Chemical processes in marine environments: with 56 tables
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Format: | Buch |
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Sprache: | English |
Veröffentlicht: |
Berlin [u.a.]
Springer
2000
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Schriftenreihe: | Environmental science
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Schlagworte: | |
Online-Zugang: | Inhaltsverzeichnis |
Beschreibung: | Literaturangaben |
Beschreibung: | XVIII, 441 S. graph. Darst. : 24 cm |
ISBN: | 3540666184 |
Internformat
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Datensatz im Suchindex
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adam_text | Titel: Chemical processes in marine environments
Autor: Gianguzza, Antonio
Jahr: 2000
Contents
Introduction - Environmental Analytical Chemistry as a Tool
for Studying Chemical Processes in Marine Environments 1
Introduction 1
Biogeochemical Cycles I
Metals and Organometallic Compounds 2
References 4
Part I Biogeochemical Cycles 7
1 The Carbonate System in Marine Environments 9
1.1 Introduction 9
1.2 Equilibria of Carbonate Species 14
1.3 Parameters of the C02 System in Sea Water 16
1.4 Distribution of Carbonate Species 21
i-4-i Pco2 21
1.4.2 pH 22
1.4.3 TA 26
1.4.4 TC02 28
1.5 CaC03 Dissolution in Sea Water 31
1.6 Calculating the Penetration of Anthropogenic C02 into the Oceans 33
3.6.1 Time Series Method 33
1.6.2 Calculation by Correcting for Dissolution of CaC03
and Oxidation of Plant Material 34
Acknowledgements 37
References 37
Appendix - Thermodynamic Equations for the Carbonic Acid System
in Sea Water 39
Solubility of C02 (Weiss 1974) 39
Carbonic Acid (Millero 1995) 39
Boric Acid (Dickson 1990b) 39
Water (Millero 1995) 39
IISO4 (Dickson 1990a) 40
HF (Dickson and Riley 1979) 40
Solubility of CaC03 (Mucci 1983) 40
Relationships for the Various pH Scales (Millero 1995) 40
VIII
Contents
Effect of Temperature and Pressure on the pH of Sea Water
{Millero 1979.1995)
References for Appendix
2 Marine Organic Geochemistry: A General Overview
2.1 Introduction
2.1.1 Organic Carbon Cycle
2.1.2 Nitrogen Cycle
2.2 Molecular Constituents of Organic Matter in the Ocean
2.2.1 Lipids
2.2.2 Amino Acids and Proteins
2.2.3 Carbohydrates
2.2.4 Lignin and Other CuO-Oxidation Products
2.2.5 Uncharacterized Organic Material
2.2.6 Dissolved Organic Matter
Acknowledgements
References
3 Photooxidation of Dissolved Organic Matter: Role for
Carbon Bioavailability and for the Penetration Depth
of Solar UV-Radiation
3.1 Introduction
3.2 Absorption of Sunlight by CDOM
3.3 Photooxidation of CDOM: Role for Carbon Bioavailability
3.4 Experimental Study on the Roles of Iron in CDOM Oxidation in
Irradiated Aqueous Systems (Voelker et al. 1997)
3.4.1 Photooxidation of SRFA by Fe(III)
3.5 Roles of Ligands in the Redox-Cycling of Iron in the Euphotic Zone
of Surface Waters
3.5.1 Roles of Ligands in the Oxidation of Iron(ll) in the Euphotic
Zone of Surface Waters
3.6 Conclusions
References
4 Redox Processes in Anoxic Waters
4.1 Introduction
4.2 Cariaco Trench
4-3 Framvaren Fjord
4-4 The Kinetics Oxidation of Hydrogen Sulfide in Natural Waters
References
Part II Organic Matter in Marine Environments
5 Organic Matter Preservation in the Ocean:
Lipid Behavior from Plankton to Sediments
5.1 Introduction
5.2 Lipids as Tracers of Organic Carbon
40
41
43
43
44
46
49
49
55
61
62
67
69
69
69
.75
. 75
.77
.78
. 80
.81
.83
. 84
.86
.87
.91
.91
. 94
101
112
122
125
127
127
128
Contents
IX
5.3 Lipid Fluxes to the Deep Sea 130
5.4 Seasonal Variations in Lipid Flux 131
5.5 Fate of Lipid Biomarkers 133
5.6 Summary 137
