Macromolecular science and engineering: new aspects
Gespeichert in:
| Format: | Buch |
|---|---|
| Sprache: | German |
| Veröffentlicht: |
Berlin [u.a.]
Springer
1999
|
| Schriftenreihe: | Springer series in materials science
35 |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | Literaturangaben |
| Beschreibung: | XVI, 400 S. Ill., graph. Darst. |
| ISBN: | 3540643788 |
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| 245 | 1 | 0 | |a Macromolecular science and engineering |b new aspects |c Yoshikazu Tanabe (ed.) |
| 264 | 1 | |a Berlin [u.a.] |b Springer |c 1999 | |
| 300 | |a XVI, 400 S. |b Ill., graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 490 | 1 | |a Springer series in materials science |v 35 | |
| 500 | |a Literaturangaben | ||
| 650 | 7 | |a Macromolécules |2 ram | |
| 650 | 7 | |a Polymères |2 ram | |
| 650 | 4 | |a Macromolecules | |
| 650 | 4 | |a Polymers | |
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Datensatz im Suchindex
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| adam_text | CONTENTS PREFACE V CONTENTS VII LIST OF CONTRIBUTORS XV 1 INTRODUCTION 1
PART I. CHEMICAL REACTIONS 2 METALLOCENE CATALYZED POLYMERIZATION OF
METHYLMETHACRY- LATE 7 AKIRA MIYAZAWA 2.1 INTRODUCTION . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . 7 2.2 POLYMERIZATION OF
METHACRYLATES . . . . . . . . . . . . . . . . . . . . 7 2.2.1
SYNDIOSPECI*C POLYMERIZATION OF MMA . . . . . . . . . . . 8 2.3
POLYMERIZATION MECHANISM OF SYNDIOTACTIC PMMA . . . . . . . . 10 2.3.1
POLYMERIZATION MECHANISM INITIATED BY LANTHANOCENE COMPLEXES . . . . . .
. . . . . . . . . . . . . . . . . . . . . . 10 2.3.2 POLYMERIZATION
MECHANISM INITIATED BY CATIONIC ZIR- CONOCENE CATALYST . . . . . . . . .
. . . . . . . . . . . . . . . 10 2.4 ISOSPECI*C POLYMERIZATION OF MMA .
. . . . . . . . . . . . . . . . . 12 2.5 CONCLUSION . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . 13 3 RADICAL ISOMERIZATION
POLYMERIZATION 17 JUN-ICHI SUGIYAMA 3.1 INTRODUCTION . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . 17 3.2 VINYLCYCLOPROPANES .
. . . . . . . . . . . . . . . . . . . . . . . . . . . 17 3.3 CYCLIC
VINYL ETHERS . . . . . . . . . . . . . . . . . . . . . . . . . . . 21
3.4 CYCLIC KETENE ACETALS . . . . . . . . . . . . . . . . . . . . . . .
. . . 22 3.5 MISCELLANEOUS . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . 28 3.5.1 ALLYL ISOMERIZATION . . . . . . . . . . . . . .
. . . . . . . . . 28 3.5.2 AROMATIZATION . . . . . . . . . . . . . . . .
. . . . . . . . . . 29 VIII CONTENTS 3.5.3 POLYENES . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . 29 3.5.4 FUTURE OF RADICAL
ISOMERIZATION. POLYMERIZATION . . . . . 29 4 HIGH PRESSURE SOLID STATE
POLYMERIZATION 33 HIROSHI YAMAWAKI, KATSUTOSHI AOKI 4.1 INTRODUCTION . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 33 4.2
EXPERIMENTAL TECHNIQUE FOR HIGH-PRESSURE RESEARCH . . . . . . . 33 4.2.1
HIGH-PRESSURE CELL . . . . . . . . . . . . . . . . . . . . . . . 33
4.2.2 DETERMINATION OF PRESSURE . . . . . . . . . . . . . . . . . . . 34
4.2.3 MICROSCOPE OBSERVATION . . . . . . . . . . . . . . . . . . . . 34
4.3 SPECTROMETRY UNDER HIGH PRESSURE . . . . . . . . . . . . . . . . . .
35 4.3.1 RAMAN MEASUREMENT . . . . . . . . . . . . . . . . . . . . . .
