Solubility and solubilization in aqueous media:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Washington, DC
American Chemical Soc. [u.a.]
1999
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XVI, 464 S. graph. Darst. |
| ISBN: | 0841235767 |
Internformat
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| 650 | 7 | |a Solubilisation |2 ram | |
| 650 | 7 | |a Solucoes (fisico-quimica) |2 larpcal | |
| 650 | 7 | |a Solutions aqueuses (chimie) |2 ram | |
| 650 | 4 | |a Organic compounds |x Solubility | |
| 650 | 4 | |a Solution (Chemistry) | |
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Datensatz im Suchindex
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|---|---|
| adam_text | SOLUBILITY AND SOLUBILIZATION IN AQUEOUS MEDIA SAMUEL H. YALKOWSKY
AMERICAN CHEMICAL SOCIETY OXFORD UNIVERSITY PRESS WASHINGTON, D.C. NEW
YORK OXFORD 1999 CONTENTS 1 MIXING AND PROPERTIES OF MIXTURES 3
THERMODYNAMICS OF MIXING 3 ENTHALPY OF MIXING 3 VOLUME OF MIXING 4
ENERGY OF MIXING 4 ENTROPY OF MIXING 5 FREE ENERGY OF MIXING 7
DESCRIPTION OF MIXTURES 8 PHASE DIAGRAMS 8 IDEAL MIXTURES 8 REAL
MIXTURES 10 VAPOR PRESSURE 10 IDEAL VAPOR PRESSURE 10 HENRY S LAW AND
RAOULT S LAW 11 COLLIGATIVE PROPERTIES 12 VAPOR PRESSURE LOWERING 12
OSMOTIC PRESSURE 13 FREEZING POINT DEPRESSION 14 BOILING POINT ELEVATION
15 OTHER PROPERTIES OF MIXTURES 15 APPENDIX 16 DERIVATION OF THE
CRYOSCOPIC EQUATION 16 DERIVATION OF THE EBULLIOSCOPIC EQUATION 18
SUMMARY 19 X CONTENTS 2 CHARACTERIZATION OF SOLUTIONS 20 IDEAL SOLUTIONS
20 IDEAL ENTHALPY OF MIXING 21 IDEAL VOLUME OF MIXING 21 IDEAL ENTROPY
OF MIXING 21 IDEAL FREE ENERGY OF MIXING 23 VAPOR PRESSURE 23 ATHERMAL
NONIDEAL SOLUTIONS 24 ENTHALPY OF MIXING 24 VOLUME OF MIXING 24 ENTROPY
OF MIXING 24 FREE ENERGY OF MIXING 26 VAPOR PRESSURE 27 REGULAR
SOLUTIONS * WEAKLY EXOTHERMIC 27 ENTHALPY OF MIXING 28 VOLUME OF MIXING
28 ENTROPY OF MIXING 28 FREE ENERGY OF MIXING 29 VAPOR PRESSURE 29
REGULAR SOLUTIONS * WEAKLY ENDOTHERMIC 29 ENTHALPY OF MIXING 30 VOLUME
OF MIXING 33 ENTROPY OF MIXING 33 FREE ENERGY OF MIXING 34 VAPOR
PRESSURE 34 SOLVATED SOLUTIONS * EXOTHERMIC 34 ENTHALPY OF MIXING 35
VOLUME OF MIXING 35 ENTROPY OF MIXING 35 FREE ENERGY OF MIXING 36 VAPOR
PRESSURE OF MIXING 36 SINGLE-COMPONENT, SELF-ASSOCIATED SOLUTIONS *
ENDOTHERMIC 37 ENTHALPY OF MIXING 37 VOLUME OF MIXING 37 ENTROPY OF
MIXING 38 FREE ENERGY OF MIXING 38 VAPOR PRESSURE 38 SOLVATED,
SELF-ASSOCIATED SOLUTIONS 39 ENTHALPY OF MIXING 39 VOLUME OF MIXING 40
ENTROPY OF MIXING 40 FREE ENERGY OF MIXING 40 AQUEOUS SOLUTIONS 40
ENERGY AND ENTHALPY OF MIXING 41 AQUEOUS SOLUTION MODEL 41 CONTENTS
VOLUME OF MIXING 43 ENTROPY OF MIXING 44 FREE ENERGY OF MIXING 44 VAPOR
PRESSURE 4 5 SUMMARY 45 3 SOLUBILITY AND PARTIAL MISCIBILITY 49 PARTIAL
MISCIBILITY OF LIQUIDS 49 EFFECT OF TEMPERATURE 5 1 EFFECT OF PRESSURE
52 CRITICAL SOLUTION TEMPERATURES 52 SOLUTIONS THAT HAVE AN UPPER
CRITICAL SOLUTION TEMPERATURE 53 SOLUTIONS THAT HAVE A LOWER CRITICAL
SOLUTION TEMPERATURE 53 SOLUTIONS THAT HAVE BOTH UPPER AND LOWER
CRITICAL SOLUTION TEMPERATURES 54 CRITICAL SOLUTION TEMPERATURE OF IDEAL
SOLUTIONS 54 CRITICAL SOLUTION TEMPERATURE OF REGULAR SOLUTIONS 54
CRITICAL SOLUTION TEMPERATURES OF AQUEOUS SOLUTIONS 56 SOLUBILITY AND
ACTIVITY COEFFICIENT OF LIQUID SOLUTES 56 IDEAL SOLUTION SOLUBILITY OF
