Free radical bulk copolymerization kinetics of acrylate and methacrylate monomers studied by pulsed laser techniques:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Göttingen
Cuvillier
1999
|
| Ausgabe: | 1. Aufl. |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | Zugl.: Göttingen, Univ., Diss., 1999 |
| Beschreibung: | III, 194 S. graph. Darst. : 21 cm |
| ISBN: | 3897127059 |
Internformat
MARC
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| 001 | BV012932103 | ||
| 003 | DE-604 | ||
| 005 | 20001206 | ||
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| 008 | 000111s1999 gw d||| m||| 00||| eng d | ||
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| 020 | |a 3897127059 |c kart. : DM 78.00, sfr 78.00, S 546.00 |9 3-89712-705-9 | ||
| 035 | |a (OCoLC)45539621 | ||
| 035 | |a (DE-599)BVBBV012932103 | ||
| 040 | |a DE-604 |b ger |e rakddb | ||
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| 100 | 1 | |a Barner-Kowollik, Christopher |d 1973- |e Verfasser |0 (DE-588)121637514 |4 aut | |
| 245 | 1 | 0 | |a Free radical bulk copolymerization kinetics of acrylate and methacrylate monomers studied by pulsed laser techniques |c vorgelegt von Christopher Kowollik |
| 250 | |a 1. Aufl. | ||
| 264 | 1 | |a Göttingen |b Cuvillier |c 1999 | |
| 300 | |a III, 194 S. |b graph. Darst. : 21 cm | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 500 | |a Zugl.: Göttingen, Univ., Diss., 1999 | ||
| 650 | 0 | 7 | |a Methacrylsäureester |0 (DE-588)4169673-6 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Radikalische Polymerisation |0 (DE-588)4325747-1 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Acrylate |0 (DE-588)4000412-0 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Reaktionskinetik |0 (DE-588)4048655-2 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Copolymerisation |0 (DE-588)4070106-2 |2 gnd |9 rswk-swf |
| 655 | 7 | |0 (DE-588)4113937-9 |a Hochschulschrift |2 gnd-content | |
| 689 | 0 | 0 | |a Acrylate |0 (DE-588)4000412-0 |D s |
| 689 | 0 | 1 | |a Methacrylsäureester |0 (DE-588)4169673-6 |D s |
| 689 | 0 | 2 | |a Copolymerisation |0 (DE-588)4070106-2 |D s |
| 689 | 0 | 3 | |a Radikalische Polymerisation |0 (DE-588)4325747-1 |D s |
| 689 | 0 | 4 | |a Reaktionskinetik |0 (DE-588)4048655-2 |D s |
| 689 | 0 | |5 DE-604 | |
| 856 | 4 | 2 | |m DNB Datenaustausch |q application/pdf |u http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=008805663&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |3 Inhaltsverzeichnis |
| 943 | 1 | |a oai:aleph.bib-bvb.de:BVB01-008805663 | |
Datensatz im Suchindex
| _version_ | 1807772956231729152 |
|---|---|
| adam_text |
T
ABLE
OF
C
ONTENTS
1.
A
BSTRACT
1
2.
I
NTRODUCTION
3
2.1
REFERENCES
8
3.
E
XPERIMENTAL
11
3.1
APPARATUS
11
3.1.1
OPTICAL
HIGH
PRESSURE
CELL
11
3.1.2
OPTICAL
INTERNAL
CELL
13
3.1.3
HEATING
AND
TEMPERATURE
CONTROL
13
3.1.4
PRESSURE
GENERATION
AND
CONTROL
14
3.1.5
FT-IR/NIR
SPECTROMETER
14
3.1.6
UV
SPECTROMETER
15
3.2
THE
SP-PLP
TECHNIQUE
15
3.2.1
DETAILS
ABOUT
THE
SET-UP
AND
ELECTRONICS
15
3.2.2
SPECTROSCOPIC
DETAILS:
THE
SP-PLP
TECHNIQUE
IN
COPOLYMERIZATIONS
18
3.2.3
SLOWLY
PROPAGATING
MONOMERS
-
EXPERIMENTAL
LIMITS
23
3.2.4
ON
THE
SELECTION
OF
EXPERIMENTAL
CONDITIONS
24
3.2.5
A
TYPICAL
SP-PLP
EXPERIMENT
25
3.3
THE
PLP-SEC
TECHNIQUE
25
3.4
DETERMINATION
OF
MH-PARAMETERS
FOR
VARIOUS
COPOLYMERS
26
3.5
THE
'H-NMR
TECHNIQUE
27
3.6
THE
ESR-SEC
TECHNIQUE
27
3.7
SUBSTANCES
USED
28
3.8
ON
A
STRATEGY
FOR
K
T
DETERMINATION
BY
THE
COMBINATION
OF
DIFFERENT
TECHNIQUES
31
3.9
CONSIDERATION
OF
ERRORS
32
3.10
REFERENCES
34
4.
