The structure and reaction processes of coal:
Gespeichert in:
| Format: | Buch |
|---|---|
| Sprache: | English |
| Veröffentlicht: |
New York [u.a.]
Plenum Press
1994
|
| Schriftenreihe: | The Plenum chemical engineering series
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XIV, 471 S. graph. Darst. |
| ISBN: | 0306446022 |
Internformat
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| 245 | 1 | 0 | |a The structure and reaction processes of coal |c K. Lee Smith ... |
| 264 | 1 | |a New York [u.a.] |b Plenum Press |c 1994 | |
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Datensatz im Suchindex
| _version_ | 1804127410665291776 |
|---|---|
| adam_text | IMAGE 1
CONTENTS
CHAPTER 1. INTRODUCTION 1
CHAPTER 2. SELECTION OF A SUITE OF COMMONLY USED RESEARCH COALS 5
2.1. CLASSIFICATION OF COAL 5
2.1A. ASTM RANK OF COAL 6
2.1B. ALTERNATIVE METHODS FOR COAL CLASSIFICATION 9
2. LC. COAL PROPERTIES 11
2.2. NATIONAL COAL BANKS 11
2.2A. THE PENN STATE COAL SAMPLE BANK AND COAL DATA BASE 11
2.2B. ARGONNE NATIONAL LABORATORY S PREMIUM COAL SAMPLE PROGRAM 17
2.2C. ILLINOIS BASIN COAL SAMPLE PROGRAM 23
2.2D. PETC/DU-AR&TD COAL SAMPLE SUITE 23
2.3. WORLDWIDE COALS 24
2.4. SUITE OF STANDARD RESEARCH COALS 25
2.4A. CRITERIA FOR STANDARD COAL SELECTION 28
2.4B. SELECTION OF STANDARD RESEARCH COALS 28
2.4C. STANDARD COAL PROPERTIES 30
CHAPTER 3. GEOCHEMISTRY AND MACROMOLECULAR STRUCTURE OF COAL 37
3.1. INTRODUCTION 37
3.2. GEOCHEMICAL ASPECTS OF COAL 38
IMAGE 2
3.2A. ANCIENT PEAT ACCUMULATION 39
3.2B. PRECURSORS OF COAL MACERALS 41
3.2C. ORIGIN OF COALS 50
3.2D. IMPORTANCE OF MACERALS IN COAL UTILIZATION 57
3.2E. PETROGRAPHIC ANALYSIS OF THE SELECTED SUITE OF COALS 59
3.3. MACROMOLECULAR STRUCTURE OF COALS 61
3.3A. THE STRUCTURE OF COAL 63
3.3B. MOLECULAR MODELS OF COAL STRUCTURE 69
3.4. SUMMARY 75
CHAPTER 4. COAL STRUCTURAL CHARACTERIZATION BY ADVANCED TECHNIQUES 77
4.1. INTRODUCTION 77
4.2. 13 C SOLID-STATE NMR SPECTROSCOPY 78
4.2A. 13 C NMR TECHNIQUES 78
4.2B. RESULTS FOR NMR COAL STRUCTURAL STUDIES 81
4.2C. NMR CHAR EVOLUTION STUDIES 86
4.2D. FUTURE CONCERNS IN NMR 93
4.2E. SUMMARY 94
4.3. PYROLYSIS MASS SPECTROMETRY 94
4.3A. METHODS OF PYROLYSIS MASS SPECTROMETRY 95
4.3B. RESULTS FROM PREVIOUS STUDIES 97
4.3C. COMPARATIVE STUDY OF SELECTED COALS BY SEVERAL PY-MS TECHNIQUES 99
4.3D. ANALYSIS OF SELECTED COALS BY TIME-RESOLVED PY-FIMS 102
4.3E. MOBILE PHASE IN COAL FROM A MS PERSPECTIVE 115
4.3F. SUMMARY 117
4.4. HIGH-RESOLUTION CHROMATOGRAPHY 117
4.4A. CHROMATOGRAPHIC EXPERIMENTAL METHODS 119
4.4B. PYRIDINE EXTRACTION RESULTS 122
4.4C. DEPOLYMERIZATION RESULTS 137
4.4D. SUMMARY 147
4.5. FTIR SPECTROSCOPY 149
4.5A. FTIR COAL STUDIES 149
4.5B. FTIR CHAR STUDIES 152
4.5C. SUMMARY 152
4.6. COAL SWELLING 154
IMAGE 3
4.7. SURFACE AREA, POROSITY, AND DENSITY MEASUREMENTS 157
4.7A. METHODS FOR SURFACE AREA, POROSITY, AND DENSITY DETERMINATION 158
4.7B. SURFACE-AREA, POROSITY, AND DENSITY DATA 161
4.7C. SUMMARY 168
18. MINERAL MATTER 168
4.8A. CHARACTER OF INORGANIC MATTER 169
4.8B. CHARACTERIZATION TECHNIQUES 170
4.8C. RESULTS FOR MINERAL MATTER DETERMINATIONS 172
4.8D. ELEMENTAL COMPOSITIONS OF THE SELECTED COALS 180
4.8E. MINERAL MATTER TRANSFORMATIONS 181
4.8F. SUMMARY 185
4.9. SUMMARY OF COAL STRUCTURAL CHARACTERIZATION 187
4.9A. INTEGRATION AND CORRELATION OF COAL CHARACTERIZATION PROGRAMS 187
4.9B. EXTENT OF CHARACTERIZATION AND RECOMMENDED FUTURE WORK 192
4.9C. CORRELATED CHARACTERIZATION OF SELECTED COALS 196
C H A P T ER 5. DEVOLATILIZATION RATE PROCESSES AND PRODUCTS 209
5.1. DEVOLATILIZATION MECHANISMS AND PROCESSES 210
5.1A. QUALITATIVE FEATURES OF DEVOLATILIZATION 210
5.1B. SOME EXPERIMENTAL CONSIDERATIONS 214
