Elementary surface reactions of hydrogen and oxygen on silicon: an optical second harmonic investigation
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | German |
| Veröffentlicht: |
München
Utz, Wiss.
1999
|
| Schriftenreihe: | Physik
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | Zugl.: München, Techn. Univ., Diss., 1999 u.d.T.: Raschke, Markus B.: Optical second harmonic investigations of the kinetics of elementary surface reactions on Si(001) and Si(111) |
| Beschreibung: | VIII, 188 S. graph. Darst. |
| ISBN: | 3896755641 |
Internformat
MARC
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| 245 | 1 | 0 | |a Elementary surface reactions of hydrogen and oxygen on silicon |b an optical second harmonic investigation |c Markus B. Raschke |
| 264 | 1 | |a München |b Utz, Wiss. |c 1999 | |
| 300 | |a VIII, 188 S. |b graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 490 | 0 | |a Physik | |
| 500 | |a Zugl.: München, Techn. Univ., Diss., 1999 u.d.T.: Raschke, Markus B.: Optical second harmonic investigations of the kinetics of elementary surface reactions on Si(001) and Si(111) | ||
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Datensatz im Suchindex
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CONTENTS
SUMMARY
.
III
1.
INTRODUCTION
.
1
2.
HYDROGEN
ON
SILICON
AND
SECOND-HARMONIC
GENERATION
.
5
2.1
CLEAN
SILICON
SURFACES
.
5
2.2
HYDROGEN
INTERACTION
WITH
SILICON
SURFACES
.
12
2.2.1
HYDROGEN-TERMINATED
SILICON
SURFACES
.
12
2.2.2
RECOMBINATIVE
DESORPTION
AND
HYDROGEN
DIFFUSION
.
13
2.2.3
CONSIDERATIONS
OF
DETAILED
BALANCE
IN
ADSORPTION
AND
DESORPTION
.
15
2.2.4
MICROSCOPIC
REACTION
MECHANISM
.
17
2.3
SECOND-HARMONIC
GENERATION
AT
SILICON
SURFACES
.
20
3.
EXPERIMENTAL
SETUP
AND
PROCEDURES
.
25
3.1
THE
ULTRA-HIGH
VACUUM
SYSTEM
.
25
3.2
SILICON
SURFACE
PREPARATION
.
30
3.3
OPTICAL
SETUP
.
33
3.4
SHG
MEASUREMENTS
OF
ADSORBATE
KINETICS
.
36
3.4.1
SURFACE
COVERAGE
CALIBRATION
.
36
3.4.2
MODEL
FOR
SH-COVERAGE
DEPENDENCE
.
39
3.4.3
ADSORPTION
AND
DESORPTION
KINETICS
.
42
4.
HYDROGEN
INTERACTION
WITH
VICINAL
SILICON
SURFACES
.
45
4.1
INFLUENCE
OF
STEPS
AND
DEFECTS
ON
THE
REACTION
OF
MOLECULAR
HYDROGEN
WITH
SILICON
SURFACES
.
46
4.1.1
MOTIVATION
.
46
4.1.2
HYDROGEN
ADSORPTION
AT
STEPS
AND
DEFECTS
.
47
4.1.3
DEFECT-MEDIATED
TERRACE
ADSORPTION
.
58
4.1.4
DISCUSSION
.
62
VIII
CONTENTS
4.1.5
CONCLUSION
.
65
4.2
HYDROGEN
INTERACTION
WITH
D
B
STEPS
ON
VICINAL
SI(001)
.
.
66
4.2.1
ADSORPTION
KINETICS
.
66
4.2.2
MOLECULAR
BEAM
EXPERIMENTS
.
71
4.2.3
THEORY
.
74
4.2.4
CONCLUSION
.
79
4.3
INTER-DIMER
REACTION
PATHWAYS
FOR
H2
ON
SI(001)
.
80
4.3.1
THEORETICAL
PREDICTIONS
.
80
4.3.2
EXPERIMENT
.
83
4.3.3
DISCUSSION
.
90
4.3.4
HYDROGEN
DESORPTION
KINETICS
.
93
4.3.5
CONCLUSION
.
98
4.4
EQUILIBRIUM
AND
NON-EQUILIBRIUM
HYDROGEN
COVERAGES
ON
VICINAL
SI(001)
.
99
4.4.1
THERMODYNAMICS
OF
H/SI
.
99
4.4.2
HYDROGEN
DIFFUSION
.
101
4.4.3
CHEMISORPTION
ENERGY
DIFFERENCE
.
109
4.4.4
CONCLUSION
.
118
5.
BINDING
ENERGY
AND
DETAILED
BALANCE
OF
HYDROGEN
ON
SILICON
SURFACES
.
119
5.1
ISOSTERIC
HEAT
OF
ADSORPTION
.
119
5.2
EXPERIMENT
.
121
5.3
ADSORPTION
ISOTHERMS
.
126
5.4
DISCUSSION
.
134
5.5
ENERGY
BALANCE
.
138
5.6
CONCLUSION
.
140
6.
DESORPTION
KINETICS
OF
SIO
FROM
SI(001)
.