35 4.3.2 INFRARED MEASUREMENT . . . . . . . . . . . . . . . . . . . . .
35 4.4 PHASE TRANSITION AND POLYMERIZATION . . . . . . . . . . . . . . .
. . 37 4.4.1 HYDROGEN CYANIDE . . . . . . . . . . . . . . . . . . . . .
. . 37 4.4.2 ACETYLENE . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . 38 5 BIODEGRADABLE POLYMERS 41 MASAO KUNIOKA 5.1 INTRODUCTION .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 41 5.2
MICROBIAL POLYESTERS . . . . . . . . . . . . . . . . . . . . . . . . . .
. 42 5.3 MICROBIAL POLY(AMINO ACID)S . . . . . . . . . . . . . . . . . .
. . . 43 5.4 MICROBIAL POLYSACCHARIDES . . . . . . . . . . . . . . . . .
. . . . . . . 47 5.5 CHEMICALLY SYNTHESIZED BIODEGRADABLE POLYMER . . .
. . . . . . . 47 PART II. SPECIALTY POLYMERS 6 POLYMER OBJECTS: TOWARDS
NEW POLYMER ARCHITECTURES 53 TOSHIMI SHIMIZU 6.1 INTRODUCTION . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . 53 6.2 NEW POLYMER
ARCHITECTURES . . . . . . . . . . . . . . . . . . . . . . . 53 6.3
INTERLOCKED POLYMERS . . . . . . . . . . . . . . . . . . . . . . . . . .
. 54 6.3.1 POLYCATENANE . . . . . . . . . . . . . . . . . . . . . . . .
. . . 54 6.3.2 POLYROTAXANE . . . . . . . . . . . . . . . . . . . . . .
. . . . . 56 6.3.3 CONJUGATED POLY-CATENATED ROTAXANE . . . . . . . . .
. . 57 6.4 DENDRIMER . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . 58 6.5 SUPRAMOLECULAR SELF-ASSEMBLY . . . . . . . . . . .
. . . . . . . . . . 63 6.6 CONCLUDING REMARKS . . . . . . . . . . . . .
. . . . . . . . . . . . . . 67 7 THERMO-RESPONSIVE POLYMER GELS 71 HISAO
ICHIJO, RYOICHI KISHI 7.1 INTRODUCTION . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . 71 7.2 PREPARATION AND SWELLING PROPERTIES
OF POLY(VINYL METHYL ETHER) HYDROGEL . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . 72 CONTENTS IX 7.3 FAST RESPONSIVE PVME
HYDROGELS HAVING MICROPOROUS STRUC- TURE . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . 74 7.4 FAST RESPONSIVE PNIPAAM
HYDROGELS HAVING MICROPOROUS STRUCTURE . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . 75 7.5 THERMO-REVERSIBLE ADSORPTION OF
NONIONIC SURFACTANTS ON PVME GEL . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . 76 7.6 SWELLING OF PVME GEL IN IONIC
SURFACTANT SOLUTIONS . . . . . . . 78 7.7 CONTROL OF ENZYME ACTIVITY . .
. . . . . . . . . . . . . . . . . . . . 80 7.8 APPLICATION FOR
THERMO-RESPONSIVE DEVICES . . . . . . . . . . . . . 81 7.9 CONCLUSION .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 82 8
BIOMIMETIC MEMBRANES 85 NORIHIKO MINOURA 8.1 INTRODUCTION . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . 85 8.2 MIMICS OF THE
TASTE CELL . . . . . . . . . . . . . . . . . . . . . . . . 85 8.3 MIMICS
OF THE RETINA . . . . . . . . . . . . . . . . . . . . . . . . . . . 89
8.4 SELECTIVE TRANSPORT OF MOLECULES . . . . . . . . . . . . . . . . . .
. . 91 9 POLYMERIC MEMBRANES FOR SEPARATION 95 KENJI HARAYA, SHUGUANG
LI, KENSAKU MIZOGUCHI 9.1 INTRODUCTION . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . 95 9.2 STRUCTURE AND VARIOUS KINDS OF
SEPARATION MEMBRANES . . . . . . 96 9.2.1 MICRO*LTRATION (MF) . . . . .
