Essentials of carbohydrate chemistry:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | German |
| Veröffentlicht: |
New York [u.a.]
Springer
1998
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| Schriftenreihe: | Springer advanced texts in chemistry
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XV, 399 S. Ill., graph. Darst. |
| ISBN: | 0387949518 |
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Datensatz im Suchindex
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|---|---|
| adam_text | JOHN F. ROBYT ESSENTIALS OF CARBOHYDRATE CHEMISTRY WITH 370
ILLUSTRATIONS SPRINGER CONTENTS SERIES PREFACE V PREFACE VII
ACKNOWLEDGMENTS IX CHAPTER 1 BEGINNINGS 1 . 1 CARBOHYDRATES AND THEIR
INVOLVEMENT IN LIFE PROCESSES 1 .2 THE NATURE OF CARBOHYDRATES 2 .3
OCCURRENCE OF CARBOHYDRATES 3 .4 ASYMMETRY AND THE STRUCTURES OF
CARBOHYDRATES 5 .5 REMEMBERING THE STRUCTURES OF CARBOHYDRATES 10 .6
DERIVED CARBOHYDRATE STRUCTURES 13 A. SUGAR ALCOHOLS 13 B. SUGAR ACIDS
13 C. DEOXY SUGARS 15 D. AMINO SUGARS 15 E. SUGAR PHOSPHATES 18 F.
CONDENSED SUGAR PRODUCTS 18 1.7 LITERATURE CITED 18 CHAPTER 2
DEVELOPMENTS 19 ,2.1 CARBOHYDRATES IN THE HISTORY AND DEVELOPMENT OF
HUMAN CULTURE 19 2.2 DEVELOPMENT OF CARBOHYDRATE CHEMISTRY 21 A.
