Electrocyclic reactions: from fundamentals to research
Gespeichert in:
| Hauptverfasser: | , , |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Weinheim [u.a.]
Wiley-VCH
1999
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XIV, 274 S. graph. Darst. 1 Diskette (9 cm) |
| ISBN: | 3527297553 |
Internformat
MARC
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| 245 | 1 | 0 | |a Electrocyclic reactions |b from fundamentals to research |c Farzana Latif Ansari ; Rumana Qureshi ; Masood Latif Qureshi |
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| 650 | 7 | |a Stéréochimie |2 ram | |
| 650 | 7 | |a Électrochimie |2 ram | |
| 650 | 4 | |a Addition reactions | |
| 650 | 4 | |a Ring formation (Chemistry) | |
| 650 | 4 | |a Stereochemistry | |
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Datensatz im Suchindex
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| adam_text | FARZANA LATIF ANSARI, RUMANA QURESHI, MASOOD LATIF QURESHI ELECTROCYCLIC
REACTIONS FROM FUNDAMENTALS TO RESEARCH WILEY-VCH WEINHEIM * NEW YORK
* CHICHESTER * BRISBANE * SINGAPORE * TORONTO CONTENTS PREFACE V
ACKNOWLEDGEMENTS VII FOREWORD IX 1. PERICYCLIC REACTIONS 1 1.1 GENERAL
FEATURES 2 1.2 CLASSIFICATION 3 1.2.1 ELECTROCYCLIC TRANSFORMATIONS 3
1.2.2 SIGMATROPIC REARRANGEMENTS 3 1.2.3 CYCLOADDITION REACTIONS 4 1.2.4
CHELETROPIC REACTIONS 4 1.2.5 GROUP TRANSFER REACTIONS 4 1.3 ANALYSIS 5
1.3.1 ORBITAL SYMMETRY CONSERVATION 5 1.3.2 FRONTIER ORBITALS APPROACH 6
1.3.3 MOEBIUS-HUECKEL APPROACH 7 1.3.4 THEORETICAL AND COMPUTATIONAL
APPROACH 7 1.4 SIGNIFICANCE 8 1.5 REFERENCES 12 2. ELECTROCYCLIC
TRANSFORMATIONS 15 2.1 MECHANISM 16 2.2 THERMAL ELECTROCYCLIZATIONS 21
2.2.1 [1,3] ELECTROCYCLIC REACTIONS 21 2.2.2 [1,4] ELECTROCYCLIC
REACTIONS 23 2.2.3 [1,5] ELECTROCYCLIC REACTIONS 27 2.2.3.1
ISOELECTRONIC EXCHANGE 29 2.2.3.2 ISOIONIC EXCHANGE 32 2.2.4 [1,6]
ELECTROCYCLIC REACTIONS 35 2.3 PHOTOCHEMICAL ELECTROCYCLIZATIONS 40 2.4
ELECTROCYCLIZATIONS OF RADICALS AND RADICAL IONS 48 2.5 METAL CATALYSIS
51 2.6 REFERENCES 55 XLL CONTENTS 3. ORBITAL SYMMETRY CONSERVATION 59
3.1 BASIC CONCEPTS 60 3.1.1 CONROTATION AND DISROTATION 60 3.1.2 ORBITAL
SYMMETRY 62 3.1.3 SYMMETRY CONSERVATION 70 3.1.3.1 DISROTATORY
CYCLIZATION 70 3.1.3.2 CONROTATORY CYCLIZATION 71 3.2 APPLICATIONS 73
3.2.1 ENERGY LEVEL CORRELATION ANALYSIS 73 3.2.1.1 EVEN-ELECTRON SYSTEMS
73 3.2.1.2 ODD-ELECTRON SYSTEMS 90 3.2.2 SYMMETRY STATE CORRELATION
ANALYSIS 91 3.2.2.1 EVEN-ELECTRON SYSTEMS 92 3.2.2.2 ODD-ELECTRON
SYSTEMS 101 3.3 LIMITATIONS 105 3.4REFERENCES 108 4. FRONTIER ORBITALS
APPROACH 109 4.1 BASIC CONCEPTS 109 4.1.1 INTERACTIONS BETWEEN ORBITALS
109 4.1.1.1 ATOMIC ORBITALS 109 4.1.1.2 MOLECULAR ORBITALS 115 4.1.2
SUPRAFACIAL AND ANTARAFACIAL GEOMETRIES 120 4.2 APPLICATIONS 126 4.2.1
CYCLOADDITIONS 126 4.2.2 ELECTROCYCLIZATIONS 129 4.2.2.1 THERMAL 129
4.2.2.2 PHOTOCHEMICAL 137 4.3 GENERALIZED SELECTION RULES 139 4.3.1
ODD-SUMRULE 140 4.3.2 ODD-EVENRULE 144 4.4 REFERENCES 147 5.
