Metal clusters at surfaces: structure, quantum properties, physical chemistry
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | German |
| Veröffentlicht: |
Berlin [u.a.]
Springer
2000
|
| Schriftenreihe: | Springer series in cluster physics
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | X, 310 S. Ill., graph. Darst. |
| ISBN: | 3540665625 |
Internformat
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| 264 | 1 | |a Berlin [u.a.] |b Springer |c 2000 | |
| 300 | |a X, 310 S. |b Ill., graph. Darst. | ||
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Datensatz im Suchindex
| _version_ | 1804127543188520960 |
|---|---|
| adam_text | KARL-HEINZ MEIWES-BROER METAL CLUSTERS AT SURFACES STRUCTURE, QUANTUM
PROPERTIES, PHYSICAL CHEMISTRY WITH 275 FIGURES AND 4 COLOUR PLATES MM
SPRINGER CONTENTS 1 CONFINEMENT AND SIZE EFFECTS IN FREE METAL CLUSTERS
1 WALT A. DE HEER 1.1 INTRODUCTION 1 1.2 FREE SIMPLE METAL CLUSTERS 6
1.2.1 THE SHELL MODEL 6 1.2.2 EXTENDED THEORETICAL MODELS 10 1.2.3
LIQUID AND SOLID CLUSTERS 11 1.2.4 MOLECULAR BEAM METHODS FOR CLUSTER
RESEARCH 12 1.2.5 ELECTRONIC AND GEOMETRICAL STRUCTURE 14 1.2.6 OPTICAL
EXCITATIONS AND PLASMA RESONANCES 20 1.3 MAGNETIC PARTICLES IN MOLECULAR
BEAMS 24 1.3.1 STERN-GERLACH DEFLECTIONS OF FERROMAGNETIC METAL CLUSTERS
... 26 1.3.2 MAGNETIC MOMENTS OF 3D TRANSITION METAL CLUSTERS 28 1.3.3
OTHER FERROMAGNETIC CLUSTER SYSTEMS 31 1.4 CONCLUSION 33 2 FUNDAMENTALS
OF ADSORBATE-SURFACE INTERACTIONS 37 HEINZ HOEVEL, LARS S. 0. JOHANSSON,
BRUNO REIHL 2.1 INTRODUCTION 37 2.2 PHYSISORPTION OF XENON ON GRAPHITE:
SUPERSTRUCTURE AND DOMAIN BOUNDARIES 38 2.3 CHEMISORPTION OF ALKALI
ATOMS ON SEMICONDUCTOR SURFACES 41 2.3.1 IONIC VS. COVALENT BONDING AND
CHARGE-TRANSFER MONITORING .. 41 2.3.2 LI, NA, * AND CS ON CLEAVED
SI(LLL) 43 2.3.3 LI, NA, * AND RB ON SI(100) 46 2.4 BONDING OF ***
MOLECULES ON AG AND AU(LLO) SURFACES 52 2.4.1 GEOMETRIC PROPERTIES 53
2.4.2 ELECTRONIC PROPERTIES 54 2.5 ELECTRONIC RESPONSE WITHIN THE
CLUSTER-SURFACE INTERACTION 58 2.6 SUMMARY 62 3 GROWTH OF METAL CLUSTERS
AT SURFACES 67 HARALD BRUNE 3.1 INTRODUCTION 67 3.2 THE ELEMENTARY
PROCESSES OF MBE GROWTH 68 VIII 3.3 NUCLEATION 71 3.4 AGGREGATION 75 3.5
COARSENING 84 3.6 ANISOTROPIC SURFACES 86 3.7 GROWTH OF CLUSTER ARRAYS
90 3.8 SINGLE CRYSTAL OXIDE SURFACES 95 3.9 CONCLUSION 99 4 COLLISION OF
CLUSTERS WITH SURFACES 107 WOLFGANG HARBICH 4.1 INTRODUCTION 107 4.2
CLUSTER-SURFACE COLLISIONS: GENERAL REMARKS 108 4.3 EXPERIMENTAL
CONSIDERATIONS 114 4.4 MOLECULAR DYNAMICS CALCULATIONS 116 4.5
SOFTLANDING 116 4.6 FRAGMENTATION 122 4.6.1 CLUSTERS SCATTERING OFF THE
SURFACE 123 4.6.2 FRAGMENTATION STUDIES ON MOLECULES AND CLUSTERS 125
4.7 IMPLANTATION 128 4.8 SPUTTERING 131 4.9 THIN FILM FORMATION BY
ENERGETIC CLUSTER IMPACT 132 4.10 CLUSTER IMPACT CHEMISTRY 134 4.11
CRATER FORMATION AND CLUSTER IMPACT INDUCED EROSION 135 4.12 ELECTRONIC
PROCESSES 136 4.13 SUMMARY AND OUTLOOK 140 5 ELECTRONIC LEVEL STRUCTURE
OF METAL CLUSTERS AT SURFACES . . 151 KARL-HEINZ MEIWES-BROER 5.1
INTRODUCTION 151 5.2 PHOTOELECTRON SPECTROSCOPY OF DEPOSITED CLUSTERS
153 5.3 SCANNING TUNNELLING SPECTROSCOPY AND INVERSE PHOTOEMISSION 158
5.3.1 TARGET PREPARATION AND EXPERIMENTAL METHODS 160 5.3.2 STS ON