O
N
THE
I
NTERPRETATION
OF
SP-PLP
S
IGNALS
35
4.1
IDEAL POLYMERIZATION
KINETICS
35
4.2
SP-PLP
SIGNALS
AT
DIFFERENT
LEVELS
OF
INITIAL
FREE
RADICAL
CONCENTRATION
37
4.3
PHOTOINITIATOR
DECOMPOSITION
45
4.4
A
KINETIC
SCHEME
FOR
DMPA
INITIATED
SP-PLP
EXPERIMENTS
48
4.5
DERIVING
"TRUE"
BIMOLECULAR
TERMINATION
RATE
COEFFICIENTS
64
4.6
THE
CHAIN-LENGTH
DEPENDENCE
OF
KT
72
4.7
CONCLUSIONS
76
4.8
REFERENCES
81
5.
P
ROPAGATION
83
5.1
PROPAGATION
IN
HOMOPOLYMERIZATIONS
83
5.1.1
ESR-SEC
EXPERIMENTS
ON
DODECYL
METHACRYLATE
(DMA)
85
5.1.2
CRITERIA
FOR
RELIABLE
ESR-SEC
EXPERIMENTS
94
5.2
PROPAGATION
IN
COPOLYMERIZATIONS
95
5.2.1
THEORETICAL
BACKGROUND
95
5.2.2
DETERMINATION
OF
COPOLYMER
COMPOSITION
BY
'H-NMR
SPECTROSCOPY
100
5.2.3
MODELING
OF
THE
PROPAGATION
RATE
COEFFICIENT
BY
PUE
MODELS
104
METHYL
ACRYLATE/BUTYL
ACRYLATE
METHYL
ACRYLATE
/DODECYL
ACRYLATE
BUTYL
ACRYLATE
/
DODECYL
ACRYLATE
5.2.4
EXPERIMENTAL
RESULTS
AND
DATA
ANALYSIS
BY
PUE
MODELS
106
BUTYL
ACRYLATE
/METHYL
METHACRYLATE
108
DODECYL
ACRYLATE/DODECYL
METHACRYLATE
112
DODECYL
ACRYLATE/METHYL
METHACRYLATE
119
METHYL
ACRYLATE
/DODECYL
METHACRYLATE
119
5.3
PROPAGATION
IN
TERPOLYMERIZATIONS
125
5.3.1
MODELING
OF
PROPAGATION
RATE
COEFFICIENTS
IN
TERPOLYMERIZATIONS
BASED
ON
BINARY
COPOLYMERIZATION
DATA
126
METHYL
ACRYLATE
/
BUTYL
ACRYLATE
/
DODECYL
ACRYLATE
METHYL
METHACRYLATE
/
BUTYL
METHACRYLATE
/DODECYL
METHACRYLATE
5.4
REFERENCES
127
6.
T
ERMINATION
131
6.1
TERMINATION
KINETICS
IN
HOMOPOLYMERIZATIONS
131
6.1.1
THE
TEMPERATURE
AND
PRESSURE
DEPENDENCE
OF
K
T
(MMA)
132
6.1.2
THE
TEMPERATURE
AND
PRESSURE
DEPENDENCE
OF
^T(STYRENE)
138
6.2
TERMINATION
IN
BINARY
COPOLYMERIZATIONS
142
6.2.1
THEORETICAL
BACKGROUND
143
6.2.2
EXPERIMENTAL
RESULTS
AND
DATA
ANALYSIS
BY
DIFFERENT
MODELS
146
ACRYLATE
/ACRYLATE
COPOLYMERIZATIONS
149
(MA/DA,
MA/BA,
BA/DA)
METHACRYLATE
/
METHACRYLATE
COPOLYMERIZATIONS
158
(MMA/BMA,
MMA/DMA)
ACRYLATE
/
METHACRYLATE
COPOLYMERIZATIONS
160
(DA/DMA,
BA/MMA)
160
(MA/DMA,
DA/MMA)
167
6.2.3
CONCLUSIONS
171
6.3
TERMINATION
IN
TERPOLYMERIZATIONS
175
6.3.1
EXPERIMENTAL
RESULTS
175
METHYL
METHACRYLATE/BUTYL
METHACRYLATE/DODECYL
METHACRYLATE
175
METHYL
ACRYLATE/BUTYL
ACRYLATE
/DODECYL
ACRYLATE
179
6.3.2
CONCLUSIONS
182
6.4
REFERENCES
183
7.
C
LOSING
R
EMARKS
186
8.