CHEMICAL PROPERTIES OF CARBOHYDRATES, 1860-1880 22 B. FISCHER S
DEMONSTRATION OF THE STRUCTURES OF GLUCOSE, MANNOSE, ARABINOSE, AND
FRUCTOSE 23 2.3 CYCLIC STRUCTURES FOR THE CARBOHYDRATES 27 2.4 NAMING
THE ANOMERIC FORMS OF CARBOHYDRATES 33 XII CONTENTS 2.5 DETERMINATION OF
THE SIZE OF CARBOHYDRATE RINGS 33 2.6 Y CONFORMATIONAL STRUCTURES OF
CYCLIC SUGARS 36 2.7 THE LITERATURE OF CARBOHYDRATE CHEMISTRY 39 2.8
CHRONOLOGICAL SUMMARY OF THE USES OF CARBOHYDRATES BY HUMANS AND THE
DEVELOPMENT OF CARBOHYDRATE CHEMISTRY 42 2.9 SPECIFIC TERMS AND CONCEPTS
USED IN CARBOHYDRATE CHEMISTRY 44 2.10 LITERATURE CITED 47 2.11
REFERENCES FOR FURTHER STUDY 47 CHAPTER 3 TRANSFORMATIONS 48 3.1
MUTAROTATION 48 3.2 REACTIONS OF CARBOHYDRATES WITH STRONG ALKALI 50 3.3
ALKALINE DEHYDRATION, FRAGMENTATION, AND OXIDATION REACTIONS OF
CARBOHYDRATES 53 3.4 REACTIONS OF CARBOHYDRATES WITH STRONG ACID, AND
THE QUALITATIVE AND QUANTITATIVE DETERMINATION OF CARBOHYDRATES 53 3.5
REDUCING REACTIONS OF CARBOHYDRATES 60 3.6 REACTIONS OF HEMIACETALS OR
HEMIKETALS WITH ALCOHOLS 64 3.7 FORMATION OF GLYCOSIDIC LINKAGES TO GIVE
DI-, TRI-, AND OLIGOSACCHARIDES 66 3.8 LITERATURE CITED 73 3.9
REFERENCES FOR FURTHER STUDY 74 CHAPTER 4 MODIFICATIONS 76 4.1 FORMATION
OF CARBOXYLIC ACID ESTERS 77 4.2 FORMATION OF SULFONIC ACID ESTERS 81
4.3 FORMATION OF ETHERS 83 A. METHYL ETHERS 83 B. TRITYL ETHERS 83 C.
BENZYL ETHERS 84 D. TRIALKYLSILYL ETHERS 85 4.4 FORMATION OF ACETALS AND
KETALS 85 4.5 MODIFICATIONS AT C-L 92 A. REDUCTION OF ALDEHYDE AND
KETONE CARBONYLS 92 B. REDUCTION OF THIOACETALS AND THE PROTECTION OF
C-L 93 C. OXIDATION OF C-L 93 D. CHAIN ELONGATION 94 E. CHAIN-LENGTH
REDUCTION 98 F. SUBSTITUTION AT C-1, THE REDUCING CARBON 99 G. FORMATION
OF GLYCOSIDES 103 H. FORMATION OF GLYCOSIDIC LINKAGES BETWEEN
MONOSACCHARIDE RESIDUES 105 4.6 MODIFICATIONS AT C-2 108 4.7
MODIFICATIONS AT C-3 113 4.8 MODIFICATIONS AT C-4 121 4.9 MODIFICATIONS
AT C-5 AND SUBSTITUTION FOR THE RING OXYGEN 125 4.10 MODIFICATIONS OF
C-6 IN HEXOPYRANOSES 128 4.11 SUMMARY OF THE STRATEGIES PRESENTED FOR
THE CHEMICAL MODIFICATION OF CARBOHYDRATES 135 CONTENTS XIII 4.12
LITERATURE CITED 137 4.13 REFERENCES FOR FURTHER STUDY 140 CHAPTER 5
SWEETNESS 142 5.1 THE SWEET TASTE OF SUGARS AND THE DEVELOPMENT OF THE
SWEET-TASTE HYPOTHESIS 142 5.2 NATURALLY OCCURRING SWEET GLYCOSIDES 146
5.3 SYNTHESIS OF SUPERSWEET SUCROSES 148 5.4 LITERATURE CITED 155 5.5
REFERENCES FOR FURTHER STUDY 155 CHAPTER 6 POLYSACCHARIDES I: STRUCTURE
AND FUNCTION 157 6.1 6.2 6.3 6.4 6.5 6.6 6.7 6.8 INTRODUCTION: STRUCTURE
AND CLASSIFICATION OF POLYSACCHARIDES PLANT POLYSACCHARIDES A. STARCH B.
CELLULOSE C. HEMICELLULOSES D. PECTINS E. EXUDATE GUMS F. FRUCTANS G.
SEAWEED POLYSACCHARIDES H. DIETARY FIBERS ANIMAL POLYSACCHARIDES A.
GLYCOGEN B. GLYCOSAMINOGLYCANS C. CHITIN MICROBIAL POLYSACCHARIDES A.
MUREIN B. DEXTRANS AND RELATED POLYSACCHARIDES: MUTAN AND ALTERNAN C.
PULLULAN D. BACTERIAL FRUCTANS E. XANTHAN F. BACTERIAL GELS G.
PNEUMOCOCCAL CAPSULE POLYSACCHARIDES H. SALMONELLA O-ANTIGEN
POLYSACCHARIDES I. CAPSULAR POLYSACCHARIDES OF OTHER GRAM-NEGATIVE
BACTERIA TEICHOIC ACIDS SIMPLIFIED REPRESENTATION OF OLIGOSACCHARIDE AND
POLYSACCHARIDE STRUCTURES LITERATURE CITED REFERENCES FOR FURTHER STUDY
157 160 160 168 171 175 177 179 180 187 187 187 189 192 193 193 194 198