. . . . . . . . . . . . . . . . . 98 9.2.2 ULTRA-FILTRATION (UF) . . . .
. . . . . . . . . . . . . . . . . . 98 9.2.3 REVERSE OSMOSIS (RO) AND
NANO*LTRATION (NF) . . . . . 99 9.2.4 PERVAPORATION (PV) . . . . . . . .
. . . . . . . . . . . . . . 101 9.3 GAS SEPARATION MEMBRANES . . . . . .
. . . . . . . . . . . . . . . . . 103 9.3.1 TRANSPORT MECHANISM . . . .
. . . . . . . . . . . . . . . . . 103 9.3.2 MEMBRANE STRUCTURES . . . .
. . . . . . . . . . . . . . . . . 105 9.3.3 MEMBRANE MATERIALS . . . . .
. . . . . . . . . . . . . . . . . 106 9.3.3.1 GLASSY POLYMERS . . . . .
. . . . . . . . . . . . . . 107 9.3.3.2 RUBBERY POLYMERS . . . . . . . .
. . . . . . . . . 117 9.3.4 PERMEABILITY PREDICTION . . . . . . . . . .
. . . . . . . . . . 121 10 METAL CLUSTERS DISPERSED IN ORGANIC MATERIALS
125 YUKIMICHI NAKAO 10.1 INTRODUCTION . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . 125 10.2 METAL ORGANOSOLS . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . 125 10.2.1 REDUCTION IN THE
SOLUTION . . . . . . . . . . . . . . . . . . . 125 10.2.2 INTERPHASE
MIGRATION . . . . . . . . . . . . . . . . . . . . . . 127 10.2.3
METAL-DISSOLVING ORGANIC SOLVENTS . . . . . . . . . . . . . . 130 10.2.4
METHODS FROM BULK METALS . . . . . . . . . . . . . . . . . . 130 10.3
METAL CLUSTER-CONTAINING SOLID SOLS . . . . . . . . . . . . . . . . .
131 10.3.1 SOLIDI*CATION OF ORGANOSOLS . . . . . . . . . . . . . . . . .
. 131 10.3.2 THERMAL DECOMPOSITION IN SOLID SOLUTION . . . . . . . . .
132 X CONTENTS 10.3.3 MICROPHASE SEPARATION . . . . . . . . . . . . . .
. . . . . . . 132 10.3.4 MIGRATION OF CLUSTERS . . . . . . . . . . . . .
. . . . . . . . . 133 11 ORGANIC MAGNETIC MATERIALS 137 KAZUHISA MURATA
11.1 INTRODUCTION . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . 137 11.2 MAGNETIC PROPERTIES . . . . . . . . . . . . . . . . .
. . . . . . . . . . 137 11.3 ORGANIC MAGNETIC MATERIALS . . . . . . . .
. . . . . . . . . . . . . . 139 11.3.1 MOLECULAR MAGNETS . . . . . . . .
. . . . . . . . . . . . . . . 139 11.3.2 POLYMERIC MAGNETS . . . . . . .
. . . . . . . . . . . . . . . . 143 11.3.3 CARBON MAGNETS . . . . . . .
. . . . . . . . . . . . . . . . . 143 12 NONLINEAR OPTICAL MATERIALS 151
HIRO MATSUDA, YOSHIKAZU TANABE 12.1 INTRODUCTION . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . 151 12.1.1 NONLINEAR OPTICAL
E*ECT . . . . . . . . . . . . . . . . . . . . 151 12.1.2 MEASUREMENT OF
HYPERPOLARIZABILITY AND NONLINEAR OP- TICAL SUSCEPTIBILITIES . . . . . .