Acknowledgements 137
References 138
6 Organic Chemical Reaction Rates in the Ocean: Molecular
Approaches to Studying Extracellular Biochemical Processes 141
6.1 Introduction 141
6.2 Oxidative Deamination of Amino Acids in Sea Water by
Cell Surface Deaminases 143
6.2.1 Synthesis of a Fluorescent Analog of L-lysine as Substrate
for Amino Acid Oxidases in the Ocean 144
6.2.2 LYA-lysine as Substrate for Cell Surface Deaminases in Sea Water .... 146
6.3 Extracellular Hydrolysis of Peptides in Sea Water and Sediments 149
6.3.1 Experimental Approaches to Studying Degradation of
Proteinaceous Material in the Ocean 149
6.3.2 Rate Measurements 151
Acknowledgements 156
References 157
7 Vapour-Particle Phase Interactions of Some Selected Persistent
Organic Pollutants in the Marine Atmosphere 159
7.1 Introduction 159
7.2 Theory of Gas-Particle Interactions 159
7.2.1 Gas-Solid Interactions 159
7.2.2 Gas-Liquid Interactions 163
7.3 Practical Applications of Partitioning Theory 163
7.3.1 PCBs 165
7.3.2 Calculation of Air-Sea Fluxes 166
7.3.3 Dry Deposition 166
7.3.4 Wet Deposition 167
7.3.5 Gas Phase Exchange Processes 168
7.3.6 Determination of the Air Phase Transfer Velocity (/ca) through
Measurement of ra 169
7.3.7 Determination of the Water Phase Transfer Velocity (kw) 170
7.4 Conclusions 171
References 171
Part III Metals and Organometallic Compounds in Marine Environments ... 173
8 Determination of Organic Complexation 175
8.1 Introduction 175
8.2 Metal Species in Solution 175
8.3 Determination of Organic Complexation Using ASV 176
8.4 Principle of Adsorptive Cathodic Stripping Voltammetry 177
Contents
X
8.5 Principle of Ligand Competition
8.6 Determination of Labile Metal Concentrations Using CSV
8.7 Calculation of «ML
8.8 Calibration of aMAL ; ^ • y y.
8.9 Determination of Ligand Concentrations and Conditional Stability
Constants Using CSV with Ligand Competition 180
8.10 How to Evaluate the Ligand Titrations: van den Berg/Ruzic Plots 182
8.10.1 Example of a Ligand Titration with Copper 184
8.11 Effects of the Detection Window 384
Acknowledgements
References
9 Organic Comptexation of Metals in Sea Water 189
9.1 Introduction 38^
9.2 Distributions of Organic Metal Complexing Ligands 190
9.2.1 Competition between Copper and Zinc 191
9.2.2 Iron Complexing Ligands 192
9.3 Sources of Ligands 194
9.4 Composition of Ligands 194
9.5 Calculation of Metal Complexation by the Ligands 194
9.5.1 At High Natural Ligand Concentrations 196
9.5.2 At Low Ligand Concentrations 197
Acknowledgements 199
References 199
10 Occurence, Pathways and Bioaccumulation of Organometallic
Compounds in Marine Environments 201
10.1 Introduction 201
10.2 Organotin Compounds: Environmental Chemical Aspects 201
10.3 High Performance Liquid Chromatography - Hydride Generation -
Inductively-Coupled Plasma Atomic Emission Spectrometry
(HPLC-HG-ICP/AES) Hyphenated System to Organotin Analysis 204
10.4 An Example of a Field Study : The Butyltin Distribution in the
Genoa Oil Port 205
References 210
11 Hydrolysis Processes of Organotin(IV) Compounds in Sea Water
11.1 Introduction
11.2 Aqueous Solution Chemistry of Organotin(IV) Compounds
11.2.1 Trialkyltin Compounds
11.2.2 Dialkyltin Compounds
11.2.3 Monoalkyltin Compounds
11.3 Salt Effect on the Hydrolysis Process
11.4 Dependence on Ionic Strength of Hydrolysis Constants
11.5 Dependence on Temperature of Hydrolysis Constants
11.6 Hydrolysis of Organotin(IV) Compounds in Sea Water
11.7 Conclusions
213
213
214
215
216
218
219
220
221
222
226
Contents XI
References 226
12 119Sn Mossbauer Spectroscopy Studies on the
Interaction of Organotin(IV) Salts and Complexes
