Biopolymers from renewable resources:
Gespeichert in:
| Format: | Buch |
|---|---|
| Sprache: | English |
| Veröffentlicht: |
Berlin [u.a.]
Springer
1998
|
| Schriftenreihe: | Macromolecular systems - materials approach
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XVIII, 417 S. graph. Darst. |
| ISBN: | 354063567X |
Internformat
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| 245 | 1 | 0 | |a Biopolymers from renewable resources |c D. L. Kaplan (ed.) |
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| adam_text | D.L.KAPLAN (ED.) BIOPOLYMERS FROM RENEWABLE RESOURCES WITH 118 FIGURES
SPRINGER CONTENTS CHAPTER 1 INTRODUCTION TO BIOPOLYMERS FROM RENEWABLE
RESOURCES D.L.KAPLAN 1 1.1 INTRODUCTION 1 1.1.1 NATURAL FUNCTIONS 1
1.1.2 BENEFITS 1 1.1.3 LIMITATIONS 2 1.1.4 INTERFACE BETWEEN BIOLOGY AND
MATERIALS SCIENCE 2 1.2 POLYSACCHARIDES 3 1.2.1 POLYSACCHARIDES (PLANT,
ALGAL) 3 1.2.2 POLYSACCHARIDES (ANIMAL) 10 1.2.3 POLYSACCHARIDES
(FUNGAL) 11 1.2.4 POLYSACCHARIDES (BACTERIAL) 12 1.3 PROTEINS 16 1.4
POLYESTERS 20 1.5 LIPIDS/SURFACTANTS 22 1.6 SPECIALTY POLYMERS 23 1.7
CONCLUSIONS 25 1.8 REFERENCES 26 CHAPTER 2 STARCH: PROPERTIES AND
MATERIALS APPLICATIONS R. L. SHOGRUN 30 2.1 INTRODUCTION 30 2.2 SOURCES
OF STARCH 30 2.3 STRUCTURE AND COMPOSITION 31 2.4 METHODS OF ISOLATION
AND CHARACTERIZATION 33 2.5 PROPERTIES 34 2.6 CHEMICALLY MODIFIED
STARCHES 35 2.7 PROCESSING METHODS 36 2.8 PROPERTIES OF PROCESSED STARCH
37 2.9 APPLICATIONS 40 2.9.1 FOOD 40 2.9.2 PAPER 41 2.9.3 TEXTILES,
ADHESIVES, AND OTHER USES 41 VIII CONTENTS 2.9.4 BIODEGRADABLE PLASTICS
42 2.10 REFERENCES 43 CHAPTER 3 POLYSACCHARIDES - CELLULOSE R. D.GILBERT
J. F.KADLA 47 3.1 INTRODUCTION 47 3.2 CHEMICAL COMPOSITION AND STRUCTURE
47 3.3 CONFORMATIONAL ASPECTS 49 3.4 HYDROGEN BONDING 49 3.5 MOLECULAR
WEIGHT 51 3.6 CRYSTALLINITY 51 3.7 CELLULOSE POLYMORPHS 52 3.8 CELLULOSE
I . 55 3.8.1 INTRA-MOLECULAR HYDROGEN BONDING 55 3.8.2 CRYSTAL STRUCTURE
OF CELLULOSE I 56 3.8.3 CELLULOSE I* AND IP 58 3.9 CELLULOSE II 61 3.9.1
CRYSTAL STRUCTURE OF CELLULOSE II 61 3.9.2 HYDROGEN-BONDING 62 3.10
FIBRILLAR STRUCTURE 64 3.11 SYNTHETIC CELLULOSE 65 3.12 CELLULOSIC
MESOPHASES 66 3.12.1 INTRODUCTION 66 3.12.2 LIQUID CRYSTAL SOLUTIONS OF