MOEBIUS-HUECKEL APPROACH 149 5.1 BASIC CONCEPTS 151 5.1.1 HUECKEL SYSTEMS
151 5.1.1.1 HMO RELATIONSHIP 154 5.1.1.2 ENERGY LEVEL PATTERNS 155 5.1.2
MOEBIUS SYSTEMS 166 5.1.2.1 GROUND STATE EXAMPLES 169 5.1.2.2 ENERGY
LEVEL PATTERNS 172 CONTENTS XM 5.2 APPLICATIONS 179 5.2.1 THERMAL
REACTIONS 179 5.2.2 PHOTOCHEMICAL REACTIONS 186 5.3 SUMMARY 187 5.4
REFERENCES 190 6. THEORETICAL AND COMPUTATIONAL APPROACH 193 6.1 STUDY
OF REACTION PATHS 195 6.1.1 EVEN-ELECTRON SYSTEMS 195 6.1.1.1 [1,3]
ELECTROCYCLIC REACTIONS 195 6.1.1.2 [ 1,4] ELECTROCYCLIC REACTIONS 199
6.1.1.3 [1,5] ELECTROCYCLIC REACTIONS 203 6.1.1.4 [1,6] ELECTROCYCLIC
REACTIONS 204 6.1.1.5 [ 1,8] ELECTROCYCLIC REACTIONS 206 6.1.2
ODD-ELECTRON SYSTEMS 206 6.1.2.1 RING OPENING OF CYCLOPROPYL RADICAL 207
6.1.2.2 ELECTROCYCLIC REACTIONS OF BICYCLOALKYL RADICALS 210 6.2
STEREOSELECTIVITY IN ELECTROCYCLIC REACTIONS 212 6.2.1 EXPERIMENTAL
ASPECT 213 6.2.1.1 EXPERIMENTAL OBSERVATIONS 213 6.2.1.2 INTERPRETATION
OF EXPERIMENTAL ACTIVATION ENERGY DATA 214 6.2.2 THEORETICAL ASPECT 218
6.2.2.1 INTERPRETATION OF THEORETICAL ACTIVATION ENERGY DATA 218 6.2.2.2
THEORETICAL EXPLANATION OF STEREOSELECTIVITY 224 6.3 REFERENCES 232
APPENDIX A. MOLECULAR ORBITAL THEORY 235 A. 1. BASIC CONCEPTS OF QUANTUM
MECHANICS 235 A. 1.1. THE SCHROEDINGER EQUATION 235 A. 1.2 ATOMIC
ORBITALS 236 A.2. DIFFERENCE BETWEEN MO AND VB THEORIES 237 A.3.