with Biological Systems and Molecules 229
12.1 Introduction 229
12.2 Analysis and Speciation of Organotins in the Environment 230
12.3 Interaction of Organotin(IV) Compounds with Biological Systems 231
12.4 Hemoglobin 232
12.5 Deoxyribonucleic Acid 232
12.6 Interaction of Organotin(IV) Complexes with Deoxyribonucleic Acid,
and Ternary Systems RnSn(IV)-Amino Acid-Nucleic Acid 235
References 241
13 Mercury in Marine Environments 245
13.1 Introduction 245
13.2 Mercury in the Environment 245
13.2.1 Chemical and Physical Properties 245
13.2.2 Mercury Emissions 246
13.2.3 The Global Mercury Cycle 247
13.3 Mercury in Coastal Marine Sediments 249
13.4 Mercury in Waters 251
13.4.1 Baltic and North Seas 251
13.4.2 Mediterranean Sea 252
13.4.3 The Pacific and Atlantic Oceans 252
13.5 Toxicity of Mercury to Marine Life 253
13.6 Mercury in the Marine Food Chain 255
13.6.1 Bioaccumulation 255
13.6.2 Human Exposure to Methyl Mercury 255
13.6.3 Human Exposure to Mercury in some Fish Eating Communities 257
13.7 Conclusions 260
References 260
14 Occurrence, Formation and Fate of Organoantimony
Compounds in Marine and Terrestrial Environments 265
14.1 Occurrence of Organoantimony Compounds in Marine and
Terrestrial Environments 265
14.2 Analysis of Organoantimony Compounds 268
14.2.1 Sample Preparation 268
14.2.2 Hydride Generation 268
14.2.3 Gas Chromatographic Separation 269
14.2.4 Detection Systems 272
14.2.5 Conclusion 274
14.3 Microbial Biotransformation of Antimony Compounds 274
14.3.1 Biomethylation of Antimony 274
14.3.2 Bioreduction and Bio-Oxidation of Antimony 277
References 278
Contents
XII
15 Redox Processes of Chromium in Sea Water 281
15.1 Introduction
15.2 Speciation of Cr(III) and Cr(VI) ^
15.3 Environmental Concentrations
15.4 Kinetic Studies
15.4.1 Oxidation Processes
15.4.2 Reduction Processes
15.5 The Chromium Cycle in Sea Water 292
Acknowledgements ^9^
References
Appendix 29^
Part IV Analytical Methodologies and Chemometrics for Sea Water 297
16 Oceanic DOC Measurements 299
16.1 Introduction 299
16.2 DOC Measurement Techniques 301
16.2.1 Sample Collection and Storage 302
16.2.2 Pretreatment and Removal of D1C 303
16.2.3 The Oxidation of DOC 303
16.2.4 The Detection and Quantitation Step 308
16.2.5 Comparative Performance of the Different Techniques 310
16.3 New Concepts for DOC Determination 311
Acknowledgements 316
References 316
17 Characterization of Marine Toxins by Means of Liquid
Chromatography - Electrospray Ionization - Mass Spectrometry 321
17.1 Introduction 321
17.2 Dinophysistoxins and Related Toxins 322
17.3 Brevetoxins 328
17.4 Saxitoxins 329
17.5 Ciguatoxins and Maitotoxins 331
17.6 Polypeptidic Toxins: Conotoxins 334
17.7 Conclusions 335
Acknowledgements 337
References 337
18 Metals Analysis by High Performance Liquid Chromatography 339
18.1 Introduction 339
18.2 Retention Mechanisms in Liquid Chromatography 340
18.2.1 Normal Phase Chromatography 340
18.2.2 Reversed-Phase Chromatography 340
18.2.3 Ion Chromatography 34q
18.2.4 Chelation Ion Chromatography 342
18.3 Procedures for Metal Separation 342
18.3.1 Normal Phase Chromatography 342
Contents XIII
18.3.2 Reversed Phase Chromatography 343
18.3.3 Ion Chromatography 343
18.3.4 Ion Interaction Chromatography 344
18.3.5 Chelation Ion Chromatography 346
18.3.6 Multimode and Multidimensional Liquid Chromatography 347
18.3.7 Preconcentration 348
18.4 Analytical Applications 348
18.5 Detection and Hyphenated Techniques 350
References 353
19 PIXE Analysis for Trace Elements in Marine Environments 357
19.1 Introduction 357
19.2 The PIXE Technique and the Experimental Set-up 358
19.3 Sensitivity and Detection Limits of the Technique 360