. . . . . . . . . . . . . . . . 154 12.1.3 POLING . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . 155 12.2 SECOND-ORDER NONLINEAR
OPTICAL MATERIALS . . . . . . . . . . . . . 156 12.2.1 TRADE-O* RELATION
BETWEEN SECOND-ORDER OPTICAL NON- LINEARITIES AND TRANSPARENCY . . . . .
. . . . . . . . . . . . 156 12.2.2 SECOND-ORDER NONLINEAR OPTICAL
CRYSTALS . . . . . . . . . 156 12.3 ELECTRO-OPTIC E*ECT . . . . . . . .
. . . . . . . . . . . . . . . . . . . . 158 12.3.1 GUEST-HOST SYSTEMS .
. . . . . . . . . . . . . . . . . . . . . 158 12.3.2 SIDE-CHAIN POLYMERS
. . . . . . . . . . . . . . . . . . . . . . 158 12.3.3 MAIN-CHAIN
POLYMERS . . . . . . . . . . . . . . . . . . . . . 159 12.3.4
CROSSLINKED SYSTEMS . . . . . . . . . . . . . . . . . . . . . . 160
12.3.5 SOL-GEL GLASSES . . . . . . . . . . . . . . . . . . . . . . . . .
161 12.3.6 ELECTRO-OPTIC DEVICES . . . . . . . . . . . . . . . . . . . .
. . 161 12.4 PHOTOREFRACTIVE E*ECT . . . . . . . . . . . . . . . . . . .
. . . . . . . 162 12.5 THIRD-ORDER NONLINEAR OPTICAL MATERIALS . . . . .
. . . . . . . . . 163 12.5.1 SWITCHING DEVICES . . . . . . . . . . . . .
. . . . . . . . . . . 163 12.5.2 POLYDIACETYLENE . . . . . . . . . . . .
. . . . . . . . . . . . . 164 12.5.3 OTHER POLYMERS AND MOLECULES . . .
. . . . . . . . . . . . . 166 PART III. POLYMER PROCESSING 13 LASER
PROCESSING OF POLYMERS 171 AKIRA YABE 13.1 INTRODUCTION . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . 171 13.2 POLYMER
PROCESSING BY LASER ABLATION . . . . . . . . . . . . . . . . 172 13.2.1
LASER ABLATION OF POLYMER . . . . . . . . . . . . . . . . . . 172 13.3
ETCHING: MICROMACHINING . . . . . . . . . . . . . . . . . . . . . . . .
175 CONTENTS XI 13.3.1 SURFACE MODI*CATION . . . . . . . . . . . . . . .
. . . . . . . 177 13.3.2 DEPOSITION: THIN FILM PREPARATION . . . . . . .
. . . . . . 182 13.4 POLYMER PROCESSING BY LASER-INDUCED CHEMICAL
REACTION . . . . 184 13.4.1 LASER-INDUCED CHEMICAL REACTIONS . . . . . .
. . . . . . . 184 13.4.2 SURFACE MODI*CATION . . . . . . . . . . . . . .
. . . . . . . . 185 13.5 SUMMARY . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . 187 14 SOLID-PHASE FORMING AND MECHANICAL
PROPERTIES OF POLYMERS 191 KAZUO NAKAYAMA, AKIRA KAITO 14.1 INTRODUCTION
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 191 14.2
HOT DRAWING OF ULTRAHIGH MOLECULAR WEIGHT POLYETHYLENE . . . . 192
14.2.1 CHARACTERISTICS OF ULTRAHIGH MOLECULAR WEIGHT POLYETHY- LENE . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 192 14.2.2