PLATINUM, SILVER AND SODIUM CLUSTERS 163 5.3.3 PHOTON MAPS OF SILVER
ISLANDS 168 5.4 SUMMARY 170 6 CONDUCTANCE QUANTISATION IN METALLIC POINT
CONTACTS 175 JAN M. VAN RUITENBEEK 6.1 INTRODUCTION 175 6.2 LANDAUER
THEORY FOR BALLISTIC CONDUCTANCE 176 6.3 EXPERIMENTAL TECHNIQUES 178 6.4
CONDUCTANCE OF ATOMIC-SCALE CONTACTS 179 6.5 HISTOGRAMS OF CONDUCTANCE
VALUES 183 6.6 THE CHARACTER OF THE CONDUCTANCE MODES THROUGH A SINGLE
ATOM . 187 6.6.1 SUBGAP STRUCTURE IN SUPERCONDUCTING CONTACTS 187 IX
6.6.2 VALENCE-ORBITAL-BASED DESCRIPTION OF THE CONDUCTANCE MODES. 191
6.6.3 FURTHER EXPERIMENTAL TECHNIQUES 194 6.6.4 IMPLICATIONS FOR
CONDUCTANCE CURVES AND HISTOGRAMS 200 6.7 CHAINS OF ATOMS 201 6.8
QUANTUM FORCES AND SHELL STRUCTURE IN ALKALI NANOWIRES 203 6.9
DISCUSSION AND OUTLOOK 205 7 MAGNETISM OF NANOMETER-SIZED PARTICLES AND
CLUSTERS .... 211 WOLFGANG WERNSDORFER 7.1 INTRODUCTION 211 7.2 SINGLE
PARTICLE MEASUREMENT TECHNIQUES 213 7.2.1 MICRO-SQUID MAGNETOMETRY 214
7.3 MECHANISMS OF MAGNETISATION REVERSAL IN SINGLE DOMAIN PARTICLES AT
ZERO KELVIN 215 7.3.1 MAGNETISATION REVERSAL BY UNIFORM ROTATION 215
7.3.2 GENERALISATION OF THE STONER-WOHLFARTH MODEL 218 7.3.3
EXPERIMENTAL VERIFICATION 218 7.4 INFLUENCE OF TEMPERATURE ON
MAGNETISATION REVERSAL 221 7.4.1 SUPERPARAMAGNETISM - NEEL-BROWN MODEL
221 7.4.2 EXPERIMENTAL METHODS 222 7.4.3 EXPERIMENTAL EVIDENCE FOR THE
NEEL-BROWN MODEL 224 7.5 MAGNETISATION REVERSAL BY QUANTUM TUNNELLING
225 7.5.1 MOLECULAR CLUSTERS 226 7.5.2 INDIVIDUAL SINGLE-DOMAIN
NANOPARTICLES 228 7.5.3 SINGLE-DOMAIN NANOPARTICLES AND WIRES AT LOW
TEMPERATURES 231 8 PHYSICAL CHEMISTRY OF SUPPORTED CLUSTERS 237 UELI
HEIZ AND WOLF-DIETER SCHNEIDER 8.1 INTRODUCTION 237 8.2 SUPPORTED
SIZE-DISTRIBUTED MODEL CATALYSTS 243 8.2.1 PREPARATION AND
CHARACTERISATION 243 8.2.2 CO DISSOCIATION ON SUPPORTED RH CLUSTERS 244
8.2.3 KINETIC EFFECTS IN THE CO OXIDATION REACTION ON SUPPORTED PD
PARTICLES 245 8.2.4 CATALYTIC ACTIVITY OF SUPPORTED AU CLUSTERS 247 8.3
SUPPORTED MONODISPERSED MODEL CATALYSTS 249 8.3.1 PREPARATION AND
CHARACTERISATION OF MONODISPERSED SUPPORTED CLUSTERS 249 8.3.2
SIZE-DEPENDENT CO DISSOCIATION ON SMALL NI CLUSTERS 252 8.3.3 THE
CATALYTIC ROLE OF SMALL SILVER CLUSTERS FOR THE LATENT IMAGE GENERATION
IN PHOTOGRAPHY 254 8.3.4 THE HYDROGENATION OF TOLUENE ON MONODISPERSED
IR 4 AND IR 6 SUPPORTED ON OXIDE SURFACES 255 8.3.5 SIZE-DEPENDENT
CYCLOTRIMERISATION OF ACETYLENE ON MONODISPERSED PALLADIUM CLUSTERS
SUPPORTED ON MGO .... 258 X 8.3.6 THE OXIDATION OF CO ON MONODISPERSED
PLATINUM CLUSTERS SUPPORTED ON MGO 261 8.3.7 THE OXIDATION OF CO ON
MONODISPERSED GOLD CLUSTERS SUP- PORTED ON MGO 266 8.4 CONCLUSIONS AND
OUTLOOK 268 9 APPLICATION OF CLUSTERS TO THE FABRICATION OF SILICON
NANO- STRUCTURES 275 KATRIN SEEGER AND RICHARD E. PALMER 9.1 PROSPECTS
FOR THE APPLICATION OF CLUSTERS 275 9.1.1 CLUSTERS AS BUILDING BLOCKS
275 9.1.2 CLUSTERS AS TOOLS 278 9.2 SILICON NANOSTRUCTURES 278 9.2.1
MOTIVATION 278 9.2.2 EXPERIMENTAL APPROACHES 280 9.3 PRODUCTION OF
CLUSTER FILMS FOR FABRICATION 283 9.3.1 CLUSTER GROWTH ON SURFACES 283
9.3.2 DEPOSITION OF SIZE-SELECTED CLUSTERS 285 9.3.3 ORGANISED ARRAYS OF
CLUSTERS 287 9.4 APPLICATION OF METAL CLUSTERS AS PLASMA ETCHING MASKS
