Foam and foam films: theory, experiment, application
Gespeichert in:
Hauptverfasser: | , |
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Format: | Buch |
Sprache: | English |
Veröffentlicht: |
Amsterdam [u.a.]
Elsevier
1998
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Schriftenreihe: | Studies in interface science
5 |
Schlagworte: | |
Online-Zugang: | Inhaltsverzeichnis |
Beschreibung: | XXII, 773 S. Ill., graph. Darst. |
ISBN: | 0444819223 |
Internformat
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245 | 1 | 0 | |a Foam and foam films |b theory, experiment, application |c Dotchi Exerowa ; Pyotr M. Kruglyakov |
264 | 1 | |a Amsterdam [u.a.] |b Elsevier |c 1998 | |
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336 | |b txt |2 rdacontent | ||
337 | |b n |2 rdamedia | ||
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490 | 1 | |a Studies in interface science |v 5 | |
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Datensatz im Suchindex
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adam_text | FOAM AND FOAM FILMS THEORY, EXPERIMENT, APPLICATION DOTCHIEXEROWA
INSTITUTE OF PHYSICAL CHEMISTRY BULGARIAN ACADEMY OF SCIENCES SOFIA
BULGARIA PYOTR M. KRUGLYAKOV STATE ACADEMY OF ARCHITECTURE AND BUILDING
PENZA RUSSIA 1998 ELSEVIER AMSTERDAM - LAUSANNE - NEW YORK - OXFORD -
SHANNON - SINGAPORE - TOKYO CONTENTS VU PREFACE ACKNOWLEDGEMENTS
INTRODUCTION CHAPTER 1 FORMATION AND STRUCTURE OF FOAMS. PRESSURE IN THE
LIQUID 1 AND GAS PHASES OF FOAMS 1.1. METHODS FOR FOAM GENERATION 4 1.2.
SHAPE OF FILMS AND BUBBLES IN FOAM 14 1.3. FOAM DISPERSITY 25 1.4.
PRESSURE IN LIQUID PHASE OF FOAM AND BUBBLES 31 REFERENCES 37 CHAPTER 2
EXPERMINETAL METHODS INVOLVED IN THE STUDY OF FOAM FILMS 42 2.1.
MICROSCOPIC THIN LIQUID FILMS 42 2.1.1. THIN LIQUID FILMS:
MICROINTERFEROMETRIC TECHNIQUE 43 2.1.2. MEASURING CELLS FOR FORMATION
AND STUDY OF MICROSCOPIC 43 FOAM FILMS 2.1.3. DETERMINATION OF FOAM FILM
THICKNESS 47 2.1.4. DETERMINATION OF THE CAPILLARY PRESSURE 50 2.1.5.
DETERMINATION OF THE CONTACT ANGLE BETWEEN THE FOAM FILM 52 AND THE BULK
PHASE 2.1.6. FOAM FILM STUDY WITH A-PARTICLE IRRADIATION 55 2.1.7.
FLUORESCENCE RECOVERY AFTER PHOTOBLEACHING (FRAP) 56 OF FOAM FILMS
2.1.8. THIN LIQUID FILMS - PRESSURE BALANCE TECHNIQUE 58 2.2.
MACROSCOPIC FOAM FILMS 60 2.2.1. LARGE FLAT FOAM FILMS ON A FRAME 61
2.2.2. METHODS FOR MEASUREMENT OF FOAM FILM ELASTICITY 64 2.2.3.
TECHNIQUES FOR MEASUREMENT OF THE LATERAL ELECTRICAL 67 CONDUCTIVITY OF
FOAM FILMS 2.2.4. ELLIPSOMETRY OF BLACK FOAM FILMS 70 2.2.5. FT-IR
SPECTROSCOPY STUDIES OF FOAM FILMS 71 2.2.6. X-RAY REFLECTIVITY OF FOAM
FILMS 73 2.3. SPHERICAL FOAM FILMS 74 2.3.1. MEASUREMENT OF THE
COEFFICIENT OF GAS PERMEABILITY TROUGH 78 FOAM FILMS 2.3.2. METHOD FOR
FORMATION OF FOAM FILMS FROM INSOLUBLE 80 SURFACTANTS REFERENCES 82
CHAPTER 3 PHYSICAL CHEMISTRY OF FOAMS FILMS 88 3.1. ELEMENTS OF THE
THERMODYNAMICS OF FOAM FILMS 89 3.1.1. CURVED LIQUID FILMS 89 3.1.2.