19.4 The PIXE Targets from Environmental Samples 361
19.5 The Proton Microbeam and its Applications 364
19.6 PIXE Application in the Study of Pollutant Enrichment in
Marine Aerosols 365
19.7 The Study of the Venice Lagoon Ecosystem by Means of the
PIXE Technique 366
19.7.1 The Fate of Pollutants Discharged into the Lagoon 366
19.7.2 Trace Element Distribution in Surface Bottom Sediment 367
19-7-3 The Vertical Profile of Trace Elements in Pore Water 367
19.7.4 Trace Elements in Surface Water and the Effect of
Fresh and Salt Water Mixing 368
References 369
20 Potentiometry for the Study of Acid-Base Properties of Sediments 371
20.1 Introduction 371
20.2 Sediment: What is it? 372
20.3 The Solid-Water Interface 373
20.4 Titration Procedure 376
20.5 Elaboration of the Potentiometric Data 379
20.6 Results of the Potentiometric Approach 381
References 384
21 Chemometrics for Sampling and Analysis:
Theory and Environmental Applications 387
21.1 Introduction 387
21.2 The Fundamental Tools of Chemometrics 388
21.2.1 Data Pretreatments
(The Importance of Data Knowledge and of Problem) 388
21.2.2 Similarity and Clustering 389
21.2.3 Principal Components 390
21.2.4 Class-Modelling Techniques 394
21.2.5 Regression Techniques, Responses and Predictors 394
21.2.6 Regression Techniques, Biased and Unbiased Techniques 396
XIV Contents
21.3 Applications 398
21.3.1 Example 1 - Rain Chemistry 398
21.3.2 Example 2 - Polycyclic Aromatic Hydrocarbons (PAHs) 402
21.3.3 Example 3 - Toxicity 403
21.4 Conclusions 404
References 404
22 Chemometric Applications to Seawater Analysis 405
22.1 Introduction 405
22.1.1 The Sea: A Very Complex Ecosystem 405
22.1.2 Chemometrics: A Helpful Tool in the Investigation of the
Marine Ecosystem 406
22.2 Chemometric Applications to Marine Samples 407
22.2.1 Classification Techniques 407
22.2.2 Optimization Methods 420
References 423
dex 425
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spelling | Chemical processes in marine environments with 56 tables Antonio Gianguzza ... (ed.) Berlin [u.a.] Springer 2000 XVIII, 441 S. graph. Darst. : 24 cm txt rdacontent n rdamedia nc rdacarrier Environmental science Literaturangaben Meereschemie (DE-588)4464850-9 gnd rswk-swf (DE-588)1071861417 Konferenzschrift 1998 Ustica gnd-content Meereschemie (DE-588)4464850-9 s DE-604 Gianguzza, Antonio 1945- Sonstige (DE-588)121560341 oth HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=008786117&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
spellingShingle | Chemical processes in marine environments with 56 tables Meereschemie (DE-588)4464850-9 gnd |
subject_GND | (DE-588)4464850-9 (DE-588)1071861417 |
title | Chemical processes in marine environments with 56 tables |
title_auth | Chemical processes in marine environments with 56 tables |
title_exact_search | Chemical processes in marine environments with 56 tables |
title_full | Chemical processes in marine environments with 56 tables Antonio Gianguzza ... (ed.) |
title_fullStr | Chemical processes in marine environments with 56 tables Antonio Gianguzza ... (ed.) |
title_full_unstemmed | Chemical processes in marine environments with 56 tables Antonio Gianguzza ... (ed.) |
title_short | Chemical processes in marine environments |
title_sort | chemical processes in marine environments with 56 tables |
title_sub | with 56 tables |
topic | Meereschemie (DE-588)4464850-9 gnd |
topic_facet | Meereschemie Konferenzschrift 1998 Ustica |
url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=008786117&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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