781-2 gnd Grundwasser (DE-588)4022369-3 gnd |
| subject_GND | (DE-588)4139781-2 (DE-588)4022369-3 |
| title | Sequenced reactive barriers for groundwater remediation |
| title_auth | Sequenced reactive barriers for groundwater remediation |
| title_exact_search | Sequenced reactive barriers for groundwater remediation |
| title_full | Sequenced reactive barriers for groundwater remediation ed. by Stephanie Fiorenza ... Authors: James F. Barker ... |
| title_fullStr | Sequenced reactive barriers for groundwater remediation ed. by Stephanie Fiorenza ... Authors: James F. Barker ... |
| title_full_unstemmed | Sequenced reactive barriers for groundwater remediation ed. by Stephanie Fiorenza ... Authors: James F. Barker ... |
| title_short | Sequenced reactive barriers for groundwater remediation |
| title_sort | sequenced reactive barriers for groundwater remediation |
| topic | Eaux souterraines - Épuration ram Membranes (technologie) ram Groundwater Purification Membranes (Technology) Gewässerreinigung (DE-588)4139781-2 gnd Grundwasser (DE-588)4022369-3 gnd |
| topic_facet | Eaux souterraines - Épuration Membranes (technologie) Groundwater Purification Membranes (Technology) Gewässerreinigung Grundwasser |
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