PLANE-PARALLEL THIN LIQUID FILMS 91 CONTENTS 3.1.3. THERMODYNAMICS OF
FOAM FILMS 93 3.1.4. MECHANICAL MODEL OF THE FOAM FILM AND ITS ADJACENT
96 MENISCUS 3.1.5. CONTACT ANGLES 98 3.1.6. LINE TENSION AT A CIRCULAR
LIQUID FILM 100 NON-EQUILIBRIUM PROPERTIES OF FOAM FILMS 102 3.2.1.
KINETICS OF THINNING OF FOAM FILMS 102 3.2.1.1. ASYMMETRIC DRAINAGE OF
FOAM FILMS 110 3.2.1.2. KINETICS OF FORMATION OF FOAM FILMS 113 3.2.2.
KINETICS OF RUPTURE OF FOAM FILMS 115 3.2.2.1. CRITICAL THICKNESS OF
FILM RUPTURE 115 3.2.2.2. CRITICAL THICKNESS OF RUPTURE AND BLACK SPOT
118 FORMATION IN MICROSCOPIC FOAM FILMS SURFACE FORCES IN FOAM FILMS 122
3.3.1. DISJOINING PRESSURE ISOTHERM AND EXPERIMENTAL 124 VERIFICATION OF
THE DLVO-THEORY 3.3.2. POTENTIAL OF THE DIFFUSE ELECTRIC LAYER AT
SOLUTION/AIR 134 INTERFACE 3.3.3. SURFACE FORCES IN FOAM FILMS FROM
AMPHIPHILIC BLOCK 150 COPOLYMERS 3.3.3.1. TRANSITION FROM ELECTROSTATIC
TO STERIC STABILISATION 150 IN FOAM FILMS FROM ABA TRIBLOCK COPOLYMERS
3.3.3.2. DYNAMIC METHOD FOR SURFACE FORCE MEASURMENT IN 157 FOAM FILMS
FROM ABA TRIBLOCK COPOLYMERS 3.3.3.3. DISJOINING PRESSURE IN FOAM FILMS
FROM ABA 162 TRIBLOCK COPOLYMERS BLACK FOAM FILMS (NANO BLACK FILMS) 167
3.4.1. SURFACE FORCES IN BLACK FOAM FILM 168 3.4.1.1. ISOTHERMS OF
DISJOINING PRESSURE OF BLACK FILMS FROM 171 NON-IONIC SURFACTANT
SOLUTIONS 3.4.1.2. ISOTHERMS OF DISJOINING PRESSURE OF BLACK FILMS FROM
179 PHOSPHOLIPIDS 3.4.1.3. ISOTHERMS OF DISJOINING PRESSURE OF BLACK
FILMS FROM 191 IONIC SURFACTANT SOLUTIONS 3.4.2. TRANSITION FROM COMMON
BLACK TO NEWTON BLACK FILMS 199 3.4.2.1. TWO EQUILIBRIUM STATES OF BLACK
FOAM FILMS 200 3.4.2.2. EXPERIMENTAL INVESTIGATIONS OF CBF/NBF
TRANSITION 201 3.4.2.3. METASTABLE BLACK FOAM FILMS 209 3.4.2.4.
ELESTROSTATIC ORIGIN OF THE TRANSITION TO NBF 212 3.4.2.5. MAIN
DIFFERENCES BETWEEN CBF AND NBF 216 3.4.2.6. THICKNESS TRANSITION IN
FOAM FILMS 218 3.4.3. RELATIONSHIP BETWEEN BLACK FOAM FILM FORMATION AND
THE 226 PROPERTIES OF THE SURFACTANT ADSORPTION LAYERS 3.4.3.1.
PROPERTIES OF THE ADSORPTION LAYERS 226 CONTENTS IX 3.4.3.2. PROBABILITY
FOR OBSERVATION OF BLACK FOAM FILMS 230 DEPENDING ON THE ADSORPTION
LAYER STATE 3.4.3.3. FORMATION OF BLACK FOAM FILMS FROM AN INSOLUBLE 234
SURFACTANT MONOLAYER 3.4.4. BILAYER BLACK FOAM FILMS (NBF) 236 3.4.4.1.
