Liquid interfaces in chemistry and biology:
Gespeichert in:
| Format: | Buch |
|---|---|
| Sprache: | English |
| Veröffentlicht: |
New York [u.a.]
Wiley
1998
|
| Schriftenreihe: | A Wiley-Interscience publication
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | X, 551 S. graph. Darst. |
| ISBN: | 0471148725 |
Internformat
MARC
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Datensatz im Suchindex
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|---|---|
| adam_text | LIQUID INTERFACES IN CHEMISTRY AND BIOLOGY ALEXANDER G. VOLKOV DAVID W.
DEAMER DEPARTMENT OF CHEMISTRY AND BIOCHEMISTRY, UNIVERSITY OF
CALIFORNIA, SANTA CRUZ, CALIFORNIA DARREIL L. TANELIAN VLADISLAV S.
MARKIN DEPARTMENT OF ANESTHESIOLOGY AND PAIN MANAGEMENT, UNIVERSITY OF
TEXAS, SOUTHWESTERN MEDICAL CENTER, DALLAS, TEXAS A WILEY-INTERSCIENCE
PUBLICATION JOHN WILEY & SONS, INC. NEW YORK * CHICHESTER * WEINHEIM *
BRISBANE * SINGAPORE * TORONTO CONTENTS PREFACE A. THERMODYNAMICS OF
INTERFACES 1. INTRODUCTION TO CLASSICAL THERMODYNAMICS / 2 1.1. BASIC
CONCEPTS AND DEFINITIONS / 2 1.2. THERMODYNAMIC POTENTIALS / 11 1.3.
GENERALIZATION OF THERMODYNAMIC POTENTIALS / 16 1.4. CHEMICAL POTENTIAL
/ 24 1.5. MULTICOMPONENT SYSTEMS / 32 1.6. EXTERNAL FIELD / 43 1.7.
SURFACES / 47 1.8. IRREVERSIBLE PROCESSES / 63 2. MEASUREMENT OF
INTERFACIAL TENSION / 69 3. ADSORPTION AT LIQUID INTERFACES / 78 3.1.
GIBBS METHOD FOR PLANAR INTERFACES / 78 3.2. HANSEN S METHOD / 87 3.3.
OTHER DEFINITIONS OF SURFACE EXCESSES / 99 3.4. VOLUME AND ENTROPY OF
INTERFACE FORMATION / 102 3.5. CURVED INTERFACES / 111 3.6. VARIABLES OF
THE SYSTEM / 120 B. ELECTRIFIED INTERFACES 4. INTERFACIAL POTENTIALS /
130 4.1. BOUNDARY POTENTIAL DIFFERENCE / 130 4.2. STANDARD POTENTIALS
AND STANDARD GIBBS FREE ENERGIES / 132 V VI CONTENTS 4.3. DISTRIBUTION
POTENTIALS / 136 4.4. INCOMPLETE DISSOCIATION OF THE SALT / 139 4.5.
COMPLEX FORMATION IN ONE OF THE PHASES / 140 4.6. THE DONNAN POTENTIAL /
142 4.7. THE NERNST POTENTIAL / 144 4.8. THE OXIDATION-REDUCTION
INTERFACIAL POTENTIAL: GIBBS FREE ENERGY OF ELECTRON AND ION TRANSPORT
COUPLING / 144 4.9. THE MIXED POTENTIAL / 146 4.10. THE ADSORPTION
POTENTIAL / 149 4.11. VERIFICATION OF THE THERMODYNAMIC THEORY OF
INTERFACIAL POTENTIALS / 150 4.12. MEASUREMENT OF INTERFACIAL
POTENTIALS: THE TETRAPHENYLBORATE HYPOTHESIS / 151 4.13. METHODS FOR
MEASURING THE INTERFACIAL POTENTIAL DIFFERENCE / 153 4.14. HUNG S METHOD
OF GALVANI-POTENTIALS CALCULATION: SMALL SYSTEMS AND THE EFFECT OF
VOLUMES / 160 4.15. INTERFACIAL POTENTIAL MEASUREMENTS AS A TOOL FOR
STUDYING MECHANISMS OF ENZYMATIC AND CATALYTIC REACTIONS / 161 5.