CELLULOSE 69 3.12.3 LIQUID CRYSTALLINE CELLULOSE DERIVATIVES 72 3.12.4
THERMOTROPIC CELLULOSE DERIVATIVES 72 3.13 CHEMICAL MODIFICATION 73
3.13.1 INTRODUCTION 73 3.13.2 CELLULOSE ESTERS 80 3.13.3 CELLULOSE
ETHERS 82 3.13.4 CELLULOSE SULFATE ESTERS 86 3.13.5 REDUCTION OF
CELLULOSE 87 3.13.6 HOMOGENEOUS DERIVATIZATION 87 3.13.7 CELLULOSE GRAFT
COPOLYMERS 88 3.14 BIOTECHNOLOGY ROUTES TO CELLULOSE 89 3.15 REFERENCES
90 CHAPTER 4 POLYSACCHARIDES: CHITIN AND CHITOSAN: CHEMISTRY AND
TECHNOLOGY OF THEIR USE AS STRUCTURAL MATERIALS S.M.HUDSON, * SMITH 96
4.1 INTRODUCTION 96 4.2 SOURCES OF CHITIN AND CHITOSAN 97 CONTENTS IX
4.3 THE STRUCTURE AND COMPOSITION OF CHITIN AND CHITOSAN 100 4.3.1
STRUCTURE 100 4.3.2 POLYMORPHS 102 4.4 METHODS OF ISOLATION AND
CHARACTERIZATION 104 4.4.1 ISOLATION OF CHITIN 104 4.4.2 DEGREE OF
N-ACETYLATION 106 4.4.3 MOLECULAR WEIGHT AND MOLECULAR WEIGHT
DISTRIBUTION 107 4.5 PHYSICAL, CHEMICAL, AND BIOLOGICAL PROPERTIES OF
CHITIN AND CHITOSAN 107 4.5.1 SOLUTION PROPERTIES 108 4.5.2 BIOLOGICAL
PROPERTIES 108 4.6 CHEMICAL MODIFICATIONS OF CHITIN AND CHITOSAN 109 4.7
PROCESSING AND PHYSICAL FORMS OF MATERIALS BASED ON CHITIN AND CHITOSAN
110 4.7.1 FIBERS 110 4.7.2 FILMS 112 4.7.3 OTHER PHYSICAL FORMS 113 4.8
PRODUCTS AND APPLICATIONS OF CHITIN AND CHITOSAN 114 4.9 REFERENCES 115
CHAPTER 5 ALGINATES D.F.DAY 119 5.1 INTRODUCTION 119 5.2 SOURCES OF
BIOPOLYMER - RENEWABLE SOURCES 120 5.2.1 SEAWEED ALGINATES 120 5.2.2
BACTERIAL ALGINATES 121 5.3 STRUCTURE AND COMPOSITION 124 5.3.1 SEAWEED
ALGINATES 124 5.3.2 BACTERIAL ALGINATES 126 5.4 METHODS OF ISOLATION,
PURIFICATION, AND CHARACTERIZATION 127 5.4.1 SEAWEED ALGINATE 127 5.4.2
BACTERIAL ALGINATES 128 5.5 PHYSICAL, CHEMICAL, AND BIOLOGICAL
PROPERTIES 130 5.5.1 SEAWEED ALGINATE 130 5.5.2 ALGINATE GELS 132 5.6
ALGINATE AS AN ION EXCHANGER 134 5.6.1 SEAWEED ALGINATE 134 5.6.2
BACTERIAL ALGINATE 135 5.7 CHEMICAL OR OTHER MODIFICATIONS 136 5.7.1
SEAWEED POLYMER 136 5.7.2 BACTERIAL POLYMER 137 5.8 PROCESSING OF THE
BIOPOLYMER 138 5.9 PRODUCTION OR POTENTIAL APPLICATIONS 140 5.9.1
SEAWEED ALGINATE 140 X CONTENTS 5.9.2 BACTERIAL ALGINATE 140 5.10
REFERENCES 142 CHAPTER 6 SOY PROTEIN AS BIOPOLYMER Y.T.-P.LY,
L.A.JOHNSON, J. JANE 144 6.1 INTRODUCTION 144 6.2 PRODUCTION OF SOY