LIQUIDS 57 REGULAR SOLUTION SOLUBILITY OF LIQUIDS 57 AQUEOUS SOLUBILITY
OF LIQUIDS 58 SOLUBILITY OF CRYSTALLINE SOLUTES 61 IDEAL SOLUTION
SOLUBILITY OF A CRYSTALLINE SOLUTE 61 REGULAR SOLUTION SOLUBILITY OF A
CRYSTALLINE SOLUTE 66 AQUEOUS SOLUTION SOLUBILITY OF A CRYSTALLINE
SOLUTE 67 DEPENDENCE OF SOLUBILITY ON GAS PROPERTIES 69 ALTERATION OF
AQUEOUS SOLUBILITY 71 TEMPERATURE AND SOLUTION COMPOSITION 71
TEMPERATURE 71 SOLUTION COMPOSITION 73 SUMMARY 76 4 PHYSICAL
MODIFICATION OF THE SOLUTE 81 APPARENT SOLUBILITY AND DISSOLUTION RATE
81 IDEAL SOLUBILITY 81 APPARENT SOLUBILITY 82 DISSOLUTION RATE 83
PARTICLE SIZE AND CRYSTAL QUALITY 86 APPARENT SOLUBILITY AND PARTICLE
SIZE 86 PARTICLE SIZE REDUCTION AND CRYSTAL QUALITY 87 DISSOLUTION,
PARTICLE SIZE, AND CRYSTAL QUALITY OF POWDERS CONTENTS RIPENING AND
CAKING 89 AMORPHIC SOLID MODIFICATION 91 APPARENT SOLUBILITY OF AMORPHS
92 DISSOLUTION OF AMORPHS 94 CRYSTAL FORM MODIFICATION 95 APPARENT
SOLUBILITY OF POLYMORPHS 95 DISSOLUTION RATE OF POLYMORPHS 101 CRYSTAL
HYDRATE FORMATION 101 APPARENT SOLUBILITY OF HYDRATES 102 DISSOLUTION OF
HYDRATES 103 CRYSTAL DESOLVATES 104 COMPLEX SYSTEMS 105 FACTORS
AFFECTING REVERSION 107 TEMPERATURE 107 SOLUTION COMPOSITION 10 8 VAPOR
PRESSURE 109 HUMIDITY 110 SUMMARY 110 5 SOLUBILIZATION BY PH CONTROL 116
BUFFERS 116 PH OF SIMPLE BUFFER SYSTEMS 117 BUFFERING CAPACITY 118
COMMON BUFFERS 119 DEPENDENCE OF SOLUBILITY ON PH 119 SOLUBILIZATION OF
WEAK MONOVALENT ACIDS AND BASES 120 SOLUBILITY PRODUCT AS A LIMITATION
TO SOLUBILIZATION 121 SOLUBILIZATION OF DIVALENT AND TRIVALENT ACIDS AND
BASES 124 SOLUBILIZATION OF ZWITTERIONIC WEAK ELECTROLYTES 125
SOLUBILIZATION OF SELF-ASSOCIATING COMPOUNDS ML DEPENDENCE OF PK A ON
SOLUTE STRUCTURE 127 ESTIMATION OFPK A VALUES FOR WEAK ACIDS 129
ESTIMATION OFPK A VALUES FOR WEAK BASES 131 DEPENDENCE OF CHARGE ON PH
AND PK A 133 STATISTICAL EFFECTS ON DISSOCIATION 133 SUBSTITUENT EFFECTS
ON PK A VALUES FOR ALIPHATIC SOLUTES 133 SUBSTITUENT EFFECTS ON PK A
VALUES FOR AROMATIC SOLUTES 13 9 HAMMETT AND TAFT RELATIONSHIPS 142
APPLICATION TO COMPLEX MOLECULES 144 EFFECTS OF SELF-ASSOCIATION ON
DISSOCIATION CONSTANTS 152 TEMPERATURE AND SOLUTION COMPOSITION 154
TEMPERATURE 154 SOLUTION COMPOSITION 154 CARBON DIOXIDE 159 CONTENTS
SODIUM IONS 159 PHARMACEUTICAL ASPECTS OF PH SOLUBILIZATION 159
PRECIPITATION OF PH SOLUBILIZED SOLUTES 160 DISSOLUTION RATE AND PH 169
PHYSIOLOGICAL EFFECTS OF PH AND BUFFERS 170 CHEMICAL STABILITY OF PH
SOLUBILIZED SOLUTES 170 BUFFER SELECTION 175 SUMMARY 176 6
SOLUBILIZATION BY COSOLVENTS 180 PROPERTIES OF PURE COSOLVENTS 180
STRUCTURE OF COSOLVENTS 180 CHARACTERIZATION OF COSOLVENT POLARITY 181
SOLUBILITY IN PURE SOLVENTS 182 SOLUBILIZATION BY COSOLVENTS 184
PROPERTIES OF COSOLVENT-WATER MIXTURES 185 CHARACTERIZATION OF SOLUTES
185 THE LOG LINEAR MODEL 18 8 OTHER MODELS FOR SOLUBILIZATION BY
COSOLVENTS 191 DEPENDENCE OF SOLUBILIZATION ON COSOLVENT 193
SOLUBILIZATION BY SINGLE COSOLVENTS 193 DEVIATION FROM THE LOG LINEAR
EQUATION 200 SOLUBILIZATION BY MULTIPLE WATER MISCIBLE COSOLVENTS 204
DEPENDENCE OF SOLUBILIZATION ON SOLUTE STRUCTURE 207 SOLUBILIZATION OF
ORGANIC COMPOUNDS BY ETHANOL 207 SOLUBILIZATION BY SPECIFIC COSOLVENTS
217 OTHER AGENTS THAT NONSPECIFICALLY AFFECT SOLUBILITY 220 TEMPERATURE