COMPARISON OF THE LIFETIME/SURFACTANT CONCENTRATION DEPENDENCE OF CBF
AND NBF 237 3.4.4.2. THEORY OF RUPTURE OF AMPHIPHILE BILAYERS 238
3.4.4.3. EXPERIMENTAL RESULTS ON STABILITY OF AMPHIPHILE 249 BILAYERS
3.4.4.4. PHASE TRANSITIONS IN PHOSPHOLIPID FOAM BILAYERS 263 3.4.4.5.
LINEAR ENERGY OF HOLES IN AMPHIPHILE BILAYERS 273 3.4.4.6. LINEAR ENERGY
OF THE CONTACT LINE BLACK FOAM FILM/ 276 BULK LIQUID 3.5. DIFFUSION
PROCESSES IN FOAM FILMS 282 3.5.1. GAS PERMEABILITY OF FOAM FILMS 282
3.5.2. GAS PERMEABILITY OF NBF 290 3.5.3. LATERAL DIFFUSION IN
PHOSPHOLIPID BLACK FOAM FILMS 295 3.5.4. LATERAL DIFFUSION OF VACANCIES
IN NBF 300 3.6. SIMILARITY OF FOAM FILMS WITH EMULSION AND ASYMMETRIC
THIN 303 LIQUID FILMS 3.6.1. EMULSION FILMS 303 3.6.2. ASYMMETRIC FILMS
OF THE LIQUID/LIQUID/GAS TYPE 309 REFERENCES 322 CHAPTER 4 FOAM
STRUCTURAL PARAMETERS AND RELATED PROPERTIES: TECHNIQUES 345 FOR
DETERMINATION 4.1. RELATION BETWEEN THE GEOMETRICAL (STRUCTURAL)
PARAMETERS OF A FOAM 345 AND ITS PHYSICOCHEMICAL CHARACTERISTICS 4.2.
DETERMINATION OF FOAM EXPANSION RATIO (FOAM DENSITY) 357 4.3.
DETERMINATION OF PRESSURE IN FOAM PLATEAU BORDERS 359 4.4. DETERMINATION
OF FOAM DISPERSITY 362 4.5. STUDY OF FOAM LIQUID DISTRIBUTION AND
PLATEAU BORDER PROFILES 375 REFERENCES 377 CHAPTER 5 FOAM DRAINAGE 381
5.1. A BRIEF CHARACTERISATION OF FOAM DRAINAGE 381 5.2. TECHNIQUES FOR
THE STUDY OF FOAM DRAINAGE 383 5.3. FOAM DRAINAGE AT HIGH PRESSURE DROP
385 5.3.1. HYDRODYNAMIC MODEL OF A FOAM 385 5.3.2. LIQUID FLOW THROUGH
POLYHEDRAL FOAMS WITH DIFFERENT TYPES 392 OF FOAM FILMS 5.3.2.1. LIQUID
FLOW IN GRAVITATIONAL FIELD 392 5.3.2.2. LIQUID FLOW UNDER PRESSURE DROP
397 X CONTENTS 5.3.3. EQUATIONS FOR DRAINAGE UNDER PRESSURE DROP 403
5.3.4. FOAM DRAINAGE AND THE KINETICS OF ESTABLISHING EQUILIBRIUM 409
PRESSURE IN THE FOAM LIQUID PHASE: EXPERIMENTAL STUDIES 5.3.4.1.
KINETICS OF ESTABLISHING PRESSURE IN THE FOAM LIQUID 410 PHASE 5.3.4.2.
INFLUENCE OF THE TYPE OF FOAM FILMS ON FOAM 418 DRAINAGE 5.4.
GRAVITATIONAL DRAINAGE OF A FOAM 420 5.4.1. EQUATIONS OF GRAVITATIONAL
DRAINAGE 420 5.4.2. INITIAL STAGE OF DRAINAGE 426 5.4.3. INFLUENCE OF
THE FOAM STRUCTURE AND THE PROPERTIES OF THE 431 FOAMING SOLUTION ON THE
DRAINAGE RATE 5.4.4. DRAINAGE OF THREE-PHASE FOAMS 439 5.5. INFLUENCE OF
INTERNAL FOAM COLLAPSE ON DRAINAGE 442 REFERENCES 442 CHAPTER 6 FOAM
COLLAPSE 447 6.1. TECHNIQUES INVOLVED IN THE STUDY OF THE KINETICS OF
INTERNAL FOAM 449 COLLAPSE 6.2. INTERNAL FOAM COLLAPSE AT DIFFUSION GAS
TRANSFER 455 6.3. COALESCENCE AND STRUCTURAL REARRANGEMENT 464 6.4.