PROTEIN 144 6.3 STRUCTURE AND COMPOSITION OF SOY PROTEIN 150 6.4
PHYSICOCHEMICAL PROPERTIES OF SOY PROTEIN 153 6.4.1 WATER BINDING
CAPACITY 153 6.4.2 WATER HOLDING CAPACITY 154 6.4.3 SWELLING 155 6.4.4
SOLUBILITY 155 6.4.5 VISCOSITY 156 6.4.6 GELATION 157 6.5 PROCESSING OF
SOY PROTEIN FOR PLASTICS 158 6.5.1 EFFECT OF PLASTICIZERS 159 6.5.2
EFFECT OF TEMPERATURE 164 6.6 PROPERTIES OF SOY PROTEIN PLASTICS 165
6.6.1 NATIVE SOY PROTEINS 166 6.6.2 ACID TREATMENT 167 6.6.3
CROSS-LINKING 167 6.6.4 ACETYLATION 168 6.6.5 ESTERIFICATION 168 6.6.6
GRAFT COPOLYMERIZATION 171 6.6.7 INCORPORATION OF OTHER BIOPOLYMERS 172
6.7 INDUSTRIAL APPLICATIONS OF SOY PROTEIN 172 6.7.1 HISTORICAL AND
CURRENT STATUS 172 6.7.2 SOY PROTEIN FOR BIODEGRADABLE PLASTICS 174 6.8
REFERENCES 174 CHAPTER 7 PROTEIN-BASED MATERIALS M.M.BUTLER, K.P.
MCGRATH 177 7.1 INTRODUCTION 177 7.2 CHEMICAL SYNTHESIS OF POLYPEPTIDES
178 7.2.1 POLYCONDENSATION 178 7.2.2 POLYMERIZATION OF
**-CARBOXYANHYDRIDES ... * 179 7.3 BIOSYNTHETIC PRODUCTION OF
POLYPEPTIDES 180 7.3.1 STRATEGIES IN GENETIC DESIGN 180 7.3.2 EXPRESSION
OF TARGET PROTEINS 181 7.4 USEFUL CLASSES OF PROTEIN MATERIALS 184 7.4.1
FIBER-FORMING PROTEINS 184 CONTENTS XI 7.4.2 ELASTOMERIC PROTEINS 187
7.4.3 ADHESIVE PROTEIN MATERIALS 190 7.5 OPPORTUNITIES AND LIMITATIONS
192 7.6 REFERENCES 192 CHAPTER 8 BACTERIAL Y-POLY(GLUTAMIC ACID) R. A.
GROSS 195 8.1 INTRODUCTION AND BACKGROUND 195 8.2 BIOLOGICAL ROLE OF
Y-PGA BIOSYNTHESIS 196 8.3 PURIFICATION FROM CULTURE BROTH 197 8.4
ANALYSES OF Y-PGA BY NUCLEAR MAGNETIC RESONANCE (NMR) AND GEL PERMEATION
CHROMATOGRAPHY (GPC) 197 8.5 FERMENTATION METHODS: MEDIUM FORMULATIONS,
NUTRITIONAL REQUIREMENTS AND STRAIN DEGENERATION 199 8.5.1 METALS AND
NITROGEN 199 8.5.2 Y-PGA FORMATION BY B. IKHENIFORMIS 9945 A ON MEDIUM
E 200 8.5.3 OTHER PRODUCTION STRAINS, MEDIA REQUIREMENTS AND CARBON
SOURCES 203 8.5.4 DEGENERACY TO A NON-Y-PGA PRODUCING VARIANT 204 8.6
STEREOCHEMICAL COMPOSITION OF Y-PGA 204 8.6.1 DIFFERENCES AS A FUNCTION
OF THE PRODUCTION STRAIN 204 8.6.2 EFFECTS OF MN (II) AND OTHER DIVALENT
METAL SALTS 205 8.7 MOLECULAR WEIGHT OF Y-PGAS 207 8.8 BIOCHEMICAL
PATHWAYS OF Y-PGA BIOSYNTHESIS 209 8.9 Y-PGA DEGRADING ENZYMES 212 8.10
MODIFICATION OF Y-PGA 214 8.11 PHYSICAL PROPERTIES AND APPLICATIONS 215