AND SOLUTION COMPOSITION 221 TEMPERATURE 221 SOLUTION COMPOSITION 222
PHARMACEUTICAL ASPECTS OF SOLUBILIZATION BY COSOLVENTS 224 DILUTION OF
COSOHENT-SOLUBILIZED SOLUTES 224 PHYSIOLOGICAL EFFECTS OF COSOLVENTS 226
STABILITY OF COSOHENT-SOLUBILIZED SOLUTES 228 COSOLVENT SELECTION 230
SUMMARY 230 7 SOLUBILIZATION BY SURFACTANTS 236 CHEMICAL STRUCTURE OF
SURFACTANTS 236 CLASSICAL (LONG-CHAIN) SURFACTANTS 238 NONCLASSICAL
SURFACTANTS 241 PROPERTIES OF MICELLES 242 XVI CONTENTS PROBLEMS
ASSOCIATED WITH SOLUBILIZATION AND SOLUBILIZED SOLUTES 431 CHEMICAL AND
PHYSICAL PROBLEMS 431 BIOLOGICAL PROBLEMS 433 STRATEGY FOR
SOLUBILIZATION 435 INDEX 441
|
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| isbn | 0841235767 |
| language | English |
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| physical | XVI, 464 S. graph. Darst. |
| publishDate | 1999 |
| publishDateSearch | 1999 |
| publishDateSort | 1999 |
| publisher | American Chemical Soc. [u.a.] |
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| spelling | Yalkowsky, Samuel H. Verfasser aut Solubility and solubilization in aqueous media Samuel H. Yalkowsky Washington, DC American Chemical Soc. [u.a.] 1999 XVI, 464 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Composés organiques - Solubilité ram Quimica farmaceutica larpcal Solubilisation ram Solucoes (fisico-quimica) larpcal Solutions aqueuses (chimie) ram Organic compounds Solubility Solution (Chemistry) Wässrige Lösung (DE-588)4124928-8 gnd rswk-swf Lösung Chemie (DE-588)4036159-7 gnd rswk-swf Lösung Chemie (DE-588)4036159-7 s DE-604 Wässrige Lösung (DE-588)4124928-8 s GBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=008881047&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Yalkowsky, Samuel H. Solubility and solubilization in aqueous media Composés organiques - Solubilité ram Quimica farmaceutica larpcal Solubilisation ram Solucoes (fisico-quimica) larpcal Solutions aqueuses (chimie) ram Organic compounds Solubility Solution (Chemistry) Wässrige Lösung (DE-588)4124928-8 gnd Lösung Chemie (DE-588)4036159-7 gnd |
| subject_GND | (DE-588)4124928-8 (DE-588)4036159-7 |
| title | Solubility and solubilization in aqueous media |
| title_auth | Solubility and solubilization in aqueous media |
| title_exact_search | Solubility and solubilization in aqueous media |
| title_full | Solubility and solubilization in aqueous media Samuel H. Yalkowsky |
| title_fullStr | Solubility and solubilization in aqueous media Samuel H. Yalkowsky |
| title_full_unstemmed | Solubility and solubilization in aqueous media Samuel H. Yalkowsky |
| title_short | Solubility and solubilization in aqueous media |
| title_sort | solubility and solubilization in aqueous media |
| topic | Composés organiques - Solubilité ram Quimica farmaceutica larpcal Solubilisation ram Solucoes (fisico-quimica) larpcal Solutions aqueuses (chimie) ram Organic compounds Solubility Solution (Chemistry) Wässrige Lösung (DE-588)4124928-8 gnd Lösung Chemie (DE-588)4036159-7 gnd |
| topic_facet | Composés organiques - Solubilité Quimica farmaceutica Solubilisation Solucoes (fisico-quimica) Solutions aqueuses (chimie) Organic compounds Solubility Solution (Chemistry) Wässrige Lösung Lösung Chemie |
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