Electrochemistry at metal and semiconductor electrodes:
Gespeichert in:
1. Verfasser: | |
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Format: | Buch |
Sprache: | English |
Veröffentlicht: |
Amsterdam [u.a.]
Elsevier
1998
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Schlagworte: | |
Online-Zugang: | Inhaltsverzeichnis |
Beschreibung: | XI, 400 S. graph. Darst. |
ISBN: | 0444828060 |
Internformat
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Datensatz im Suchindex
_version_ | 1804127155755417600 |
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adam_text | CONTENTS CHAPTER 1 THE ENERGY LEVEL OF PARTICLES 1 1.1 PARTICLES AND
PARTICLE ENSEMBLES 1 1.2 CHEMICAL POTENTIAL AND ELECTROCHEMICAL
POTENTIAL 4 1.3 ELECTROCHEMICAL POTENTIAL OF ELECTRONS 5 1.4 THE
REFERENCE LEVEL OF PARTICLE ENERGY 8 1.5 ELECTROSTATIC POTENTIAL OF
CONDENSED PHASES 9 1.6 ENERGY LEVELS OF CHARGED PARTICLES IN CONDENSED
PHASES 11 REFERENCES 13 CHAPTER 2 THE ENERGY LEVEL OF ELECTRONS 15 2.1
ENERGY LEVELS OF ELECTRONS IN CONDENSED PHASES 15 2.2 ELECTRONS IN
METALS 19 2.2.1 ENERGY BAND AND THE FERMI LEVEL 19 2.2.2 THE REAL
POTENTIAL AND THE CHEMICAL POTENTIAL OF ELECTRONS IN METALS 21 2.3
ELECTRON ENERGY BANDS OF SEMICONDUCTORS 24 2.4 ELECTRONS AND HOLES IN
SEMICONDUCTORS 27 2.4.1 INTRINSIC SEMICONDUCTORS 27 2.4.2 N-TYPE AND
P-TYPE SEMICONDUCTORS 29 2.5 ENERGY LEVELS OF ELECTRONS IN
SEMICONDUCTORS 32 2.6 METAL OXIDES 35 2.6.1 FORMATION OF ELECTRON ENERGY
BANDS 35 2.6.2 LOCALIZED ELECTRON LEVELS 38 2.7 THE SURFACE OF
SEMICONDUCTORS 39 2.7.1 THE SURFACE STATE 39 2.7.2 THE SPACE CHARGE
LAYER 42 2.7.3 SURFACE DEGENERACY (QUASI-METALLIZATION OF SURFACES) 44
2.8 AMORPHOUS SEMICONDUCTORS 44 2.9 ELECTRON ENERGY BANDS OF LIQUID
WATER 45 2.10 REDOX ELECTRONS IN AQUEOUS SOLUTION 47 2.10.1 ELECTRON
LEVELS OF GASEOUS REDOX PARTICLES 47 2.10.2 ELECTRON LEVELS OF HYDRATED
REDOX PARTICLES 48 2.10.3 FLUCTUATION OF ELECTRON ENERGY LEVELS 51
2.10.4 THE FERMI LEVEL OF HYDRATED REDOX ELECTRONS 53 2.11 THE ELECTRON
LEVEL OF NORMAL HYDROGEN ELECTRODE 55 REFERENCES 58 CHAPTER 3 THE ENERGY
LEVEL OF IONS 61 3.1 IONIC DISSOCIATION OF GASEOUS MOLECULES 61 3.2
METAL ION LEVELS IN SOLID METALS 63 3.2.1 THE UNITARY ENERGY LEVEL OF
SURFACE METAL IONS 63 3.2.2 METAL ION LEVELS AT THE SURFACE AND IN THE