198 200 202 204 206 208 210 215 218 226 CHAPTER 7 POLYSACCHARIDES II:
CHEMICAL MODIFICATIONS AND THEIR APPLICATIONS 228 7.1 INTRODUCTION 228
7.2 FORMATION OF POLYSACCHARIDE ESTERS 229 7.3 FORMATION OF
POLYSACCHARIDE ETHERS 231 XIV CONTENTS 7.4 FORMATION OF CROSS-LINKED
POLYSACCHARIDE ETHERS 234 7.5 POLYSACCHARIDE PHOSPHATES 235 7.6
POLYSACCHARIDE SULFATES 238 7.7 POLYSACCHARIDE DYE DERIVATIVES 238 7.8
ACTIVATION OF POLYSACCHARIDES FOR COVALENTLY ATTACHING LIGANDS AND
PROTEINS 239 7.9 OXIDATION OF PRIMARY ALCOHOLS OF POLYSACCHARIDES TO
CARBOXYL GROUPS 240 7.10 PERIODATE OXIDATION OF POLYSACCHARIDES 240 7.11
MISCELLANEOUS MODIFICATIONS OF ALCOHOL GROUPS OF POLYSACCHARIDES 241
7.12 MODIFICATION OF STARCH GRANULES BY ACID HYDROLYSIS 241 7.13
LITERATURE CITED 243 CHAPTER 8 CYCLODEXTRINS 245 8.1 CYCLOMALTODEXTRINS
245 8.2 CYCLIC (3-1 -» 2 GLUCANS (CYCLOSOPHORANS) 251 8.3 CYCLIC B-L -
6 AND B-L - 3 D-GLUCANS 252 8.4 CYCLOISOMALTODEXTRINS 254 8.5
CYCLOALTERNANOTETRAOSE (ALTERNATING A-1 * 6/A-L * 3 CYCLOTETRAOSE)
255 8.6 CYCLOINULODEXTRIN 256 8.7 CHEMICAL SYNTHESIS OF CYCLODEXTRINS
256 8.8 MACROCYCLIC MALTODEXTRINS 258 8.9 LITERATURE CITED 258 8.10
REFERENCES FOR FURTHER STUDY 261 CHAPTER 9 GLYCOCONJUGATES 262 9.1
INTRODUCTION 262 9.2 STRUCTURES OF IV-LINKED GLYCOSIDES IN GLYCOPROTEINS
264 9.3 STRUCTURES OF O-LINKED GLYCOSIDES IN GLYCOPROTEINS 274 9.4
STRUCTURES OF GLYCOLIPIDS 279 A. GLYCOGLYCEROLIPIDS 279 B.
GLYCOSPHINGOLIPIDS 280 C. GLYCOSYL PYROPHOSPHO POLYPRENOLS 284 D.
LIPOPOLYSACCHARIDE OF GRAM-NEGATIVE BACTERIA 284 9.5 LITERATURE CITED
287 9.6 REFERENCES FOR FURTHER STUDY 289 CHAPTER 10 BIOSYNTHESIS 290
10.1 PHOTOSYNTHESIS AND THE FORMATION OF CARBOHYDRATES 290 10.2
BIOSYNTHESIS OF SUGAR NUCLEOTIDES 298 10.3 BIOSYNTHESIS OF DIFFERENT
MONOSACCHARIDES BY EPIMERIZATION, OXIDATION, AND DECARBOXYLATION 299
10.4 BIOSYNTHESIS OF D-AND L-6-DEOXYHEXOSES 301 10.5 BIOSYNTHESIS OF
EIGHT- AND NINE-CARBON SUGARS: A -ACETYL-D-NEURAMINIC ACID,
/V-ACETYL-D-MURAMIC ACID, AND 2-KETO-3-DEOXY-D-MANNOOCTULOSONIC ACID
(KDO) 301 10.6 BIOSYNTHESIS OF THE NATURALLY OCCURRING DISACCHARIDES:
A,A-TREHALOSE, SUCROSE, AND LACTOSE 304 CONTENTS XV 10.7 BIOSYNTHESIS OF
SUCROSE AND STARCH IN PLANTS 304 10.8 BIOSYNTHESIS OF THE BACTERIAL CELL
WALL: PEPTIDOMUREIN 305 10.9 BIOSYNTHESIS OF THE SALMONELLA O-ANTIGEN
OUTER CAPSULAR POLYSACCHARIDE 311 10.10 BIOSYNTHESIS OF ESCHERICHIA COLI
AND NEISSERIA MENINGITIDIS COLOMINIC ACID 311 10.11 BIOSYNTHESIS OF
TEICHOIC ACIDS 313 10.12 BIOSYNTHESIS OF DEXTRANS AND RELATED
POLYSACCHARIDES 313 10.13 BIOSYNTHESIS OF STARCH, GLYCOGEN, AND
CELLULOSE 318 10.14 BIOSYNTHESIS OF GLYCOPROTEINS 322 10.15 LITERATURE
CITED 324 10.16 REFERENCES FOR FURTHER STUDY 327 CHAPTER 11
BIODEGRADATION 328 11.1 DIGESTION OF STARCH 328 11.2 HYDROLYSIS OF
STARCH BY MICROORGANISMS 331 11.3 BIODEGRADATION OF STARCH AND DEXTRAN
TO CYCLODEXTRINS 333 11.4 BIODEGRADATION OF LIVER AND MUSCLE GLYCOGEN
335 11.5 BIODEGRADATION OF CELLULOSE AND RELATED POLYSACCHARIDES 336
11.6 CHEMICAL ENERGY FROM CARBOHYDRATES 337 11.7 LITERATURE CITED 343
CHAPTER 12 DETERMINATIONS 345 12.1 DETERMINATION OF THE PRESENCE OF
CARBOHYDRATE 345 12.2 PURIFICATION OF CARBOHYDRATES 345 12.3
MONOSACCHARIDE COMPOSITION OF CARBOHYDRATES 346 12.4 DETERMINATION OF
THE POSITIONS OF GLYCOSIDIC LINKAGE 347 12.5 DETERMINATION OF THE