ELECTROCAPILLARITY / 167 5.1. THE ELECTROCAPILLARY EQUATION / 167 5.2.
PARTICULAR CASES OF THE ELECTROCAPILLARY EQUATION / 173 5.3.
THERMODYNAMIC CHARGE AT THE INTERFACE / 176 5.4. POLARIZABLE INTERFACE /
177 5.5. NON-POLARIZABLE INTERFACE / 183 6. ENERGETICS OF EXTRACTION /
192 6.1. ELECTROSTATIC CONTRIBUTION TO THE SOLVATION ENERGY / 195 6.2.
THE BORN MODEL / 198 6.3. NON-LINEAR DIELECTRIC EFFECTS / 200 6.4. OTHER
APPROACHES TO THE SATURATION PROBLEM / 204 6.5. THE NON-LOCAL
ELECTROSTATIC METHOD / 208 6.6. STATISTICAL SOLVENT MODEIS / 210 6.7.
CONTRIBUTION OF THE SOLVOPHOBIC EFFECT TO THE RESOLVATION ENERGY / 214
6.8. THE TOTAL RESOLVATION ENERGY / 215 6.9. DIPOLE RESOLVATION / 217 C.
STRUCTURE OF INTERFACES 7. INTERFACIAL STRUCTURES AND ELECTRICAL DOUBLE
LAYERS / 222 7.1. THE MODIFIED VERWEY-NIESSEN (MVN) MODEL / 223 CONTENTS
VII 7.2. POTENTIALS OF ZERO FREE CHARGE AND ZERO THERMODYNAMIC CHARGE /
229 7.3. MEASURING THE CAPACITANCE OF THE ELECTRICAL DOUBLE LAYER / 239
7.4. PARSONS-ZOBEL DEPENDENCIES / 243 7.5. POTENTIAL DISCONTINUITIES IN
THE COMPACT LAYER / 245 7.6. SPECIFIC ADSORPTION: IONIC ASSOCIATION AND
LIGAND BINDING / 249 7.7. ADSORPTION ISOTHERM AND STRUCTURE OF THE
INTERFACE / 256 7.8. ROUGHNESS OF THE INTERFACE BETWEEN TWO IMMISCIBLE
ELECTROLYTE SOLUTIONS / 266 7.9. IMAGE FORCES / 270 7.10. DRAWBACKS AND
DEVELOPMENT OF MVN AND THE GOUY-CHAPMAN-STERN THEORIES / 278 7.11.