INTERIOR 65 3.3 ION LEVELS OF COVALENT SEMICONDUCTORS 67 3.3.1 THE
UNITARY LEVEL OF SURFACE IONS 67 3.3.2 ION LEVELS AT THE SURFACE AND IN
THE INTERIOR 69 3.4 ION LEVELS OF COMPOUND SEMICONDUCTORS 71 3.4.1 THE
UNITARY LEVEL OF SURFACE IONS 71 3.4.2 ION LEVELS AT THE SURFACE AND IN
THE INTERIOR 74 3.5 ION LEVELS IN AQUEOUS SOLUTION 76 3.5.1 LEVELS OF
HYDRATED IONS 76 3.5.2 PROTON LEVELS IN AQUEOUS SOLUTION 78 3.6
THERMODYNAMIC REFERENCE LEVEL FOR IONS 85 REFERENCES 86 CHAPTER 4
ELECTRODE POTENTIAL 87 4.1 ELECTRODE 87 4.1.1 ELECTRODE 87 4.1.2 ANODE
AND CATHODE 88 4.1.3 ELECTRONIC ELECTRODE AND IONIC ELECTRODE 88 4.1.4
POLARIZABLE AND NONPOLARIZABLE ELECTRODES 89 4.2 THE INTERFACE OF TWO
CONDENSED PHASES 90 4.2.1 POTENTIAL DIFFERENCE BETWEEN TWO CONTACTING
PHASES 90 4.2.2 THE INTERFACE OF ZERO CHARGE 93 4.2.3 INTERFACES IN
CHARGE TRANSFER EQUILIBRIUM 94 4.3 ELECTRODE POTENTIAL 96 4.3.1
ELECTRODE POTENTIAL DEFINED BY ELECTRON ENERGY LEVELS 96 4.3.2 ELECTRODE
POTENTIAL AND ION ENERGY LEVELS IN ELECTRODES 101 4.4 ELECTRODE
POTENTIAL IN CHARGE TRANSFER EQUILIBRIUM 103 4.4.1 ELECTRODE POTENTIAL
IN ELECTRON TRANSFER EQUILIBRIUM 103 4.4.2 ELECTRODE POTENTIAL IN ION
TRANSFER EQUILIBRIUM 105 4.4.3 POTENTIAL OF FILM-COVERED IONIC
ELECTRODES IN EQUILIBRIUM 107 4.4.4 POTENTIAL OF GAS ELECTRODES IN
EQUILIBRIUM 108 4.5 MEASUREMENT OF ELECTRODE POTENTIALS 110 4.6
POTENTIAL OF THE EMERSED ELECTRODE 112 4.6.1 POTENTIAL OF EMERSED
ELECTRODES IN VACUUM 113 4.6.2 POTENTIAL OF EMERSED ELECTRODES IN
INACTIVE GAS 114 REFERENCES 117 CHAPTER 5 ELECTRIC DOUBLE LAYER AT
ELECTRODE INTERFACES 119 5.1 SOLID SURFACE AND ADSORPTION 119 5.1.1
CLEAN SURFACE OF SOLIDS 119 5.1.2 ADSORPTION 121 5.1.3 ELECTRON LEVEL OF
ADSORBED PARTICLES 122 5.2 ELECTRIC DOUBLE LAYER AT SOLID/AQUEOUS
SOLUTION INTERFACES 127 5.2.1 ELECTRIC DOUBLE LAYER MODEL 127 5.2.2
DIFFUSE CHARGE LAYER (SPACE CHARGE LAYER) 129 5.3 THE POTENTIAL OF ZERO
CHARGE ON METAL ELECTRODES 132 5.3.1 CLASSICAL MODEL OF THE COMPACT
DOUBLE LAYER AT INTERFACES 132 5.3.2 THE POTENTIAL OF ZERO CHARGE 135
5.4 THERMODYNAMICS OF ADSORPTION ON METAL ELECTRODES 138 5.4.1 GIBBS
ADSORPTION EQUATION 138 5.4.2 ION ADSORPTION ON MERCURY ELECTRODES 139
5.4.3 CONTACT ADSORPTION OF IONS 142 5.5 ELECTRIC DOUBLE LAYER AT METAL
ELECTRODES 143 5.5.1 INTERFACIAL ELECTRIC CAPACITY (ELECTRODE CAPACITY)
