Correlation of local deformation and chain dynamics in polymer networks:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
1998
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| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | Münster, Univ., Diss., 1998 |
| Beschreibung: | IV, 173 S. graph. Darst. |
Internformat
MARC
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| 245 | 1 | 0 | |a Correlation of local deformation and chain dynamics in polymer networks |c vorgelegt von Stephan Westermann |
| 264 | 1 | |c 1998 | |
| 300 | |a IV, 173 S. |b graph. Darst. | ||
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Datensatz im Suchindex
| _version_ | 1812452972818333696 |
|---|---|
| adam_text |
CONTENTS
1 INTRODUCTION
2 THEORY
2.1 MECHANICS OF DEFORMABLE SOLIDS.
2.1.1 ST LESS AND ST RAIN LONSORS .
2.1.2 BASIC LAWS OF ('OUT INNNM MECHANICS
2.1.'L MECHANICS'IN HETEROGENEOUS SYSTEMS
2.2 BASIC PRINCIPLES IN POLYMER PHYSICS
.
2.2.1 VISCOELASTIC BEHAVIOUR OF POLYMERS
2.2.2 CHAIN STATISTICS.
2.2.3 CHAIN DYNAMICS.
2.3 THERMODYNAMICS OF BLOCK COPOLYMERS . . .
2.1 POLYMER NETWORKS.
2.1.1 PHANTOM MODELS.
2.1.2 TUBE MODELS .
2.5 NEUTRON SCATTERING.
2.5.1 ELASTIC SCAT 1 ('RING.
2.5.2 INELASTIC SCATTERING.
1
3
3
3
?)
!)
L(I
21
23
23
27
32
33
3X
3 EXPERIMENTAL ASPECTS 41
3.1 SAMPLE PREPARATION. II
3.1.1 SYNTHESIS
I
11
BIBLIOGRAFISCHE INFORMATIONEN
HTTP://D-NB.INFO/954108655
II_CONTEXTS
YY5.1.2 CHARACTERIZATION . 1-5
3.1.3 CROSSLINKING. 11
.'5.1.1 SWELLING. -1")
3.2 SCATTERING METHODS. TO
3.2.1 SMALL ANGLE NEUTRON SCATTERING. 16
3.2.2 NEUTRON SPIN ECHO SPECTROSCOPY (NSE) . 53
3.2.3 SMALL ANGLE X-HAV SCATT('RING. 57
4 STRUCTURE FACTORS 59
1.1 THE WARNER-EDWARDS APPROACH . 59
1.2 EXTENSION OF THE
1 WARNER-EDWARDS APPROACH ACCORDING TO THE TUBE
MODEL OF HEINRICH AND STRAUBE. 60
1.3 R PA OF MULTICOMPONENT SYSTEMS . 61
1.1 THE RPA STRUCTURE FACTOR OF A TRIBLOCK-COPOLYMER. 63
5 RESULTS: UNFILLED ELASTOMERS 65
5.1 POLYISOPRENE-HOMOPOLYMERS. 65
5.1.1 SAMPLES. 67
5.1.2 SANS RESULTS. 68
5.1.3 NSE RESULTS. 83
5.1.1 COMPARISON TO OTHER MODELS. 87
5.2 111)11-TRIBLOCK COPOLYMERS. 89
5.2.1 SAMPLES. 89
5.2.2 SANS RESULTS FROM 111)11 COPOLYMER MELTS . 90
5.2.3 SANS RESULTS FROM ISOTROPIC HI)H COPOLYMER NETWORKS . . 91
5.2.1 SANS RESULTS FROM 11DH COPOLYMER NETWORKS UNDER DEFOR
MATION . 92
6 RESULTS: FILLED ELASTOMERS 109
6.1 MOTIVATION.109
CONTEXTS
III
0.2 PHASE AND COMPOSITION MATCHING.
0.3 SAMPLES.
0.4 CHARACTERIZATION OF THE FILLER.
0.1.1 INTERPRETATION OF THE SAXS DATA.
0.4.2 RESULTS.
6.5 DEFORMATION OF THE MATRIX CHAINS.YY .
0.5.1 ANALYSIS OF THE SANS DATA.
0.5.2 INTERPRETATION OF THE MICROSCOPIC OVERSTRAIN
7 CONCLUSION
A KINETICS OF RANDOM SCISSION PROCESSES
A.L SCISSION KINET ICS IN HOMOPOLYMER SYSTEMS.