8.12 REFERENCES 217 CHAPTER 9 POLYHYDROXYALKANOATES
P.J.HOCKING,R.H.MARCHESSAULT 220 9.1 INTRODUCTION 220 9.2 HISTORY 220
9.3 BIOLOGICAL PRODUCTION 222 9.3.1 BIOSYNTHESIS OF PHB AND PHBV 222
9.3.2 OTHER BACTERIAL PHAS 224 9.3.3 ISOLATION 226 9.3.4 COMMERCIAL
PRODUCTION 227 9.4 PROPERTIES 228 9.4.1 PHYSICAL PROPERTIES 228 9.4.2
CRYSTAL STRUCTURE 229 9.5 DEGRADATION 232 XII CONTENTS 9.5.1
INTRACELLULAR BIODEGRADATION 232 9.5.2 EXTRACELLULAR BIODEGRADATION 234
9.5.3 THERMAL DEGRADATION 235 9.5.4 HYDROLYTIC DEGRADATION 235 9.5.5
ENVIRONMENTAL DEGRADATION 236 9.6 APPLICATIONS 237 9.7 ECONOMICS 240 9.8
GENETIC ENGINEERING 241 9.9 SYNTHETIC PHAS AND BLENDS 242 9.10
CONCLUSION 243 9.11 REFERENCES 244 CHAPTER 10 SURFACTANTS AND FATTY
ACIDS: PLANT OILS S.F. THAMES, M.D. BLANTON, S. MENDON, R. SUBRAMENIAN,
H.YU 249 10.1 CHINESE MELON OIL (CMO) 249 10.1.1 INTRODUCTION 249 10.1.2
FATTY ACID COMPOSITION 249 10.1.3 CHARACTERIZATION 250 10.1.4
EPOXIDATION 254 10.1.5 CHINESE MELON OIL S FUTURE PROSPECTS 254 10.2
CRAMBEOIL 255 10.2.1 INTRODUCTION 255 10.2.2 FATTY ACID COMPOSITION AND
PROPERTIES 255 10.2.3 DERIVATIVES OF CRAMBE OIL 257 10.3 LESQUERELLA OIL
258 10.3.1 INTRODUCTION 258 10.3.2 FATTY ACID COMPOSITIONS 259 10.3.3
OIL PROPERTIES 260 10.3.4 SIGNIFICANCE OF LESQUERELLA OIL RESEARCH 260
10.3.5 DEHYDRATED LESQUERELLA OIL (DLO) 261 10.3.6 POLYESTERS DERIVED
FROM LESQUERELLA OIL 262 10.3.7 LESQUERELLA OIL ACRYLATES 263 10.3.8
LESQUERELLA OIL ALKOXYLATES 265 10.4 SOYBEAN OIL 267 10.4.1 INTRODUCTION
267 10.4.2 OIL COMPOSITION AND PROPERTIES 267 10.4.3 POLYESTERS 268
10.4.4 URETHANE POLYMERS 268 10.4.5 EPOXIDIZED OIL 269 10.4.6 EPOXYOIL
270 10.4.7 COPOLYMERS 270 10.5 TUNG OIL 270 10.5.1 INTRODUCTION 270
10.5.2 COMPOSITION AND PROPERTIES 271 CONTENTS XIII 10.5.3 MODIFICATION
OF ELEOSTEARIC ACID (ESA) 272 10.5.4 APPLICATIONS 274 10.6 VERNONIAOIL
274 10.6.1 INTRODUCTION 274 10.6.2 COMPOSITION AND PROPERTIES 274 10.6.3
APPLICATIONS 275 10.6.4 MODIFICATION OF EPOXY RESINS 276 10.6.5
ULTRAVIOLET CURE SYSTEMS 276 10.6.6 VERNONIA OIL IN POWDER COATINGS 276
10.6.7 EPOXIDATION OF VERNONIA OIL 277 10.7 REFERENCES 278 CHAPTER 11
SURFACE ACTIVE POLYMERS FROM THE GENUS ACINETOBACTER E. ROSENBERG, E. Z.