DRAWING OF ULTRAHIGH MOLECULAR WEIGHT POLYETHYLENE . . 192 14.2.3
MECHANICAL PROPERTIES OF DRAWN UHMW-PE SHEETS . . . 193 14.2.4 STRUCTURE
OF DRAWN UHMW-PE . . . . . . . . . . . . . . . 194 14.3 HYDROSTATIC
EXTRUSION . . . . . . . . . . . . . . . . . . . . . . . . . . 195 14.3.1
HYDROSTATIC EXTRUSION METHOD . . . . . . . . . . . . . . . . 195 14.3.2
TUBE EXTRUSION OF HIGH DENSITY PE . . . . . . . . . . . . . 196 14.3.3
EXTRUSION OF HEAT-TREATED UHMW-PE . . . . . . . . . . . 197 14.4 ROLLING
OF FILMS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 200
14.4.1 APPLICATION OF VARIOUS ROLLING METHODS . . . . . . . . . . 200
14.4.2 ROLLING OF POLYPROPYLENE SHEETS . . . . . . . . . . . . . . . 201
14.4.3 ROLLING OF MULTILAYER POLYMER SHEETS . . . . . . . . . . . . 202
14.5 ROLLER-DRAWING OF POLYMERS . . . . . . . . . . . . . . . . . . . .
. . 203 14.5.1 ROLLER-DRAWING METHOD . . . . . . . . . . . . . . . . . .
. . 203 14.5.2 MECHANICAL PROPERTIES OF ROLLER-DRAWN SHEET . . . . . . .
205 14.5.3 HIGHER-ORDER STRUCTURE OF ROLLER-DRAWN POLYMER SHEET . 206
14.6 PREPARATION OF ULTRA-THIN POLYMER FILMS BY MECHANICAL DE- POSITION
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
207 14.6.1 MECHANICAL DEPOSITION METHOD . . . . . . . . . . . . . . . .
207 14.6.2 HIGHLY ORIENTED FILMS OF POLY(DIMETHYLSILANE) BY ME- CHANICAL
DEPOSITION . . . . . . . . . . . . . . . . . . . . . . . 208 14.6.3
ORIENTED FILMS OF POLY(P-PHENYLENE) BY MECHANICAL DE- POSITION . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . 210 PART IV. NEW
MEASUREMENTS 15 PRECISE MEASUREMENT OF MOLECULAR WEIGHT 217 SHINICHI
KINUGASA 15.1 INTRODUCTION . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . 217 15.2 ACCURACY AND PRECISION . . . . . . . . . . .
. . . . . . . . . . . . . . 218 15.3 SIZE EXCLUSION CHROMATOGRAPHY . . .
. . . . . . . . . . . . . . . . . 218 15.4 SIZE EXCLUSION CHROMATOGRAPHY
WITH MULTIPLE DETECTION . . . . . 221 XII CONTENTS 15.5 LIGHT SCATTERING
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 223 15.6
NUCLEAR MAGNETIC RESONANCE (NMR) . . . . . . . . . . . . . . . . . 224
15.7 MATRIX-ASSISTED LASER DESORPTION/IONIZATION TIME-OF-FLIGHT MASS
SPECTROMETRY (MALDI-TOFMS) . . . . . . . . . . . . . . . . . . . 225
15.8 UNIFORM OLIGOMERS . . . . . . . . . . . . . . . . . . . . . . . . .
. . . 227 16 SURFACE FORCES IN POLYMERIC SYSTEMS 231 MASAKATSU HATO,
SATOMI OHNISHI, MASAMI MURATA 16.1 INTRODUCTION . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . 231 16.2 METHODS . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . 231 16.2.1 SURFACE
FORCE APPARATUS (SFA) . . . . . . . . . . . . . . . 231 16.2.2 THE
COLLOID PROBE TECHNIQUE . . . . . . . . . . . . . . . . . 233 16.3
INTERACTIONS BETWEEN POLYMER LAYERS IN LIQUIDS . . . . . . . . . . 234
16.3.1 INTERACTIONS BETWEEN NEUTRAL POLYMERS . . . . . . . . . . . 234
16.4 ATTRACTIVE FORCES BETWEEN HYDROPHOBIC SURFACES ACROSS WATER 242
16.5 CONCLUDING REMARKS . . . . . . . . . . . . . . . . . . . . . . . .
. . . 246 PART V. STRUCTURE AND PROPERTIES 17 STRUCTURE OF ORGANIC THIN
FILMS 253 KIYOSHI YASE 17.1 INTRODUCTION . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . 253 17.2 PROBLEMS AND THEIR SOLUTIONS IN
TEM OBSERVATION OF ORGANIC AND POLYMER MATERIALS . . . . . . . . . . . .