A.2 SCISSION KINETICS IN
IIDII COPOLYMERS.
113
111
111
1
10
121
121
124
131
135
135
138
B SCATTERING FUNCTIONS IN TRIBLOCK SYSTEMS 141
C MULTICOMPONENT RPA FOR RANDOMLY SCISSIONED HDH COPOLYMERS 143
D NON-AFFINE DEFORMATIONS IN HDH COPOLYMERS 145
D.L CALCULATION OF A REDUCED DEFORMATION.145
D. 2 CALCULATION OF THE SCATTERING FUNCTION.117
E THERMAL DEGRADATION IN POLYISOPRENE NETWORKS 149
E. L THE SANS EXPERIMENT.149
E.2 INTERPRETATION.151
LIST OF FIGURES 154
LIST OF TABLES 160
REFERENCES 162
CONTENTS
IV
DANKSAGUNG 170
LEBENSLAUF 172 |
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| genre_facet | Hochschulschrift |
| id | DE-604.BV012015145 |
| illustrated | Illustrated |
| indexdate | 2024-10-09T16:04:08Z |
| institution | BVB |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-008132064 |
| oclc_num | 245816510 |
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| owner_facet | DE-91 DE-BY-TUM DE-29T DE-355 DE-BY-UBR DE-11 |
| physical | IV, 173 S. graph. Darst. |
| publishDate | 1998 |
| publishDateSearch | 1998 |
| publishDateSort | 1998 |
| record_format | marc |
| spelling | Westermann, Stephan Verfasser aut Correlation of local deformation and chain dynamics in polymer networks vorgelegt von Stephan Westermann 1998 IV, 173 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Münster, Univ., Diss., 1998 Röntgen-Kleinwinkelstreuung (DE-588)4178309-8 gnd rswk-swf Deformation (DE-588)4070262-5 gnd rswk-swf Neutronenkleinwinkelstreuung (DE-588)4171646-2 gnd rswk-swf Polyisoprene (DE-588)4175216-8 gnd rswk-swf Polymeres Netzwerk (DE-588)4307122-3 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Polyisoprene (DE-588)4175216-8 s Polymeres Netzwerk (DE-588)4307122-3 s Deformation (DE-588)4070262-5 s Neutronenkleinwinkelstreuung (DE-588)4171646-2 s Röntgen-Kleinwinkelstreuung (DE-588)4178309-8 s DE-604 DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=008132064&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Westermann, Stephan Correlation of local deformation and chain dynamics in polymer networks Röntgen-Kleinwinkelstreuung (DE-588)4178309-8 gnd Deformation (DE-588)4070262-5 gnd Neutronenkleinwinkelstreuung (DE-588)4171646-2 gnd Polyisoprene (DE-588)4175216-8 gnd Polymeres Netzwerk (DE-588)4307122-3 gnd |
| subject_GND | (DE-588)4178309-8 (DE-588)4070262-5 (DE-588)4171646-2 (DE-588)4175216-8 (DE-588)4307122-3 (DE-588)4113937-9 |
| title | Correlation of local deformation and chain dynamics in polymer networks |
| title_auth | Correlation of local deformation and chain dynamics in polymer networks |
| title_exact_search | Correlation of local deformation and chain dynamics in polymer networks |
| title_full | Correlation of local deformation and chain dynamics in polymer networks vorgelegt von Stephan Westermann |
| title_fullStr | Correlation of local deformation and chain dynamics in polymer networks vorgelegt von Stephan Westermann |
| title_full_unstemmed | Correlation of local deformation and chain dynamics in polymer networks vorgelegt von Stephan Westermann |
| title_short | Correlation of local deformation and chain dynamics in polymer networks |
| title_sort | correlation of local deformation and chain dynamics in polymer networks |
| topic | Röntgen-Kleinwinkelstreuung (DE-588)4178309-8 gnd Deformation (DE-588)4070262-5 gnd Neutronenkleinwinkelstreuung (DE-588)4171646-2 gnd Polyisoprene (DE-588)4175216-8 gnd Polymeres Netzwerk (DE-588)4307122-3 gnd |
| topic_facet | Röntgen-Kleinwinkelstreuung Deformation Neutronenkleinwinkelstreuung Polyisoprene Polymeres Netzwerk Hochschulschrift |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=008132064&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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