RON 281 11.1 INTRODUCTION 281 11.2 PRODUCTION AND PURIFICATION OF
SURFACE ACTIVE POLYMERS 282 11.3 GENETICS 282 11.4 DISPERSANTS OF
OIL-IN-WATER - BIOEMULSIFIERS 283 11.4.1 A. CALCOACETICUS RAG-1 EMULSAN:
284 11.4.2 THE EMULSAN OF A. CALCOACETICUS BD4 285 11.4.3 ALASAN 286
11.4.4 OTHER ACINETOBACTER EMULSIFIERS 287 11.5 POTENTIAL APPLICATIONS
287 11.6 BIODISPERSAN - DISPERSION OF SOLID PARTICLES 288 11.7 POTENTIAL
APPLICATIONS FOR BIODISPERSAN 290 11.8 REFERENCES 291 CHAPTER 12 LIGNIN
D. S. ARGYROPOULOS, S. B. MENACHEM 292 12.1 OCCURRENCE AND ROLE OF
LIGNIN 292 12.1.1 WOOD STRUCTURE 293 12.2 BIOSYNTHESIS 294 12.2.1 THE
SYNTHESIS OF LIGNIN PRECURSORS 294 12.2.2 THE DEHYDROGENATION OF THE
PRECURSORS 296 12.2.3 THE RADICAL POLYMERIZATION 297 12.2.4 THE
LIGNIN-CARBOHYDRATE CONNECTIVITY 301 12.3 LIGNIN ARCHITECTURE 303 12.3.1
THE GEL DEGRADATION THEORY 304 12.3.2 POSSIBILITY OF ORDER IN LIGNIN 305
12.4 SOLUTION PROPERTIES OF LIGNIN 307 12.4.1 LIGNIN ASSOCIATIVE
INTERACTIONS 308 XIV CONTENTS 12.4.2 LIGNIN POLYDISPERSITY 308 12.5
LIGNIN PREPARATIONS 309 12.5.1 LABORATORY LIGNIN PREPARATIONS 309 12.5.2
COMMERCIALLY PRODUCED LIGNINS 310 12.6 METHODS OF LIGNIN ANALYSIS 310
12.6.1 DEGRADATIVE METHODS 310 12.6.2 NON-DEGRADATIVE METHODS 312 12.7
REFERENCES 314 CHAPTER 13 NATURAL RUBBER FROM PLANTS R.A.BACKHAUS 323
13.1 INTRODUCTION AND HISTORY OF NATURAL RUBBER 323 13.2 SOURCES OF
NATURAL RUBBER 325 13.2.1 RUBBER PRODUCING PLANTS 325 13.2.2 CELLULAR
SOURCES OF RUBBER BIOSYNTHESIS 326 13.3 STRUCTURE AND COMPOSITION OF
NATURAL RUBBER 329 13.4 METHODS OF RUBBER ISOLATION, PURIFICATION, AND
CHARACTERIZATION . . 334 13.4.1 HEVEA RUBBER 334 13.4.2 GUAYULE RUBBER
339 13.5 PHYSICAL, CHEMICAL, AND BIOLOGICAL PROPERTIES OF RUBBER
PARTICLES FROM PLANT CELLS 340 13.6 CHEMICAL OR OTHER MODIFICATIONS OF
NATURAL RUBBER - NATURE OF THE REACTIONS, EFFECT ON PROPERTIES 344 13.7
PROCESSING OF NATURAL RUBBER 345 13.8 PROPERTIES AND TESTING OF RAW AND
PROCESSED RUBBER 347 13.9 NEW PRODUCTS OR POTENTIAL APPLICATIONS 349
13.10 CONCLUSION 349 13.11 REFERENCES 350 CHAPTER 14 FAILURE PROPERTIES
OF GUAYULE RUBBER P. G.SANTANGELO, * M.ROLAND 355 14.1 INTRODUCTION 355
14.2 HISTORICAL BACKGROUND 355 14.3 PHYSICAL PROPERTIES 357 14.4
INTRINSIC FLAW SIZE 358 14.5 CRYSTALLIZATION 361 14.6 BARRIER
PERFORMANCE 363 14.7 SUMMARY 364 14.8 REFERENCES 364 CONTENTS XV CHAPTER
15 HIGH MOLECULAR WEIGHT POLYLACTIC ACID POLYMERS M.H. HARTMANN 367 15.1
INTRODUCTION 367 15.2 LACTIC ACID FERMENTATION, SYNTHESIS, AND
PURIFICATION 367 15.3 POLYMER SYNTHESIS 370 15.3.1 CONDENSATION