143 5.5.2 THE EFFECTIVE IMAGE PLANE ON METAL SURFACES 144 5.5.3 THE
CLOSEST APPROACH OF WATER MOLECULES TO ELECTRODE INTERFACES 146 5.5.4
ELECTRIC CAPACITY OF THE COMPACT LAYER 148 5.5.5 POTENTIAL DIFFERENCE
ACROSS THE COMPACT DOUBLE LAYER 150 5.6 CONTACT ADSORPTION AND ELECTRIC
DOUBLE LAYER 151 5.6.1 CONTACT ADSORPTION AND WORK FUNCTION 151 5.6.2
INTERFACIAL DIPOLE MOMENT INDUCED BY CONTACT ADSORPTION 153 5.6.3
INTERFACIAL POTENTIAL DIFFERENCE AFFECTED BY CONTACT ADSORPTION 155 5.7
PARTICLE ADSORPTION ON METAL ELECTRODES 158 5.7.1 ADSORPTION OF WATER
MOLECULES 158 5.7.2 COADSORPTION OF WATER MOLECULES AND THIRD-PARTICLES
161 5.7.3 SURFACE LATTICE TRANSFORMATION DUE TO CONTACT ADSORPTION 162
5.7.4 ELECTRON ENERGY LEVELS OF ADSORBED PARTICLES 165 5.8 ELECTRIC
DOUBLE LAYER AT SEMICONDUCTOR ELECTRODES 168 5.8.1 ELECTRIC DOUBLE LAYER
MODEL 168 5.8.2 POTENTIAL DISTRIBUTION ACROSS THE ELECTRODE INTERFACE
169 5.9 BAND EDGE LEVEL PINNING AND FERMI LEVEL PINNING 171 5.10 THE
SPACE CHARGE LAYER OF SEMICONDUCTOR ELECTRODES 174 5.10.1 SPACE CHARGE
LAYERS 174 5.10.2 DIFFERENTIAL ELECTRIC CAPACITY OF SPACE CHARGE LAYERS
176 5.10.3 SCHOTTKY BARRIER 181 5.11 THE COMPACT LAYER AT SEMICONDUCTOR
ELECTRODES 181 5.11.1 HYDROXYLATION OF ELECTRODE INTERFACES 181 5.11.2
THE COMPACT LAYER 184 5.11.3 DIFFERENTIAL ELECTRIC CAPACITY OF ELECTRODE
INTERFACES 187 5.12 THE SURFACE STATE OF SEMICONDUCTOR ELECTRODES 188
5.12.1 SURFACE STATES 188 5.12.2 DIFFERENTIAL ELECTRIC CAPACITY OF
SURFACE STATES 190 5.13 THE FLAT BAND POTENTIAL OF SEMICONDUCTOR
ELECTRODES 192 5.13.1 FLAT BAND POTENTIAL 192 5.13.2 BAND EDGE POTENTIAL
195 REFERENCES 196 CHAPTER 6 ELECTROCHEMICAL CELLS 201 6.1
ELECTROCHEMICAL CELLS 201 6.2 ELECTROMOTIVE FORCE OF ELECTROCHEMICAL
CELLS 204 6.3 EQUILIBRIUM POTENTIAL OF ELECTRODE REACTIONS 206 6.3.1
EQUILIBRIUM POTENTIAL OF ELECTRON TRANSFER REACTIONS 206 6.3.2
EQUILIBRIUM POTENTIAL OF ION TRANSFER REACTIONS 208 6.4 ELECTROCHEMICAL
REFERENCE LEVEL FOR HYDRATED IONS 210 REFERENCES 211 CHAPTER 7 ELECTRODE
REACTIONS 213 7.1 ELECTRODE REACTIONS 213 7.1.1 ELECTRON TRANSFER AND
ION TRANSFER REACTIONS 213 7.1.2 CATHODIC AND ANODIC REACTIONS 213 7.1.3
ELECTRON TRANSFER OF HYDRATED PARTICLES AND ADSORBED PARTICLES 214 7.2
REACTION RATE 216 7.2.1 FORWARD AND BACKWARD REACTION AFFINITIES 216
7.2.2 REACTION RATE 217 7.2.3 POLARIZATION CURVE OF ELECTRODE REACTIONS
218 7.3 REACTION MECHANISM 220 7.3.1 THE STOICHIOMETRIC NUMBER OF
REACTIONS 220 7.3.2 THE ACTIVATION ENERGY 221 7.3.3 QUANTUM TUNNELING
AND ACTIVATED FLOW OF PARTICLES 223 7.3.4 THE REACTION ORDER 225 7.4