5.1C. DEVOLATILIZATION REACTIONS AND CHEMISTRY 216
5.ID. MASS AND HEAT TRANSPORT CONSIDERATIONS 225
5.2. DEVOLATILIZATION PRODUCT AND RATE MEASUREMENTS 228
5.2A. PYROLYSIS MASS SPECTROSCOPY 228
5.2B. TG-FTIR CHARACTERIZATION 237
5.2C. DATA FROM ROCK-EVAL AND PY-TQMS 251
5.3. DEVOLATILIZATION MODELING APPROACHES 254
5.3A. KINETIC EXPRESSIONS AND GLOBAL REACTION MODELS 258
5.3B. EFFECTS OF COAL STRUCTURE 259
5.3C. FUNCTIONAL GROUP DEVOLATILIZATION MODELS 261
5.3D. A PHENOMENOLOGICAL DEVOLATILIZATION SEQUENCE 265
5.3E. A SEMIEMPIRICAL TAR FORMATION CORRELATION 270
5.4. NETWORK MODELS OF COAL DEVOLATILIZATION 273
5.4A. PROPERTIES OF MACROMOLECULAR NETWORKS AND LATTICE STATISTICS 274
5.4B. THE FG-DVC MODEL 277
IMAGE 4
5.4C. THE FLASHCHAIN MODEL 290
5.4D. THE CPD MODEL 302
5.4E. COMPARISON OF NETWORK MODELS 317
5.5. SUMMARY 321
CHAPTER 6. CHAR OXIDATION, CONVERSION, AND REACTION RATE PROCESSES 325
6.1. INTRODUCTION 325
6.2. CHAR OXIDATION AND GASIFICATION MECHANISMS AND PROCESSES 326 6.2A.
CHAR REACTION PROCESSES 326
6.2B. CHEMICAL STRUCTURE OF COAL CHARS 328
6.2C. HETEROGENEOUS CHAR REACTION REGIMES 329
6.2D. KINETIC CHAR REACTION MECHANISMS 331
6.2E. CHAR MORPHOLOGY 349
6.2F. EFFECTS OF MINERAL MATTER 354
6.2G. EFFECTS OF PRESSURE 356
6.2H. CHAR OXIDATION RATES OF LARGE PARTICLES 357
6.2I. COAL AND CHAR IGNITION 365
6.3. PARTICLE REACTION MODELS 370
6.3A. GLOBAL MODELING APPROACH 372
6.3B. INTRINSIC MODELING APPROACH 378
6.4. CHAR REACTIVITY DATA AND OXIDATION STUDIES OF THE SELECTED COALS
389
6.4A. INTRINSIC REACTIVITY MEASUREMENT TECHNIQUES 389
6.4B. EFFECT OF PREPARATION VARIABLES ON CHAR 390
6.4C. CHAR REACTIVITY DATA 394
6.5. SUMMARY 404
ACRONYMS 409
NOMENCLATURE 413
REFERENCES 419
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| indexdate | 2024-07-09T18:32:55Z |
| institution | BVB |
| isbn | 0306446022 |
| language | English |
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| physical | XIV, 471 S. graph. Darst. |
| publishDate | 1994 |
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| publisher | Plenum Press |
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| spelling | The structure and reaction processes of coal K. Lee Smith ... New York [u.a.] Plenum Press 1994 XIV, 471 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier The Plenum chemical engineering series Charbon - Industrie et commerce ram Coal Kohlechemie (DE-588)4164493-1 gnd rswk-swf Kohlechemie (DE-588)4164493-1 s DE-604 Smith, K. Lee Sonstige oth OEBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=008665284&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | The structure and reaction processes of coal Charbon - Industrie et commerce ram Coal Kohlechemie (DE-588)4164493-1 gnd |
| subject_GND | (DE-588)4164493-1 |
| title | The structure and reaction processes of coal |
| title_auth | The structure and reaction processes of coal |
| title_exact_search | The structure and reaction processes of coal |
| title_full | The structure and reaction processes of coal K. Lee Smith ... |
| title_fullStr | The structure and reaction processes of coal K. Lee Smith ... |
| title_full_unstemmed | The structure and reaction processes of coal K. Lee Smith ... |
| title_short | The structure and reaction processes of coal |
| title_sort | the structure and reaction processes of coal |
| topic | Charbon - Industrie et commerce ram Coal Kohlechemie (DE-588)4164493-1 gnd |
| topic_facet | Charbon - Industrie et commerce Coal Kohlechemie |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=008665284&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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