. . . . . . . . . . . . . 254 17.3 HIGH RESOLUTION OBSERVATION OF
ORGANIC AND POLYMER THIN FILMS 254 17.3.1 PHTHALOCYANINE THIN FILMS . .
. . . . . . . . . . . . . . . . 254 17.3.2 POLYMER THIN FILMS . . . . .
. . . . . . . . . . . . . . . . . 257 17.3.3 FATTY ACIDS . . . . . . . .
. . . . . . . . . . . . . . . . . . . . 260 17.4 ELECTRON SPECTROSCOPIC
IMAGING OF PLASMA-POLYMERIZED FILMS . . 261 17.5 SUMMARY . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . 265 18 MOLECULAR
MOTIONS IN BULK POLYMERS 267 YOSHIKAZU TANABE 18.1 CHAIN DYNAMICS . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . 267 18.1.1
EXPERIMENTAL OBSERVATIONS . . . . . . . . . . . . . . . . . . 267 18.1.2
COMPUTER SIMULATION OF POLYMER CHAIN MOTIONS IN THE BULK STATE . . . . .
. . . . . . . . . . . . . . . . . . . . . . . 269 18.1.3 E*ECTS OF
TORSIONAL LIBRATIONS . . . . . . . . . . . . . . . . 274 18.2 GLASS
TRANSITION . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 275
18.2.1 EXPERIMENTAL FEATURES OF THE GLASS TRANSITION . . . . . . 275
18.2.2 TRAPPING DI*USION MODEL OF THE GLASS TRANSITION . . . . 278 18.3
CIS-TRANS THERMAL ISOMERIZATION OF POLYACETYLENE . . . . . . . . . 280
CONTENTS XIII 19 COMPUTER SIMULATION OF POLYMERS 287 MASAO DOI 19.1
INTRODUCTION . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . 287 19.2 MEAN FIELD MONTE CARLO METHOD . . . . . . . . . . . . . . .
. . . . 287 19.2.1 THE PRINCIPLE . . . . . . . . . . . . . . . . . . . .
. . . . . . 287 19.2.2 APPLICATION TO RIGID ZIG-ZAG MOLECULES . . . . .
. . . . . 289 19.3 MEAN FIELD CALCULATION FOR POLYMERS . . . . . . . . .
. . . . . . . . 290 19.3.1 GENERAL FORMULATION . . . . . . . . . . . . .
. . . . . . . . . 290 19.3.2 APPLICATION TO POLYMERS GRAFTED ON SOLID
SURFACES . . . . 292 19.4 DYNAMICAL MEAN FIELD CALCULATION . . . . . . .
. . . . . . . . . . . 293 19.4.1 PRINCIPLE OF CALCULATION . . . . . . .
. . . . . . . . . . . . . 293 19.4.2 PHASE SEPARATION . . . . . . . . .
. . . . . . . . . . . . . . . 295 19.4.3 ORDERING OF BLOCK COPOLYMERS .
. . . . . . . . . . . . . . . 295 19.4.4 DYNAMICS OF POLYMER ADSORPTION
. . . . . . . . . . . . . . 296 19.5 SUMMARY AND FUTURE CHALLENGES . . .
. . . . . . . . . . . . . . . . 298 20 MORPHOLOGY DEVELOPMENT DURING
MELT PROCESSING OF IMMIS- CIBLE POLYMER BLENDS 301 SHIN HORIUCHI, KAZUO
NAKAYAMA 20.1 INTRODUCTION . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . 301 20.2 DROP BREAKUP AND COALESCENCE IN POLYMER
BLENDS . . . . . . . . 302 20.2.1 MORPHOLOGY DEVELOPMENT DURING THE
INITIAL STAGES OF BLENDING . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . 302 20.2.2 BREAKUP/COALESCENCE EQUILIBRIUM . . . . . . . . .
. . . . . 303 20.2.3 COMPATIBILIZATION-SUPPRESSION OF COALESCENCE . . .