RATE-DETERMINING STEPS OF REACTIONS 226 7.4.1 REACTION OF ELEMENTARY
STEPS IN SERIES 226 7.4.2 REACTION RATE DETERMINED BY A SINGLE STEP 228
7.4.3 REACTION RATE DETERMINED BY MULTIPLE STEPS 229 7.4.4 AFFINITY
DISTRIBUTED TO ELEMENTARY STEPS 230 7.4.5 RATE OF MULTISTEP REACTIONS
232 REFERENCES 233 CHAPTER 8 ELECTRODE REACTIONS IN ELECTRON TRANSFER.
235 8.1 ELECTRON TRANSFER AT METAL ELECTRODES 235 8.1.1 KINETICS OF
ELECTRON TRANSFER 235 8.1.2 THE STATE DENSITY OF REDOX ELECTRONS 238
8.1.3 EXCHANGE REACTION CURRENT AT THE EQUILIBRIUM POTENTIAL 240 8.1.4
REACTION CURRENT UNDER POLARIZATION 242 8.1.5 DIFFUSION AND REACTION
RATE 245 8.2 ELECTRON TRANSFER AT SEMICONDUCTOR ELECTRODES 249 8.2.1
SEMICONDUCTOR ELECTRODES COMPARED WITH METAL ELECTRODES 249 8.2.2 THE
CONDUCTION BAND AND THE VALENCE BAND MECHANISMS 250 8.2.3 ELECTRON STATE
DENSITY IN REDOX ELECTRODE REACTIONS 252 8.2.4 EXCHANGE REACTION CURRENT
AT THE EQUILIBRIUM POTENTIAL 254 8.3 REACTION CURRENT AT SEMICONDUCTOR
ELECTRODES 258 8.3.1 REACTION CURRENT UNDER POLARIZATION 258 8.3.2
REACTION CURRENT VERSUS POTENTIAL CURVE 262 8.3.3 THE TRANSPORT
OVERVOLTAGE OF MINORITY CARRIERS 266 8.3.4 RECOMBINATION OF MINORITY
CARRIERS 267 8.3.5 POLARIZATION CURVES OF REDOX ELECTRON TRANSFERS 268
8.3.6 REDOX FERMI LEVEL AND BAND EDGE LEVEL 270 8.3.7 ELECTRON TRANSFER
VIA THE SURFACE STATE 272 8.3.8 ELECTRON TUNNELING THROUGH THE SPACE
CHARGE LAYER 274 8.4 COMPLEXATION AND ADSORPTION IN ELECTRON TRANSFER
REACTIONS .....274 8.4.1 COMPLEXATION SHIFTS THE REDOX ELECTRON LEVEL
275 8.4.2 CONTACT ADSORPTION SHIFTS THE REDOX ELECTRON LEVEL 278 8.5
ELECTRON TRANSFER AT FILM-COVERED METAL ELECTRODES 281 8.5.1 ELECTRON
TRANSFER BETWEEN THE ELECTRODE METAL AND THE REDOX PARTICLES 282 8.5.2
ELECTRON TRANSFER BETWEEN THE FILM AND THE REDOX PARTICLES 284 8.5.3
POLARIZATION CURVES OBSERVED 286 REFERENCES 287 CHAPTER 9 ELECTRODE
REACTIONS IN ION TRANSFER 289 9.1 METAL ION TRANSFER AT METAL ELECTRODES
289 9.1.1 METAL ION TRANSFER IN A SINGLE ELEMENTAL STEP 289 9.1.2 METAL
ION TRANSFER IN A SERIES OF TWO ELEMENTAL STEPS 294 9.2 ION TRANSFER AT
SEMICONDUCTOR ELECTRODES 298 9.2.1 SURFACE ATOM IONIZATION OF COVALENT
SEMICONDUCTOR ELECTRODES 298 9.2.2 DISSOLUTION OF COVALENT
SEMICONDUCTORS 302 9.2.3 DISSOLUTION OF IONIC SEMICONDUCTORS 305 9.2.4
OXIDATIVE AND REDUCTIVE DISSOLUTION OF IONIC SEMICONDUCTORS 309 9.3 ION
ADSORPTION ON METAL ELECTRODES 314 9.3.1 ION ADSORPTION EQUILIBRIUM 314
9.3.2 ELECTRON LEVELS OF ADSORBED IONS 315 9.4 ION ADSORPTION ON
SEMICONDUCTOR ELECTRODES 317 9.4.1 ION ADSORPTION EQUILIBRIUM 317 9.4.2
ELECTRON LEVELS OF ADSORBED IONS 317 9.4.3 PROTON LEVELS ON ELECTRODE