141
6.1
ISOTHERMAL
DESORPTION
.
142
6.2
ARRHENIUS
PARAMETER
.
148
6.3
DISCUSSION
OF
THE
DESORPTION
MECHANISM
.
151
6.4
CONCLUSION
.
154
A.
LINEAR
OPTICAL
DIFFRACTION
FROM
ADSORBATE
GRATINGS
.
155 |
| any_adam_object | 1 |
| author | Raschke, Markus B. 1970- |
| author_GND | (DE-588)121195104 |
| author_facet | Raschke, Markus B. 1970- |
| author_role | aut |
| author_sort | Raschke, Markus B. 1970- |
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| building | Verbundindex |
| bvnumber | BV012715372 |
| ctrlnum | (OCoLC)75996700 (DE-599)BVBBV012715372 |
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| genre | (DE-588)4113937-9 Hochschulschrift gnd-content |
| genre_facet | Hochschulschrift |
| id | DE-604.BV012715372 |
| illustrated | Illustrated |
| indexdate | 2024-08-18T00:04:01Z |
| institution | BVB |
| isbn | 3896755641 |
| language | German |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-008643956 |
| oclc_num | 75996700 |
| open_access_boolean | |
| owner | DE-19 DE-BY-UBM DE-12 DE-703 |
| owner_facet | DE-19 DE-BY-UBM DE-12 DE-703 |
| physical | VIII, 188 S. graph. Darst. |
| publishDate | 1999 |
| publishDateSearch | 1999 |
| publishDateSort | 1999 |
| publisher | Utz, Wiss. |
| record_format | marc |
| series2 | Physik |
| spelling | Raschke, Markus B. 1970- Verfasser (DE-588)121195104 aut Elementary surface reactions of hydrogen and oxygen on silicon an optical second harmonic investigation Markus B. Raschke München Utz, Wiss. 1999 VIII, 188 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Physik Zugl.: München, Techn. Univ., Diss., 1999 u.d.T.: Raschke, Markus B.: Optical second harmonic investigations of the kinetics of elementary surface reactions on Si(001) and Si(111) Silicium (DE-588)4077445-4 gnd rswk-swf Kristallfläche (DE-588)4151344-7 gnd rswk-swf Frequenzverdopplung (DE-588)4155417-6 gnd rswk-swf Wasserstoff (DE-588)4064784-5 gnd rswk-swf Sauerstoff (DE-588)4051803-6 gnd rswk-swf Oberflächenreaktion (DE-588)4140095-1 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Silicium (DE-588)4077445-4 s Kristallfläche (DE-588)4151344-7 s Wasserstoff (DE-588)4064784-5 s Oberflächenreaktion (DE-588)4140095-1 s Frequenzverdopplung (DE-588)4155417-6 s DE-604 Sauerstoff (DE-588)4051803-6 s DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=008643956&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Raschke, Markus B. 1970- Elementary surface reactions of hydrogen and oxygen on silicon an optical second harmonic investigation Silicium (DE-588)4077445-4 gnd Kristallfläche (DE-588)4151344-7 gnd Frequenzverdopplung (DE-588)4155417-6 gnd Wasserstoff (DE-588)4064784-5 gnd Sauerstoff (DE-588)4051803-6 gnd Oberflächenreaktion (DE-588)4140095-1 gnd |
| subject_GND | (DE-588)4077445-4 (DE-588)4151344-7 (DE-588)4155417-6 (DE-588)4064784-5 (DE-588)4051803-6 (DE-588)4140095-1 (DE-588)4113937-9 |
| title | Elementary surface reactions of hydrogen and oxygen on silicon an optical second harmonic investigation |
| title_auth | Elementary surface reactions of hydrogen and oxygen on silicon an optical second harmonic investigation |
| title_exact_search | Elementary surface reactions of hydrogen and oxygen on silicon an optical second harmonic investigation |
| title_full | Elementary surface reactions of hydrogen and oxygen on silicon an optical second harmonic investigation Markus B. Raschke |
| title_fullStr | Elementary surface reactions of hydrogen and oxygen on silicon an optical second harmonic investigation Markus B. Raschke |
| title_full_unstemmed | Elementary surface reactions of hydrogen and oxygen on silicon an optical second harmonic investigation Markus B. Raschke |
| title_short | Elementary surface reactions of hydrogen and oxygen on silicon |
| title_sort | elementary surface reactions of hydrogen and oxygen on silicon an optical second harmonic investigation |
| title_sub | an optical second harmonic investigation |
| topic | Silicium (DE-588)4077445-4 gnd Kristallfläche (DE-588)4151344-7 gnd Frequenzverdopplung (DE-588)4155417-6 gnd Wasserstoff (DE-588)4064784-5 gnd Sauerstoff (DE-588)4051803-6 gnd Oberflächenreaktion (DE-588)4140095-1 gnd |
| topic_facet | Silicium Kristallfläche Frequenzverdopplung Wasserstoff Sauerstoff Oberflächenreaktion Hochschulschrift |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=008643956&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT raschkemarkusb elementarysurfacereactionsofhydrogenandoxygenonsiliconanopticalsecondharmonicinvestigation |