KINETICS OF INTERNAL FOAM COLLAPSE 468 6.5. DECAY OF THE FOAM COLUMN 473
6.5.1. FOAM COLUMN DECAY IN GRAVITATIONAL FIELD 474 6.5.2. INFLUENCE OF
PLATEAU BORDER PRESSURE ON FOAM COLUMN 476 DESTRUCTION 6.5.3. FOAM
BREAKDOWN IN CENTRIFUGAL FIELD 486 6.6. COMPARISON BETWEEN THE RATE OF
INTERNAL FOAM COLLAPSE AND THE 494 DECREASE IN FOAM VOLUME REFERENCES
498 CHAPTER 7 FOAM STABILITY AND THE STABILISING ABILITY OF SURFACTANTS
502 7.1. DEFINITION OF THE TERM FOAM STABILITY AND FOAMING ABILITY OF
SOLUTIONS 502 7.2. CHARACTERISTICS OF STABILITY RELATED TO FOAM COLUMN
DECAY 505 7.3. KINETIC FACTORS OF FOAM STABILITY 510 7.4. THERMODYNAMIC
FACTORS OF FOAM STABILITY 519 7.5. MODEL APPROACH TO THE STUDY OF FOAM
STABILITY AND ANALYSIS OF 520 THE STABILISING FACTORS 7.5.1. ROLE OF
FOAM FILMS IN THE STABILITY OF FOAMS 520 7.5.2. STABILITY OF A REAL FOAM
527 7.6. PHYSICOCHEMICAL PROPERTIES OF SURFACTANTS AND THE STABILISING
ABILITY 530 OF THEIR SOLUTIONS 7.6.1. FOAM STABILISING PROPERTIES OF
SURFACTANTS DETERMINED BY 534 FOAM PRESSURE DROP TECHNIQUE AND
ROSS-MILES TEST CONTENTS XI 7.6.2. EFFECT OF THE ISOELECTRIC STATE AT
THE SOLUTION/AIR INTERFACE ON 539 THE STABILITY OF FOAMS FROM NONIONIC
SURFACTANTS 7.7. DEPENDENCE OF THE FOAMING ABILITY ON THE MODE OF FOAM
FORMATION 543 AND THE PROPERTIES OF THE SURFACTANT SOLUTIONS 7.8.
FOAMING ABILITY OF SOLUTIONS AND FOAM STABILITY 545 7.9. STABILISING
ABILITY AND HYDROPHILE-LIPOPHILE BALANCE OF SURFACTANTS 549 7.10.
STABILITY OF DYNAMIC FOAMS 556 7.11. FOAMED EMULSIONS WITH LARGE VOLUME
FRACTION OF THE DISPERSE PHASE 561 REFERENCES 565 CHAPTER 8 PHYSICAL
PROPERTIES OF FOAMS 571 8.1. MECHANICAL PROPERTIES 571 8.2. RHEOLOGICAL
PROPERTIES 574 8.3. ELECTRICAL PROPERTIES 586 8.3.1. ELECTRICAL
CONDUCTIVITY 586 8.3.2. ELECTROKINETIC PROPERTIES 590 8.4. OPTICAL
PROPERTIES 593 8.5. THERMOPHYSICAL PROPERTIES 601 REFERENCES 606 CHAPTER
9 FOAM BREAKDOWN BY ANTIFOAMS 610 9.1. TECHNIQUES FOR DETERMINATION OF
THE DEFOAMING EFFICIENCY OF 611 SUBSTANCES 9.2. ADSORPTION (HOMOGENEOUS)
MECHANISM OF FOAM BREAKDOWN 619 9.3. DEFOAMING IN HETEROGENEOUS SYSTEMS
623 9.3.1. INHIBITION OF BLACK SPOT FORMATION IN MICROSCOPIC FOAM 626
FILMS 9.3.2. ROLE OF ANTIFOAM SPREADING 628 9.3.3. MECHANISM OF
HETEROGENEOUS DEFOAMING 631 9.4. DEFOAMING ABILITY OF SOLID HYDROPHOBIC
PARTICLES 638 9.5. INVERSION OF THE DEFOAMING ABILITY OF ALCOHOLS 647
REFERENCES 652 CHAPTER 10 TECHNOLOGICAL APPLICATION OF FOAMS:
PHYSICOCHEMICAL GROUND 656 10.1. CLASSIFICATION OF FOAMS AND FILMS BY
THE PROPERTIES DETERMINING THEIR 656 TECHNOLOGICAL APPLICATION 10.2.