SURFACES 319 REFERENCES 322 CHAPTER 10 SEMICONDUCTOR PHOTOELECTRODES 325
10.1 QUASI-FERMI LEVEL OF EXCITED ELECTRONS AND HOLES 325 10.1.1
QUASI-FERMI LEVEL 325 10.1.2 QUASI-FERMI LEVELS AND ELECTRODE REACTIONS
328 10.2 PHOTOPOTENTIAL 330 10.3 PHOTOEXCITED ELECTRODE REACTIONS 334
10.3.1 PHOTOEXCITED ELECTRODE REACTION CURRENT (PHOTOCURRENT) 334 10.3.2
THE RANGE OF ELECTRODE POTENTIAL FOR PHOTOELECTRODE REACTIONS 338 10.3.3
THE FLAT BAND POTENTIAL OF PHOTOEXCITED ELECTRODES 344 10.4 THE RATE OF
PHOTOELECTRODE REACTIONS 347 10.4.1 ANODIC TRANSFER REACTIONS OF
PHOTOEXCITED HOLES 347 10.4.2 GENERATION AND TRANSPORT OF HOLES 349
10.4.3 INTERFACIAL OVERVOLTAGE OF HOLE TRANSFER 350 10.4.4 RECOMBINATION
OF PHOTOEXCITED HOLES IN ANODIC REACTIONS 352 10.4.5 CATHODIC HOLE
INJECTION REACTIONS 354 10.5 PHOTOELECTROCHEMICAL CELLS 357 10.6
PHOTOELECTROLYTIC CELLS 357 10.6.1 PHOTOELECTROLYTIC CELLS OF METAL AND
SEMICONDUCTOR ELECTRODES 357 10.6.2 PHOTOELECTROLYTIC CELLS OF TWO
SEMICONDUCTOR ELECTRODES 364 10.7 PHOTOVOLTAIC CELLS 367 REFERENCES 371
CHAPTER 11 MIXED ELECTRODES 373 11.1 THE SINGLE ELECTRODE AND THE MIXED
ELECTRODE 373 11.2 CATALYTIC REACTIONS ON MIXED ELECTRODES 375 11.3
MIXED ELECTRODE POTENTIAL 377 11.4 PASSIVATION OF METAL ELECTRODES 381
11.4.1 POLARIZATION CURVE OF ANODIC METAL DISSOLUTION 381 11.4.2 METAL
DISSOLUTION IN THE PASSIVE AND TRANSPASSIVE STATES 383 11.4.3
SPONTANEOUS PASSIVATION OF METAL ELECTRODES 387 REFERENCES 389 LIST OF
SYMBOLS 391 INDEX 397
|
any_adam_object | 1 |
author | Sato, Norio |
author_facet | Sato, Norio |
author_role | aut |
author_sort | Sato, Norio |
author_variant | n s ns |
building | Verbundindex |
bvnumber | BV012512490 |
callnumber-first | Q - Science |
callnumber-label | QD572 |
callnumber-raw | QD572.O85 |
callnumber-search | QD572.O85 |
callnumber-sort | QD 3572 O85 |
callnumber-subject | QD - Chemistry |
classification_rvk | VE 6300 |
classification_tum | CHE 144f |
ctrlnum | (OCoLC)245882419 (DE-599)BVBBV012512490 |
dewey-full | 541.3724 |
dewey-hundreds | 500 - Natural sciences and mathematics |
dewey-ones | 541 - Physical chemistry |
dewey-raw | 541.3724 |
dewey-search | 541.3724 |
dewey-sort | 3541.3724 |
dewey-tens | 540 - Chemistry and allied sciences |
discipline | Chemie / Pharmazie Physik Chemie |
format | Book |
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id | DE-604.BV012512490 |
illustrated | Illustrated |
indexdate | 2024-07-09T18:28:51Z |
institution | BVB |
isbn | 0444828060 |
language | English |
oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-008492889 |
oclc_num | 245882419 |