. . . . 305 20.3 E*ECT OF SHEAR FLOW ON THE PHASE BEHAVIOR . . . . . . .
. . . . . . 308 20.4 TERNARY BLENDS-MANIPULATION OF PHASE FORMATION . .
. . . . . . . 310 20.4.1 PREDICTION OF PHASE FORMATION IN NON-REACTIVE
TERNARY BLENDS . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . 310 20.4.2 CONVERSION OF PHASE FORMATION BY ADDITION OF A DI- BLOCK
COPOLYMER . . . . . . . . . . . . . . . . . . . . . . . . 312 20.4.3
MANIPULATION OF THE PHASE FORMATION BY INTERFACIAL CHEMICAL REACTION . .
. . . . . . . . . . . . . . . . . . . . . 313 20.5 SUMMARY . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . 317 21 ELECTRONIC
STRUCTURE OF CONDUCTIVE AND CONJUGATED POLY- MERS 319 YOSHIKAZU TANABE
21.1 INTRAMOLECULAR ELECTRONIC STATE . . . . . . . . . . . . . . . . . .
. . 319 21.1.1 * -CONJUGATED POLYMERS . . . . . . . . . . . . . . . . .
. . . 319 21.1.2 * -CONJUGATED POLYMERS . . . . . . . . . . . . . . . .
. . . . 333 21.2 INTERMOLECULAR CHARGE TRANSPORT . . . . . . . . . . . .
. . . . . . . 335 21.3 METALLIC CONDUCTION . . . . . . . . . . . . . . .
. . . . . . . . . . . . 341 XIV CONTENTS 22 ORGANIC ELECTROLUMINESCENT
DEVICES 345 NORIYUKI TAKADA, SHOGO SAITO 22.1 INTRODUCTION . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . 345 22.2 PRINCIPLE AND
STRUCTURES OF ELECTROLUMINESCENT DEVICES . . . . . . 345 22.3 MATERIALS
FOR EL DEVICES . . . . . . . . . . . . . . . . . . . . . . . . 346 22.4
RATIONAL SELECTION OF ORGANIC MATERIALS FOR MULTILAYER EL DE- VICES . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
347 22.5 E*ECTS OF DOPANT MOLECULES ON EL CHARACTERISTICS . . . . . . .
. 349 22.6 CON*NEMENT OF EXCITONS WITHIN THE EML-A DEVICE OF MOLEC- ULAR
SIZE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
351 22.7 SIZE E*ECTS IN ORGANIC EL DEVICES . . . . . . . . . . . . . . .
. . . 353 22.8 STRONGLY DIRECTED EMISSION FROM
CONTROLLED-SPONTANEOUS-EMISSION EL DEVICES . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . 355 22.9 LASER ACTION FROM ORGANIC
THIN FILMS . . . . . . . . . . . . . . . . 360 22.10 CONCLUSIONS . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 361 23 OPTICAL
AND ELECTRICAL PROPERTIES OF C 60 ,C 70 , NANOTUBES AND ENDOHEDRAL
FULLERENES 363 SAID KAZAOUI, NOBUTSUGU MINAMI 23.1 INTRODUCTION . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 363 23.2 C 60
AND C 70 FULLERENES . . . . . . . . . . . . . . . . . . . . . . . . .
364 23.2.1 MOLECULAR GEOMETRY AND ELECTRONIC STRUCTURE OF C 60 . . 364
23.2.2 PROPERTIES OF C 60 SOLIDS . . . . . . . . . . . . . . . . . . . .
366 23.3 INTERMOLECULAR CHAXGE-TRANSFER STATES IN C 60 AND C 70 SOLIDS .
. 368 23.3.1 EVIDENCE FOR INTERMOLECULAR CHARGE-TANSFER STATES . . . .
368 23.3.2 DYNAMIC BEHAVIOR OF EXCITED STATES IN SOLID FULLERENES . 371
23.3.3 PHOTOCARRIER GENERATION DYNAMICS IN SOLID FULLERENES . 373 23.4
APPLICATIONS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . 373 23.4.1 XEROGRAPHIC PHOTORECEPTORS . . . . . . . . . . . . . . .