GENERAL PRINCIPLES OF REGULATION OF THE PHYSICOCHEMICAL PROPERTIES 658
OF FOAMS 10.3. ACCUMULATION AND SEPARATION OF SURFACTANTS IN A FOAM 663
10.3.1. CLASSIFICATION OF THE METHODS OF SURFACE SEPARATION 663 10.3.2.
CHARACTERISTICS OF THE EFFECTIVENESS OF ACCUMULATION, 666 SEPARATION AND
PURIFICATION OF SURFACTANT SOLUTIONS 10.3.3. EXPERIMENTAL STUDIES ON THE
ACCUMULATION OF INDIVIDUAL 682 SURFACTANTS AND MIXTURES XU CONTENTS
10.3.4. FOAM SEPARATION OF SURFACTANT COMPONENTS FROM MIXTURES 697 10.4.
OPTIMISATION OF THE PROCESSING PROPERTIES OF SOLIDIFYING FOAMS 703
10.4.1. THERMAL INSULATORS FROM FROZEN AQUEOUS FOAMS 704 10.4.2.
OLIGOMER POLYMER FOAMS 712 10.5. EXAMPLES OF FOAM INHIBITION IN THE
PROCESS OF EXTRACTION AND IN 716 EMULSION METALWORKING FLUIDS 10.6.
EXAMPLES OF THE USE OF NATURAL PRODUCTS AS FOAMING AGENTS 718 10.7. USE
OF FOAMS IN PETROLEUM AND GAS INDUSTRIES 719 REFERENCES 729 CHAPTER 11
BLACK FOAM FILMS: APPLICATION IN MEDICINE 738 11.1. BLACK FILM METHOD
FOR ASSESSMENT OF FOETAL LUNG MATURITY 738 11.2. PHASE STATE OF FOAM
BILAYER (NBF) FROM AMNIOTIC FLUID 744 11.3. A NEW HYPOTHESIS OF THE
STRUCTURE AND STABILITY OF ALVEOLAR SURFACE 751 11.4. BLACK FILM METHOD
FOR ASSESSMENT OF THERAPEUTIC SURFACTANTS 754 REFERENCES 758 SYMBOLS
SUBJECT INDEX 761 768
|
any_adam_object | 1 |
author | Exerowa, Dotchi Krugljakov, Pjotr M. |
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dewey-search | 541.34514 |
dewey-sort | 3541.34514 |
dewey-tens | 540 - Chemistry and allied sciences |
discipline | Chemie / Pharmazie Chemie-Ingenieurwesen |
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id | DE-604.BV012310071 |
illustrated | Illustrated |
indexdate | 2024-07-09T18:25:20Z |
institution | BVB |
isbn | 0444819223 |
language | English |
oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-008345096 |
oclc_num | 632272106 |
open_access_boolean | |
owner | DE-91G DE-BY-TUM DE-83 |
owner_facet | DE-91G DE-BY-TUM DE-83 |
physical | XXII, 773 S. Ill., graph. Darst. |
publishDate | 1998 |
publishDateSearch | 1998 |
publishDateSort | 1998 |
publisher | Elsevier |
record_format | marc |
series | Studies in interface science |
series2 | Studies in interface science |
spelling | Exerowa, Dotchi Verfasser aut Foam and foam films theory, experiment, application Dotchi Exerowa ; Pyotr M. Kruglyakov Amsterdam [u.a.] Elsevier 1998 XXII, 773 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Studies in interface science 5 Foam Membranes (Technology) Schaum (DE-588)4116372-2 gnd rswk-swf Schaum (DE-588)4116372-2 s DE-604 Krugljakov, Pjotr M. Verfasser aut Studies in interface science 5 (DE-604)BV010480178 5 GBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=008345096&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
spellingShingle | Exerowa, Dotchi Krugljakov, Pjotr M. Foam and foam films theory, experiment, application Studies in interface science Foam Membranes (Technology) Schaum (DE-588)4116372-2 gnd |
subject_GND | (DE-588)4116372-2 |
title | Foam and foam films theory, experiment, application |
title_auth | Foam and foam films theory, experiment, application |
title_exact_search | Foam and foam films theory, experiment, application |
title_full | Foam and foam films theory, experiment, application Dotchi Exerowa ; Pyotr M. Kruglyakov |
title_fullStr | Foam and foam films theory, experiment, application Dotchi Exerowa ; Pyotr M. Kruglyakov |
title_full_unstemmed | Foam and foam films theory, experiment, application Dotchi Exerowa ; Pyotr M. Kruglyakov |
title_short | Foam and foam films |
title_sort | foam and foam films theory experiment application |
title_sub | theory, experiment, application |
topic | Foam Membranes (Technology) Schaum (DE-588)4116372-2 gnd |
topic_facet | Foam Membranes (Technology) Schaum |
url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=008345096&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
volume_link | (DE-604)BV010480178 |
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