open_access_boolean | |
owner | DE-91G DE-BY-TUM DE-355 DE-BY-UBR |
owner_facet | DE-91G DE-BY-TUM DE-355 DE-BY-UBR |
physical | XI, 400 S. graph. Darst. |
publishDate | 1998 |
publishDateSearch | 1998 |
publishDateSort | 1998 |
publisher | Elsevier |
record_format | marc |
spelling | Sato, Norio Verfasser aut Electrochemistry at metal and semiconductor electrodes by Norio Sato. Amsterdam [u.a.] Elsevier 1998 XI, 400 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Elektrochemie - Halbleiterelektrode Metall (DE-588)4038860-8 gnd rswk-swf Elektrode (DE-588)4014247-4 gnd rswk-swf Elektrochemie (DE-588)4014241-3 gnd rswk-swf Elektrodenprozess (DE-588)4151783-0 gnd rswk-swf Halbleiterelektrode (DE-588)4158799-6 gnd rswk-swf Elektrodenprozess (DE-588)4151783-0 s DE-604 Elektrode (DE-588)4014247-4 s Metall (DE-588)4038860-8 s Elektrochemie (DE-588)4014241-3 s Halbleiterelektrode (DE-588)4158799-6 s 1\p DE-604 OEBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=008492889&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
spellingShingle | Sato, Norio Electrochemistry at metal and semiconductor electrodes Elektrochemie - Halbleiterelektrode Metall (DE-588)4038860-8 gnd Elektrode (DE-588)4014247-4 gnd Elektrochemie (DE-588)4014241-3 gnd Elektrodenprozess (DE-588)4151783-0 gnd Halbleiterelektrode (DE-588)4158799-6 gnd |
subject_GND | (DE-588)4038860-8 (DE-588)4014247-4 (DE-588)4014241-3 (DE-588)4151783-0 (DE-588)4158799-6 |
title | Electrochemistry at metal and semiconductor electrodes |
title_auth | Electrochemistry at metal and semiconductor electrodes |
title_exact_search | Electrochemistry at metal and semiconductor electrodes |
title_full | Electrochemistry at metal and semiconductor electrodes by Norio Sato. |
title_fullStr | Electrochemistry at metal and semiconductor electrodes by Norio Sato. |
title_full_unstemmed | Electrochemistry at metal and semiconductor electrodes by Norio Sato. |
title_short | Electrochemistry at metal and semiconductor electrodes |
title_sort | electrochemistry at metal and semiconductor electrodes |
topic | Elektrochemie - Halbleiterelektrode Metall (DE-588)4038860-8 gnd Elektrode (DE-588)4014247-4 gnd Elektrochemie (DE-588)4014241-3 gnd Elektrodenprozess (DE-588)4151783-0 gnd Halbleiterelektrode (DE-588)4158799-6 gnd |
topic_facet | Elektrochemie - Halbleiterelektrode Metall Elektrode Elektrochemie Elektrodenprozess Halbleiterelektrode |
url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=008492889&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
work_keys_str_mv | AT satonorio electrochemistryatmetalandsemiconductorelectrodes |