POSITION OF SUBSTITUTION OF MONOSACCHARIDE RESIDUE(S) BY PERIODATE
OXIDATION 348 12.6 CONFIGURATION OF GLYCOSIDIC LINKAGES 350 12.7
SEQUENCE OF MONOSACCHARIDES AND THEIR LINKAGES 352 12.8 USE OF ENZYMES
IN DETERMINING STRUCTURE 352 12.9 DETERMINATION OF CARBOHYDRATE
STRUCTURE BY USING NMR 355 12.10 SEPARATION AND DETERMINATION OF
CARBOHYDRATE STRUCTURE BY USING LECTINS 359 12.11 REMOVAL OF GLYCOSIDES
FROM GLYCOPROTEINS FOR STRUCTURE DETERMINATION 361 12.12 LITERATURE
CITED 362 12.13 REFERENCES FOR FURTHER STUDY 364 APPENDIX A PRIMER ON
CARBOHYDRATE NOMENCLATURE 365 APPENDIX B PRIMER ON ENZYME NAMES AND
THEIR CATALYZED REACTIONS 377 INDEX 385
|
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| id | DE-604.BV011799260 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T18:15:57Z |
| institution | BVB |
| isbn | 0387949518 |
| language | German |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-007966184 |
| oclc_num | 36858098 |
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| owner | DE-29T DE-20 DE-355 DE-BY-UBR DE-703 DE-83 |
| owner_facet | DE-29T DE-20 DE-355 DE-BY-UBR DE-703 DE-83 |
| physical | XV, 399 S. Ill., graph. Darst. |
| publishDate | 1998 |
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| publishDateSort | 1998 |
| publisher | Springer |
| record_format | marc |
| series2 | Springer advanced texts in chemistry |
| spelling | Robyt, John F. 1935- Verfasser (DE-588)118127446 aut Essentials of carbohydrate chemistry John F. Robyt New York [u.a.] Springer 1998 XV, 399 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Springer advanced texts in chemistry Carboidratos larpcal Cyclodextrine gtt Glucides Glucides ram Glycoconjugaten gtt Koolhydraten gtt Polysacchariden gtt Carbohydrates Chemie (DE-588)4009816-3 gnd rswk-swf Kohlenhydrate (DE-588)4164517-0 gnd rswk-swf Kohlenhydrate (DE-588)4164517-0 s Chemie (DE-588)4009816-3 s DE-604 HEBIS Datenaustausch Darmstadt application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=007966184&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Robyt, John F. 1935- Essentials of carbohydrate chemistry Carboidratos larpcal Cyclodextrine gtt Glucides Glucides ram Glycoconjugaten gtt Koolhydraten gtt Polysacchariden gtt Carbohydrates Chemie (DE-588)4009816-3 gnd Kohlenhydrate (DE-588)4164517-0 gnd |
| subject_GND | (DE-588)4009816-3 (DE-588)4164517-0 |
| title | Essentials of carbohydrate chemistry |
| title_auth | Essentials of carbohydrate chemistry |
| title_exact_search | Essentials of carbohydrate chemistry |
| title_full | Essentials of carbohydrate chemistry John F. Robyt |
| title_fullStr | Essentials of carbohydrate chemistry John F. Robyt |
| title_full_unstemmed | Essentials of carbohydrate chemistry John F. Robyt |
| title_short | Essentials of carbohydrate chemistry |
| title_sort | essentials of carbohydrate chemistry |
| topic | Carboidratos larpcal Cyclodextrine gtt Glucides Glucides ram Glycoconjugaten gtt Koolhydraten gtt Polysacchariden gtt Carbohydrates Chemie (DE-588)4009816-3 gnd Kohlenhydrate (DE-588)4164517-0 gnd |
| topic_facet | Carboidratos Cyclodextrine Glucides Glycoconjugaten Koolhydraten Polysacchariden Carbohydrates Chemie Kohlenhydrate |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=007966184&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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