. . . 373 23.4.2 PHOTOVOLTAIC DEVICES . . . . . . . . . . . . . . . . .
. . . . . 376 23.5 ENDOHEDRAL FULLERENES . . . . . . . . . . . . . . . .
. . . . . . . . . . 379 23.5.1 DE*NITION . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . 379 23.5.2 ELECTRONIC STRUCTURE AND PROPERTIES
. . . . . . . . . . . . . 379 23.6 ELECTRICAL AND OPTICAL PROPERTIES OF
CARBON NANOTUBES . . . . . 381 23.6.1 DE*NITION AND ELECTRONIC STRUCTURE
OF NANOTUBES . . . . 382 23.6.2 PRODUCTION, PURI*CATION AND ELABORATION
METHODS . . . . 384 23.6.3 EXPERIMENTAL CHARACTERIZATION OF NT . . . . .
. . . . . . . 384 23.7 CONCLUSIONS AND PERSPECTIVES . . . . . . . . . .
. . . . . . . . . . . 387 SUBJECT INDEX 393
|
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| id | DE-604.BV012369747 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T18:26:23Z |
| institution | BVB |
| isbn | 3540643788 |
| language | German |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-008389033 |
| oclc_num | 40707013 |
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| owner_facet | DE-703 DE-1102 DE-526 DE-634 DE-83 DE-11 |
| physical | XVI, 400 S. Ill., graph. Darst. |
| publishDate | 1999 |
| publishDateSearch | 1999 |
| publishDateSort | 1999 |
| publisher | Springer |
| record_format | marc |
| series | Springer series in materials science |
| series2 | Springer series in materials science |
| spelling | Macromolecular science and engineering new aspects Yoshikazu Tanabe (ed.) Berlin [u.a.] Springer 1999 XVI, 400 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Springer series in materials science 35 Literaturangaben Macromolécules ram Polymères ram Macromolecules Polymers Makromolekulare Chemie (DE-588)4168684-6 gnd rswk-swf Kunststoff (DE-588)4033676-1 gnd rswk-swf Polymere (DE-588)4046699-1 gnd rswk-swf Polymere (DE-588)4046699-1 s Makromolekulare Chemie (DE-588)4168684-6 s DE-604 Kunststoff (DE-588)4033676-1 s Tanabe, Yoshikazu 1945- Sonstige (DE-588)120713713 oth Springer series in materials science 35 (DE-604)BV000683335 35 SWB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=008389033&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Macromolecular science and engineering new aspects Springer series in materials science Macromolécules ram Polymères ram Macromolecules Polymers Makromolekulare Chemie (DE-588)4168684-6 gnd Kunststoff (DE-588)4033676-1 gnd Polymere (DE-588)4046699-1 gnd |
| subject_GND | (DE-588)4168684-6 (DE-588)4033676-1 (DE-588)4046699-1 |
| title | Macromolecular science and engineering new aspects |
| title_auth | Macromolecular science and engineering new aspects |
| title_exact_search | Macromolecular science and engineering new aspects |
| title_full | Macromolecular science and engineering new aspects Yoshikazu Tanabe (ed.) |
| title_fullStr | Macromolecular science and engineering new aspects Yoshikazu Tanabe (ed.) |
| title_full_unstemmed | Macromolecular science and engineering new aspects Yoshikazu Tanabe (ed.) |
| title_short | Macromolecular science and engineering |
| title_sort | macromolecular science and engineering new aspects |
| title_sub | new aspects |
| topic | Macromolécules ram Polymères ram Macromolecules Polymers Makromolekulare Chemie (DE-588)4168684-6 gnd Kunststoff (DE-588)4033676-1 gnd Polymere (DE-588)4046699-1 gnd |
| topic_facet | Macromolécules Polymères Macromolecules Polymers Makromolekulare Chemie Kunststoff Polymere |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=008389033&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| volume_link | (DE-604)BV000683335 |
| work_keys_str_mv | AT tanabeyoshikazu macromolecularscienceandengineeringnewaspects |