EFFECTS OF VARIABLE DIELECTRIC PERMITTIVITY / 282 7.12. NON-LOCAL
ELECTROSTATICS / 285 7.13. ELECTRIC DOUBLE LAYER WITH HYDRATION FORCES /
287 7.14. MODIFIED POISSON-BOLTZMANN (MPB) MODEL / 294 7.15. IONIC
PLASMA IN A CONTINUOUS DIELECTRIC NEXT TO A CHARGED INTERFACE / 301
7.16. ION-DIPOLE PLASMA AT A CHARGED INTERFACE / 303 7.17. THE MONTE
CARLO METHOD AND THE DOUBLE LAYER / 309 7.18. COMPUTER SIMULATIONS OF
ITIES / 313 7.19. MOLECULAR DYNAMICS AND THE STRUCTURE OF INTERFACES /
319 CHEMISTRY AT LIQUID INTERFACES INTERFACIAL CATALYSIS / 324 8.1.
OIL-WATER INTERFACE AS A MODEL OF MEMBRANES / 324 8.2. MULTIELECTRON
REACTIONS AT INTERFACES / 325 8.3. SOLVENT REORGANIZATION ENERGY / 329
8.4. SELECTIVE CATALYTIC PROPERTIES OF LIQUID INTERFACES / 331 8.5.
CHARGE TRANSFER REACTIONS AT OIL-WATER INTERFACES / 333 8.6. EXAMPLES OF
CHEMICAL REACTIONS AT LIQUID INTERFACES / 334 8.7. CHLOROPHYLL AS A
CATALYST OF ELECTRON TRANSFER REACTIONS IN BILAYERS AND AT THE LIQUID
HYDROCARBON-WATER INTERFACE / 338 8.8. PORPHYRINS AS INTERFACIAL
CATALYSTS / 342 8.9. REDUCTION OF PORPHYRIN AT THE OCTANE-WATER
INTERFACE CONTROLLED BY SPECIFIC ADSORPTION / 347 8.10. COUPLING OF TWO
REDOX REACTIONS AT THE OCTANE-WATER INTERFACE / 351 8.11. ENZYME
COMPLEXES OF THE MITOCHONDRIAL RESPIRATORY CHAIN / 355 8.12. ATPASE /
359 VIII CONTENTS LIGHT ENERGY CONVERSION AT LIQUID-LIQUID INTERFACES:
ARTIFICIAL PHOTOSYNTHETIC SYSTEMS / 361 9.1. STRUCTURE AND COMPOSITION
OF THE OXYGEN-EVOLVING COMPLEX IN VIVO I 362 9.2. THERMODYNAMICS OF
WATER OXIDATION / 362 9.3. KINETIC ASPECTS OF MULTIELECTRON REACTIONS /
365 9.4. MOLECULAR MECHANISM OF OXYGEN EVOLUTION IN VIVO I 368 9.5.
PHOTOINDUCED CHARGE TRANSFER ACROSS AN OIL-WATER INTERFACE / 369 9.6.
ARTIFICIAL PHOTOSYNTHESIS AT THE OIL-WATER INTERFACE IN THE PRESENCE OF
CHLOROPHYLL / 370 9.7. WATER PHOTO-OXIDATION / 379 E. MEMBRANES 10.
MEMBRANE THERMODYNAMICS AND ELECTROSTATICS / 406 10.1. STRUCTURE AND
PROPERTIES OF BIOLOGICAL MEMBRANES / 406 10.2. MEMBRANE ELECTROSTATICS /
410 10.3. CONSECUTIVE STAGES OF MEMBRANE ION TRANSPORT / 417 10.4.
MECHANISMS OF PASSIVE PERMEATION OF IONS AND DIPOLES THROUGH MEMBRANES /
422 10.5. FACILITATED TRANSPORT*MOBILE CARRIERS AND CHANNELS / 433 10.6.
COUPLED TRANSPORT AND MEMBRANE EQUILIBRIUM / 435 11. MECHANICS OF
INTERFACES / 452 11.1. DEFINITION OF SURFACE TENSION AT A NON-SPHERICAL
INTERFACE / 452 11.2. ELASTIC PROPERTIES OF INTERFACES AND THE SHAPE OF
VESICLES / 464 11.3. EDGE ENERGY AND PORES IN MEMBRANES / 475 11.4.
MEMBRANE FUSION / 483 BIBLIOGRAPHY / 492 APPENDIX / 544 INDEX / 547
|
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| isbn | 0471148725 |
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| spelling | Liquid interfaces in chemistry and biology Alexander G. Volkov ... New York [u.a.] Wiley 1998 X, 551 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier A Wiley-Interscience publication Flüssigkeit (DE-588)4017621-6 gnd rswk-swf Grenzfläche (DE-588)4021991-4 gnd rswk-swf Flüssigkeit (DE-588)4017621-6 s Grenzfläche (DE-588)4021991-4 s DE-604 Volkov, Alexander G. 1951- Sonstige (DE-588)132293641 oth GBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=008067572&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Liquid interfaces in chemistry and biology Flüssigkeit (DE-588)4017621-6 gnd Grenzfläche (DE-588)4021991-4 gnd |
| subject_GND | (DE-588)4017621-6 (DE-588)4021991-4 |
| title | Liquid interfaces in chemistry and biology |
| title_auth | Liquid interfaces in chemistry and biology |
| title_exact_search | Liquid interfaces in chemistry and biology |
| title_full | Liquid interfaces in chemistry and biology Alexander G. Volkov ... |
| title_fullStr | Liquid interfaces in chemistry and biology Alexander G. Volkov ... |
| title_full_unstemmed | Liquid interfaces in chemistry and biology Alexander G. Volkov ... |
| title_short | Liquid interfaces in chemistry and biology |
| title_sort | liquid interfaces in chemistry and biology |
| topic | Flüssigkeit (DE-588)4017621-6 gnd Grenzfläche (DE-588)4021991-4 gnd |
| topic_facet | Flüssigkeit Grenzfläche |
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