MATHEMATICAL FORMULATION OF MOLECULAR ORBITAL THEORY 238 A.3.1. LCAO
APPROACH 23 8 A.3.2. SHAPES AND ENERGIES OF MOS 240 A.3.3. DIFFERENT MO
METHODS 241 A.4. HUECKEL MOLECULAR ORBITAL METHOD 242 A.4.1. LIMITATIONS
AND ASSUMPTIONS OF HMO METHOD 242 A.4.2. APPLICATIONS OF HMO METHOD 243
A.4.2.1. ETHYLENE 243 A.4.2.2. ALLYL SYSTEM 244 A.4.2.3.BUTADIENE 245
XIV CONTENTS A.4.4. EHMO METHOD 249 A.5. SCFMETHODS 250 A.5.1.RHF METHOD
250 A.5.2. UHF METHOD 250 A.6. AB INITIO METHODS 251 A.7. CONFIGURATION
INTERACTION 251 A.7.1. ELECTRONIC CONFIGURATION AND ELECTRONIC STATES
251 A.7.2. SCHEMES FOR CONFIGURATION INTERACTION 253 A.8. REFERENCES 254
APPENDIX B. SYMMETRY CLASSIFICATION OF MOLECULES 255 B.L. SYMMETRY
ELEMENTS 256 B. 1.1. CENTRE OF SYMMETRY 256 B. 1.2. ROTATION AXIS OF
SYMMETRY 256 B.1.3. PLANE OF SYMMETRY 257 B. 1.4. ROTATION-REFLECTION
AXIS OF SYMMETRY 259 B.1.5.IDENTITY 259 B.2. POINT GROUPS 261 B.2.1.
SCHOENFLIES NOTATIONS 261 B.2.2. ESTABLISHING THE MOLECULAR POINT GROUP
266 B.3. REFERENCES 268 INDEX 269
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| spelling | Ansari, Farzana Latif Verfasser (DE-588)121019381 aut Electrocyclic reactions from fundamentals to research Farzana Latif Ansari ; Rumana Qureshi ; Masood Latif Qureshi Weinheim [u.a.] Wiley-VCH 1999 XIV, 274 S. graph. Darst. 1 Diskette (9 cm) txt rdacontent n rdamedia nc rdacarrier Cyclisation (chimie) ram Electrochemistry Réactions dáddition ram Stéréochimie ram Électrochimie ram Addition reactions Ring formation (Chemistry) Stereochemistry Elektrocyclische Reaktion (DE-588)4151778-7 gnd rswk-swf CD-ROM (DE-588)4139307-7 gnd rswk-swf Elektrocyclische Reaktion (DE-588)4151778-7 s DE-604 CD-ROM (DE-588)4139307-7 s Qureshi, Rumana Verfasser (DE-588)121958981 aut Qureshi, Masood Latif Verfasser (DE-588)121959023 aut GBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=008314475&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Ansari, Farzana Latif Qureshi, Rumana Qureshi, Masood Latif Electrocyclic reactions from fundamentals to research Cyclisation (chimie) ram Electrochemistry Réactions dáddition ram Stéréochimie ram Électrochimie ram Addition reactions Ring formation (Chemistry) Stereochemistry Elektrocyclische Reaktion (DE-588)4151778-7 gnd CD-ROM (DE-588)4139307-7 gnd |
| subject_GND | (DE-588)4151778-7 (DE-588)4139307-7 |
| title | Electrocyclic reactions from fundamentals to research |
| title_auth | Electrocyclic reactions from fundamentals to research |
| title_exact_search | Electrocyclic reactions from fundamentals to research |
| title_full | Electrocyclic reactions from fundamentals to research Farzana Latif Ansari ; Rumana Qureshi ; Masood Latif Qureshi |
| title_fullStr | Electrocyclic reactions from fundamentals to research Farzana Latif Ansari ; Rumana Qureshi ; Masood Latif Qureshi |
| title_full_unstemmed | Electrocyclic reactions from fundamentals to research Farzana Latif Ansari ; Rumana Qureshi ; Masood Latif Qureshi |
| title_short | Electrocyclic reactions |
| title_sort | electrocyclic reactions from fundamentals to research |
| title_sub | from fundamentals to research |
| topic | Cyclisation (chimie) ram Electrochemistry Réactions dáddition ram Stéréochimie ram Électrochimie ram Addition reactions Ring formation (Chemistry) Stereochemistry Elektrocyclische Reaktion (DE-588)4151778-7 gnd CD-ROM (DE-588)4139307-7 gnd |
| topic_facet | Cyclisation (chimie) Electrochemistry Réactions dáddition Stéréochimie Électrochimie Addition reactions Ring formation (Chemistry) Stereochemistry Elektrocyclische Reaktion CD-ROM |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=008314475&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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