A
PPENDIX
188
8.1
ABBREVIATIONS
188
8.2
PROGRAM
FOR
THE
CALCULATION
OF
"TRUE"
OVERALL
MONOMER
CONVERSIONS
FROMFT-NIR
SPECTRA
191 |
| any_adam_object | 1 |
| author | Barner-Kowollik, Christopher 1973- |
| author_GND | (DE-588)121637514 |
| author_facet | Barner-Kowollik, Christopher 1973- |
| author_role | aut |
| author_sort | Barner-Kowollik, Christopher 1973- |
| author_variant | c b k cbk |
| building | Verbundindex |
| bvnumber | BV012932103 |
| ctrlnum | (OCoLC)45539621 (DE-599)BVBBV012932103 |
| edition | 1. Aufl. |
| format | Book |
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| genre | (DE-588)4113937-9 Hochschulschrift gnd-content |
| genre_facet | Hochschulschrift |
| id | DE-604.BV012932103 |
| illustrated | Illustrated |
| indexdate | 2024-08-19T00:17:17Z |
| institution | BVB |
| isbn | 3897127059 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-008805663 |
| oclc_num | 45539621 |
| open_access_boolean | |
| owner | DE-703 |
| owner_facet | DE-703 |
| physical | III, 194 S. graph. Darst. : 21 cm |
| publishDate | 1999 |
| publishDateSearch | 1999 |
| publishDateSort | 1999 |
| publisher | Cuvillier |
| record_format | marc |
| spelling | Barner-Kowollik, Christopher 1973- Verfasser (DE-588)121637514 aut Free radical bulk copolymerization kinetics of acrylate and methacrylate monomers studied by pulsed laser techniques vorgelegt von Christopher Kowollik 1. Aufl. Göttingen Cuvillier 1999 III, 194 S. graph. Darst. : 21 cm txt rdacontent n rdamedia nc rdacarrier Zugl.: Göttingen, Univ., Diss., 1999 Methacrylsäureester (DE-588)4169673-6 gnd rswk-swf Radikalische Polymerisation (DE-588)4325747-1 gnd rswk-swf Acrylate (DE-588)4000412-0 gnd rswk-swf Reaktionskinetik (DE-588)4048655-2 gnd rswk-swf Copolymerisation (DE-588)4070106-2 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Acrylate (DE-588)4000412-0 s Methacrylsäureester (DE-588)4169673-6 s Copolymerisation (DE-588)4070106-2 s Radikalische Polymerisation (DE-588)4325747-1 s Reaktionskinetik (DE-588)4048655-2 s DE-604 DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=008805663&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Barner-Kowollik, Christopher 1973- Free radical bulk copolymerization kinetics of acrylate and methacrylate monomers studied by pulsed laser techniques Methacrylsäureester (DE-588)4169673-6 gnd Radikalische Polymerisation (DE-588)4325747-1 gnd Acrylate (DE-588)4000412-0 gnd Reaktionskinetik (DE-588)4048655-2 gnd Copolymerisation (DE-588)4070106-2 gnd |
| subject_GND | (DE-588)4169673-6 (DE-588)4325747-1 (DE-588)4000412-0 (DE-588)4048655-2 (DE-588)4070106-2 (DE-588)4113937-9 |
| title | Free radical bulk copolymerization kinetics of acrylate and methacrylate monomers studied by pulsed laser techniques |
| title_auth | Free radical bulk copolymerization kinetics of acrylate and methacrylate monomers studied by pulsed laser techniques |
| title_exact_search | Free radical bulk copolymerization kinetics of acrylate and methacrylate monomers studied by pulsed laser techniques |
| title_full | Free radical bulk copolymerization kinetics of acrylate and methacrylate monomers studied by pulsed laser techniques vorgelegt von Christopher Kowollik |
| title_fullStr | Free radical bulk copolymerization kinetics of acrylate and methacrylate monomers studied by pulsed laser techniques vorgelegt von Christopher Kowollik |
| title_full_unstemmed | Free radical bulk copolymerization kinetics of acrylate and methacrylate monomers studied by pulsed laser techniques vorgelegt von Christopher Kowollik |
| title_short | Free radical bulk copolymerization kinetics of acrylate and methacrylate monomers studied by pulsed laser techniques |
| title_sort | free radical bulk copolymerization kinetics of acrylate and methacrylate monomers studied by pulsed laser techniques |
| topic | Methacrylsäureester (DE-588)4169673-6 gnd Radikalische Polymerisation (DE-588)4325747-1 gnd Acrylate (DE-588)4000412-0 gnd Reaktionskinetik (DE-588)4048655-2 gnd Copolymerisation (DE-588)4070106-2 gnd |
| topic_facet | Methacrylsäureester Radikalische Polymerisation Acrylate Reaktionskinetik Copolymerisation Hochschulschrift |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=008805663&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT barnerkowollikchristopher freeradicalbulkcopolymerizationkineticsofacrylateandmethacrylatemonomersstudiedbypulsedlasertechniques |