289 9.4.1 FABRICATION OF SILICON PILLARS AND CONES USING CLUSTER FILMS
GROWN ON THE SURFACE 289 9.4.2 PRODUCTION OF SILICON PILLARS USING
CLUSTER BEAM DEPOSITION .. 292 9.4.3 ORDERED ARRAYS OF SILICON PILLARS
296 9.5 SUMMARY 298 INDEX 303
|
| any_adam_object | 1 |
| author | Meiwes-Broer, Karl-Heinz 1951- |
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| dewey-search | 530.4/17 |
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| discipline | Chemie / Pharmazie Physik |
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| indexdate | 2024-07-09T18:35:01Z |
| institution | BVB |
| isbn | 3540665625 |
| language | German |
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| publishDate | 2000 |
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| series2 | Springer series in cluster physics |
| spelling | Meiwes-Broer, Karl-Heinz 1951- Verfasser (DE-588)138134340 aut Metal clusters at surfaces structure, quantum properties, physical chemistry Karl-Heinz Meiwes-Broer Berlin [u.a.] Springer 2000 X, 310 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Springer series in cluster physics Cristaux métalliques Microagrégats Surfaces (Physique) Metal crystals Microclusters Surfaces (Physics) Metallcluster (DE-588)4128942-0 gnd rswk-swf Festkörperoberfläche (DE-588)4127823-9 gnd rswk-swf Metallcluster (DE-588)4128942-0 s Festkörperoberfläche (DE-588)4127823-9 s DE-604 GBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=008752399&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Meiwes-Broer, Karl-Heinz 1951- Metal clusters at surfaces structure, quantum properties, physical chemistry Cristaux métalliques Microagrégats Surfaces (Physique) Metal crystals Microclusters Surfaces (Physics) Metallcluster (DE-588)4128942-0 gnd Festkörperoberfläche (DE-588)4127823-9 gnd |
| subject_GND | (DE-588)4128942-0 (DE-588)4127823-9 |
| title | Metal clusters at surfaces structure, quantum properties, physical chemistry |
| title_auth | Metal clusters at surfaces structure, quantum properties, physical chemistry |
| title_exact_search | Metal clusters at surfaces structure, quantum properties, physical chemistry |
| title_full | Metal clusters at surfaces structure, quantum properties, physical chemistry Karl-Heinz Meiwes-Broer |
| title_fullStr | Metal clusters at surfaces structure, quantum properties, physical chemistry Karl-Heinz Meiwes-Broer |
| title_full_unstemmed | Metal clusters at surfaces structure, quantum properties, physical chemistry Karl-Heinz Meiwes-Broer |
| title_short | Metal clusters at surfaces |
| title_sort | metal clusters at surfaces structure quantum properties physical chemistry |
| title_sub | structure, quantum properties, physical chemistry |
| topic | Cristaux métalliques Microagrégats Surfaces (Physique) Metal crystals Microclusters Surfaces (Physics) Metallcluster (DE-588)4128942-0 gnd Festkörperoberfläche (DE-588)4127823-9 gnd |
| topic_facet | Cristaux métalliques Microagrégats Surfaces (Physique) Metal crystals Microclusters Surfaces (Physics) Metallcluster Festkörperoberfläche |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=008752399&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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