POLYMERIZATION OF LACTIC ACID 370 15.3.2 AZEOTROPIC DEHYDRATION
CONDENSATION OF LACTIC ACID 374 15.3.3 LACTIDE PRODUCTION AND
PURIFICATION 379 15.3.4 CATALYSIS, KINETICS, AND MECHANISM OF LACTIDE
RING OPENING POLYMERIZATIONS 382 15.3.5 POLYMER THERMAL STABILIZATION
395 15.4 POLYMER PHYSICAL, MECHANICAL AND CRYSTALLIZATION PROPERTIES
.... 396 15.5 COPOLYMERS AND BLENDS 399 15.6 CROSSLINKING 404 15.7
CONCLUSION 405 15.8 REFERENCES 405 SUBJECT INDEX 413
|
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| id | DE-604.BV012006428 |
| illustrated | Illustrated |
| indexdate | 2024-08-01T10:50:08Z |
| institution | BVB |
| isbn | 354063567X |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-008125106 |
| oclc_num | 318384441 |
| open_access_boolean | |
| owner | DE-703 DE-355 DE-BY-UBR DE-19 DE-BY-UBM DE-91G DE-BY-TUM DE-863 DE-BY-FWS DE-1046 DE-M49 DE-BY-TUM DE-526 DE-634 DE-83 DE-1051 |
| owner_facet | DE-703 DE-355 DE-BY-UBR DE-19 DE-BY-UBM DE-91G DE-BY-TUM DE-863 DE-BY-FWS DE-1046 DE-M49 DE-BY-TUM DE-526 DE-634 DE-83 DE-1051 |
| physical | XVIII, 417 S. graph. Darst. |
| publishDate | 1998 |
| publishDateSearch | 1998 |
| publishDateSort | 1998 |
| publisher | Springer |
| record_format | marc |
| series2 | Macromolecular systems - materials approach |
| spellingShingle | Biopolymers from renewable resources Polímeros - Biotecnología Nachwachsender Rohstoff (DE-588)4171069-1 gnd Biopolymere (DE-588)4006893-6 gnd |
| subject_GND | (DE-588)4171069-1 (DE-588)4006893-6 |
| title | Biopolymers from renewable resources |
| title_auth | Biopolymers from renewable resources |
| title_exact_search | Biopolymers from renewable resources |
| title_full | Biopolymers from renewable resources D. L. Kaplan (ed.) |
| title_fullStr | Biopolymers from renewable resources D. L. Kaplan (ed.) |
| title_full_unstemmed | Biopolymers from renewable resources D. L. Kaplan (ed.) |
| title_short | Biopolymers from renewable resources |
| title_sort | biopolymers from renewable resources |
| topic | Polímeros - Biotecnología Nachwachsender Rohstoff (DE-588)4171069-1 gnd Biopolymere (DE-588)4006893-6 gnd |
| topic_facet | Polímeros - Biotecnología Nachwachsender Rohstoff Biopolymere |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=008125106&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT kaplandavidl biopolymersfromrenewableresources |
Inhaltsverzeichnis
THWS Würzburg Zentralbibliothek Lesesaal
| Signatur: |
1000 WF 9785 K17 |
|---|---|
| Exemplar 1 | ausleihbar Verfügbar Bestellen |